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In this study, we explore the heterointerface of MgB$_2$ film on SiC substrate at atomic scale using electron microscopy and spectroscopy. We detect ~1 nm MgO between MgB$_2$ and SiC. Atomic-level electron energy loss spectra (EELS) show MgB$_2$-E2g mode splitting and softening near the MgB$_2$/MgO interface. Orbital-resolved core-level EELS link the phonon softening to in-plane boron-atom electron states' changes. Ab initio calculations confirm this softening enhances electron-phonon coupling at the interface. Our findings highlight interface engineering's potential for superconductivity enhancement.

In single unit-cell FeSe grown on SrTiO3, the superconductivity transition temperature features a significant enhancement. Local phonon modes at the interface associated with electron-phonon coupling may play an important role in the interface-induced enhancement. However, such phonon modes have eluded direct experimental observations. Indeed, the complicated atomic structure of the interface brings challenges to obtain the accurate structure-phonon relation knowledge from either experiment or theory, thus hindering our understanding of the enhancement mechanism. Here, we achieve direct characterizations of atomic structure and phonon modes at the FeSe/SrTiO3 interface with atomically resolved imaging and electron energy loss spectroscopy in a scanning transmission electron microscope. We find several phonon modes highly localized (~1.3 nm) at the unique double layer Ti-O termination at the interface, one of which (~ 83 meV) engages in strong interactions with the electrons in FeSe based on ab initio calculations. The electron-phonon coupling strength for such a localized interface phonon with short-range interactions is comparable to that of Fuchs-Kliewer (FK) phonon mode with long-rang interactions. Thus, our atomic-scale study provides new insights into understanding the origin of superconductivity enhancement at the FeSe/SrTiO3 interface.

Phonons are the primary heat carriers in non-metallic solids. In compositionally heterogeneous materials, the thermal properties are believed to be mainly governed by the disrupted phonon transport due to mass disorder and strain fluctuations, while the effects of compositional fluctuation induced local phonon states are usually ignored. Here, by scanning transmission electron microscopy electron energy loss spectroscopy and sophisticated calculations, we identify the vibrational properties of ingredient-dependent interface phonon modes in AlxGa1-xN and quantify their various contributions to the local interface thermal conductance. We demonstrate that atomic-scale compositional fluctuation has significant influence on the vibrational thermodynamic properties, highly affecting the mode ratio and vibrational amplitude of interface phonon modes and subsequently redistributing their modal contribution to the ITC. Our work provides fundamental insights into understanding of local phonon-boundary interactions in nanoscale inhomogeneities, which reveal new opportunities for optimization of thermal properties via engineering ingredient distribution.

The nanoscale lattice imperfections, such as dislocations, have a significant impact on the thermal transport properties in non-metallic materials. Understanding such effects requires the knowledge of defect phonon modes, which however is largely unexplored in experiments due to the challenge in characterization of phonons for the atomic-sized defects. Here, at the atomic scale we directly measure the localized phonon modes of dislocations at a Si/Ge interface using scanning transmission electron microscopy electron energy loss spectroscopy. We find that the dislocation induces new phonon modes localized within ~2-unit cells of the core, which experience a redshift of several milli-electron-volts compared to the dislocation-free case. The observed spectral features agree well with simulations. These localized modes are expected to reduce the phonon transmission channels across the defect and thus the local thermal conductivity. The revealed phonon modes localized at dislocations may help us to improve the thermal properties in thermoelectric generators and thermal management systems with proper defect engineering.

Nanoscale materials usually can trap light and strongly interact with it leading to many photonic device applications. The light-matter interactions are commonly probed by optical spectroscopy, which, however, have some limitations such as diffraction-limited spatial resolution, tiny momentum transfer and non-continuous excitation/detection. In this work, using scanning transmission electron microscopy-electron energy loss spectroscopy (STEM-EELS) with ultra-wide energy and momentum match and sub-nanometer spatial resolution, we study the optical microcavity resonant spectroscopy in a single SiC nanowire. The longitudinal Fabry-Perot (FP) resonating modes and the transverse whispering-gallery modes (WGMs) are simultaneously excited and detected, which span from near-infrared (~ 1.2 {\mu}m) to ultraviolet (~ 0.2 {\mu}m) spectral regime and the momentum transfer can be ranging up to 108 cm{^{-1}}. The size effects on the resonant spectra of nanowires are also revealed. Moreover, the nanoscale decay length of resonant EELS is revealed, which is contributed by the strongly localized electron-photon interactions in the SiC nanowire. This work provides a new alternative technique to investigate the optical resonating spectroscopy of a single nanowire structure and to explore the light-matter interactions in dielectric nanostructures, which is also promising for modulating free electrons via photonic structures.

Defects in oxides usually exhibit exotic properties that may be associated with the local lattice dynamics. Here, at atomic spatial resolution, we directly measure phonon modes of an antiphase boundary (APB) in SrTiO3 freestanding membrane and correlate them with the picometer-level structural distortion. We find that the SrTiO3 APB introduces new defect phonon modes that are absent in bulk SrTiO3. These modes are highly sensitive to the subtle structure distortion, i.e., the SrTiO3 APB generates the local electric dipoles forming an antiferroelectric configuration, which significantly softens the transverse optical (TO) and longitudinal optical (LO) modes at {\Gamma} point. Correlating the local phonons with the subtle structural distortion, our findings provide valuable insights into understanding the defect properties in complex oxides and essential information for their applications such as thermoelectric devices.