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Permo-Triassic intrusive rocks and back-arc basins are exposed in the İstanbul-Zonguldak Tectonic Unit in the West Pontides. Their tectono-magmatic history, thus to the evolution of the back-arc basins, is poorly understood. Here, I present on olivine-bearing basalt and andesite dykes and granite dykes and pyroxene-bearing andesite dykes of Permo-Triassic crystallization and their Pb-loss ages from the basement rocks and sedimentary rocks in the İstanbul-Zonguldak Tectonic Unit (NW Turkey). They have holocrystalline and porphyritic to vitrophyric textures. U-Pb dating of igneous zircon grains from olivine-bearing basalt and andesite dykes and granite dykes yielded Middle Permian ages of ca. 270.1 ± 1.1 to 261.4 ± 1.7 Ma (2σ), and pyroxene-bearing andesite dykes obtained Early Triassic ages of ca. 252.1 ± 2.4 to 250.1 ± 2.0 Ma (2σ). Their young ages of the dykes yielded Late Triassic ages of ca. 228 to 220 Ma (2σ). Geochemically, the Middle Permian dykes have a calc-alkaline affinity and are notable for subduction components, as indicated by the presence of distinct negative Nb anomalies. Early Triassic dykes show alkaline signatures and show within-plate character, corresponding to prominent positive Nb anomalies. Combined with data from the literature, the Middle Permian dykes are magmatic products associated with the Tethys Ocean subducting under the Pontides and the Early Triassic dykes are magmatic pulses related to the rifting of the Permo-Triassic back-arc basins. The Late Triassic young ages of the Permo-Triassic dykes in the İstanbul-Zonguldak Tectonic Unit represent a deformation event corresponding to the Cimmerian Orogeny, and this implies that the Permo-Triassic back-arc basins closed during the late Triassic. [ABSTRACT FROM AUTHOR]

The Amazonian Craton is home to many Statherian to Calymmian taphrogenesis events that evolved over Large Igneous Provinces. The NW-SE faults on the Western Amazonian Igneous Belt (1.82–1.74Ga) and their reactivations, which facilitated the deposition of the Beneficente Group (1.76–1.60Ga), Prainha Formation (1.46Ga), and Alto Tapajós Group (Silurian-Devonian), are associated with these events in the southwest Amazonian Craton. Mineralogical composition, whole-rocks geochemistry, and Nd-Sr-Pb isotopic data show that the three sedimentary successions originated in the provinces of Rondônia-Juruena and Tapajós Parima, particularly during two rift stages. Beneficente Group deposition is associated with Paleoproterozoic Rift 1, while the Prainha Formation represents the post-rift 1, and Alto Tapajós Group deposition is associated with Paleozoic Rift 2. In addition, the Prainha Formation also received sediment supply from the Sunsás Province. These three sedimentary successions have an intrinsic relationship with the reworking of the local basement and their own reworking that occurred from the Paleoproterozoic to the Paleozoic. Autochthonous reworking, particularly in the Colíder and Beneficente groups, is demonstrated by Ti-magnetite grains, volcanic and arenite fragments in the Prainha Formation sublitharenite, and by angular microcline grains, high Au content, a Pb whole-rock isochron yielding the 1.796±0.096Ga age, and by ${\varepsilon _{Sr\left(0 \right)}}$ ε Sr 0 vs 1/Rb relationship in Alto Tapajós Group. ${\varepsilon _{Nd\left(t \right)}}$ ε Nd t and flat REE patterns and some positive Eu anomalies in the Prainha Formation and Alto Tapajós Group record the influence of the mafic rocks of the Mata-Matá suite. A Pb-Pb whole-rock isochron allowed hydrothermal activity recognition at 1.32Ga in the Vila do Carmo Formation. This event was ratified by positive Eu/Eu* (1.3–1.43), Ce/Ce* (1.24–2.84), and Gd/Gd*(~1.5) anomalies. Finally, Nd model ages, geochemistry, and Sr isotopes allow for correlating the local basement and the overlaying sedimentary successions along the Columbia and Gondwana boundaries. [ABSTRACT FROM AUTHOR]

We integrate the existing detrital zircon data from multiple modern river sediment samples on Viti Levu, Fiji, with the most current available geological and topographic mapping of the respective river drainage basins to compare detrital populations with potential bedrock sources. The temporal and spatial variations in zircon geochemistry supplement what is known from igneous rocks and confirm the petrological differences between plutonic and volcanic rocks from the Eocene to early Oligocene (Yavuna age, >30 Ma), middle Oligocene to middle Miocene (Wainimala age, 30–12.5 Ma), late Miocene (Colo age, 12.5–6.5 Ma) and latest Miocene (Namosi age, 6.5–5 Ma). The >30 Ma Yavuna-age zircons are restricted to areas that drain the previously mapped Yavuna Group. The 30–12.5 Ma zircons are found across central Viti Levu from west to east, and the 30–15 Ma zircons have distinctively low U/Yb and high Dy/Yb ratios. They are the best radiometric evidence of widespread early to middle Miocene arc magmatism in Fiji that was relatively U-poor. Peak deconvolution of the Colo age zircons from individual basins suggests the following ages for undated or poorly dated plutons from central Viti Levu. The large Mavuvu pluton is probably composed of multiple intrusions in the 12–10 Ma range, the Waiqa pluton is probably ca 10 Ma, and the Noikoro pluton is probably ca 9 Ma. There are zircons from unknown plutonic or volcanic sources between 8 and 7 Ma in western Viti Levu that have distinct Eu/Eu* ratios. We attribute the highest U/Yb ratios in some Colo age zircons to crustal anatexis. Namosi-age zircons are abundant in the Medrausucu Group and can be found scattered across Viti Levu. Detrital zircon samples have aided geological mapping of the tropical and poorly exposed terrain in Fiji and elucidated the magmatic history. Detrital zircons indicate widespread early to middle Miocene arc magmatism across central Viti Levu. Detrital zircon ages have provided further constraints on the ages of 12-9 Ma plutons in central Viti Levu. Detrital zircon ages indicate that there is an unknown igneous source of 8-7 Ma zircons in western Viti Levu. [ABSTRACT FROM AUTHOR]

Some Archean and Phanerozoic gold deposits demonstrate a close spatial relationship with alkalic intrusions, although the genetic connotations of this association are contentious. Only a few of the alkalic intrusions in the Kurnalpi Terrane of the Archean Kalgoorlie–Kurnalpi Rift are associated with economic gold mineralisation (e.g. at Wallaby, Karari). The subvolcanic syenitic intrusions at the 2 Moz Karari–Whirling Dervish gold deposit are markedly different from most other alkalic rocks in the Kalgoorlie–Kurnalpi Rift. Although preserving pristine to slightly modified igneous textures, the syenitic intrusions are thoroughly altered by hypogene hydrothermal fluids, such that igneous minerals, comprising apatite micro-phenocrysts and relicts of Ba-rich K-feldspar, Ba-rich biotite, sodic amphibole and Cr-rich magnetite, total <5 modal %. Elevated SO3 (up to 1 wt%) in igneous apatite shows that the alkalic magmas were S-bearing and oxidised, and a high oxidation state carried through to the hydrothermal stages that followed, including potassic (biotite) alteration, at 650 °C (apatite–biotite geothermometry). Oxidised hydrothermal activity was interrupted by periods of sodic and sodic–calcic alteration in structurally controlled zones, interpreted to record the influx of reduced, external fluids at around 400–450 °C. A second, volumetrically minor stage of potassic (K-feldspar–pyrite–hematite) alteration in the intrusions is nevertheless significant, as it matches the proximal alteration assemblage in volcaniclastic country rock-hosted gold lodes. Overall, the hydrothermal system in the intrusions evolved from pervasive, high-temperature to more focussed, structurally controlled, mesothermal alteration. The source of the high-temperature, oxidised, alkaline hydrothermal fluid is considered to be the oxidised, alkalic magma itself, including an alkalic magma chamber underlying the gold deposits. Based on evidence from Karari–Whirling Dervish, gold fertility indicators for alkalic intrusions include: (i) widespread high-temperature alkaline metasomatism, including coarsening of alkali-feldspar intergrowths, abundant hydrothermal magnesian biotite and advanced to total replacement of igneous minerals; (ii) low SiO2 and high K2O, relative to unmineralised alkalic rocks in the region; (iii) alteration of igneous titanite to hydrothermal rutile with concomitant depletion of Nb; (iv) low rare earth element/P owing to depletion of rare earth element in apatite by the potassic (biotite) alteration fluid; and (v) high V/Th relative to regional alkalic rocks. The Karari syenitic intrusions are characterised by almost complete replacement of igneous minerals by >400 °C metasomatic products, despite good textural preservation. Apatite composition indicates high-fO2 S-bearing magma. Intrusion mineralogy and textural relationships suggest a hydrothermal evolution similar to that in the gold mineralised volcaniclastic sedimentary country rocks. The alkalic magma is a potential source of the gold ore fluid, and the syenitic intrusions retain several mineralogical and chemical characteristics that probably indicate magma fertility. [ABSTRACT FROM AUTHOR]

