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Scheelite, one kind of common REE-rich and U-bearing hydrothermal mineral, is extensively developed in various types of gold deposits, which can be used to record nature and timing of metallogenesis. The Zhaishang Carlin-like gold deposit in the Qinling Orogen is a giant Au deposit, hosting 127t of Au @ 2.67 g/t with economic concentrations of tungsten and antimony. The study reports two types of scheelite based on the characteristics of petrography and geochemistry. Sch A shows significant oscillatory zoning with dark gray cathodoluminescence (CL) response, whereas Sch B displays patchy textures with brighter CL response. Systematic LA-ICP-MS U–Pb dating of Sch A and Sch B yields ages of 227.1 ± 3.2 Ma and 226.2 ± 6.9 Ma, respectively. The new dates, constraining the Zhaishang Au–W mineralization to ~ 227Ma, coincide well with the western Qinling magmatism, metallogenic and tectonic events. There are significant variations in concentration, the Sch A has low REE content (mean = 41.3 ppm), negative Eu-anomaly with slightly positive Ce-anomaly, whereas Sch B, with small negative or positive Eu-anomaly, has higher REE content (mean = 247 ppm) and higher positive Ce-anomaly. The positive correlation of EuN and EuN* records oxidizing condition during the whole W mineralization event. Additionally, Sch B intergrown with selenides with an increase in the Ce-anomaly supports that the latter has higher oxygen fugacity environment. The Sr isotope signature for scheelite supports that ore-forming metals mostly inherited the host rock component, while the proportion of magma-derived Sr increased in the Sch B. Fluid–rock interactions co-precipitated Au and W caused by the release of Fe and Ca cations and the increase of pH. The study highlights that scheelite as a recorder can help in deciphering the nature and timing of metallogenesis of the studied Au–Sb–W deposit, and thus other similar Au–W deposits. [ABSTRACT FROM AUTHOR]

The Hongyuan porphyry Mo–Cu deposit (PMCD) is a rare example of a "reduced" deposit, in contrast to classical oxidized porphyry Cu or Mo–Cu deposits. It is characterized by an ilmenite–series I–type felsic granitoid intrusion, reduced ore‐forming fluids with methane‐rich fluid inclusions, and widely distributed primary pyrrhotite. Mo–Cu mineralization in the Hongyuan PMCD occurs as disseminated in porphyry, granular in miarolitic cavity, and vein‐type in the quartz vein. These three types of mineralization are generally produced in the late magmatic period, magmatic‐hydrothermal transition period, and hydrothermal period, respectively. Molybdenite from miarolitic cavities shows a greater contribution from mantle fluid, as evidenced by mantle He proportions of 37.6%–16.8%. Molybdenite in quartz veins has relatively lower mantle He proportions of 1.63%–10.5%, indicating a predominantly crustal fluid source. The 3He/4He variations of these two groups of molybdenite illustrate an increasing input of crustal fluid during the magmatic to hydrothermal transition. Molybdenite samples from miarolitic cavities and quartz veins yield a Re‐Os model age of 300.5 ± 3.7 Ma, which is consistent with the U–Pb ages of zircons in the wallrock porphyries (300–302 Ma). This further indicates simultaneous diagenesis accompanied by mineralization. The Sr–Nd isotopic compositions (initial 87Sr/86Sr: 0.703404–0.703552; initial 143Nd/144Nd: 0.512585–0.512655; εNd[t]: +6.56 to +7.90) and young T2DM model ages (421–531 Ma) of the Hongyuan porphyries suggest that these rocks were derived from partial melting of the basaltic lower crust. We propose that mantle‐derived fluids rose up and mixed with fluids from the lower crust under an extensional tectonic setting, forming mantle‐like Sr–Nd–He–Ar isotopic compositions. The pre‐mineralization stage of the Hongyuan reduced PMCD is marked by quartz‐molybdenite ± K‐feldspar ± pyrite veins or veinlets and miarolitic cavities in the intensively potassic alteration zone. These veins formed at high temperatures (400–476°C) and high salinities (47.5–56.6 wt.%). The syn‐mineralization stage is the main metallogenic stage represented by numerous quartz‐molybdenite ± pyrrhotite veins associated with moderate to high temperatures (248°C–424°C) and low to high salinities (1.57–50.1 wt.%). The post‐mineralization stage is characterized by low temperatures (104–270°C) and low salinities (0.35–8.81 wt.%). Fluid immiscibility, mixing with meteoric water, ore fluid‐wall rock interactions, and decreasing temperature and salinity have played important roles during molybdenum mineralization. [ABSTRACT FROM AUTHOR]

Skarn-type tungsten deposits are widely distributed all over the world and contribute more than 70% of the world's W supply. The temporal relation between the W mineralization and causative intrusions and the evolution of ore-forming fluids are matters of ongoing debate. In this study, we combine in situ LA-ICP-MS U-Pb dating and trace element compositions of scheelite from Zhuxi, the world's largest W deposit, and compare them with literature data to address the above issues. Three primary ore stages exist at Zhuxi: prograde skarn, retrograde skarn, and quartz-sulfide stages. Most scheelite occurs in the retrograde skarn stage and is further subdivided into three generations: Sch A, B, and C. The obtained LA-ICP-MS U-Pb ages for three scheelite generations in the Zhuxi deposit are 154.0 ± 2.8, 150.3 ± 3.5, and 150.4 ± 6.3 Ma, respectively, indicating that the entire W mineralization is closely related to the emplacement of the nearby Late Jurassic granites (~154 to 150 Ma, zircon U-Pb ages). In situ LA-ICP-MS trace element results demonstrate that Sch A shows the highest Mo content (mean = 1002 ppm), where those for Sch B and Sch C are 109 and 45 ppm, respectively. These, combined with the gradually increasing trend of Ce contents and δCe values, indicate a shift from oxidizing to reducing conditions for the ore-forming fluid. All three scheelite generations yield significant positive δEu anomalies, which are considered to be unrelated to the redox state, but caused by the addition of Eu (e.g., feldspar dissolution). The high-Y/Ho ratio of scheelite and a good correlation between Y/Ho ratio and δEu (R2 = 0.96) suggest that intense fluid-rock interactions between ore fluids and the Shuangqiaoshan Group metasedimentary rocks as well as earlier-formed skarns drove fluid evolution. This study demonstrates that scheelite U-Pb geochronology is a useful technique when identifying the temporal link between hydrothermal W mineralization and the causative intrusion. Our results also highlight that the reactions of the ore fluids with wall rocks and earlier-formed skarns significantly modify the primary fluid compositions. [ABSTRACT FROM AUTHOR]

With the northward subduction and final closure of the Neo-Tethyan oceanic crust, the Indian and Eurasian plates finally collided together and underwent a strong collision orogenic event, resulting in large-scale crust–mantle magmatic interactions. In order to clarify the controversies about tectono-magmatic activities after the Indian–Eurasian continental collision, we report the newly dated Eocene Qiongduojiang gabbro explored in the Tethyan–Himalaya belt, southern Tibet. LA-ICP-MS zircon U-Pb dating shows that the crystallization age of the Qiongduojiang gabbro is 46.1 ± 1.7 Ma. The whole-rock major and trace elements, as well as Rb-Sr, Sm-Nd, and Pb isotopic data results, show that the Qiongduojiang gabbro is apparently depleted in Nd isotopes, is enriched in Pb isotopes, and has maintained a consistent 87Sr/86Sr(t) value. This paper argues that the E-MORB-like Qiongduojiang gabbro originated from asthenosphere upwelling caused by slab breakoff of the Neo-Tethyan oceanic plate. This event caused large-scale magmatic activities, a magmatic mixing process between ancient crust and deep mantle, and wild distribution of Eocene Gangdese plutons along the Yarlung–Tsangpo Suture Zone, and it rendered the subduction-modified Tibetan lithosphere fertile from the Gangdese porphyry Cu deposits. [ABSTRACT FROM AUTHOR]

Garnet is the most common alteration mineral in skarn-type deposits, and the geochronological research on it can limit the mineralization age. The Longwan Pb–Zn deposit, situated within the Fozichong Pb–Zn ore field in Guangxi, lacks precise geochronological data, limiting the in-depth comprehension of its genesis and tectonic setting. This study employs LA-ICP-MS U–Pb dating of garnets developed in the skarn orebody and zircons in the associated granitic porphyry to determine the deposit's mineralization age. Backscatter electron images and electron probe microanalysis reveal common zonation characteristics in garnets from the Longwan Pb–Zn deposit, with dominant end-member compositions of Andradite and Grossular. The values of U concentrations range from 1.8 ppm to 3.7 ppm, and a garnet U–Pb age of 102.6 ± 1.9 Ma was obtained, consistent with the zircon U–Pb age of 102.1 ± 1.2 Ma from the granite porphyry within the deposit. The Longwan Pb–Zn deposit formed during the late Early Cretaceous as a skarn deposit resulting from contact metasomatism between the granite porphyry and the host rock. The deposit likely formed in response to the Neo-Tethys plate subducting beneath the South China continent during the Cretaceous, followed by a retreat during the Late Cretaceous. The Cenxi-Bobai Fault experienced reactivation under the extensional tectonic regime induced by the Neo-Tethys Ocean's retreat, leading to a series of magmatic activities along the NE-trending direction within the Fault. The Longwan Pb–Zn deposit formed during the processes of magma emplacement and contact metasomatic reactions with the country rock. [ABSTRACT FROM AUTHOR]

The Chakabeishan (CKBS) deposit is the first pegmatite-type Li-Be deposit discovered in the eastern North Qaidam Tectonic Belt (NQTB) of Tibetan Plateau. The correct understanding of its petrogenesis and the precise determination of its formation age are of great significance for further regional prospecting and the discovery of new economically valuable rare-metal deposits. Therefore, a systematic study of texture, major-element composition, and U-Pb dating of columbite-tantalite group minerals (CGMs) in the spodumene pegmatite dyke from the CKBS deposit was undertaken. Three types of CGMs were identified, including concentric oscillatory ferrocolumbite (CGMs-1), homogeneous ferrocolumbite (CGMs-2), and irregular ferrotantalite (minor manganocolumbite) with abundant early ferrocolumbite replacement remnants (CGMs-3). The zoning patterns and chemical compositions in the CGMs record the complex evolutionary history of their host pegmatite from the magmatic stage (CGMs-1, disequilibrium crystallization) to the magmatic-hydrothermal transition stage (CGMs-2, equilibrium crystallization) and then to the late metasomatic stage (CGMs-3, replacement/re-equilibrium). CGMs U-Pb dating results suggest that the spodumene pegmatite dyke (No.15) emplaced at 230.1 ± 2.6 Ma. Subsequently, it experienced fluid metasomatism at 221 ± 5.3 Ma. Based on the new age data and published geochronological data, it can be concluded that the spodumene pegmatite dykes in the CKBS deposit formed in an oceanic subduction-related setting, representing a new metallogenic event in western China. Except for the CKBS deposit, a large number of rare-metal pegmatite dykes have also been discovered in the eastern NQTB, indicating that the eastern NQTB may be an important potential rare-metal metallogenic belt that should be explored in detail and arouse painstaking attention. [ABSTRACT FROM AUTHOR]

