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The East Kunlun Orogenic Belt (E‐KOB) of the northern Tibetan Plateau is an accretionary orogenic belt, which has experienced complicated tectonic evolutionary processes of the Proto‐ to Palaeo‐Tethys Ocean. The Muztagh‐Buqingshan‐Anemaqen ophiolitic mélange zone (MBAM) is an accretionary complex related to the northward subduction of the Tethyan Ocean. Numerous intrusions outcropped in MBAM have witnessed the long‐term subduction‐accretionary process and thus site the key to comprehending the tectonic evolution of the E‐KOB, as well as the Tethyan Ocean. In this study, petrological, geochronological, and geochemical studies of the Marzheng diorites in the MBAM were carried out to explore the Early Palaeozoic tectonic evolution of the E‐KOB. Zircon U–Pb dating analysis suggests that the diorites were formed in the Early Ordovician at ca. 470 Ma. Furthermore, the εHf(t) values (5.3–14.1), Mg# values (39.7–51.2), and Nb/Ta (12.8–14.8), Zr/Hf (33.8–44.8), and Lu/Yb (0.15–0.16) ratios are generally close to those of depleted mantle‐derived rocks and the diorites were originated from a depleted asthenosphere mantle source. In addition, these diorites are characterized by enriched light rare earth elements (LREEs) (La and Nd) and depleted high‐field‐strength elements (HFSEs) (Nb, Ta, P, and Ti), similar to the fingerprints of arc‐related gabbroic‐dioritic rocks. This is also consistent with their high H2Omelt (6.0–8.3%) and oxygen fugacity (logfO2 = −14.3 to −13.5) features, indicating that they were formed in a subduction‐related setting. Our new investigations suggest that the Proto‐Tethys Ocean in the East Kunlun was still actively subducting northward during the Early Ordovician. [ABSTRACT FROM AUTHOR]