The evolution of the Gondwana along the flank of the West African Craton was complex and is far from understood. Subduction-related activity along this margin spanned between c. 750 and 500 Ma. Sections close to African cratons record the earliest stages, while Autochthonous and Allochthonous domains of the Variscan Belt preserve the latest stages of the arc system, essentially between c. 540 and 500 Ma. The geochemistry of the Ediacaran-early Cambrian siliciclastic series deposited along this Cadomian active margin preserves the evolutionary history of their sources, which are related to activity in the arc and nearby continental areas. In this sense, the SW Iberian Massif (Ossa-Morena Complex) preserves a section of this Ediacaran-early Cambrian peri-Gondwanan arc. Its evolution can be tracked through the characterization of the subduction-related magmatism (including the Mérida Massif) and coeval metasedimentary record (Serie Negra Group and Malcocinado Formation) during a time interval spanning almost 100 m.y., from pre-602 Ma to at least c. 534 Ma. This study reveals that arc magmatism is closely linked with synorogenic deposition in a complex way so far unexplored. Arc recycling is revealed by the isotopic equivalence of synorogenic strata to the first magmatic event (pre-602 Ma), and by geochronological data of the arc-building pulses. The earliest magmatic pulses (c. 602–550 Ma) are characterized by significant crustal input, likely favoured by subduction erosion. Subsequently, magmatism evolved towards larger mantle involvement (c. 540–534 Ma), likely associated with progressive variation in the slab angle. These slab-mantle-upper plate interactions generated changes in the arc dynamics leading to an extensional setting with alkaline magmatism during the Cambrian. This review proposes a model of petrogenetic and geodynamic arc evolution between the Ediacaran and the Early Cambrian. The gathered data could improve the accuracy of future palaeogeographic reconstructions for the northern margin of Gondwana. [ABSTRACT FROM AUTHOR]

Earth's first continental crust is formed by Archaean and mainly consisted of tonalite–trondhjemite–granodiorite with a small amount of diorites (DTTGs), which has an essential role in probing early crust–mantle dynamic regime and in understanding the formation mechanism of continental crust. Here, we present zircon U‒Pb dating and Lu‒Hf isotopes, whole-rock geochemistry, and petrography on DTTGs rocks in the Dunhuang Block. Three episodes of DTTGs were emplaced circa 2.67 Ga, 2.60 Ga, and 2.50 Ga. The circa 2.67 Ga TTGs exhibit high SiO2 contents (68.14–71.70 wt%), low MgO contents (0.65–1.31 wt%), and high ratios of (La/Yb)N (146 on average), with their enriched Nd-Hf isotopes [ƐHf (t) = -5.48–3.19 and ƐNd (t) = -5.77–0.53], indicating origination from partial melting of amphibolites at thickened lower crust. In contrast, the circa 2.60 Ga transitional TTGs exhibit relatively high MgO contents (2.80–3.39 wt%), flat REE (Rare earth element) patterns with moderate ratios of (La/Yb)N (20.49 on average), and dispersed Nd-Hf isotopes [ƐHf (t) = -5.48–3.19 and ƐNd (t)= −3.99–3.08]. Accordingly, circa 2.60 Ga transitional TTGs melts were produced by partial melting of the shallower crust induced by mantle-derived magma upwelling. The circa 2.50 Ga diorites exhibit low SiO2 (55.72–59.11 wt%) but high MgO (3.51–4.52 wt%) contents with positive Nd-Hf isotopes [ƐHf (t) = -0.16–4.17 and ƐNd (t) = 2.00–4.45], suggesting that they originated from partial melting of mantle wedges metasomatized by fluid from subduction slabs. Combined with the detailed petrogenetic studies and crustal thickness variation, we conclude that the complex crust–mantle interaction may be an essential reason for the Neoarchaean diversity of DTTGs from the Dunhuang Block, which experienced prolonged arc accretion before Neoarchaean, followed by delamination between 2.67 and 2.60 Ga and subsequently transitioned to subduction. [ABSTRACT FROM AUTHOR]

The paper presents new geological, geochronological, geochemical and Nd-Sr isotopic data on the Meso- Neoproterozoic dolerites of the Siberian Craton. New U-Pb baddeleyite and apatite ages of a E-W-trending dyke and two sills from southeastern Siberia are 982 ± 11, 977 ± 7, 970 ± 31 and 972 ± 60 Ma, respectively, extending the area of distribution of the event by more than 100 km to the north. The Sette-Daban intrusions are subalkalic mostly low-Ti dolerites, although high-Ti dolerites have been locally documented as well. Trace element abundances in dolerites vary from typical to E-MORB to OIB with arc-like signatures represented by high Th/Yb and low TiO2/Yb ratios. All dolerite samples display moderately positive εNd(t) values varying from +3.3 to +7.7 and indicating the magmas were derived from a depleted mantle source. E-MORB and OIB intrusions are attributed to the different degree of interaction of magma between the depleted asthenospheric mantle and regions within the sub-continental lithospheric mantle (SCLM) that were metasomatically enriched during earlier subduction events. Available data on Sette-Daban event distribution, composition and duration satisfy the characteristics of a typical Large Igneous Province (LIP). Similar age 1000–950 Ma mafic magmatism is also recognized in the Baltic and Amazonian cratons and can be potentially correlated with the Sette-Daban event. [ABSTRACT FROM AUTHOR]

The widespread Cenozoic Himalayan leucogranites (HLs) are representative rocks evolving from relatively pure crust-derived melts with few mantle material inputs and are believed to be highly fractionated and rare-metal mineralization developed. Over the past several decades, high-quality geochronological and geochemical analyses for the HLs have facilitated exploring the metamorphism, deformation, anatexis, and tectonic settings, enabling us to decipher the evolution process of the Himalayan orogen. In this study, we collected a large amount of geochronological, geochemical, and thermodynamic data from previous studies. Generally, the HLs exhibit (strongly) peraluminous (1.06–1.22) features and are characterized by high SiO2 (70.95–75.08 wt. %) and Al2O3 (14.18–15.85 wt. %) and low TiO2 (0.02–0.26 wt. %), MgO (0.07–0.73 wt. %), MnO (0.01–0.07 wt. %), and total iron (FeOT = 0.44–1.71 wt. %) contents, and are enriched in large ion lithophile elements (e.g. K, Rb, Pb, U). Moreover, rare-metal elements (Li, Be, Ta, W, Sn) also show their enrichments in the HLs; and the deviations of K/Rb (72.16–190.45), Zr/Hf (15.00–35.19), Nb/Ta (2.65–12.75), and Y/Ho (26.07–36.75) ratios from the chondritic values are also notable. All these geochemical structures above suggest that the HLs are (highly) fractionated. Considering the diverging whole-rock isotopic Sr and Nd compositions of the HLs, with the (87Sr/86Sr)t ratios and εNd(t) values mostly ranging from 0.7159 to 0.8052 and −16.78 to −10.43, respectively, the source rocks of the HLs should be multiplex. Additionally, different melting mechanisms (including fluid-absent/present partial melting of muscovite, biotite, and hornblende) can be identified in the HL productions. The occurrences of beryl (Be), columbite (Nb and Ta), spodumene (Li), and many other rare-metal minerals have been frequently reported recently, suggesting the enrichment of rare-metal elements associated with the HLs. To provide a comprehensive and meticulous summary of these HLs (1593 leucogranite samples), we divide them into five stages based on different tectonic backgrounds. After comparing them, we propose that: (1) from Stage I to V, the HL emplacements were strongly related to the tectonic backgrounds: thickened crust from ca. 49 to 40 Ma (I), transition from compression to N-S extension (onset of the South Tibetan Detachment System (STDS)) from ca. 39 to 30 Ma (II), large-scale N-S extension (active movement of the STDS) from ca. 29 to 15 Ma (III), N-S extension to E-W extension tectonic transition (construction of N-S trending rifts (NSTRs)) from ca. 14 to 7 Ma (IV) and rapid uplift of two Himalayan syntaxes from ca. 6 to 2 Ma (V), respectively; (2) the coeval leucogranites emplaced in the Tethyan Himalayas (THLs) and Greater Himalayas (GHLs) had many similarities (particularly in Stages III and IV) in: geochemical compositions, peak emplacement ages, tectonic backgrounds, melting mechanisms, source domains, and fractional crystallization degrees; (3) materials from the Lesser Himalayan Sequence were increasingly significant in producing the HLs from the Eocene to the Pleistocene temporally, and from the Tethyan Himalayan Sequence to the Greater Himalayan Crystalline Complex spatially; (4) owing to the depleted abundances of rare-metal elements in mafic source rocks (e.g. amphibolites) and relatively lower fractional crystallization degrees of the Eocene leucogranites, rare-metal mineralization was rarely reported; (5) excessive fractional crystallization may be the dominant driving force for enriching rare-metal elements (Li-Be-Nb-Ta-W-Sn) of the HLs, making the Himalayas a new potential global orogen scale of polymetallic ore belt. [ABSTRACT FROM AUTHOR]