The Tudigou porphyry Cu deposit is located in the central part of the southern Qinling belt. Copper mineralization is closely associated with monzogranite porphyry. Zircon LA–ICP–MS U–Pb dating of monzogranite porphyry suggests that the ages of magmatism at Tudigou vary between 150 ± 1 and 148 ± 1 Ma and overlap with the molybdenite Re–Os age of 150–148 Ma, indicating that the Tudigou intrusion and associated mineralization formed during the Late Jurassic. The enrichment in large‐ion lithophile elements, depletion in high‐field‐strength elements, high Ba/Th and La/Yb ratios, and negative correlation between Dy/Yb and La/Sm ratios, together with narrow ranges of εHf(t) values (εHf(t) = −4.0 to +1.4) suggest monzogranite porphyry was derived from a metasomatized lithospheric mantle with minor crustal components contribution, which is also evidenced by the lead isotopic result. The La/Yb ratios of 30 Mesozoic plutons in the southern Qinling belt were used to calculate the Moho depth, which suggests that the magmatism and mineralization in the region occurred during lithosphere thinning in response to the tectonic transition from compression to extension transitional regime. The calculated oxygen fugacity of the Late Mesozoic porphyry deposits in the Qinling–Dabie orogen have identical ΔFMQ values (averaging +1.4 to +2.4). However, the V/Sc ratios (the proxy for water content) are distinct among different deposit sizes, indicating that the dissolved water in the magma plays a critical role in porphyry‐type mineralization. [ABSTRACT FROM AUTHOR]

East Junggar is an important part of the Central Asia Orogenic Belt and has developed a multi‐epoch and multi‐type metallogenic system. Yundukala is a recently discovered large intrusion‐related Au–Cu–Co deposit. The No. 1 main mineralization zone mainly occurs in the contact area between fine‐grained diorite and basalt. Massive and vein mineralization have developed there, but the ore‐bearing stratum, ore‐bearing intrusive rocks, and metallogenic ages are not clear. Zircon SHRIMP U–Pb dating of the porphyritic diorite and fine‐grained diorite yields ages of 416.1 ± 3.9 Ma and 411.1 ± 7.5 Ma, respectively. The dioritoid intruded into the ore‐bearing stratum, indicating that this formation is part of the Early Palaeozoic strata rather than the Middle Devonian Beishan Formation. The Re–Os isochron age of the chalcopyrite in the massive mineralization is 402.6 ± 5.2 Ma; thus, the massive mineralization is related to fine‐grained diorite and formed in the Early Devonian. Six sulphides and four sulphides from the vein mineralization yield Re–Os isochron ages of 352.8 ± 1.8 Ma and 354 ± 23 Ma, respectively, and the limited vein mineralization was formed during 353–354 Ma. The massive and vein mineralizations in the Yundukala deposit were formed in the Early Devonian and Early Carboniferous. [ABSTRACT FROM AUTHOR]

The Chang'an Chong Cu-Mo deposit is located in the Chang'an Cu-Mo-Au ore cluster in the southern Ailaoshan tectonic belt in southwestern China. There are six intrusive bodies in the mining area, among which the No.Ⅱ intrusive body is the largest and most closely related to Cu-Mo mineralization of skarn. The No. 1 main orebody is composed of the No. 1 copper orebody and No. 1 molybdenum orebody, which are distributed in parallel with similar shapes. In this paper, the age of skarn is determined by the LA-SF-ICP-MS U-Pb dating of garnet, and it is nearly consistent with the age of alkaline porphyry in this region (41–32 Ma). Compared with the U-Pb age of zircon from the ore-bearing porphyry and the Re-Os age of molybdenite, the U-Pb age of garnet was consistent with them within error, indicating that they were the same mineralization event, which further proves that the porphyry-skarn Cu-Mo-Au mineralization event along the Ailaoshan-Red River fault zone mainly occurred at 38~32 Ma. In-situ S isotope results show that the δ34S mean values of disseminated pyrite (PyI), pyrite of sulfide veins (PyⅡ) and chalcopyrite (Ccp) in the main mineralization period are 2.35‰, 3.60‰ and 0.55‰, respectively. These δ34S values are similar to those of magma and slightly enriched in δ34S, and the δ34S value of chalcopyrite is mainly concentrated near 0‰, so it can be considered that the S of the ore-forming fluid came from magmatic-hydrothermal fluids. Based on the comprehensive analysis of the regional metallogenic background, deposit chronology and isotope geochemistry, it is concluded that the Chang'an Chong Cu-Mo deposit was formed in an intra-plate post-collision strike-slip environment. [ABSTRACT FROM AUTHOR]

Demingding is a promising porphyry Mo-dominated deposit recently discovered in the eastern Gangdese metallogenic belt in Tibet, China. We present zircon U-Pb-Lu-Hf isotopic studies, as well as geochemical data of the late monzogranites and the prior rhyolites from the Demingding porphyry deposit to uncover their origin and geodynamic mechanism. Zircon U–Pb dating yielded precise crystallization ages of 17.3 ± 0.6 Ma (MSWD = 2.5) and 186.5 ± 3.0 Ma (MSWD = 2.0) for monzogranite and rhyolite, respectively. The monzogranite is characterized by high-K calc-alkaline, adakitic affinities, and positive zircon εHf(t) values (+0.9∼+5.6, avg.+3.1) with TDM2 (0.73–1.04 Ga), while the rhyolite has εHf(t) values of (+2.1∼+7.3, avg.+5.2) and TDM2 of (0.76–1.09 Ga) similar to the monzogranite. Our results suggest that the Demingding porphyry Mo (Cu) deposit is related to magma generated from the Neo-Tethyan oceanic subduction. The subsequent monzogranite porphyry was likely formed by the remelting of previously subduction-modified arc lithosphere, triggered by continental collision crustal thickening in Miocene. The lower positive εHf(t) values of monzogranites suggest minor inputs from the Mo-rich ancient crust, suggesting that Mo favors the silicate melt. Such magmatic events and special metallogenesis typify intracontinental processes and porphyry copper deposits, which are normally confined to oceanic subduction and Cu-dominated style, thereby making the continental setting and Mo-dominated style of Demingding exceptional and possibly unique. [ABSTRACT FROM AUTHOR]

The large Bayanbaolege Ag polymetallic ore deposit is located in the Tuquan-Linxi Fe (Sn)-Cu-Pb-Zn-Ag-Nb (Ta) polymetallic metallogenic belt, which is an important part of the Great Xing'an Range metallogenic province, northeast China. The sulfide–quartz vein-type orebodies in the deposit are mainly hosted in the Cretaceous granodiorite porphyry and Late Permian Linxi formation. The U-Pb dating of the zircon from the post-ore diorite porphyrite yields an age of 124.8 ± 1.1 Ma, which constrains the mineralization time at the Early Cretaceous. The Sr-Nd isotope values (87Sr/86Sr)i = 0.708576~0.710536; εNd (t) = −0.51~+0.69; the Hf isotope values 176Hf/177Hf = 0.2827278~0.2830095, the εHf (t) = +3.1~+11.2, TDM2 = 615~1341 Ma of the metallogenic granodiorite porphyry. The Hf isotope values 176Hf/177Hf = 0.2828596~0.2829451, and the εHf (t) = +5.7~+8.8 of the diorite porphyrite, TDM2 = 827~1108 Ma, indicating that the ore-forming materials were the possible involvement of heterogeneous juvenile sources including moderately depleted mantle and newly underplated lower crust. The major and trace elements (including REEs) implied that these intrusions are the I-type granite and linked intimately to the westward subduction of the Paleo-Pacific Ocean plate. From these whole-rock major and trace elements and zircon U-Pb ages, as well as Sr-Nd-Hf isotope data, we conclude that the ore-associated I-type granites in the Bayanbaolege deposit formed in an extensional tectonic setting of the Early Cretaceous, and are compactly related to the retreat of the Paleo-Pacific Ocean subducted plate linked intimately to the westward subduction of the Paleo-Pacific Ocean plate rather than the closure of the Mongol–Okhotsk Ocean. Furthermore, by integrating geological background work and previous research work, implying the mineralization age of the Bayanbaolege deposit should have been formed in the 125–130 Ma. [ABSTRACT FROM AUTHOR]

The Qin-Hang Metallogenic Belt (QHMB), an important metallogenic belt in South China, hosts Cu and W–Sn polymetallic deposits. The Tongshanling ore field in the QHMB is characterized by the coexistence of Cu- and W-bearing polymetallic deposits, which are related to granodiorite and granite porphyry. This study examined whole-rock geochemistry, geochronology, and Sr–Nd–Hf isotopes to determine the genetic relationship between diverse ore-related granitoids (i.e., granodiorite and granite porphyry) and Cu–W metallogeny in the Tongshanling ore field. Zircon LA-ICP-MS U–Pb dating shows that the granodiorite and granite porphyry in the Tongshanling ore field were emplaced at 163.7 ± 0.4 Ma to 154.7 ± 0.6 Ma and 161.1 ± 0.3 Ma, respectively. Geochemically, the granodiorites are classified as oxidized I-type, while the highly evolved granite porphyry is reduced A-type. The Lu–Hf isotopic composition of the granodiorites is characterized by εHf(t) values ranging from –10.49 to –4.99 (average = –7.17), with corresponding TDMC ages ranging from 1524 to 1877 Ma (average = 1682 Ma). In contrast, the granite porphyry has higher εHf(t) values (–3.60 to –1.58, average = –2.78) and younger TDMC (1310–1438 Ma, average = 1387 Ma). The εNd(t) values of granodiorite are −8.06 to −7.37 and the two-stage model ages (TDM2) are 1543–1598 Ma, while the granite porphyry has higher εNd(t) values (−3.0 to −3.4) and younger TDM2 ages (1195–1223 Ma). The results show that the granodiorite and granite porphyry were formed from partial melting of different Mesoproterozoic basement rocks under varying degrees of crust–mantle interaction. Granite porphyry underwent well-recorded fractional crystallization. Compared to the Cu-forming granodiorite, the W-forming granite porphyry has a higher differentiation index, higher crystallization temperatures of zircon (average = 708 °C versus 631 °C), and lower oxygen fugacity (median ΔFMQ = –2.21 versus –1.77). [ABSTRACT FROM AUTHOR]

Northwest Hebei province is one of the gold-producing areas in China. Based on a geochronological analysis of the Zhangjiakou-Xuanhua area, zircon U–Pb with an age of 2487–142 Ma and zircon fission-track (ZFT) with a cooling age of 155–66 Ma were obtained. Zircon U–Pb dating of the Xiaoyingpan deposit revealed two ages of 2487 ± 92 Ma and 1745 ± 89 Ma, representing the Archaean and Early Proterozoic metamorphism of the Sanggan Group. The ZFT cooling age of 155 ± 10 Ma represents the deposit's lower limit metallogenic age. The Shuiquangou (SQG) alkaline complex emplaced at 388.9 ± 3.0 Ma and experienced magmatic activities until the Late Devonian (ca 377 Ma), considering the response to the collision between the Siberian plate and the North China Craton. The emplacement age of Shangshuiquan (SSQ) granite is 142.3 ± 1.1 Ma and is coeval with the thinning of the North China Craton during the Late Jurassic–Early Cretaceous. The intrusion of SSQ might partially reheat the SQG complex, resulting in the Yanshanian gold mineralization in Dongping. The SQG complex and SSQ granite underwent a relatively consistent rapid cooling process in the Cretaceous based on the ZFT ages. [ABSTRACT FROM AUTHOR]

