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Mafic rocks are the most common type of igneous rocks on Earth, however, constraining the crystallization age of mafic rocks can be challenging. Apatite is a common accessory phase in mafic rocks and is amenable to dating using the U–Pb system. However, the U–Pb system in apatite has a relatively low closure temperature (∼350°-550 °C) and is therefore prone to resetting by later thermal and metasomatic events. Here, a recently developed Lu Hf dating method using laser ablation reaction-cell mass spectrometry is applied to apatite from mafic rocks. The Lu Hf system in apatite has a higher closure temperature (∼650°-750 °C) compared to U–Pb, increasing the chances of obtaining primary crystallization ages. Furthermore, the laser-ablation method allows rapid data collection compared to traditional solution-based Lu Hf dating techniques. Four study areas were selected to compare the Lu Hf vs U–Pb systematics of apatite in mafic igneous rocks: the Paleoproterozoic Sudbury Igneous Complex (Canada), the Neoproterozoic Borborema Province (NE Brazil), the Paleoproterozoic Fennoscandian Shield (Finland), the Archean Yilgarn Craton and adjacent Mesoproterozoic Albany Fraser Orogen (Western Australia). For all analyzed samples that have apatite trace element compositions typical of an undisturbed primary mafic igneous lithology, the Lu Hf system retains primary igneous apatite crystallization ages, whereas the U–Pb system in the same grains often records isotopic disturbance or a cooling age. In few cases, the Lu Hf system has also been disturbed in response to recrystallization, however, such disturbance is readily detected with trace element data. Hence, this study demonstrates the potential of laser ablation apatite Lu Hf dating to obtain primary crystallization ages for otherwise difficult to date mafic rocks. • First study on Lu-Hf systematics for apatite from mafic rocks • U U-Pb system in apatite readily resets by thermal and metasomatic events • Lu Lu-Hf system is robust to volume diffusion < ∼660–730 °C, retaining primary crystallization ages. • Deformation leading to recrystallization 'resets' both U U-Pb and Lu Lu-Hf systems in apatite. • Apatite trace element data to differentiate isotopic disturbances related to recrystallisation versus volume diffusion [ABSTRACT FROM AUTHOR]

Alkaline rocks of prevailing sodic composition form major ring complexes and stocks along a seismically active N–S structural lineament parallel to the Paraguay river course. All these occurrences are encompassed by the Alto Paraguay Province, their rocks corresponding to the oldest known alkaline magmatic activity in the Paraná Basin, with a Middle Triassic age of 241.5 ± 1.3 Ma. Intrusive rocks ranging from silica-undersaturated (nepheline and/or sodalite syenites) to silica-oversaturated (quartz syenites and alkali granites) and their fine-grained counterparts constitute the most abundant rock-types. Clinopyroxenes, associated amphiboles and varying amounts of biotite are the main mafic minerals present. Alkali feldspar (mainly mesoperthites and subordinate sanidine and anorthoclase) and feldspathoids (nepheline and/or sodalite) are widespread. A late-stage magmatic to metasomatic/deuteric mineral assemblage is mostly typical of miaskitic to agpaitic rocks of the Cerro Boggiani complex, whereas rare accessory silicate minerals are found in peralkaline syenites of the Cerro Siete Cabezas major intrusion. Positive Nb–Ta and Zr–Hf anomalies and negative Sr, P, and Ti spikes are common features to the whole province. REE behavior shows enrichment in LREE and strong LREE/HREE fractionation with various parallel subtrends. This paper addresses petrological aspects of the origin and evolution of these alkaline rocks. • The paper reviews knowledge about the Alto Paraguay Alkaline Province (border between Brazil and Paraguay). • The main rock types vary from undersaturated (nepheline and sodalite syenites) to silica-oversaturated (quartz syenites and alkali granites) and their fine-grained equivalents. • The intrusion of the alkaline bodies took place along an N–S-oriented structure that marks the boundary of the Pampia and Rio Apa cratonic blocks. • The rocks are dated from the Middle Triassic and constitute the oldest alkaline magmatic event on the edge of the Paraná Basin. [ABSTRACT FROM AUTHOR]