Sedimentary manganese (Mn) deposits in the southeastern Yangtze Platform of China have been newly discovered with considerable potential for resource exploration. Such deposits formed due to dynamic changes in the global environment, including the break-up of the supercontinent Rodinia, Snowball Earth glaciation, and the Neoproterozoic Oxygenation Event. The Mn-bearing sequences are hosted in the basal Datangpo Formation and are interbedded with black carbonaceous shale in a series of graben sub-basins in the Nanhua Rift Basin. We investigated the origin of these Mn deposits by analysing the major and trace elements, total organic carbon, and stable carbon and oxygen isotopes. Positive Eu anomalies were observed, indicating that the Mn was derived from a hydrothermal system. Redox-related elements, including Ce, Mo, U, V, S, and P, indicated that the depositional environment of the Mn layers was oxidative and that Mn2+ was initially oxidized to Mn oxides. However, the host rock (i.e. black carbonaceous shale) was deposited under dysoxic – anoxic and even sulfidic water conditions. The alternating distribution of Mn ore and host rock suggested alternating redox conditions in the sub-basins. A negative correlation between the Mn content and δ13Ccarb values (−10‰–−7‰) and a deficiency of sulphide minerals indicate that the diagenetic degradation of organic matter (δ13Corg from − 34‰ to − 31.9‰) took place through Mn oxide reduction rather than microbial sulphate reduction and can contribute to a considerable source of bicarbonates. The approximately homogeneous δ13Ccarb depletion and their apparent discrepancy with δ13Corg indicate that the post-depositional genesis of the Mn carbonate ore occurred in a relatively open early diagenetic pore water system with a considerable contribution from seawater-derived carbon sources. [ABSTRACT FROM AUTHOR]

Located in the central part of the Central Asian Orogenic Belt, East Junggar represents one of the most important sites of juvenile crustal growth during the Phanerozoic. However, the mechanism of juvenile crustal growth during the Permian remains controversial. The Daheishan granites in the eastern segment of East Junggar are dated at ~292 Ma (Early Permian) and 269 Ma–267 Ma (Middle Permian). The Early Permian granites are coarse-grained with very high SiO2 (76.64 wt%–80.02 wt%), Al2O3 (10.72 wt%–12.96 wt%), and K2O/Na2O (1.27‒2.14), and low TiO2 (0.12 wt%–0.18 wt%), CaO (0.27 wt%–0.90 wt%), Mg# (25–32), and Sr/Yb (16–25). The Middle Permian granites are medium‒fine-grained with relatively high SiO2 (71.84 wt%–76.26 wt%), Al2O3 (11.26 wt%–13.00 wt%), and K2O/Na2O (0.53–1.54), and low TiO2 (0.17 wt%–0.21 wt%), CaO (0.37 wt%–3.20 wt%), Mg# (33–43), and Sr/Yb (5–9). These Permian granites display slightly positive whole-rock εNd(t) (+0.77 to + 1.04) and highly positive zircon εHf(t) (+7.3 to + 8.7) values, and low Ga/Al (2.04–2.55 < 2.6), P2O5 (0.02%–0.05% <0.14%), and zircon saturation temperature (690°C–749°C, take the median for each sample). Moreover, they display characteristic tetrad rare earth element patterns and non-CHARAC (CHArge-and-RAdius-Controlled) trace element behaviour, suggesting that the Daheishan granites are I-type granites that underwent both fractional crystallization (K-feldspar and plagioclase, e.g.) and crustal contamination prior to their emplacement. In combination with data from volcanic rocks in the Santanghu Basin, we infer that the Early Permian granitic magmas were derived from delamination of a thickened lithospheric mantle base and partial melting of pre-Permian arc components, while the Middle Permian granites formed during the subsequent stretching and thinning of the lithosphere. [ABSTRACT FROM AUTHOR]

We report the whole-rock major and trace element and Sr – Nd – Pb isotopic compositions of volcanic rocks from the Nansatsu area in South Kyushu. We analysed samples from the Oldest stage (middle Miocene), Older stage (late Miocene), and Middle stage (early Pliocene) Nansatsu volcanic rocks, which are andesite to dacite in composition, with an island-arc trace element signature. The compositional variabilities within the Older and the Middle stage rocks are relatively small compared to those in the Oldest stage and Quaternary volcanic rocks. Isotopic characteristics suggested that the Oldest stage volcanic rocks had magma sources similar to regional ilmenite-series granitoids of later ages (Outer Zone granitoids), which incorporated a substantial amount of graphite-bearing accretionary sediments (Shimanto Supergroup). The sources for the Older and Middle stage magmas were similar to those of primary Quaternary basalts in South Kyushu, indicating that Pliocene and Quaternary volcanic rocks in South Kyushu share a common mantle source, despite the change in the nature of volcanic activity from andesite-dominated to more variable volcanism of basalt to rhyolite. [ABSTRACT FROM AUTHOR]

Subduction-related magmatism is a significant contributor to arc building and continental growth. In the active convergent margin of the SW Japan arc, voluminous volcanic rocks and mafic dykes formed through subduction and back-arc rifting during Miocene. In this study, we investigate a suite of felsic volcanic rocks (rhyolite and dacite) and lamprophyres from central Shikoku Island, which occur in the north-central part of the Chichibu belt and Sanbagawa belt in the Outer zone of the SW Japan arc. Whole-rock geochemistry results show that the rhyolite and dacite samples are peraluminous, belong to the high-K calc-alkaline series, show LREE and LILE enrichment, HREE and HFSE depletion that suggest arc volcanic affinity. The lamprophyre samples belong to alkali lamprophyre, show LREE and HFSE enrichments, and display OIB (oceanic island basalt)-like geochemical features. The 206Pb/238U weighted mean ages of the zircons from the rhyolite and dacite samples range from 14.39 ± 0.21 Ma to 13.92 ± 0.30 Ma, whereas the lamprophyre shows 206Pb/238U weighted mean age of 12.21 ± 0.35 Ma. Zircon Lu-Hf isotope data suggest that the rhyolite and dacite were derived from the remelting of the arc crustal rocks and that the lamprophyre was derived from depleted mantle sources and was contaminated by crustal materials. The felsic volcanic rocks (rhyolite and dacite) can be correlated to Miocene (15.5 Ma to 13.5 Ma) magmatism in the Outer Zone of the SW Japan arc. The formation of lamprophyre dykes in the SW Japan arc may be related to the subhorizontal mantle flows beneath the SW Japan arc associated with the opening of the Japan Sea back-arc basin or asthenosphere upwelling through the slab-tear of the Philippine Sea Plate beneath the SW Japan arc. Our study shows that the SW Japan Arc was built by multiple magmatism from diverse sources in an active convergent margin. [ABSTRACT FROM AUTHOR]

The Nkout banded iron formations (BIFs)-hosted iron deposit is located in the Ntem Complex at the northwestern part of the Congo craton, southern Cameroon. We report geochronological and geochemical data of magnetite BIFs and interlayered mica schists from the Nkout iron ore deposit. The BIFs show typical features of chemical precipitates characterized by seawater-like shale-normalized rare earth elements plus yttrium spectra. Weak positive Eu anomalies indicate the contribution of high-temperature hydrothermal fluids to the BIFs, with low detrital input. The absence of true Ce anomalies indicates that the BIFs were likely to be deposited in anoxic seawater. LA-ICP-MS U-Pb detrital zircon data for the BIFs and associated metasiliciclasltic rocks constrained the maximum depositional age at ca. 2.8 Ga, suggesting that the Nkout BIFs are likely the oldest iron formations in the Ntem Complex. Our zircon U-Pb isotope data indicate that the Nkout succession experienced lower-amphibolite facies metamorphism at ca. 2.0 Ga, which correlates with the regional tectono-thermal event linked to the convergence and assembly of terranes between the Congo and São Francisco cratons during the Eburnean-Transamazonian orogeny. [ABSTRACT FROM AUTHOR]