[Display omitted] • The host granite belongs to the ca. 1860 Ma Donington Suite. • The host granite experienced a thermal event (>350 °C) at ca. 1770 Ma. • Porphyritic volcanic units and polylithic breccias formed at ca. 1590 Ma. • Iron Oxide Copper-Gold mineralisation formed at ca. 1585 Ma. • Uranium mineralisation, post-ore veining and late alteration formed at ca. 600–500 Ma. The Carrapateena Iron Oxide Copper-Gold (IOCG) deposit is located on the eastern margin of the Gawler Craton, approximately ∼475 km NE of Adelaide, South Australia. The deposit is hosted within a granite belonging to the Donington Suite and contains various polylithic breccias and intrusive volcanic units. Multiple stages of alteration/mineralisation are present throughout the deposit, which includes: (1) pre-mineralisation alteration; (2) hematite I; (3) Cu-Au mineralisation; (4) hematite II & REE mineralisation; (5) uranium mineralisation; (6) post-mineralisation alteration/veining. In order to establish a temporal framework, multi-mineral U–Pb geochronology was conducted on a variety of lithologies throughout the deposit and across multiple stages of alteration/mineralisation. Zircons from the host granite are predominantly discordant, with two concordant analyses from two samples producing 207Pb/206Pb ages of ca. 1880–1861 Ma, consistent with the emplacement of the Donington Suite (1860–1850 Ma). Apatite U–Pb geochronology performed on the granite-bearing samples produced ages of ca. 1775–1767 Ma, indicating the presence of a moderate temperature (≥350 °C) thermal event approximately 100 Ma after the crystallisation of the host rock. Zircon U–Pb geochronology conducted on a porphyritic volcanic unit and two polylithic breccia samples produce bi-modal age populations at ca. 1880–1860 Ma & ca. 1590 Ma. The ca. 1880–1860 Ma age reflects zircons inherited from the host granite, while the younger ca. 1590 Ma population represents the crystallisation age of the porphyritic volcanic unit and the maximum formation age of the polylithic breccias. U–Pb geochronology conducted on apatite, hematite and xenotime associated with various stages of mineralisation produce ages of ca. 1585 Ma, consistent with a major Fe-Cu-Au metallogenic event throughout the Gawler Craton. U–Pb geochronology performed on uraninite, apatite located within a late vein, and "vuggy" hematite records a second hydrothermal event from ca. 600–500 Ma, reflecting a period of minor deformation and deposit-wide fluid circulation. [ABSTRACT FROM AUTHOR]

[Display omitted] • The magmatic-hydrothermal system of Yangla skarn Cu deposit is relatively reduced. • The barren quartz porphyry was also originated from reduced magmas and thus less fertile for porphyry Cu formation. • Intense fluid-carbonate rocks interaction and fluid focusing could be the key to formation of the reduced Yangla Cu deposit. In the Paleo-Tethyan orogenic belt, reduced mineralization systems result in extensive saturation and segregation of magmatic sulfide phases, which in turn leads to the loss of chalcophile elements and hinders the precipitation of large amounts of copper. As a result, porphyry Cu deposits are rare within the belt. In this contribution, we investigate the composition of zircons from the granodiorite, fluid inclusions and hydrothermal scheelite from orebodies of the Yangla Skarn Cu deposit, and assess the magmatic-hydrothermal redox state of the system. The igneous zircons from ore-causative granodiorite have negative Eu anomalies (Eu N /Eu N * = 0.27 ± 0.03, n = 11) and the calculated ΔFMQ values are -0.23 ± 0.31 (n = 11). The ore-forming fluids in the pre-ore stage was rich in CH 4 , and precipitating hydrothermal scheelite in the syn -ore stage with low Mo contents (Mo = 17.4 to 149 ppm, mean 57.7 ppm) and positive Ce anomalies (Ce N /Ce N * = 1.14 ± 0.06, n = 29). The geochemistry suggests that the magmatic-hydrothermal system at Yangla is relatively reduced, consistent with the abundant development of pyrrhotite in the ore body. In addition, we have carried out zircon SIMS U-Pb dating and trace analysis of the barren quartz porphyry in the Yangla ore field, which gives an emplacement age of 227 Ma and is also derived from reduced magmas (ΔFMQ = -1.27 ± 0.55; Eu N /Eu N * = 0.32 ± 0.10, n = 7) that were less fertile for porphyry Cu formation. By comparing with the barren quartz porphyry, we suggest that the key control of the skarn ore body may have been that the low-permeability of carbonate units seal the mineralizing fluids, enhancing fluid-carbonate reactions and concentrating the sulfides in a relatively small area. Without these processes, it can only form barren porphyry system. We highlight that, unlike typical porphyry Cu deposits, intense fluid-carbonate rocks interaction and fluid focusing could result in skarn Cu formation, even though in relatively reduced magmatic-hydrothermal conditions. [ABSTRACT FROM AUTHOR]

[Display omitted] • Diverse W metallogeny of the Baiyunxian ore field intensively occurred in 156–153 Ma. • W metallogeny was associated with Late Jurassic highly evolved magmatic phases. • Metal element are derived from remelting of metasedimentary crustal basement. • Lithology of wall rocks is the major cause of varied W mineralization types. The Baiyunxian ore field, a large tungsten ore filed in the Nanling Metallogenic Belt of South China, hosts a variety of tungsten deposits such as the Dapu (quartz wolframite vein type), Chashanjiao (skarn type), Toutianmen (greisen type), and Dashan (quartz scheelite vein type). However, precise mineralization ages of these deposits remain poorly constrained and this has long vexed a better understanding of genetic relationships between diverse W mineralization types and the spatially associated Jiufeng granitic complexes. Here, we report firsthand zircon U–Pb, monazite U–Pb, garnet U–Pb, cassiterite U–Pb, and molybdenite Re–Os ages of different granites and ores from the Baiyunxian ore field. The Jiufeng granitic complexes consists of phase Ⅰ biotite granite (P1), phase Ⅱ two-mica granite (P2), and phase Ⅲ granitic dikes (P3, including greisen W ore). Zircons from P1 granite define a concordant U–Pb age of 166.0 ± 0.9 Ma (MSWD = 1.1). Monazites from P2 granite yielded a Tera–Wasserburg lower intercept age of 159.2 ± 0.7 Ma (MSWD = 0.45). In addition, zircons and monazites from P3 granite in the Toutianmen deposit yield a concordant U–Pb age of 154.7 ± 1.3 Ma (MSWD = 1.3) and a Tera–Wasserburg lower intercept age of 156.6 ± 1.9 Ma (MSWD = 0.14), respectively, suggestive of multi-stage emplacement processes of the Jiufeng complexes. Ten molybdenite samples from the Dapu deposit generate an isochron age of 156.0 ± 3.0 Ma (MSWD = 0.93). In situ garnet and cassiterite LA-ICP-MS U–Pb dating results of the Chashanjiao skarn deposit yield lower Tera–Wasserburg intercept ages of 155.3 ± 1.2 Ma (MSWD = 1.6) and 153.4 ± 3.7 Ma (MSWD = 1.3), respectively. These dating results indicate that different W mineralization events in the Baiyunxian ore field intensively occurred in the Late Jurassic (∼159–153 Ma). Despite a close spatial relationship between various W orebodies and P1 granite, the geochronological results demonstrate that extensive W metallogeny in the Baiyunxian ore filed likely occurred later than P1 granite and contemporaneous with P2–3 granites. In addition, scheelites from the four deposits have similar REE patterns that are characterized by weak MREE enrichment, despite few exceptions being found in scheelites from the Dashan and Chashanjiao deposits. This suggests that the diverse W metallogeny in the Baiyunxian ore field were derived from the same magmatic hydrothermal system and changed as the ore-forming fluid evolved. Multidisciplinary evidence indicates that the Late Jurassic highly evolved P2–3 granites of the Jiufeng complexes were crucial to W mineralization in the Baiyunxian ore field and the lithology of wall rocks exerted first-order control of W mineralization types. [ABSTRACT FROM AUTHOR]

[Display omitted] • Garnet U-Pb dating constrains the age of the Lazhushan deposit at ca. 150 Ma. • Fe skarn mineralization in the Edong district started earlier than previously thought. • The Th/U ratio of garnet is a potential redox indicator of ore fluids. Garnet is ubiquitous in skarn deposits. It is a sensitive recorder of physiochemical conditions and also a powerful geochronometer. In this study, we use garnet trace element geochemistry and U-Pb geochronology as well as sulfur isotopes of sulfides to constrain the age and mineralization process of the Lazhushan Fe skarn deposit. Garnets in the Lazhushan Fe skarn belong to the andradite-grossular solution series and yield a compositional range from Adr 47.2 Gro 50.7 to Adr 97.4 Gro 0.9. There are strong correlations between La N /Yb N ratios and andradite contents in garnet, indicating that garnet major element composition exerts a strong control on the REE fractionation. The decrease of HFSEs (Nb, Ta, Zr, Hf, and Ti) and Co, V, and Mn concentrations from prograde to retrograde garnets may reflect increasing water/rock ratio and decreasing temperature during skarn evolution, respectively. Co-precipitation with magnetite may be responsible for the low concentration of V in the retrograde garnets. The Th/U ratio increase from endoskarn garnet to exoskarn counterparts, probably reflecting an increase of fluid f O 2 due to interactions with evaporate sulfate from the wall rocks. The sulfides in this deposit are enriched in δ34S (up to 13 ‰), conforming the involvement of evaporate sulfate during Fe skarn mineralization. The incursion of evaporate sulfate may have played an important role in magnetite mineralization for the Lazhushan deposit by increasing fluid f O 2 and facilitating the oxidation of Fe2+ to precipitate magnetite. LA-ICP-MS U-Pb dating of garnets from 4 garnet-bearing samples yielded ages of 150.8 ± 6.8 Ma (2σ), 150.9 ± 5.3 Ma (2σ), 150.2 ± 7.9 Ma (2σ), and 150 ± 11 Ma (2σ), which are consistent with zircon weighted mean U–Pb ages of 150.1 ± 2.0 Ma (2σ) and 150.5 ± 1.0 Ma (2σ) of the ore-related intrusion. Combined with previously published metallogenetic ages of skarn deposits in the Edong district, we suggest that the Lazhushan deposit may represent the initiation of Fe skarn mineralization for the Edong district during the Late Mesozoic. [ABSTRACT FROM AUTHOR]

