1. A Ferrocene Capping Layer Enabling Highly Efficient and Stable Sn–Pb Mixed Perovskite Solar Cells.
- Author
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Tao, Hong, Zhang, Hao‐Ze, Zhi, Rui, Zhou, Yi‐Chen, Xie, Zheng‐Wen, Zhang, Jin, Rothman, Mathias Uller, Jiang, Yang, Yin, Zhiwen, Tong, Jinhui, Cheng, Yi‐Bing, and Li, Wei
- Subjects
SOLAR cells ,FERROCENE ,PEROVSKITE ,SUNSHINE ,PRODUCTION sharing contracts (Oil & gas) ,CYCLOPENTADIENE - Abstract
The Sn–Pb mixed perovskite with a narrow bandgap is essential for the construction of all‐perovskite tandem solar cells. However, the oxidation of Sn2+ to Sn4+ makes the fabrication of Sn–Pb perovskite solar cells (PSCs) challenging. Herein, a ferrocene (Fc) capping layer is introduced on the surface of Sn–Pb mixed perovskite to maintain a reducing environment. This is due to a strong electron supply capacity from the π‐orbitals in cyclopentadiene in Fc, which effectively suppresses the oxidation of Sn2+, reduces the defect density, and leads to an improvement in carrier lifetime. Therefore, the Fc capping layer significantly improves the power conversion efficiency (PCE) of single‐junction Sn–Pb PSCs from 17.49% to 21.02%. It maintains 87% of its initial PCE after light exposure at 1 sun condition in N2 atmosphere for 288 h, demonstrating good long‐term stability. The strategy outlined herein offers a straightforward and efficient approach to enhance the stability and PCE of narrow‐bandgap Sn–Pb mixed PSCs. [ABSTRACT FROM AUTHOR]
- Published
- 2024
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