Permian mafic dikes crop out widely within Beishan area in the southernmost Central Asian Orogenic Belt (CAOB). These mantle-derived products provide important clues for elucidating the genesis and geodynamic setting of Permian magmatism. The mafic dikes within the Beishan area display zircons U–Pb ages of 281 ± 4 Ma. Characterized by low SiO2 (44.88–47.73 wt.%) and high Mg# values (62.2–68.6), the type 1 dikes are relatively depleted in light rare earth elements (LREEs; (La/Yb)n = 0.72–1.43) but enriched in large ion lithophile elements (LILEs). They show high positive εNd(t) values (6.6–8.5) with a range of (87Sr/86Sr)i (0.703477–0.705789) ratios. In contrast, the type 2 dikes have higher SiO2 content (47.47–51.13 wt.%) and lower Mg# (40.9–63.0). They are enriched in LREEs ((La/Yb)n = 1.79–5.02) and LILEs, and have lower εNd(t) values (3.8–7.4) with a variable range of (87Sr/86Sr)i (0.702873–0.706949) ratios. Thus, the type 1 dikes resulted from lower degrees of fractional crystallization and contamination than the type 2 dikes. Considering the LILEs and Pb enrichments, high field strength elements depletions, and high Ba/Th (86–460) ratios, the mantle source was metasomatized by subduction-related fluids. These dikes should be derived from high degrees (>20%) of partial melting of a Sr–Nd isotope-depleted, phlogopite-bearing spinel lherzolite lithospheric mantle according to their high Rb/Sr (0.04–0.24), low Ba/Rb (0.9–3.3), low La/Sm, and constant Sm/Yb ratios in addition to Sr–Nd depletion. Combined with the coeval evidence of regional geology and novel tectonic discriminate diagrams, we suggest that the mafic dikes in Beishan area formed in arc-related setting rather than intracontinental setting during the Permian. The metasomatized lithospheric mantle by subduction-related fluids were heated by upwelling asthenosphere mantle triggered by the slab roll-back, resulting in the formation of the parental magma of the mafic dikes. [ABSTRACT FROM AUTHOR]

The Eastern Pontide Orogenic Belt (EPOB), a well-preserved palaeo-magmatic arc, exists south of the Black Sea, from Bulgaria to Georgia. The region, which forms an essential part of the Alpine-Himalayan belt, contains volcanic rocks formed in the Late Cretaceous. This paper aims to investigate the petrogenesis of the Late Cretaceous volcanic rocks using both new and previously existing geochemical and geochronological data. Based on the geochemical features, the studied volcanics are divided into Group I (dacite/rhyolite) and Group II (basalt/basaltic andesite). According to LA-ICP-MS zircon U–Pb data, the crystallization age of Group I is 83.43 ± 0.87 Ma. The εNd(t) values of Group I are −1.4 and + 4.5, and the εNd(t) value of Group II is +3.0. The Lu–Hf isotope data from zircon shows that Group I have positive εHf(t) values (+14.20 - +12.15), and their crustal model age is 240–339 Ma. The εHf(t) values indicate that the Group I rocks are derived from the melting of a depleted mantle source. Whole-rock geochemistry data show that Group II samples were formed by partial melting of metasomatised spinel-bearing lherzolites at shallow depths. It is thought that the Late Cretaceous volcanic rocks are the products of arc magmatism associated with the northward subduction of the Neotethys oceanic lithosphere under the Eurasian plate, and the EPOB was an active continental margin arc during the Late Cretaceous. [ABSTRACT FROM AUTHOR]

This article discusses the mineral willemseite, which is the nickel analogue of talc and minnesotaite. It was first described in material from the Bon Accord nickel deposit in South Africa and is characterized by its light green color, Mohs hardness of 2, and perfect cleavage. The mineral is named after Professor Johannes Willemse, an authority on layered intrusions and the head of the Department of Geology at the University of Pretoria. The article also provides information about the Bon Accord nickel deposit and Willemse's contributions to the field of geology. [Extracted from the article]

Halophytic plant communities have developed on exposed coastal landforms to form low-stature turf in several locations around New Zealand. We quantify the inorganic geochemistry, mineralogy and simulated ephemeral surface water composition of saline soil-free bare ground at a well-preserved site at Maori Head on Otago Peninsula, where halophytes have colonised from adjacent coastal turf. The community at this site is dominated by Leptinella dioica, Samolus repens, Disphyma australe and Selliera radicans. Maori Head substrates are dominated by clay-altered basalt colluvium and show a general trend from high electrical conductivity (EC > 10 mS/cm) and weakly acid pH (< 6) on bare ground to low EC (< 1 mS cm−1) and higher pH (> 7) in turf and adjacent pasture soils. High salinities on dry substrates and in simulated ephemeral surface waters result from surface evaporation of airborne sea spray and contain halite (NaCl) with some gypsum (CaSO4.2H2O). Chemical interactions with the substrate are minor. The high surface salinities were maintained despite a major winter rain event with strong onshore winds. However, surface salinity is frequently leached by rain and shallow groundwater, whereas inland saline sites (pH 8–11) have substantial salt accumulations driven by lower rainfall, high evaporation and chemical interaction with Otago Schist-derived substrates. [ABSTRACT FROM AUTHOR]

The Lord Howe Volcanic Complex (LHVC) is part of a seamount chain associated with the detached continental crust of Zealandia. We present petrographic and geochemical data for the LHVC, including the first reported data for Balls Pyramid and the first trace element data for Lord Howe Island, clarifying the tectonic affiliation and general mantle source characteristics. Classification and discrimination diagrams based on concentrations and ratios of immobile elements, such as rare earth and high field strength elements, Th, Ti, Y, and Mg, show the LHVC comprises transitional to alkali basalts and at least two, and probably three, shield building complexes, consistent with an intraplate tectonic setting. Primitive-mantle normalised trace element patterns, variation in Dy/Yb for a restricted range of Dy/Dy*, Zr/Yb > 90, and variations in Zr/Hf and P2O5/TiO2 through the eruptive sequences indicate the mantle source may be a laterally heterogeneous enriched garnet peridotite that has undergone varying degrees of partial melting and carbonatitic metasomatism, both within the LHVC and along the Lord Howe Seamount Chain. The LHVC is thus an ideal natural laboratory for probing the probability of small intraplate volcanic fields originating via mantle plumes or from previously subducted slabs stagnating at the mantle transition zone. [ABSTRACT FROM AUTHOR]

The Cobar Basin, in central New South Wales, is an Early Devonian extensional basin that formed in the western Lachlan Orogen. The basin was filled with shallow- to deep-water sequences of the Cobar Supergroup and hosts small to large polymetallic deposits. Detrital zircon geochronology and whole-rock geochemical data collected from the Amphitheatre Group of the Cobar Supergroup provide constraints on the history of basin fill and illustrate the dynamic interplay between basin provenance and mineralisation, corresponding to the evolving tectonic regime. Data reveal provenance dissimilarity between the southern and northern parts of the basin. In the south, units of the Amphitheatre Group received abundant detritus from ca 430–410 Ma magmatic rocks situated to the southwest and southeast of the basin. By contrast, the northern successions were predominately sourced from recycled Ordovician basement found to the northwest, north, northeast of the basin, along with contributions associated with the Macquarie Arc. This spatial provenance variation, however, is less significant in the younger formations: the northern and southern sequences both exhibit an increase in older recycled detritus upwards with time. This reflects a progressive modification of basin paleogeography, during the transition from rift phase to sag phase. The rift-phase basin geography is characterised by fault-restricted deposition with predominant sediments derived from local proximal sources. The subsequent sag-phase subsidence exhibits a uniform depositional system with more homogenised basin input. This provenance variation is coeval with the stratigraphically controlled mineralisation features within the Amphitheatre Group successions, implying a provenance influence on mineralisation. Data suggest the different sediment source regions have produced distinct detrital mineral compositions between the major mineral-hosting and mineral-barren formations. The enrichment of some detrital minerals in the mineral-hosting units, such as feldspar, muscovite, Ti-minerals (and carbonate), is suggested to be an important factor for mineralisation in the basin. Detrital zircon geochronology and whole-rock geochemistry illustrate the history of basin fill for the Cobar Basin. Spatial and temporal variation of basin provenance reflects a modification of basin geography, corresponding to the evolving tectonic regimes. The change in basin source regions is one of key controls on the mineralisation within the Cobar Basin. [ABSTRACT FROM AUTHOR]

The Dakrong-A Luoi area is located in the South Truong Son belt in the Indochina block and has been affected by multiple stages of magmatic-metamorphic events. In this paper, Paleozoic-Mesozoic granitoids from the Dakrong-A Luoi area were studied using LA ICP-MS U-Pb zircon geochronologies, Hf isotopes on zircon and whole-rock geochemistry of the Paleozoic to examine the tectonic-magmatic history of the Southern Truong Son belt. The magmatism history of the area can be divided into three phases, at ~ 452 Ma (Ordovician), ~259 Ma (Permian), and ~ 243 Ma (Triassic). The Ordovician granites were exposed in the narrow belt of NW-SE trending, while the later two granite phases were exposed in E-W trending. The Ordovician granites show consistent LA-ICP-MS zircon ꜪHf(t) values from + 6.2 to + 8.3. Their corresponding Hf model ages (TDM2) from 0.9 Ga to 1.0 Ga suggest that the Ordovician granite was derived from the partial melting of ancient crustal rocks, which is related to the subduction of the Tam Ky-Phuoc Son (TKPS) ocean beneath the Truong Son belt. The Permian granites have Hf isotopic natures (ꜪHf(t)=-1.6 to 1.3, TDM2 = 1.2–1.3 Ga) of partial melting from ancient mantle components with minor Paleoproterozoic ancient continental crust The Triassic granites have negative ɛHf(t) values ranging from −11.9 to −7.0 and Hf model ages of 1.7–2.0 Ga suggesting that they were a product of partial melting from the Paleoproterozoic crust, corresponding to subduction/collision of the Paleo-Tethys ocean beneath the Indochina block along the Song Ma suture. [ABSTRACT FROM AUTHOR]