[Display omitted] • Latest Oligocene–Miocene arc magmatism in central Oaxaca developed in a thick continental crust. • Early–mid-Miocene metallogenic epoch in southern Mexico comprises Au-Ag rich epithermal deposits. • Precious metal-rich intermediate-sulfidation epithermal deposits occur at Natividad. • Detailed vein stratigraphy reveals multi-episodic fluid pulses and interaction with wall rocks. • First formal report of argyrodite (Ag 8 GeS 6) in Mexico. The final magmatic arc—Miocene in age—of the long-lived Sierra Madre del Sur igneous province in southern Mexico hosts several epithermal deposits that have hitherto received little attention. The Natividad Au-Ag(-Ge) epithermal deposit is one of them and holds a mining record of > 200 years. Here, we present the first petrogenetic and metallogenic study on the Natividad deposit, in which we use a multi-methodological approach to assess the genesis and evolution of the deposit and its associated igneous rocks. Natividad is mostly hosted by Oligocene–Miocene arc-related dacites (U-Pb zircon dates of 22.8–24.7 Ma), whose geochemical features suggest lower-crustal differentiation (i.e., involvement of garnet) at the base of a thickened continental crust. The mineralization occurs in three multi-stage quartz + carbonate veins and consists of Fe-poor sphalerite (<5 mol. % FeS), galena, chalcopyrite, acanthite, and marcasite (sulfide-dominated stage) overprinted by pearceite-polybasite, pyrargyrite-proustite, tetrahedrite-group minerals, electrum, and argyrodite (Ag 8 GeS 6 ; Ag-sulfosalt-dominated stage). Geothermometry and fluid inclusion data for ore-bearing assemblages reveal fluid temperatures of 170°–400 °C and salinities of 14.6–19.5 wt% NaCl equiv. δ18O from 0.8 ‰ to 7.5 ‰ in mineralizing fluids suggests mixtures of magmatic brines and meteoric waters, while δ13C from –8.4 ‰ to 2.2 ‰ indicates the recycling of organic carbon from the meta -sedimentary basement. Further, δ34S from –3.2 ‰ to –0.3 ‰ in sulfides attest to magmatic S. These results align with an intermediate-sulfidation epithermal model, whereby upwelling magmatic ore-bearing brines precipitated the ores due to conductive cooling, dilution, and, locally, boiling. Our study highlights the metallogenic potential of Miocene magmatism in the eastern Sierra Madre de Sur. [ABSTRACT FROM AUTHOR]

[Display omitted] • Four phases of deformation are recorded with the D3 event closely related to gold. • SHRIMP zircon U-Pb dating of granite dikes yields ages of 216 ± 3.0 Ma to 210 ± 9.7 Ma. • Ar-Ar dating of gold-related muscovite gives a mineralization age of 210.9 ± 1.6 Ma. • The Yangshan mineral systems comprise epizonal orogenic gold deposits. The West Qinling Orogen in central China resulted from Late Devonian to Triassic collisional orogenesis involving accreted terranes along the southwestern margin of the North China Block with subsequent ocean closure and collision of the South China Block with those terranes. The Yangshan gold district, with a pre-mining resource of more than 308 t gold, is situated along the Mianlue Suture Zone on the southern margin of the orogen. The gold orebodies are mainly controlled by the ENE-trending Anchanghe-Guanyinba Fault and its subparallel second-order faults. The relatively low pressure–temperature mineralization is dominated by disseminated pyrite, arsenopyrite, and stibnite hosted in phyllite and granite dikes, accompanied by intense muscovite-silica-carbonate alteration. Four major phases of deformation related to collisional tectonics are recorded in the Yangshan gold district. Early N-S-oriented compressional deformation (D1) is characterized by an alignment of muscovite, overgrowths on framboidal pyrite, and quartz veinlets. D2 is characterized by a series of continuous ENE-trending reverse faults and folds at multiple scales related to SSE-NNW-oriented compression. D3 is related to gold mineralization and is characterized by a series of ENE-trending, largely normal faults, formed during transtensional tectonics. D4 post-dates gold mineralization and is associated with the development of nearly N-S-trending, low-displacement normal faults. New high-precision SHRIMP zircon U-Pb dating of three types of granite dikes in the Yangshan gold district yields broadly coincident ages of 216 ± 3.0 Ma to 210 ± 9.7 Ma, which is a range identical to that of existing dates of 217–211 Ma for more regional granite magmatism in this district. New Ar-Ar dating of gold-related muscovite gives an age of 210.9 ± 1.6 Ma for the Yangshan gold deposit, indicating that hydrothermal activity overlapped or post-dated the final stages of granite intrusion. Pre-226 Ma peak metamorphism of the ore-hosting rocks occurred prior to extensional ductile shear deformation that is constrained by a published 40Ar/39Ar muscovite cooling age of 223 ± 2 Ma. In good agreement, U-Pb constrained ages of retrograde metamorphism and associated late magmatism of around 215 Ma are reported for rocks along the Mianlue Suture Zone. These geological and geochronological data suggest that relatively shallow-level gold mineralization was broadly coeval with Late Triassic transtensional, orogen-parallel deformation along the regional-scale fault system, late in the tectonic evolution of the West Qinling Orogen. This is consistent with its classification as epizonal orogenic gold mineralization. [ABSTRACT FROM AUTHOR]

[Display omitted] • Magmatic and metamorphic columbite crystallized at 1359 ± 31 Ma, 346 ± 18 Ma and 284 ± 16 Ma, respectively. • The niobium in Bayan Obo is sourced from Mesoproterozoic carbonatite. • Local enrichment of niobium is attributed to the process of fenitization. • Nb and REE mineralization display spatial and temporal coupling in Bayan Obo deposit. The Bayan Obo deposit is world-famous for its giant rare earth reserves, and also accompanied with 2.2 Mt Nb 2 O 5 resources at an average grade of 0.13 %, renowned as the second largest Nb deposit globally. Previous studies have focused on the origin of carbonatite (igneous/sedimentary), and variation composition during evolution, as well as its super-enrichment of light rare earth elements (LREE), while the metallogenic mechanism of niobium is being overlooked despite the identification of plenty Nb-bearing minerals. In this study, we identify four types of columbite as major Nb-bearing minerals, instead of pyrochlore in the west pit of Bayan Obo. Detailed mineralogical study has revealed large primitive columbite (Clb1-I, 100–200 μm) is hosted in the coarse-grained Fe-dolomite carbonatite (FeO = 5.46–10.47 wt%), being an ideal target for future mineral beneficiation. Those columbites (Clb1-I) are featured by lowest Sr, Y, and ∑REE but enriched in iron in composition, revealing its magmatic origin. Sieve-textured columbite (Clb1-II, ∼100 μm) dispersed in the fluorination and chloritization dolomite carbonatite, with a U–Pb age of 1359 ± 31 Ma, contemporary with ages of the regional carbonatite magma intrusion and rift-related magmatism, indicating niobium being sourced from mantle-derived carbonatite. The occurrence of fluorite as inclusions in Clb1-I indicates the solubility of Nb was enhanced by fluxes, and the columbite saturation was easily achieved during the carbonatite magma evolution into ferroan carbonatite. Strong fenitization metasomatism further locally concentrated columbite either within the mineral assemblages of pyrite + phlogopite + allanite (Clb2) or in the mica-dominated fenite (Clb3), and crystallized at 346 ± 18 Ma and 284 ± 16 Ma, respectively. The latter metalogenetic epoch is accordant with late Permian granitic magmatism event (ca. 280 Ma) while the former age may attribute to its occurrences related to the early Paleozoic arc-continent collision. Differ from pristine columbite (Clb1-I and Clb1-II), the metamorphic columbite (Clb2 and Cl3, especially Clb3) are enriched in Ta (1803–4092 ppm), Y (560–2029 ppm) and ∑REE (720–6317 ppm) content, probably suggesting the highest degree of evolution. The similar metallogenesis framework between Nb and REE, combined with the coexistence of columbite and REE minerals assemblages, implies the spatial and temporal coupling of Nb and REE mineralization. This first innovative and systematic mineralogical and geochronological work directly constrains the nature of Mesoproterozoic mantle-derived carbonatite with fertile Fe and fluxes, and the Paleozoic and Permian fenitization metasomatism, are the major factors contribute to the metallogenic specialization of niobium in Bayan Obo. [ABSTRACT FROM AUTHOR]

[Display omitted] • This study is the first attempt of a systematic horizontal skarn profile in Beiya. • Two types of garnet have been distinguished in endoskarn and exoskarn. • The conditions and compositions of hydrothermal fluid in different environments vary. • The skarn mineralization age is restricted by crystallization age of garnet. Garnet is one of the most typical minerals in skarn deposits, and its texture and composition is a proxy for the changing physicochemical conditions. Thus, mineralogical and geochemical characterization of different garnet types can provide important information on the nature and evolution of ore-forming fluids. The Beiya gold-polymetallic deposit is China's largest skarn-type Au deposit with Au reserves of >380 t. Although several studies have addressed the skarn formation mechanism and nature of fluid evolution, a systematic study on the changes in the composition and texture of garnet from wall rocks to ore-related intrusion has not yet been attempted. In this work, we carry out a systematic investigation along a horizonal profile in the open pit of the Beiya deposit. Our results show that the garnet in the profile belongs to grossular-andradite solid solution series with all grains showing well-developed fine oscillatory zoning. The garnets are of two types: the first type (Grt I) formed within the endoskarn, is reddish to red with euhedral-subhedral megacryst structure (>10 mm) and has altered surfaces. The second type (Grt II) occur in the proximal exoskarn, is red to brown–red, euhedral-subhedral, with medium- to fine- grained structure (0.3–4 mm) and displaying oscillatory zoning. Unlike Grt I, hydrous minerals occur in the pores among Grt II garnets, such as calcite, quartz, epidote and chlorite. Also, calcite-chlorite vein, quartz vein and quartz-chalcopyrite-pyrite vein cuts the Grt II garnets. Grt I is dominantly grossular (Adr 14.88-43.58 Grs 55.25-82.87), depleted in the large ion lithophile elements (LILE), relatively enriched in high field strength elements (HFSEs) and enriched in heavy rare earth elements (HREEs) with negative Eu anomalies. Grt II is mostly andradite (Adr 62.18-98.91 Grs 0-36.22), depleted in the LILE and HFSE, enriched in light rare earth elements (LREEs) with slightly positive Eu anomalies. Here we selected Grt II for in-situ LA-ICP-MS U-Pb dating, since Grt I contains negligible uranium. The results yielded a lower intercept 206Pb/238U age of 35.3 ± 1.8 Ma (MSWD = 0.68, n = 23). The calculated oxygen isotopic compositions of hydrothermal fluids in equilibrium with two types of garnets range from 6.46 ‰ to 8.56 ‰ (average 7.89 ‰), which are within the range of values for magmatic fluids. We infer that the physicochemical conditions of the hydrothermal fluid changed from relatively reduced, nearly neutral, and low water/rock ratios to slightly oxidized, slightly acidic, and high water/rock ratios. The chlorine content in the fluid increased during garnet growth. The fluctuating compositions of garnets in the skarn suggest multistage ore-fluid activities and the fluid evolution provide insights into the ore-forming process. [ABSTRACT FROM AUTHOR]

Petrogenesis of the Gaozhuang granitic aplites (GZGA) plays an important role in understanding the regional tectonic evolution and metallogenesis of the Gaozhuang gold deposit (GZGD) in the northern Qinling orogenic belt (NQOB). Here, we present new zircon U–Pb dating on two granitic aplite samples yielding a 25‐zircon grain weighted average age of 129 ± 1 Ma (MSWD = 0.6), suggesting that GZGA formed in the Early Cretaceous. Major element results show that GZGA are: (a) characterized by higher SiO2 and alkali and lower MgO and CaO, belonging to the high‐K calc–alkaline series; (b) enriched in large‐ion lithophile elements and depleted in high‐field‐strength elements, which show negative spider–diagram anomalies of Nb, Ta, P, and Ti; (c) enriched in light rare earth elements and depleted in heavy rare earth elements without obvious Eu negative anomalies and (La/Yb) N ratios ranging from 71.9–107. GZGA compositional variation is controlled mainly by source composition and degree of partial melting and suggests no obvious relationship with fractional crystallization. GZGA samples belongs to the adakite, showing higher Sr (346–528 ppm), lower in Y (4.71–5.67 ppm) and Yb (0.26–0.33 ppm), and Sr/Y ratios of 63.5–93.2, indicating that GZGA originated from partial melting of the thickened lower crust (source depth >50 km) with residual phases of garnet, rutile, and insignificant plagioclase. Results find that GZGA is a product of the Early Cretaceous regional lithosphere delamination, in which Gaozhuang area adakitic aplite magmas and ore‐bearing fluids were discharged nearly simultaneously, and the mixed magma–fluid systems crystallized, forming GZGA and GZGD, while rapidly ascending to the shallow crust along faults. Using GZGA, a prospecting indicator, we infer that the deep part of the GZGD should possess endogenetic Au metallogenic potential. [ABSTRACT FROM AUTHOR]

