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With four companions at separations from 16 to 71 au, HR 8799 is a unique target for direct imaging, presenting an opportunity for the comparative study of exoplanets with a shared formation history. Combining new VLTI/GRAVITY observations obtained within the ExoGRAVITY program with archival data, we perform a systematic atmospheric characterisation of all four planets. We explore different levels of model flexibility to understand the temperature structure, chemistry and clouds of each planet using both petitRADTRANS atmospheric retrievals and fits to self-consistent radiative-convective equilibrium models. Using Bayesian Model Averaging to combine multiple retrievals, we find that the HR 8799 planets are highly enriched in metals, with [M/H] $\gtrsim$1, and have stellar to super-stellar C/O ratios. The C/O ratio increases with increasing separation from $0.55^{+0.12}_{-0.10}$ for d to $0.78^{+0.03}_{-0.04}$ for b, with the exception of the innermost planet which has a C/O ratio of $0.87\pm0.03$. By retrieving a quench pressure and using a disequilibrium chemistry model we derive vertical mixing strengths compatible with predictions for high-metallicity, self-luminous atmospheres. Bayesian evidence comparisons strongly favour the presence of HCN in HR 8799 c and e, as well as CH$_{4}$ in HR 8799 c, with detections at $>5\sigma$ confidence. All of the planets are cloudy, with no evidence for patchiness. The clouds of c, d and e are best fit by silicate clouds lying above a deep iron cloud layer, while the clouds of the cooler HR 8799 b are more likely composed of Na$_{2}$S. With well defined atmospheric properties, future exploration of this system is well positioned to unveil further detail in these planets, extending our understanding of the composition, structure, and formation history of these siblings., Comment: 45 pages, 25 figures, accepted by Astronomy & Astrophysics

Dual-field interferometric observations with VLTI/GRAVITY sometimes require the use of a "binary calibrator", a binary star whose individual components remain unresolved by the interferometer, with a separation between 400 and 2000 mas for observations with the Units Telescopes (UTs), or 1200 to 3000 mas for the Auxiliary Telescopes (ATs). The separation vector also needs to be predictable to within 10 mas for proper pointing of the instrument. Up until now, no list of properly vetted calibrators was available for dual-field observations with VLTI/GRAVITY on the UTs. Our objective is to compile such a list, and make it available to the community. We identify a list of candidates from the Washington Double Star (WDS) catalogue, all with appropriate separations and brightness, scattered over the Southern sky. We observe them as part of a dedicated calibration programme, and determine whether these objects are true binaries (excluding higher multiplicities resolved interferometrically but unseen by imaging), and extract measurements of the separation vectors. We combine these new measurements with those available in the WDS to determine updated orbital parameters for all our vetted calibrators. We compile a list of 13 vetted binary calibrators for observations with VLTI/GRAVITY on the UTs, and provide orbital estimates and astrometric predictions for each of them. We show that our list guarantees that there are always at least two binary calibrators at airmass < 2 in the sky over the Paranal observatory, at any point in time. Any Principal Investigator wishing to use the dual-field mode of VLTI/GRAVITY with the UTs can now refer to this list to select an appropriate calibrator. We encourage the use of "whereistheplanet" to predict the astrometry of these calibrators, which seamlessly integrates with "p2Gravity" for VLTI/GRAVITY dual-field observing material preparation., Comment: 16 pages, 6 figures. Submitted to A&A