During the Late Cretaceous, a magmatic arc extended from the Lesser Caucasus through the northern margin of the Pontides into Srednogorie, Timok, Banat, and Apuseni (ABTS) in the Balkans for a distance of 2700 km. We studied the arc volcanic rocks in three regions in the Western Pontides and reviewed the geological data on the Lesser Caucasus-Pontide-ABTS magmatic arc, which shows several common features. Prior to the start of the arc magmatism, the region underwent uplift and erosion. New and published geochronologic and biostratigraphic data show that magmatism in the Lesser Caucasus-Pontide-ABTS arc started in the Turonian (ca. 93 Ma) peaked in the middle Campanian (80–78 Ma) and became rare and sporadic after the late Campanian (ca. 75 Ma). Magmatism was dominantly calc-alkaline to high-K calc-alkaline and shows typical subduction geochemical signatures. Late Cretaceous volcanism took place in a submarine and extensional environment. In the Lesser Caucasus-Pontide-ABTS belt, the arc volcanic rocks are overlain by Maastrichtian to Palaeocene marine limestones and sandstones, marking the end of the main phase of arc magmatism. However, in the Kefken region in the Western Pontides, Maastrichtian limestone sequence includes a volcanic horizon with a U-Pb zircon age of ca. 71 Ma. The Maastrichtian volcanic rocks show a more varied geochemistry than the older arc volcanic rocks, and include alkaline basalts, calc-alkaline basalts, and adakites. The coeval start of arc magmatism in the 2700-km-long Lesser Caucasus-Pontide-ABTS belt is related to the inception of the Africa-Eurasia convergence at ca. 96 Ma, which is also independently indicated by the beginning of intra-oceanic subduction, inferred from the ages of sub-ophiolite metamorphic rocks in Anatolia. The end of magmatism is linked to a marked decrease in the convergence rate during the Campanian, which was also partitioned between the northern and southern Tethyan subduction zones. [ABSTRACT FROM AUTHOR]

A combined study of whole-rock geochemical and Sr-Nd isotopic data, and zircon U-Pb geochronological and Hf isotopes has been carried out for several Neoproterozoic intrusions, including the Lung Thang, Posen and Sin Quyen in the Phan Si Pan Zone, northwest Vietnam to constrain their age, petrogenesis and tectonic implications. The Lung Thang and Posen intrusions, mainly composed of granodiorite, were formed at 803–777 Ma and are characterized by moderate SiO2 (64.43–66.65 wt.%), and K2O (4.05–4.89 wt.%), with A/CNK and A/NK values of (0.94–1.03) and (1.72–2.11), respectively. They have negative whole-rock εNd(t) (−6.16 to −3.73) and zircon εHf(t) values (−7.9 to −4.1), which suggest that the Lung Thang and Posen intrusions were generated by partial melting of ancient, K-rich crustal rocks. The Sin Quyen intrusion, occurring as dykes, is composed of monzodiorite and was emplaced at 742 ± 3 Ma. The Sin Quyen intrusion has high alkalies (K2O+Na2O = 7.42–7.47 wt.%), and low MgO (<1.31 wt.%) and Ni (6.55–6.93 ppm), with A/CNK and A/NK values of (0.67–0.68) and (1.64–1.68), respectively. Their whole-rock εNd(t) and zircon εHf(t) values are −6.15 to −5.92 and −5.8 to + 8, respectively. These geochemical characteristics suggest that the Sin Quyen intrusion was produced by the partial melting of ancient crustal sources mingled with mantle-derived components. Geochemically, the Lung Thang, Posen and Sin Quyen intrusions are medium- to high-K, calc-alkaline in nature and show enrichment in LILE (Th, U, K, Rb) and LREE, and strong negative anomalies of Nb, Ta, and Ti. Such geochemical characteristics suggest that they formed in a subduction-related tectonic environment. The geochronological and geochemical correlation of these intrusions with those along the southwestern margin of the Yangtze Block in South China suggests that the Phan Si Pan zone in northwestern Vietnam is a constituent of the SW Yangtze Block. Additionally, these intrusions show a significant correlation with other contemporaneous magmatic rocks in the northeast Indochina Block, Lhasa Block, the northwestern margin of Greater India as well as those in Seychelles and northern Madagascar. This correlation suggests a similar history and synchronous episode of crustal growth/recycling in an Andean-type arc system along the western and northern margin of the Rodinia supercontinent during the Neoproterozoic. [ABSTRACT FROM AUTHOR]

The plain around the intraplate Changbaishan Tianchi volcano in NE China includes monogenetic cones whose shallowest plumbing system consists of dikes, and three main phases of activity are recognized since 2.8 Ma. The monogenetic volcanism mainly developed in the shield-forming phase (2.8–0.3 Ma), but the age and geochemical features of many of these vents remain poorly known. Here, we present geochemical, Sr‒Nd‒Pb isotopic and zircon trace element data from two dikes feeding monogenetic vents located north and northwest of the Changbaishan Tianchi volcano. Our aim is to constrain the emplacement age, the magma evolution processes, and the mantle source. We compare our results with those from the Jingbohu and Longgang monogenetic vents located north and west of the Changbaishan Tianchi volcano to investigate possible mantle heterogeneities in the recent NE China volcanism. The two Changbaishan dikes have 230Th disequilibrium-corrected ages of 1.27 and 1.00 Ma and show a basaltic composition with a potassic affinity. The Mg# values are 35.48–34.27 and 66.09–65.79. The whole-rock compositions, trace element compositions, and Sr‒Nd variations are consistent with fractional crystallization and minor contamination with lower crustal material, indicating an OIB-like mantle source with an EMI component possibly related to fluids released from the underlying Pacific flat slab. The melting depth determined from Na/Ti and Sm/Yb is between 140 and 180 km, i.e. the asthenospheric mantle. The dikes are characterized by (K2O+Na2O)/δEu, La/Ba, Ba/Nb, La/Sm, and La/Nb values similar to those of the Jingbohu and Longgang basaltic rocks. We conclude that the NE China volcanism at approximately 1 Ma was related to a single, relatively homogeneous OIB-like mantle source modified by ascending slab-derived fluids. According to the available geophysical data, the ascending magmas stopped at the mantle/lower crust interface and experienced limited crustal contamination. [ABSTRACT FROM AUTHOR]

High-grade granitoid gneisses (740–710 Ma) and elongate bodies of amphibolite and hornblende schist with cm-scale layers of garnet pyroxenite form an overturned fold in the Gabal Um Gunud area, South Eastern Desert of Egypt. Whole-rock geochemical data combined with zircon U-Pb-Hf isotope data suggest that the metabasites represent relics of oceanic crust with an N-MORB affinity, which has been derived from partial melting (2.0–1.4 GPa; ~65- ~ 45 km depth) of a depleted mantle source beneath an intra-oceanic, spreading forearc basin. Such increment of melting degree resulted in small basaltic melt batches with transitional tholeiitic to boninitic affinities. Progressive slab subduction and partial melting of the tholeiitic amphibolite produced high-Al and low HREE melts for trondhjemite at av. T = 854°C and low-Al and high HREE melts for tonalite at higher temperatures (av. 949°C). The low Mg# of the trondhjemite-tonalite rocks may be attributed to limited contamination of subduction components, as evidenced by the weak lanthanide tetrad effects (TE1,3~1) and near-chondritic Zr/Hf, Nb/Ta, and Y/Ho ratios, while the garnet pyroxenite was the residuum produced in equilibrium with the trondhjemite-tonalite melts. [ABSTRACT FROM AUTHOR]

Across western and northern Chukotka, a region spanning 400 000 km2, we have defined three different tectono-magmatic systems that were active during the Aptian-Albian (123–100 Ma) time span: (1) the Tytylveem post-collisional belt (123–105 Ma); (2) the Chaun province of extension-related magmatism (109–100 Ma); and (3) the earliest eruptive units (106–100 Ma) of the subduction-related Okhotsk-Chukotka volcanic belt (OCVB). The observed tectono-magmatic systems are characterized by their location and by their different chemical and isotopic compositions. The general enrichment of magma sources successively increases from the OCVB to the Tytylveem belt and then to the Chaun province. While the Tytylveem belt was active, the volcanic loci shifted northwest along the strike of the belt, perhaps because of diachronous delamination of the lithosphere of the once present, but extinct, South Anyui ocean. On the scale of the entire region of NE Asia, the tectonic re-arrangement that controlled magmatism in the Early Cretaceous was marked by the extinction of major subduction zones on the periphery of the closing Oimyakon and South Anyui oceanic basins followed by magmatic events likely caused by lithospheric delamination and/or extension. Along the Pacific margin of Asia, subduction-related volcanism was nearly continuous during the entire Cretaceous. [ABSTRACT FROM AUTHOR]