[Display omitted] • A giant porphyry-skarn-epithermal Mo-W-Cu-Zn-Pb-Ag metallogenic system is recognized in the Nannihu ore field. • New geochronological data reveal that the porphyry-related metallogenic system formed in the Early Cretaceous (145–139 Ma). • The episodic magmatism and mineralization resulted in the remarkable enrichment of mineral resources at Nannihu. • The model of this porphyry-related metallogenic system has a significant implication for mineral prospecting in the area. The southern North China Craton owns substantial Mo, W, Zn, Pb, Cu, and Ag resources, and most of them are hosted in hydrothermal deposits that may co-exist in the same ore field. However, the relationship between the different types of deposits is not well-constrained. To better understand this, here we present a comprehensive geological, geochronological, and pyrite geochemical study on the Nannihu ore field in the Luanchuan district. The Nannihu ore field is largely represented by the Nannihu Mo-W deposit, Luotuoshan Zn-Cu-W deposit, and Lengshuibeigou Pb-Zn-Ag deposit. Mo-W mineralization at Nannihu occurs in the contact zone between the Nannihu intrusion and the wall rocks, showing typical characteristics of the porphyry-type deposit. Three paragenetic stages are recognized at Nannihu, including quartz-potassium feldspar stage, quartz-sulfide stage, and quartz-carbonate stage. The Zn-Cu-W orebodies at Luotuoshan are mainly layered or lens-like, occurring within the skarn zones in the Luanchuan Group. Skarn stage, polymetallic sulfide stage, and carbonate stage are revealed at Luotuoshan. Pb-Zn-Ag mineralization at Lengshuibeigou is characterized by banded sulfide veins that are hosted in the NNE-trending fault zone. Three paragenetic stages are developed at Lengshuibeigou: quartz-pyrite stage, quartz-polymetallic sulfide stage, and quartz-carbonate stage. New geochronological data confirm that the Nannihu intrusion was formed by at least two phases of magmatism including the granite porphyry (zircon U-Pb age of 145 ± 2 Ma) and the porphyritic monzogranite (zircon U-Pb ages of 142 ± 1 Ma and 140 ± 1 Ma), which accompanied by two episodes of Mo mineralization at the Nannihu deposit identified by molybdenite Re-Os dating (144.9 ± 0.7 Ma and 142.8 ± 0.6 Ma). The Luotuoshan deposit and Lengshuibeigou deposit formed at 141 ± 1 Ma to 140 ± 1 Ma and 140 ± 3 Ma to 139 ± 3 Ma revealed by U-Pb dating of garnet and monazite, respectively, which are contemporaneous with the late episode of the Nannihu intrusion and Mo mineralization. Pyrite grains of the three deposits have Co/Ni ratios higher than 1, suggesting a unified magmatic-hydrothermal origin for them. Pyrite from Nannihu and Luotuoshan is enriched in Co, Ni, Se, Mo, Mn, and Bi, whereas pyrite from Lengshuibeigou contains high Zn, Pb, As, Cu, Ag, and Au. The regular elemental distribution of pyrite in the Nannihu ore field is consistent with that of typical porphyry-related systems worldwide. Collectively, the Early Cretaceous magmatic rocks and diverse deposits in the Nannihu ore field make up a giant magmatic-hydrothermal Mo-W-Cu-Zn-Pb-Ag metallogenic system, with the porphyry, skarn, and epithermal types of mineralization displaying a zonation from inside to outside. The multi-episode magmatism and mineralization could result in the remarkable enrichment of mineral resources. The close spatial relationship among different types of mineralization in the Nannihu ore field has a significant implication for porphyry-related mineral prospecting in the southern NCC. [ABSTRACT FROM AUTHOR]

[Display omitted] • Two episodes of garnet and Fe mineralization were identified at Jia'erbasidao Fe deposit. • The 1st garnet generation was formed at 270.6 Ma and skarn related. • The 2nd garnet generation was formed at 248.3–246.0 Ma and skarn related. Over a hundred iron ore occurrences have been discovered in the Chinese Altay Orogenic Belt (AOB), which is a key Fe-ore belt in NW China. In the Jia'erbasidao ore district, Fe skarn mineralization was mainly developed along the contact zone between biotite granite and the marble of Altay Formation, which is different from most Fe mineralization (non-skarn contact zone) in the Chinese AOB. Two generations of garnet (Grt1and Grt2) have been identified to be related to the two stages of Fe-ore formation at Jia'erbasidao, and Grt1 and Grt2 can be further divided into Grt1a, 1b and Grt2a, 2b, respectively. Our U-Pb dating indicates that the biotite granite and garnet from prograde skarn stage 1 (Grt1a) were formed at 275.6 ± 3.1 Ma and 270.6 ± 4.4 Ma, respectively. The mineralized biotite granite is metaluminous to peraluminous, LREE-enriched and HREE-depleted. Meanwhile, two Grt2a samples from the prograde skarn stage 2 yielded lower intercept 206Pb/238U ages of 248.3 ± 2.9 Ma and 246.0 ± 6.0 Ma, respectively. Grt1 and Grt2 may have formed from different ore-forming fluids: Grt1a was precipitated from a LREE-depleted, near neutral and low f O 2 fluid (δEu = 1.92–2.84); Grt1b and magnetite (Mag1) were precipitated from the same fluid with higher f O 2 (δEu = mostly 1.22–2.63); Grt2a was precipitated from a fluid with relative LREE enrichment, relatively lower pH and higher f O 2 (δEu = 0.98–1.69); Grt2b and magnetite (Mag2) was formed from a fluid that was HREE-enriched, near neutral, and higher f O 2 (δEu = 0.76–1.09). Our study shows a two-stage Fe mineralization at Ja'erbasidao, including the Early Permian Fe skarn mineralization and the Early Triassic skarn mineralization. [ABSTRACT FROM AUTHOR]

[Display omitted] • Zircon U-Pb dating results refine the emplacement age of the Xikeng pluton at 232.2 ± 1.1 Ma. • Cassiterite and wolframite U-Pb dating constrains the timing of W-Sn mineralization from Xigkeng deposit at 228.4 ± 0.90 Ma and 227.8 ± 1.60 Ma, respectively. • Source of magmatic materials was derived from reworking of crustal materials under an extensional setting. The Chongyi–Shangyou–Dayu ore-concentrated district represents one of the most important wolframite production bases in China, and most of the W-Sn deposits formed in the early Yanshanian period. The Xikeng quartz vein-type W-Sn deposit is located spatially not far from the Triassic Keshuling granitic pluton. The deposit contains 43 ore-bearing quartz veins, in which the ore minerals are mainly cassiterite and wolframite. These ore veins are concentrated in the Sinian metasandstone and sandy slate of the Laohutang Formation and extend down to the top of the concealed granite. The concealed intrusion is composed of medium- to fine-grained muscovite granites, which relate to the Indosinian Keshuling granite, according to geophysical data. Zircon grains from the concealed Xikeng granitic intrusion have a concordant U-Pb age of 232.1 ± 1.1 Ma (MSWD = 0.9). The zircon εHf(t) values range from −11.0 to −7.9, indicating primary reworking of the ancient crustal materials. Wolframite and cassiterite grains yield Tera-Wasserburg concordia intercept ages of 228.4 ± 0.9 Ma (MSWD = 1.2) and 227.8 ± 1.6 Ma (MSWD = 0.3) for the Xikeng deposit, respectively. These data demonstrate that the Indosinian W-Sn mineralization events were genetically related to granitic magma activities that share similar magmatic sources with the Yanshanian W-Sn mineralization-associated granitic intrusions. Combined with previous robust granitic and metallogenic ages, this paper identifies a new Indosinian W-Sn mineralization event in southern Jiangxi Province, Nanling Range. [ABSTRACT FROM AUTHOR]

[Display omitted] • Hydrothermal rutile formed in a magmatic-hydrothermal system. • Dashuigou Te-Bi deposit formed at the Oligocene (32.4 ± 3 Ma). • Te-Bi mineralization related to the Eocene-Oligocene alkaline magmatism. The Dashuigou deposit, located in the transitional zone between the Yangtze craton to the east and the Songpan-Ganze orogen to the west, is the world's only known deposit where tellurium and bismuth are exploited as primary products. The Te-Bi orebodies mainly occur as the dolomite-tetradymite and Te-bearing pyrrhotite veins in Triassic low-grade metamorphic rocks. The ore minerals mainly consist of tetradymite, tsumoite, tellurobismuthite, pyrrhotite, and chalcopyrite. While mineralogy and geochemistry of the ores in the Dashuigou deposit have been well documented in the past decades, the age of the Te-Bi mineralization in the Dashuigou district is not well defined due to lack of both suitable dating mineral and chronometer, and thereby impedes further understanding on its ore genesis. Hydrothermal rutile coeval with tetradymite has been identified in this study from a high-grade dolomite-tetradymite vein in the Dashuigou deposit. This rutile is closely associated with tetradymite, tsumoite, Te-bearing pyrrhotite, and contains many tiny tetradymite inclusions. Here, we present the first in situ trace element compositions and U-Pb age of these rutile crystals using laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS). The rutile is enriched in V, Nb, Ta, Sn, and Cr, but has low contents of As, Sb, and W, indicating a magmatic origin. U-Pb dating on rutile demonstrates a well-constrained age of 32.4 ± 3 Ma, which is interpreted as the timing of Te-Bi mineralization for the Dashuigou deposit. This new age provides the first evidence suggesting that the Dashuigou deposit is contemporary with regional Eocene-Oligocene alkaline magmatism and related metallogenic event in Sanjiang region. Compared with the Beiya Te-Bi-bearing porphyry Cu-Au and Yao'an Au deposits in the alkaline magmatic belt, we propose that the Dashuigou Te-Bi deposit was likely product of a concealed alkaline magmatic-hydrothermal system. This study also demonstrates the rutile U-Pb geochronology being a powerful tool for dating unusual ore systems. [ABSTRACT FROM AUTHOR]