The Juiz de Fora Complex (JFC) in the Araçuaí-Ribeira orogenic system, southeastern Brazil, is a basement unit displaying a variety of rock types that is tectonically imbricated with the supracrustal rocks of the Raposos Group in the Upper Thrust System of the Occidental Terrane, Ribeira Belt. Here we report new petrological, geochemical, and zircon U–Pb and Lu–Hf isotopic data on mafic garnet-granulites from the JFC with a view to evaluate the timing and P-T conditions of the collisional event as well as protolith formation. This work presents the most comprehensive metamorphic study on the Juiz de Fora Complex rocks to date. Metamorphic P-T estimates for the metamorphic peak conditions of 800–900 °C and 8–9 kbar in basic garnet-bearing granulites were obtained for the JFC, indicating that metamorphism took place at deeper crustal levels. Geochemical, zircon U–Pb geochronology, whole-rock Sm–Nd, Rb–Sr isotopes, and Lu–Hf isotopic data of mafic granulites yielded U–Pb ages of ca. 2201 Ma, and moderately juvenile εNd(t) = −0.5 and were obtained from the JFC marking the timing of volcanic arc magmatism during the Rhyacian period. This arc-related stage was followed by the post-collisional period during the Early Paleoproterozoic with ca. 1.94 Ga E-MORB signature granulites that shows evidence of magma sourced from Neoarchean (∼2.8 Ga) crust with addition of juvenile components. The high-grade metamorphism is possibly related to the final collision of the Congo and São Francisco Cratons at 590–560 Ma, which placed the Neoproterozoic metasediments and the JFC rocks at the same level. The integrated information sheds light on two collisional episodes where the oldest is represented by arc-related granulites during the Rhyacian Orogeny and the youngest is the higher-pressure Neoproterozoic overprint during the Brasiliano Orogeny. • The garnet-bearing mafic granulites formed under 800–900 °C with pressures of 8–9 kbar. • Rhyacian and Brasiliano orogenic cycles imprinted the Juiz de Fora Complex rocks. • Zircon data and metamorphic textures indicate a complicated evolution over the two orogenic cycles. [ABSTRACT FROM AUTHOR]

Absolute dating of sedimentary rocks and fossils from the Mesozoic are still rare, mainly due to the difficulties arising from diagenetic changes. Diagenesis promotes changes in the primary structure and chemical composition of biomineralization, which should remain unchanged from the time of deposition and fossilization. Three bioapatite teeth extracted from a jaw fragment of Cladocyclus gardneri from the Romualdo Formation, Araripe Basin, Northeastern Brazil were dated by the U/Pb method in order to obtain an absolute age. The rocks that contain this fossil are dated to Aptian by biostratigraphy of palynomorphs (Sergipea variverrucata biozone, Petrobras P-270), ostracods (Damonella grandiensis biozone, Petrobras) and from the international biozoning of planktonic foraminifera Microhedbergella miniglobularis. The teeth were mounted in 25 mm epoxy resin rounds, imaged by optical microscope and SEM and dated with a Nu Instruments AttoM single-collector ICP-MS coupled to an NWR193nm UC (Ultra Compact) ArF excimer laser system. A Discordia U–Pb date obtained from three separate Cladocyclus gardneri dentine is 110.5 ± 7.4 Ma (2s, MSWD = 2.6), consistent with the biostratigraphic age. This date was based on 155 integrations of line scan analyses (spot size of 30 μm, scan moved at 2 μm per second/100 μm in total length). 238U/206Pb ratios that differed from the mean value by more than 2SD for each tooth were excluded based on the likelihood they reflect U-redistribution during fossilization/post-fossilization fluid alteration. Remaining variations in 238U/206Pb and 207Pb/206Pb ratios along the Discordia reflect variable contributions from common Pb, both within and between the three teeth. They reflect primary U/Pb compositions given that they date the expected age of fossilization. • Direct dating on fossils is still a challenge to be overcome in Geochronology. • Biomineralized parts are more likely to be preserved in the fossilization. • First absolute dating result for the Romualdo Formation, Araripe Basin. • The U–Pb dating corroborates biostratigraphy data. [ABSTRACT FROM AUTHOR]

Although the extinct Quaternary megafauna is widely recorded in northeastern Brazil, geochronological studies carried out on its fossiliferous deposits are still scarce. In this study, Electron Spin Resonance (ESR) was applied to date 12 tooth fragments of Toxodon platensis (Mammalia, Notoungulata) collected in the tank deposit of Lago do Rumo, Baixa Grande, state of Bahia, Brazil. The results obtained in the geochronological analysis performed here reveal ages from around 60 ka to 34 ka for T. platensis in Lagoa do Rumo; and, considering the integration data in the paleontological literature, our results evidence the largest time-averaging ever recorded for tank deposits: around 51 thousand years. • Twelve teeth of Toxodon platensis from Brazilian Northeast were dated using Electron Spin Resonance. • Absolute dating revealed fossils of Toxodon platensis ranging from around 60 ky to 34 ky. • Considering the literature, time-averaging in Lagoa do Rumo is around 51 thousand years. [ABSTRACT FROM AUTHOR]