The Santos Basin comprises the most voluminous hydrocarbon accumulations in its 'Pre-salt' reservoirs. Magmatic rocks have been recorded in the basin mostly by the tholeiitic basalts (Camboriú Formation) within its rift megasequence at Hauterivian time. Recent studies have shown that magmatic rocks are also found interbedded with Aptian sedimentary rocks in the basin, related to its post-rift (mostly Aptian) megasequence. This paper presents petrological data obtained from sidewall core samples of magmatic rocks interbedded with Early Aptian coquina in a well drilled in the Santos Basin. The well comprises six magmatic sections of alkaline basalts being overlain and underlain by the Barra Velha limestones. The basalts are mostly plagioclase-phyric, amygdaloidal rocks but vary in texture and modal compositions. Magmatic compositions seem to have been slightly affected by alteration processes. Basalts comprise an alkaline, miaskitic series with relatively evolved compositions (MgO = 5.55 ± 1.50 wt%; Ni < 220 ppm; Cr < 400 ppm). The patterns in the Primitive Mantle normalized multielement diagram displays the typical Nb peak (0.3 < La/Nb(N)<0.7) of the OIB. Geochemical modelling showed that basalts within five magmatic sections are not cogenetic by differentiation, representing basaltic flows emitted from different vents. Modal batch partial melting model indicates that it is possible, although unlikely, to generate the differences in La/Yb(N) and Zr/Y ratios of the least evolved samples in the studied well by different partial melting degrees (0.5–11%) from the same mantle source. Binary mixing models using lithogeochemical datapoint to a role for the Tristan da Cunha plume tail in the petrogenesis of the alkaline basalts with no clear evidence for a possible role for the local subcontinental lithospheric mantle. The results of the petrogenetic models are consistent with a shallow MOHO and a high-temperature mantle below part of the Santos Basin in Early Aptian time. [ABSTRACT FROM AUTHOR]

In the region of Pichilemu (Central Chile), the exhumed roots of the Carboniferous paleo-accretionary wedge developed during subduction of an oceanic realm underneath the western Gondwana margin are exposed. We focus on the areas of Infiernillo beach and Punta de Lobos: the former representing a well-characterized transitional blueschist-facies coherent stack of metabasitic lithologies interlayered at the centimetre- to metre-scale within metasedimentary rocks and glaucophanites, whereas the latter corresponds to a massive, up to hundreds of metres thick, strained metapillow lavas edifice surrounded (not interlayered) by metasedimentary rocks. We provide new field, geochemical, Raman thermometry and zircon SHRIMP U-Th-Pb geochronology on the lithologies forming the Infiernillo-Punta de Lobos complex aiming at characterizing the sedimentary sources and the extent of mechanical mixing. Field observations suggest that the Infiernillo-Punta de Lobos complex can be considered as part of the same successions, subducted and basally accreted almost coherently at high pressure-low temperature (HP-LT) conditions. The geochemistry signal in metasedimentary rocks and maximum deposition ages point to a marked forearc source for all the metasedimentary and glaucophanite lithologies, whereas massive metapillow lavas and greenschists might represent volcanic products and oceanic roughnesses erupted near the trench when the oceanic material approached the Gondwana margin at c. 329 Ma. It is suggested that the interlayering now observed in the field is mostly the consequence of sedimentary and/or volcanic processes close to the trench environment, with minor tectonic reworking of the pre-subduction structures (e.g. lithological contacts). Our results suggest that the Punta de Lobos edifice is closely related to the subduction of large volumes of continent-derived, trench-filling sediments towards HP-LT conditions. Thus, in line with previous experimental and numerical simulations, we emphasize the potential role of oceanic roughness as stress perturbations that could contribute to the subduction of thick sedimentary sequences, and discuss their implications for seismogenesis. [ABSTRACT FROM AUTHOR]

The exposures of the lower member of Um Bogma Formation (Early Carboniferous) in a vast area east of Wadi Baba were studied in six localities. The member is dominated by argillaceous rocks in the western and southwestern occurrences, carbonates in the central sector of the area and sandstones at the east.These rock types, especially the carbonates in Allouga locality, consist of large assemblages of non-radioactive, radioactive and REEs- and base metals- bearing minerals of a mixed allogenic-authigenic and primary-secondary origin. Most of the allogenic minerals were inherited from unaltered and altered precursors in felsic igneous rocks. The results of extensive geochemical studies confirmed varying enrichment of the studied rocks in many trace and rare earth elements as well as base metals. The rocks in Allouga locality and, to a lesser extent, those in Talet Seliem and Abu Zarab have the highest potential as possible resources of these elements. Sequential extraction of Mn, Cu, Fe, Pb, U, Th, Y, La and Dy from five fractions revealed that these elements are exchangeable, bound to carbonates, iron and manganese oxides and organic matter and/or residual. The distributions of trace elements and REEs among the different rock types show variation based on their affinities to specific lithologies. The REEs generally show enriched patterns and negative Eu anomalies. U enrichment in rocks of this member is correlated with the occurrence of several types of uranyl silicate minerals. The co-existence of these minerals reflects variations in the activities of Ca, Mg, Cu and Pb. The hydrothermal activities related to the Red Sea extension were responsible for the oxidation of sulphides, alteration of primary minerals and genesis of Mn oxides, surficial uranyl and REEs mineralisations. Based on the obtained data, certain localities are recommended for future prospecting plans. [ABSTRACT FROM AUTHOR]

The formation and distribution of late Mesozoic volcanic rocks in northeast (NE) China remain unclear due to the superimposed influence of the tectonic regimes of the Mongol–Okhotsk Ocean (MOO) and Palaeo-Pacific Ocean (PPO) in Northeast Asia. This study reports the petrogenesis and tectonic settings of Early Cretaceous volcanic rocks from the Erlian Basin (EB) using petrology, geochronology, whole-rock geochemistry, and Sr–Nd–Hf isotopes. The U–Pb data for the magmatic zircons indicate that the volcanic rocks, including the trachytic rocks and rhyolites, erupted approximately at ~141–135 Ma. Trachytic rocks and rhyolites exhibit comparatively high SiO2 (58.74–65.77 wt. % and 71.35–72.99 wt. %, respectively) and alkali content, low Mg values (mean 25 and 24, respectively), and Cr, Co, and Ni contents, which differ from the geochemical characteristics of mantle-derived magmas. Furthermore, the positive εHf(t) (1.7–10.5) and εNd(t) (2.4–2.9) values of trachytic rocks and the positive εHf(t) values (4.3–6.6) of rhyolites indicate that these rocks were derived from the partial melting of the juvenile crustal materials. The relatively homogeneous zircon Hf isotopes and systematic variation of major and trace elements in these coeval volcanic rocks suggest that they have a common magma source and resulted from the development of the parent magma in the crustal magma chamber. Our results, combined with previous studies, demonstrate that Early Cretaceous volcanism in the EB records an extensional tectonic regime caused by lithospheric delamination after the closure of the MOO. During the Late Cretaceous, NE China was predominantly controlled by the PPO tectonic regime, accompanied by overall uplift and denudation of large-scale faulted basin groups. [ABSTRACT FROM AUTHOR]

Salt plays a vital role in many body functions. Humans must consume a well-balanced amount of salt to remain healthy as deficiency or excess of it causes many health problems. The major oxide element's values are only evaluated while processing for production; however, the type and amount of the trace elements in the salt are also important as they may entail risks for human health. This study concerns the mineralogy and geochemistry of salt samples which are taken from several salt mines and localities in Turkey. In addition, these local samples are compared with well-known samples from Himalayas and Asal Lake (Djibouti Southeast Africa) salt mines. The X-Ray Diffraction (XRD) and Confocal Raman Spectroscopy (CRS) analysis reveal that the most of Turkish salts are mainly composed of halite with minor amounts of thenardite and gypsum as well as the low concentrations of some potentially toxic elements (PTEs) such as As, Cd, Co, Hg, Mn, Ni, Pb and Zn. The samples from Tuz Lake have significant contents of As, Co, Cu, Mn, Ni, U and Zn. The mineralogy and geochemistry of the samples reveal a mixture of residual seawaters with the redissolving of the crystalized salt minerals in the region. Although the quality of the salts is mostly evaluated with the content of NaCl, the significant contents of the PTEs in the salt may be accumulated by time and danger human health. [ABSTRACT FROM AUTHOR]