[Display omitted] • Precise geochronology define the magmatism and mineralization age. • The Late Triassic weakly Mo mineralization and Late Jurassic Ag–Pb–Zn mineralization. • The in situ Sulfur isotope data herein confirm the sulfur was mainly derived from a magmatic source. The large-scale Meng'entaolegai Ag–Pb–Zn polymetallic deposit is located in the Great Hinggan Range metallogenic belt, northeastern China. To better understand the formation of the Meng'entaolegai deposit, we present in situ S isotope data, zircon U–Pb isotope data, sulfide Rb–Sr data, and molybdenite Re–Os data for the units associated with the deposit and surrounding regions. In situ analyses show that the δ34S values of the sulfides (galena, sphalerite, and pyrite) vary from + 2.4‰ to + 6.6‰ (mean = +4.7‰, n = 60). The data herein confirm that the sulfur was mainly derived from a magmatic source. Zircon U–Pb dating of the medium- to coarse-grained monzogranite, plagiogranite, and fine-grained monzogranite from the Duerji batholiths and granodiorite and monzogranite from the Meng'entaolegai deposit yield weighted mean ages of 244.3 ± 1.7, 243.0 ± 2.1, 151.8 ± 1.5, 232.6 ± 2.2, and 223.1 ± 2.3 Ma, respectively. The Meng'entaolegai deposit yields a molybdenite Re–Os age of 229.5 ± 1.5 Ma, but sulfide Rb–Sr dating yields an isochron age of 147.2 ± 2.3 Ma. These new age data have revealed that the Meng'entaolegai polymetallic deposit formed during two mineralization episodes: an early episode at 230 Ma and a second episode at 147 Ma. The Late Triassic hydrothermal activity and weakly Mo mineralization formed in an extensional setting after the final closure of the Palaeo-Asian Ocean. The Late Jurassic hydrothermal activity and Ag–Pb–Zn mineralization formed in an extensional environment related to the Mongol–Okhotsk Ocean, but these exposed granitic rocks are unlikely to be related to the Ag–Pb–Zn mineralization, suggesting that more research is needed on the magmatic hydrothermal activity within the study area. [ABSTRACT FROM AUTHOR]

[Display omitted] • Three stages of W-Sn mineralization in the Xitian Ore Field have been identified. • Triassic skarn-type mineralization occurred in a relatively closed metallogenic system. • Jurassic quartz vein-type mineralization occurred in an open system with addition of meteoric water. • Deeply buried Early Cretaceous magmatic-hydrothermal deposits may exist in the Xitian Ore Field. • Evolution from skarn-type to vein-type mineralization was related to tectonic environment changing. The Nanling Metallogenic Belt is a major W-Sn province in South China containing numerous ore deposits formed during a complex history of magma emplacement and mineralization. The Xitian ore field in Hunan Province is a typical example of a late magmatic-metallogenic system. In this study, garnets from skarn-type ores in the Xitian ore field yield a U-Pb age of 231.7 ± 1.3 Ma (n = 33), whereas cassiterite grains from quartz vein-type ores give U-Pb ages of 158 to 154 Ma (n = 72) and 140.7 ± 3.3 Ma (n = 6), suggesting three stages of W-Sn mineralization (Late Triassic, Late Jurassic, and Early Cretaceous). In the Late Triassic skarn-type ores, the REE patterns of scheelite change from MREE-enriched to LREE-enriched with time, whereas the REE patterns of scheelite shift from MREE-enriched to MREE-depleted in the Late Jurassic quartz vein-type ores, indicating diverse metallogenic processes. Differences in the Y/Ho ratios and Sr-O isotope compositions of scheelite further confirm discrete metallogenic pathways for the Late Triassic skarn-type W ore and the Late Jurassic quartz vein-type ore, with fluid-rock interaction of the former dominated by magmatic-hydrothermal fluids whereas the latter was influenced by large amounts of meteoric water. A model emphasizing the evolution from skarn-type to vein-type metallogeny is proposed to account for the complex genesis of multistage W–Sn deposits related to the Xitian granite complex. More generally, this study demonstrates that in-situ LA-ICP(MC)-MS U-Pb dating and isotopic analysis of hydrothermal minerals are powerful tools to decipher the nature, timing, and evolution of multistage W-Sn metallogenic systems. [ABSTRACT FROM AUTHOR]

[Display omitted] • U-Pb dating of syn -ore monazite and xenotime constrains the Xiayu Ag-Pb-Zn-Au(-Cu) mineralization age to be 125.7±1.8 Ma to 123.3±1.7 Ma. • Detailed geological characteristics indicate there are genetic connections among granite porphyry, breccia pipe, and steeply-dipping Ag-Pb-Zn-Au(-Cu) veins. • The Xiayu Ag-Pb-Zn-Au(-Cu) mineralization is the first recognized intermediate-sulfidation epithermal deposit in the world-class East Qinling porphyry Mo ore belt. Porphyry Cu deposits are often temporal-spatial-genetically associated with epithermal polymetallic (Ag-Pb-Zn-Au-Cu) veins in some important metallogenic belts, forming a porphyry–epithermal ore systems. However, the genetic type of the large-scale vein-type Ag, Pb, Zn and Au mineralization in the world-class East Qinling porphyry Mo ore belt (Central China) has not been delineated. Here, we provide a case study of the Xiayu orefield as an example for a typical intermediate-sulfidation epithermal Ag-Pb-Zn-Au(-Cu) deposit. The Xiayu Ag-Pb-Zn-Au(-Cu) orefield, the largest Ag producer in the East Qinling ore belt, contains the Haopinggou Ag-Pb-Zn-Au, Shagou Ag-Pb-Zn, Tieluping Ag-Pb(-Cu), and Houzhanggou Ag(-Cu) deposits, which share similar geological characteristics. The Ag-Pb-Zn-Au(-Cu) mineralization occurs as open-space fillings, veins and local hydrothermal breccias and stockworks, infilled with carbonates (siderite, ankerite, and calcite), quartz, pyrite, sphalerite, galena, chalcopyrite, tetrahedrite, electrum, silver minerals (argentiferous tetrahedrite, stromeyerite, pyrargyrite, polybasite, argentite and native silver). The vein crosscutting and overprinting relationships indicate four hydrothermal stages: (I) siderite-pyrite-quartz-electrum ± magnetite, (II) dark-brown sphalerite-siderite-quartz ± galena, (III) galena-tetrahedrite-chalcopyrite-silver minerals-ankerite-quartz ± light-brown sphalerite, and (IV) ankerite-calcite-chalcedony-fluorite. Mineral zoning at the orefield-scale is recognized from north to south: pyrite, sphalerite-galena, and tetrahedrite-native silver, which corresponds to ore metal zoning from Au ± Zn to Zn-Pb-Ag and Cu-Ag. The Haopinggou granite porphyry consists of the megacrystic granite porphyry (P1) and granite porphyry (P2), which were emplaced at 134.6±1.2 Ma and 125.9±0.7 Ma, respectively. Anhedral monazite (Mon1) encapsulated in pyrite and siderite from stage I of the Haopinggou and Shagou deposits constrains the early hydrothermal activity at 133.3±1.0 Ma. U-Pb dating of syn -ore monazite (Mon2) and xenotime (intergrown with electrum, galena, sphalerite and quartz) from the Shagou, Haopinggou, and Tieluping deposits constrains the Ag-Pb-Zn-Au(-Cu) mineralization age to be 125.7±1.8 Ma to 123.3±1.7 Ma. The consistency of the magmatic and mineralization ages indicates that the magmatic-hydrothermal process may have played an important role in the Ag-Pb-Zn-Au(-Cu) mineralization. Gold distribution, mineral association, and geochronological data, all suggest that the Au and Zn-Pb-Ag ores were formed from the same mineralization event rather than two discrete mineralization events as previously suggested. Considering the geological characteristics, metal zoning, mineralization ages, mineral chemical composition and published data of fluid inclusion, we conclude that the Xiayu Ag-Pb-Zn-Au(-Cu) veins belong to typical intermediate-sulfidation epithermal mineralization and further propose a porphyry–breccia–intermediate-sulfidation epithermal Ag-Pb-Zn-Au(-Cu) mineralization system. It is the first reported intermediate-sulfidation epithermal mineralization in the East Qinling ore belt, which implies that the epithermal mineralization may have been developed in the world-class East Qinling porphyry Mo ore belt. [ABSTRACT FROM AUTHOR]

[Display omitted] • The geochronology of apatites can help constrained their origin. • The geochemistry of apatites can be used to indicate magmatic-hydrothermal evolution and tectonic background. • Apatites can record information of ore-forming processes. Apatite is a common accessory phase in magmatic rocks and associated hydrothermal deposits that holds information about the evolution from magma to ore-forming fluid. In this study, we systematically studied the geochronological and geochemical characteristics of apatites hosted in the Fe skarn ores and associated intrusions of syenogranite and monzogranite in the Hutouya polymetallic Fe–Cu–Pb–Zn ore district, Qiman Tagh Metallogenic Belt (QTMB), NW China, in order to gain insight into the metallogenic processes from magmatic crystallization to hydrothermal fluid exsolution. The apatite U–Pb dating results of skarns and related intrusions are 229–228 Ma, and the monzogranite emplacement is slightly later than the syenogranite emplacement and skarn formation. The REE concentrations of the apatites from the skarn-related intrusions are characterized by LREE-enriched patterns and weak negative Eu anomalies. However, the apatites from the skarn ores have high HREE contents, and are characterized by flat chondrite-normalized patterns and strong negative Eu anomalies. These data, combined with variations of element concentrations and ratios in the apatites (eg., Sr, SO 3 , F, Cl, REE, (La/Yb) N , (Sm/Nd) N , (La/Sm) N , (Eu/Eu*) N , (Ce/Ce*) N), record the transition of ore-forming processes from the magmatic crystallization to hydrothermal exsolution, and indicate that the skarn-related magmas with moderately reduced signatures may have been derived from partial melting of crustal materials potentially affected by the limited mantle input under an extensional environment. [ABSTRACT FROM AUTHOR]

[Display omitted] • A four-stage post-Paleozoic cooling history of the Tianyu Cu-Ni ore deposits. • The deformation history of the eastern Central Tianshan during the Mesozoic-Cenozoic. • The post-mineralization exhumation is vital for exposing deep metallogenic systems. The Chinese Eastern Tianshan is an important metallogenic region where major Cu-Ni ores are mined. Previous research in the region primarily focused on the ore genesis. Precise thermochronological data to constrain the exhumation history and preservation of the ore deposits are limited at best. Tianyu is one of these Cu-Ni deposits in the area. Here we present new low-temperature thermochronological data to contribute to the understanding of its exhumation and preservation history. Zircon (U-Th)/He ages of ∼ 134–69 Ma, apatite fission track ages of ∼ 100–75 Ma, and apatite (U-Th)/He ages of ∼ 117–38 Ma from five granodiorite samples of the ore wall rock at different depths of a borehole in the Tianyu deposit were obtained. Our thermochronological data and inverse thermal history modeling reveal a moderate to rapid and final basement cooling phase during the Cretaceous (∼115–85 Ma) with an averaged cooling rate of ∼ 3–4 ℃/Ma. It is envisaged that this phase eventually exposed the ore deposits and that posterior erosion was limited, contributing to the preservation of the deposit. Combined with previously published geochronological and thermochronological data, a multi-stage cooling history of the ore bearing host rocks can be established. After its late Permian (∼280–260 Ma) magmatic-hydrothermal formation, two phases of accelerated regional cooling (i.e., in the late Permian-Early Triassic, ∼260–240 Ma; and the mid-Cretaceous, ∼115–85 Ma) can be recognized. The more intense Cretaceous cooling is associated with the ore body finally being exhumed to the surface, and provides essential information for ore exploration in the region. Further, we propose that areas in the Eastern Tianshan with similar thermal histories to the Tianyu Cu-Ni deposit may be potential exploration targets. [ABSTRACT FROM AUTHOR]