The Indus Suture Zone preserves the ophiolitic remnants of the eastern part of the Neo-Tethys Ocean. Parts of these ophiolitic remnants are exposed along the Khangral-Chiktan and Dras-Kargil road sections of western Ladakh. The observed rock types include ultramafic-mafic cumulates, gabbros, and volcanics emplaced as faulted blocks over the Mesozoic Dras arc complex. Geochemically, these rocks show sub-alkaline tholeiitic characteristics with basalt to basaltic-andesite compositional variation. Based on modal mineralogy, the ultramafic cumulates classify as olivine-websterite, the mafic cumulates as olivine-norite, and the gabbros as norite to hornblende-gabbro. The ultramafic cumulates depict depleted chondrite normalized REE patterns [(La/Yb)N = 0.6–1.1] while the mafic cumulates display depleted to enriched REE patterns [(La/Yb)N = 0.6–3.2]. Fractionated patterns are observed in gabbros [(La/Yb)N = 1.6–4.1], while flat and enriched chondrite normalized REE-patterns in volcanics [(La/Yb)N = 1.0–12.3] similar to NMORB, and EMORB. The multi-element patterns depict subduction-related geochemical characteristics such as enriched LILE and depleted HFSE compared to the primitive mantle. Presence of Mg-rich olivines, orthopyroxenes, and clinopyroxenes while Ti-poor clinopyroxenes in ultramafic-mafic cumulates reflect their derivation from previously depleted mantle sources at high-pressure and temperature comparable to the base of modern intra-oceanic island arc tholeiitic sequences. The studied rocks exhibit close similarity to an intra-oceanic subduction system contemporaneous to the Dras-Shergol-Suru-Thasgam ophiolitic slices of western Ladakh. [ABSTRACT FROM AUTHOR]

Informed by Māori oral histories that refer to past catastrophic marine inundations, multi-proxy analysis of stratigraphic records from Swamp Bay, Rangitoto ki te Tonga (D'Urville Island) shows evidence of an anomalous deposit extending some 160 m inland. The deposit includes two distinct lithofacies. The lower sand unit is inferred to have been transported from the marine environment, with corresponding increases in the percentages of benthic marine and brackish–marine diatoms, and geochemical properties indicative of sudden changes in environmental conditions. Radiocarbon dating indicates the deposit formation is less than 402 yrs BP, and pollen indicates it is unlikely to be younger than 1870 CE. Core stratigraphy age models and co-seismic chronologies point to the marine unit most likely being emplaced by tsunami transport associated with rupture of the Wairarapa Fault in 1855 CE. The overlying unit of gravel and silt is inferred to be fluvial deposit and slope-wash from the surrounding hills, loosened by ground-shaking following the earthquake. These findings indicate the 1855 CE earthquake may have been more complex than previously thought and, or, available tsunami modelling does not fully capture the local complexities in bathymetry and topography that can cause hazardous and localized tsunami amplification in embayments like Swamp Bay. [ABSTRACT FROM AUTHOR]

A first pass workflow for placing cover sequence materials into four broad lithological groups using A-CNK-FM (Al2O3-CaOþNa2OþK2O-Fe2O3þMgO) and A-CN-K (Al2O3-CaOþNa2O-K2O) ternary diagrams in conjunction with the SiO2 vs Al2O3, Fe2O3 and CaO plus the Ca versus Sr XY diagrams has been derived from lithological logging and laboratory whole-rock geochemistry of 2346 samples. These lithological groups include siliciclastics (quartz sands and clays), weathered material, carbonate lithologies (marine limestone, pedogenic carbonate and compositions intermediate between the two end members) and ferruginous lithologies (including ferricrete and ferruginous sediments). Depositional, weathering and groundwater processes influence sample geochemistry during or after the formation of the material and will influence where the sample will plot on the geochemical diagrams used in this study. Geochemical data for discrete lithologies targeted during sampling (e.g. carbonate lithologies) clusters on diagrams used in the geochemical workflow, whereas data from targeted stratigraphic horizons (e.g. basement-cover interface) are more variable. The ability to characterise rock types that are texturally defined using the geochemical workflow is limited. For instance, the geochemistry of diamictite/conglomerate samples is dependent on the matrix versus clast content and composition as well as the source rock and catchment area. This workflow has the potential to be applied in a mineral exploration environment for rapid interpretation of real-time geochemical (e.g. portable XRF) data to gain an understanding of background geochemistry and geochemical signatures that may be related to underlying mineralisation. [ABSTRACT FROM AUTHOR]

Geochemical data are frequently collected from mineral exploration drill-hole samples to more accurately define and characterise the geological units intersected by the drill hole. However, large multi-element data sets are slow and challenging to interpret without using some form of automated analysis, such as mathematical, statistical or machine learning techniques. Automated analysis techniques also have the advantage in that they are repeatable and can provide consistent results, even for very large data sets. In this paper, an automated litho-geochemical interpretation workflow is demonstrated, which includes data exploration and data preparation using appropriate compositional data-analysis techniques. Multiscale analysis using a modified wavelet tessellation has been applied to the data to provide coherent geological domains. Unsupervised machine learning (clustering) has been used to provide a first-pass classification. The results are compared with the detailed geologist's logs. The comparison shows how the integration of automated analysis of geochemical data can be used to enhance traditional geological logging and demonstrates the identification of new geological units from the automated litho-geochemical logging that were not apparent from visual logging but are geochemically distinct. [ABSTRACT FROM AUTHOR]

Water-driven percussion drilling techniques, such as that used by the RoXplorerVR coiled tubing drill rig, return a rock sample as cuttings that are carried to the surface by the circulating drilling fluid. This drilling technique does not deliver a core sample. In order for the RoXplorerVR to be effective as a mineral-exploration drill rig, it is critical to develop robust, representative and repeatable sampling techniques for the rock cuttings and to establish with confidence the depth interval from which the sample was derived. The RoXplorerVR produces more than 7 kg/m of cuttings every few minutes (rate of penetration dependent) that are carried to the surface by the drilling fluid with a fluid return rate of 80-150 L/min. The cuttings, which range in size from <10 mm to 5 mm, require extraction from the drilling fluid and preparation prior to analysis. Subsampling of the fluid/cuttings stream can reduce the sample size to allow easier processing. A modified static cone splitter and ancillary flow-control system were designed and tested during field deployment of the RoXplorerVR drill rig in South Australia in February 2017. We drilled a vertical hole with RoXplorerVR starting 10m to the northeast of an existing vertical diamond drill hole with well-characterised, shallow-dipping sedimentary and volcanic units. This allows comparison of drilling performance and sample quality against industry-standard drilling and sampling techniques. The performance of the splitter to take a representative continuous 1/8th subsample of drilling fluid and cuttings by volume was assessed based on its ability to resolve a 1m interval of low-grade Cu mineralisation (0.74-1.03 wt% Cu) at 398m that was detected in the reference diamond drill hole. The coiled tubing samples produced an equivalent and unbiased (chemistry and particle-size distribution) subsample, with sub-metre depth accuracy and comparable signal magnitude of the mineralisation at 398m as detected in the diamond core. [ABSTRACT FROM AUTHOR]

The Eastern Pontides in NE Turkey hosts a very limited number of plutonic rocks from the Jurassic period. Here we submit new geochemical, Sr-Nd-Pb and zircon Lu-Hf isotope data, and zircon U-Pb ages for plutonic rocks in this region. Zircon U-Pb dating for the Alemdar and Işıkdere plutons yielded an age of 175–170 Ma (Middle Jurassic). The Alemdar and Işıkdere plutons have I-type, medium to high-K calc-alkaline series, and metaluminous to slightly peraluminous characteristics. On PM-normalized diagrams, the plutons are enriched in large-ion lithophile elements (LILEs) with pronounced depletion of high field strength elements (HFSEs, Ta, Nb, Ti). Chondrite-normalized plots for the plutons show variable enrichment in light rare earth elements (LREEs) with depletion of heavy rare earth elements (HREEs). The rocks of the Alemdar Pluton have homogeneous ISr values (0.70585 to 0.70673), low εNd(i) values (−3.9 to −1.6), pozitif εHf(i) values (+3.3 to +9.1), and Hf single-stage model ages (563–712 Ma), whereas those of Işıkdere have high ISr values (0.70666 to 0.70673), low εNd(i) values (−3.9 to −3.8), εHf(i) values (−3.1 to +1.1), and Hf single-stage model ages (791–969 Ma). These values imply that they have different sources. These results suggest that the magma of the Alemdar was formed by the partial melting of a relatively depleted lithospheric mantle wedge interaction of the OIB-like melts, while those of Işıkdere have derived from the partial melting of an enriched mantle metasomatized by slab-derived sediments and then modified by fractional crystallization and crustal contamination in crustal magma chambers. Considering the available data, we conclude that the studied plutons were related to extensional tectonic events during the Middle Jurassic in response to the roll-back of the Paleotethys oceanic slab in the final stage of oceanic closure. These rocks are an example of the formation of deep subduction products following Early Jurassic subduction. [ABSTRACT FROM AUTHOR]