[Display omitted] • The Huanggangliang mineralization may have formed from magmatic-hydrothermal fluids. • U-Pb dating of zircon, cassiterite and garnet provide constraining on the deposit initiations. • The physicochemical conditions of hydrothermal fluids for Huanggangliang deposit cassiterite were constrained. • Cassiterite as a speciation mineral to determine the genesis of tin polymetallic deposits. The Huanggangliang Fe-Sn deposit is located in the southern Da Hinggan Range (NE China), and it's one of the most important deposits within the Huanggangliang-Ganzhuermiao Sn polymetallic metallogenic belt. Nearly 90% of the orebodies (stratiform/lenticular) at Huanggangliang are hosted in the Lower Permian andesite or marble. Three ore deposit types were proposed, including: 1) stratabound skarn-type (Yanshanian); 2) exhalative sedimentary (SEDEX)-type (Hercynian); and 3) SEDEX (Hercynian) - hydrothermal (Yanshanian) superimposing-type. Two generations of cassiterite (Cst-1 and Cst-2) were identified based on their microscopic features and CL images: Cst-1 is dark brown with distinct banded texture (euhedral-subhedral), whilst Cst-2 is light brown in color and cut Cst-1 (as veins) or distributed on the Cst-1 margin. They are both replaced by chlorite and quartz. The Huanggangliang cassiterite has relatively high Fe (median 4828 ppm) and W (median 273 ppm), but low Nb 2 O 5 (<0.08 wt%) and Ta 2 O 5 (<0.09 wt%) contents, distinct from SEDEX-type cassiterite but similar to granite-related cassiterite. Cst-1 has higher Fe-W-U contents than Cst-2, which reflects that Cst-1 was formed under relatively high temperature. Meanwhile, Cst-2 is relatively HFSEs-enriched, suggesting that the metallogenic environment had become more acidic. The cassiterite, zircon and garnet samples were U–Pb dated to be 137.10 ± 3.65 Ma, 138.45 ± 0.45 Ma, and 136.03 ± 1.22 Ma, respectively. Considering the Huanggangliang geology, cassiterite geochemistry and published ages from Sn-polymetallic deposits in the southern Da Hinggan Range, we suggest that the regional Sn mineralization occurred mainly in 139–134 Ma, and that the Huanggangliang deposit is best classified as skarn-type, closely related to Yanshanian magmatic-hydrothermal activity. [ABSTRACT FROM AUTHOR]

[Display omitted] • The Songshan tin deposit occurred at the end of Late Cretaceous, not in Triassic as previous suggested. • The end of Late Cretaceous is another important tin metallogenic period in the Lancangjiang tin belt. • The tin mineralization not only can occur in the magmatic arc, but also in the hinterland behind the magmatic arc. The Songshan tin deposit is located in the northern Lincang granitic batholith along the Lancangjiang tin belt, Western Yunnan, southwestern China. The ore bodies mainly occur as tourmaline-quartz veins with NNE- and/or NW-trending in the Triassic Pinghejie granitic pluton, and the schist of the Proterozoic Songshan Formation. The previous study suggested the tin mineralization in the Songshan deposit should occur in the Triassic, but no directed age data support it. This hinders the understanding of the genesis of the Songshan tin deposit, especially the tin mineralization in the Lancangjiang tin belt. Here, we report the zircons U-Pb ages of 222.7 ± 1.6 and 222.0 ± 2.4 Ma for the granodiorite, 215.1 ± 1.5 and 223.0 ± 2.0 Ma for the biotite monzogranite, and 222.3 ± 2.3 Ma for the alter granite from the Pinghejie granitic pluton. The monazite from the monzogranite yields a U-Pb age of 212.8 ± 1.9 Ma. We also obtain two garnet U-Pb ages of 215.1 ± 8.7 Ma and 213.5 ± 7.2 Ma from skarn, and two cassiterite U-Pb ages of 76.6 ± 1.5 Ma and 79.6 ± 3.6 Ma from tin ores. These data suggest that tin mineralization in the Songshan deposit occurred at the end of Late Cretaceous, which is quite different from the ages of the Pinghejie granitic pluton emplaced and the formation of skarn. The zircon Hf isotopes (εHf(t) = –22 ∼ -12) and monazite Nd isotopes (εNd(t) = -13.04 ∼ -11.80) indicate that the Pinghejie granitic pluton was derived from the remelting of Paleoproterozoic crust. The paper concluded that the tin mineralization in the Songshan deposit occurred at the end of Late Cretaceous. It is another important metallogenic period in the Lancangjiang tin belt, which may be related to the subduction of the NeoTethys oceanic crust. The tin mineralization can not only occur in the magmatic arc, but also in the hinterland behind the magmatic arc. [ABSTRACT FROM AUTHOR]

[Display omitted] • Here we characterize the geology and mineralization of the Sangri porphyry-skarn Cu-Mo deposit. • Zircon and garnet U-Pb, molybdenite Re-Os and K-feldspar Ar-Ar geochronology link magmatism, mineralization and alteration. • The Multi-isotopic dating could help to construct the defined time-framework of porphyry system. Obtaining a precise time framework has been a key but difficult problem for the study of metallogenic porphyry systems. This is more complicated when there are several stages of intrusion emplacement, different alterations, and mineralization events. To solve this problem, the Sangri porphyry-skarn Cu-Mo deposit in the Bangongco-Nujiang metallogenic belt, Tibet, was used as a study site for multiple isotopic dating studies. Zircon U-Pb dating of different intrusions shows that the magmatism of intermediate-felsic intrusions dates from 83.2 ± 0.8 Ma to 81.7 ± 0.7 Ma. Garnet U-Pb dating places the skarn as being formed in 83.2 ± 2.3 Ma. Re-Os dating of molybdenite in quartz-molybdenite vein and Ar-Ar dating of K-feldspar indicate ore-forming and alteration periods of 82.6 ± 0.6 Ma and 80.3 ± 1.8 Ma, respectively. The Sangri deposit is a product of magmatic-hydrothermal mineralization between 84 and 80 Ma in the Late Cretaceous. The mineralization of the Sangri deposit and precise geochronology data indicate that there was a Late Cretaceous metallogenic event in the Central Bangongco-Nujiang metallogenic belt, which provides a new clue for regional exploration and metallogeny. Finally, multi-element isotopic dating is shown to be an important method for constructing the time framework of porphyry systems. [ABSTRACT FROM AUTHOR]

[Display omitted] • Ages of W ores by wolframite U-Pb dating in Jinzhuping, Changkeng, Keshuling, Taoxikeng and Bikeng deposits, southern Jiangxi, are 154.2 ± 4.1 Ma, 157.8 ± 9.4 Ma, 150.3 ± 1.8 Ma, 153.8 ± 4.0 Ma and 152.3 ± 5.6 Ma, respectively. • Three stages of W mineralization occurred from the Triassic to the Lower Cretaceous in the Nanling Range of South China. In situ LA-ICP-MS provide high-resolution spatial analysis of wolframite grains. In this paper, wolframite U-Pb isotope dating is presented to directly constrain the timing of W mineralization in five granite-related vein-type W-polymetallic deposits from different ore-concentrated areas in southern Jiangxi Province, South China. In the Jinzhuping, Changkeng, Keshuling, Taoxikeng, and Bikeng deposits, wolframite is the dominant ore mineral, occurring as coarse, euhedral grains that are associated with gangue minerals such as cassiterite, scheelite, molybdenite, sphalerite, (±) galena, (±) marmatite, pyrite, quartz, (±) chlorite, (±) fluorite, and calcite. Wolframite U-Pb dating yielded 206Pb/238U ages of 154.2 ± 4.1 Ma for the Jinzhuping deposit, 157.8 ± 9.4 Ma for the Changkeng deposit, 150.3 ± 1.8 Ma for the Keshuling deposit, 153.8 ± 4.0 Ma for the Taoxikeng deposit, and 152.3 ± 5.6 Ma for the Bikeng deposit, respectively. By comparing the published minerlizing ages of the W-Sn polymetallic deposits in the Nanling region, we suggest that three stages of W mineralization occurred from the Triassic to the Lower Cretaceous. [ABSTRACT FROM AUTHOR]

[Display omitted] • LA-ICP-MS monazites analysis confirms the emplacement of two-mica monzogranites occurred in ∼ 221.7–218.2 Ma. • W mineralization in Zanshi shows accordant mineralization age of ∼ 218.7–215.1 Ma. • A new Late Triassic W mineralization and magmatism are recognized. • the cooling rate of the ore-forming hydrothermal system may be a key controlling factor of ore grade. The Nanling metallogenic belt is rich in critical metal minerals, e.g., tungsten, tin, and rare earth element (REE). The newly discovered Zanshi tungsten deposit, located at the northeastern part of the Nanling metallogenic belt, has drawn great attention from geologists for its rare Triassic magmatic-hydrothermal event in this region. Based on detailed field work, a series of geochemical and geochronological analyses, including whole-rock geochemical analyses consisting of major and trace elements, LA-ICP-MS monazite U-Pb dating of the granites and quartz Rb-Sr and muscovite 40Ar-39Ar isotopic dating of the ore-bearing quartz veins, were carried out in this study, aiming to constrain the rock- and ore-forming ages of the deposit as well as the petrogenesis of granites. The whole-rock geochemical analyses, the medium to fine-grained two-mica monzonitic granites in the Zanshi tungsten deposit are peraluminous S-type granites and derived from the partial melting of metamorphic graywackes in a post-collisional extensional tectonic setting. The LA-ICP-MS monazite U-Pb dating on the two medium- to fine-grained two-mica monzonitic granite samples yields weighted average ages of 218.2 ± 1.2 Ma (MSWD = 1.3) and 221.7 ± 1.7 Ma (MSWD = 2.7), respectively. These ages are consistent with the quartz Rb-Sr and muscovite 40Ar-39Ar isotopic ages of the ore-bearing quartz veins, which are 218.7 ± 3.2 Ma and 215.1 ± 2.0 Ma, respectively, revealing that the tungsten mineralization in this deposit is related to the Triassic magmatic-hydrothermal activity. Combined with previous studies, the Zanshi tungsten deposit likely experienced about 5 M.y. of magmatic evolution and 3.6 M.y. of mineralization. Meanwhile, the cooling rate of the ore-forming fluids of this deposit was about 111 °C/M.y., which may be regarded as a controlling factor which affects the ore grade of the deposit. [ABSTRACT FROM AUTHOR]

The Jinchanghe Fe-Cu-Pb-Zn polymetallic deposit is located in the northern Baoshan block in the Sanjiang metallogenic belt, southwestern China, and is one of the major large-scale Pb-Zn polymetallic deposits. This region is characterized by numerous diabase intrusions; however, research work is limited. This study elucidated systematic geochemistry and chronology of the diabase closely associated with orebodies in Jinchanghe to provide constraints for magma evolution. The results indicated that the Jinchanghe diabase was enriched in CaO, MgO, and Al2O3 and depleted in TiO2 and P2O5. Large ion lithophile elements were depleted, while for high field strength elements, the ratio of LREEs but depleted in HREEs. The zircon U-Pb dating results suggested that the diabase age could be divided into two stages, indicating the occurrence of two-stage tectonic-magmatic events in the Late Triassic and Early Cretaceous. The results also suggested that the metallogenic age of the Jinchanghe deposit is the Early Cretaceous. Moreover, the age was closely related to the collision after the closure of the mid-Tethys Ocean in the Early Cretaceous. Therefore, the results of this study provide new evidence for the tectonic-magmatic evolution and mineralization of the Baoshan block. [ABSTRACT FROM AUTHOR]

The Bawang deposit, located in the west of Wuxu ore field, southern section of the Nandan-Hechi metallogenic belt, is a medium-sized tin–zinc polymetallic deposit. Its genesis has been a matter of debate because of lacking constraints from isotope geology. In this study, LA-MC-ICP-MS U-Pb dating of cassiterite and C-O-S-Pb isotope analyses of monominerals were used to investigate the mineralization age and source of the ore-forming minerals in the Bawang deposit. LA-ICP-MS U–Pb dating of cassiterite yielded ages of 93.1 ± 4.8 Ma and 85.3 ± 6.3 Ma, indicating that the mineralization occurred in the early Late Cretaceous. The δ13CPDB and δ18OSMOW values of calcites at the ore stage range between −0.41‰ and 0.44‰ (average = −11‰) and between 13.8‰ and 15.40‰ (average = 14.59‰), respectively. This shows that ore fluid sources were a mixture of those derived from magma and stratum. Pyrite and sphalerite have uniform δ34S values (−4.45‰~−2.20‰), indicating that sulfur is also derived from the mixing of magmatic hydrothermal and stratum fluids. The Pb isotopic composition of sulfide (206Pb/204Pb = 18.4055~18.7625, 207Pb/204Pb = 15.6745~15.7209, 208Pb/204Pb = 38.6232~39.0370) is consistent with the granite of the same age, indicating that ore-forming metals are mainly derived from magmatic hydrothermal solution. The Bawang deposit is a hydrothermal vein-type deposit in the external contact zone of Late Cretaceous granite, controlled by tectonic fractures, and formed by the interaction of magmatic hydrothermal fluid and carbonate rock. There may be large skarn-type ore bodies in the deep part. The results of this study provide insights into the research and exploration of similar deposits in Nandan-Hechi metallogenic belt and in the Youjiang Basin. [ABSTRACT FROM AUTHOR]

[Display omitted] • Late Cretaceous-Paleogene thermochronological signals revealed in the East Qinling Orogen. • Two rapid cooling (125–100; 73–50 Ma) and one slow cooling stages in between are identified. • More than 1 km metallogenic depth preserved for mineral exploration in the Yumugou deposit. As a result of the continued depletion of shallow ore resources, there has been renewed focus on the tectonic preservation of mineralized systems. Specifically, it is vital to constrain the post-mineralization exhumation and preservation history of existing economic deposits, in order to identify new regions suitable for mineral exploration. In this study, we present results from apatite U-Pb, fission-track and (U-Th-Sm)/He thermochronological and associated thermal history modeling studies on the Yumugou Mo-W deposit within the world-class East Qinling Mo polymetallic metallogenic belt, central China. Our major aim is to constrain the exhumation history and to evaluate preservation potential of the Yumugou Mo-W deposit, and provide related guidance for mineral exploration in the East Qinling Orogen. Apatite U-Pb dating yield Early Cretaceous lower intercept Terra-Wasserburg ages in the range of 153–141 Ma, interpreted as crystallization age of apatite, coeval with the formation of Yumugou deposit (ca. 145 Ma). Integrated apatite fission-track and apatite (U-Th-Sm)/He dating give ages varying from Late Cretaceous to Early Paleogene, representing the post-mineralization cooling ages. We also integrate these age data with confined fission-track length measurements and geological constraints from previous studies into the thermal history models, the resulting models suggest three cooling pulses: 1) a phase of Early Cretaceous (125–100 Ma) rapid cooling, followed by 2) a phase of Late Cretaceous (100–73 Ma) slow cooling, before finally, 3) a phase of Late Cretaceous to Paleogene (73–50 Ma) rapid cooling. The Early Cretaceous rapid cooling pulse correlates temporally with extension tectonic setting in the East Qinling Orogen, the magma emplacement and post-magmatic rapid cooling at ca. 160–130 Ma in the Luanchuan region might cause related exhumation at ca. 125–100 Ma to upper crustal temperatures. The Late Cretaceous slow cooling possibly corresponds to regionally slow extensive erosion in response to crustal shortening triggered by the westward subduction of the Paleo-Pacific Plate at this time. The Late Cretaceous-Paleogene rapid cooling likely result from the major far-field effects of the Pacific Plate subduction and the sinistral strike-slip motion of the Tan-Lu Fault Zone, as well as possible minor expansion effects derived by the Paleogene India-Eurasia collision. Moreover, we adopt thermal history modeling method to determine cooling rate, exhumation rate and depth of different cooling stages. In comparison with the calculated exhumation depth (∼5.6 km) and previously reported metallogenic depth (3–7 km) in the Luanchuan ore cluster, we infer that more than one kilometer metallogenic depth is theoretically preserved in the Yumugou Mo-W deposit. Combined the similar metallogenic setting and features with other giant Mo deposits in the East Qinling Orogen, we further suggest that the Mo deposits in this orogen possibly have underwent a similar degree of exhumation and show good prospecting potential. [ABSTRACT FROM AUTHOR]

[Display omitted] • Summaries of Mesozoic intrusions and related Cu-Au deposits in Tongling, eastern China. • Tongling region experienced two stages of magmatic activities corresponding to compressional and extensional settings. • Two stages of magmatism and mineralization are closely related to the subduction of the Paleo-Pacific plate. • Ore-forming fluids mainly come from magma and are mixed with a small amount of meteoric water. The Tongling ore-cluster region is one of the most important Cu-Au polymetallic producers in the famous Lower Yangtze River Metallogenic Belt (LYRMB) in eastern China. The Cu-Au polymetallic ore deposits can be divided into four types, i.e., skarn, strata-bound hydrothermal, porphyry, and cryptobreccia, closely related to the Late Jurassic to Early Cretaceous magmatism. We summarize the geology of the Mesozoic Cu-Au deposits in Tongling, eastern China, and revisit the age distributions and geochemical characteristics of associated Mesozoic intrusions, by integrating a large number of published geochemical data (including major and trace elements for both early-stage and late-stage intrusions, whole-rock Sr-Nd-Pb isotopes, and zircon U-Pb age and Hf isotopes for early-stage intrusions), to reveal their sources and genesis. According to the U-Pb ages of intrusions, the main magmatic events in the area can be divided into two stages, i.e., 152–135 Ma and 135–124 Ma, respectively. The early-stage magmatism mainly produced Cu-Au mineralization-related dioritic intrusions, including pyroxene diorite-pyroxene monzodiorite, quartz diorite-quartz monzodiorite, and granodiorite, showing unobvious geochronological order. Geochemical data of Late Jurassic-Early Cretaceous intrusions from the early-stage magmatism suggest that they are all derived from a similar source composed of different proportions of slab-derived melt, metasomatized lithospheric mantle, and a lesser content of lower crust materials. Among them, the key differences lie in that more lower crust materials are incorporated in the source of intermediate-felsic rocks compared to intermediate-basic rocks. The late-stage magmatism produced a wide variety of rocks (diorite porphyry, syenite porphyry, granite porphyry, monzonite, and granite porphyry), which are related to Pb-Zn deposits. The late-stage igneous rocks may evolve from the early-stage rocks and have experienced fractional crystallization of apatite, ilmenite, and other minerals. Both early and late-stage magmatic events in the Tongling region were formed in the subduction setting, and corresponding to compression and extensional setting, respectively. Besides, the H-O isotopes of different kinds of minerals suggest that the ore-forming fluids of most ore deposits were mainly derived from the magma and mixed with a small amount of meteoric water in the late-stage mineralization. The S isotopes of sulfides show that the ore-forming materials come from the magma, accompanied by the addition of original sediments. [ABSTRACT FROM AUTHOR]

Chuankou tungsten (W) ore field, with an estimated WO3 reserve exceeding 300,000 tonnes, is so far the largest Indosinian (Triassic) granite-related W ore field in South China. However, the precise emplacement ages, sources of granitoids, and their relationship with W mineralization are still not well understood. In this research, four main magmatic stages (G-1 to G-4) have been identified in the Chuankou ore field, including G-1 (phase I, biotite monzogranite), G-2 (phase II, two-mica monzogranite), G-3 (phase III, fine-grained granite), and G-4 (phase IV, granite porphyry). LA-ICP-MS U-Pb dating of zircon grains from granitoids of the Chuankou W ore field yields emplacement ages of 230.8 ± 1.6 Ma, 222.1 ± 0.56 Ma, 203.1 ± 1.6 Ma, and 135.5 ± 2.4 Ma, respectively. Granitoids from the Chuankou ore field contain a large amount of peraluminous minerals such as biotite, musvite, garnet and tourmaline. Geochemically, the granitoids have high Si and Al (A/CNK > 1.1) content but low alkali, Fe, Mg, Mn, and Ca content. Moreover, there is enrichment of Rb, Zr, Hf, Th, and U, but depletions of Ba, Sr, P, and Ti. The granitoids have especially low Zr + Nb + Ce + Y and high Rb/Ba ratios, further indicating a highly fractionated S-type granite affinity with a significant crystal fractionation process in regard to K-feldspar, plagioclase, biotite, Ti-bearing minerals (except rutile), zircon, apatite, allanite, and monazite. Whole-rock εNd(t) and TDM2 values are −10.77 and 2090 Ma for G-1, −9.09 to −7.47 and 1764–1684 Ma for G-2, −10.07 to −6.53 and 1669–1471 Ma for G-3, respectively, indicating that the Chuankou granitoids were derived from two episodes of partial melting of the Paleoproterozoic to Mesoproterozoic metamorphic basement. Trace elements within the zircons and whole-rock geochemistry yielded evidence of the close relationship between W mineralization and G-1 and G-2 granitoids of the Chuankou ore field. The batholith of the Chuankou ore field was formed 20–10 Ma later than the peak age of the collisions orogeny and formed in a post-collisional setting. [ABSTRACT FROM AUTHOR]

[Display omitted] • Hydrothermal titanite in Kaladawan yielded an U-Pb age of 482.6 ± 4.4 Ma. • Garnet in Kaladawan yielded an U-Pb age of 481.0 ± 3.9 Ma. • The deposits in Kaladawan are skarn-type. The Kaladawan Fe–Mo orefield is located in the east of the Altyn Mountains, NW China. It contains six Fe(–Mo) deposits, with total reserves of 60 Mt Fe and 10 kt Mo by-product. Mineralization is hosted in the contact zone between Early Paleozoic volcanic–sedimentary rocks and Ordovician granite, with intense and pervasive skarn alteration. Skarns exhibit some stratabound features. These deposits were variably classified as sedimentary-type with hydrothermal overprints, submarine volcanogenic iron-oxide- (SVIO-) type or skarn-type, centered on whether they are syngenetic or epigenetic. Titanite and garnet from skarn in the ore field are newly U–Pb dated to be ca. 482.6–481.0 Ma, consistent with the intrusive age of the granite but later than the formation age of the host rocks. These age data also further support that mineralization in the Kaladawan orefield is skarn-type. [ABSTRACT FROM AUTHOR]