Modelling and analysis of helicopter electromagnetic data result in resistivity and susceptibility models and derivatives of magnetic data that characterise shallow parts of the Stillwater Complex, critical for aiding exploration and expansion of globally scarce critical and battery mineral resources that include platinum group elements, nickel, copper and chromium. The magnetic susceptibly models derived from the electromagnetic data and the tilt derivative of the magnetic data image layering, mafic dikes, banded iron formation, and serpentinised peridotite. Known areas with contact-type mineralisation are generally characterised by low resistivities and susceptibilities where the volume of mineralised rock is large and/or the depth is shallow. We use iso-cluster and edge detection analysis of both resistivities and susceptibilities to identify potential mineralisation in poorly characterised regions as well as faults. Low resistivity layers beneath large landslides reflect water saturated porous slip surfaces which can interfere with drilling. This uncommon approach of tightly linking the resistivity and susceptibility models and magnetic anomaly data to rock property, surficial geologic, drill hole and soil geochemistry data to image the geology in the upper ∼100 m, aids identification of prospective mineralised regions as well landslides and faults that can impact mineral exploration and local hazards. [ABSTRACT FROM AUTHOR]

The East Kunlun Orogenic Belt (E-KOB) documents successive subduction and accretion processes of the Paleo-Tethyan Ocean. However, the tectonic regime of the E-KOB at the late orogenic stage remains ambiguous. This study presents new results of whole-rock geochemistry and zircon U-Pb-Hf isotopes of the Xidatan pluton in the southern E-KOB. Detailed investigation reveals that the pluton is composed of quartz monzodiorite, host monzogranite, and igneous microgranular enclaves (IMEs). Zircon U-Pb dating results suggest that they are coeval magmatic rocks emplaced at ca. 206–203 Ma. Geochemical studies reveal that the quartz monzodiorite and IMEs share a common magma source, evidenced by consistent compositions of major elements, congruently enriched LREEs and LILEs, and consistently moderately depleted HFSEs and HREEs. Enriched to slightly juvenile zircon Hf isotopes (εHf(t) = −4.24 to +0.49) indicate that the primitive magmas of the quartz monzodiorite and IMEs involve the addition of mantle-derived magmas. The quartz monzodiorite and IMEs have identical ages, and consistent isotope features with the host monzogranite, together with the observation of ingestion of xenocrysts from host felsic rocks into the IMEs indicating that they were produced through the mixing of the mantle-derived mafic magmas and host felsic magmas. In contrast, The host monzogranite has moderately high SiO2 and Na2O+K2O, but low Fe2O3T and MgO contents. It shows crust-like trace element patterns such as strong enrichments in LREEs and LILEs, but remarkable depletions in HREEs. Along with enriched zircon Hf isotopes (εHf(t) = −3.51 to −0.25), the host monzogranite was most likely to have originated from partial melting of lower crustal mafic rocks induced by underplated mantle-derived magmas. Considering abundant Late Triassic igneous rocks across the E-KOB, these new data provide further evidence that the Late Triassic magmatism in the E-KOB may be related to the delamination of thickened orogenic root under an extensional setting. [ABSTRACT FROM AUTHOR]

The East Sulawesi Ophiolite, one of the three largest ophiolites in the world, contains important podiform chromitites. However, the origin of these chromite deposits is not well constrained. Here, we present the detailed mineralogy and in situ chemistry of chromite and solid inclusions within chromite for podiform chromitites from the Kabaena Island, Southeast Sulawesi. Chromite grains have low TiO2 (0.17–0.27 wt%) and Al2O3 (13.4–15.1 wt%) contents and high Cr# [Cr/(Cr+Al), molar] of 0.70–0.74 and Mg# [Mg/(Mg+Fe2+), molar] of 0.69–0.75, which resemble those of other high-Cr podiform chromitites worldwide. The MORB-normalized patterns for some selected major-trace elements of chromite show slightly positive slopes from Al2O3 to Mn. Chromite-hosted silicate inclusions include olivine, clinopyroxene, orthopyroxene and amphibole and are characterized by higher Mg/Fe ratios than those of host peridotites. The geothermobarometry of chromite-hosted clinopyroxene-orthopyroxene pairs indicates that the estimated T-P conditions of the parental magma of the Kabaena chromitites are 950–1010°C and 7.0–8.4 Kbar. The extreme-Mg-rich olivine inclusions (Fo >96) with extremely high Ni (5300–8200 ppm) and Cr (1500–6700 ppm) contents are interpreted to have crystallized from high-Mg and Cr boninitic melts, and the Fo contents were then elevated by subsolidus re-equilibration (Fe–Mg and Fe–Ni exchange) with chromite. Sulfide inclusions contain base metal minerals containing millerite with rare pentlandite and chalcopyrite, and platinum-group minerals that include the laurite-erlichmanite series, Ir–Ni monosulfide, irarsite and cuproiridsite. This sulfide assemblage reveals that their parental magmas experienced the evolution of high T and low f(S2) to low T and high f(S2) from the early to late stage. Finally, combined with the palaeogeographic reconstruction in Sulawesi, we propose that the high-Cr chromitites in this region were formed by the reaction of depleted mantle and boninitic magma beneath a juvenile island arc, implying the initiation of a new subduction in the Miocene. [ABSTRACT FROM AUTHOR]

A descriptive model of calcification in the coralline red algae is integral to understanding their contributions to marine geochemistry, the responses of seascapes to global change, and their own evolution and ecology. Yet, the development of a holistic model of this process has so far been limited by the intrinsic challenge of assembling multiple lines of experimental and observational evidence from varied disciplines. To resolve this synthetic gap, we integrated ultrastructural, geochemical, biochemical and physiological data against a backdrop of anatomy and morphogenesis, which provide context for the localized process at play within the algal thallus. This synthesis represents a comprehensive description of calcification in the coralline red algae. [ABSTRACT FROM AUTHOR]

The danburite crystals from Larak Island are most often doubly terminated and can be quickly distinguished from those from Hormuz, which are characterized by a well-developed {001} face and more modifications including the forms {120}, {110}, {100}, and {011}. Danburite crystals on rhyolitic matrix from Larak Island; specimen width 12 cm, largest crystal 2.5 cm. Vachik Hairapetian specimen and photo. In addition to the differences in crystal size, transparency, and color, crystals of danburite from Hormuz Island tend to develop as more complex clusters than those from Larak Island. Danburite crystals on rhyolitic matrix from Larak Island; specimen width 7.1 cm, largest crystal 1.3 cm. Vachik Hairapetian specimen and photo. [Extracted from the article]

Lamprophyre is one of the most important probes to understand the enrichment and depletion processes of the lithospheric evolution. Determining the age and petrogenesis of lamprophyres could provide critical data for deducing the timing and process of lithospheric revolution of the Sulu Orogenic Belt (SOB) and North China Craton (NCC). In this study, the Taolin lamprophyre in SOB was delineated by zircon U–Pb dating with the ages of 126 Ma. This lamprophyre is characterized by high contents of SiO2 and total alkali contents (Na2O + K2O), low Mg# value, low contents of total Fe2O3, MgO, and compatible elements, enriched in LREE and LILE but strong depleted in HFSE, as well as enriched Sr–Nd and depleted Pb isotope compositions (87Sr/86Sr(i) = 0.707757 to 0.708048, εNd(t) = – 13.0 to – 12.7, 206Pb/204Pb(t) ratios of 16.934 to 17.000, 207Pb/204Pb(t) of 15.435 to 15.442, and 208Pb/204Pb(t) of 37.682 to 37.706). Interpretations of whole-rock elemental data suggest the Taolin lamprophyre was derived from 1% to 5% partial melting of spinel peridotite; and MELTS modelling indicates fractional crystallization of ~16.7% orthopyroxene and ~16.6% clinopyroxene under 1.5 Gbar. Based on the analyses of Neoproterozoic relic zircons and Sr–Nd–Pb isotopic components of the Taolin lamprophyre and adjacent lamprophyres, we put forwards that there are several subducted crustal materials were trapped into the SOB lithospheric mantle, and the magma source of these lamprophyres might have experienced metasomatic processes not only by the hydrous fluids derived from the subducting Paleo–Pacific oceanic crust in the Jurassic, but also by melts derived from partial melting of the subducting South China continental crust in the Triassic. A geodynamic trigger for generation of the Taolin lamprophyre is proposed to be related to lithospheric thinning coupled with asthenospheric upwelling beneath the North China Craton. [ABSTRACT FROM AUTHOR]

Mesozoic igneous rocks are widely distributed in the South China Sea (SCS) and its adjacent areas and are exposed in the SCS, South China, Hainan, Indochina, Taiwan, the Philippines, and Borneo; these rocks are mostly dominated by granitoids. This paper presents a complete map of the Mesozoic igneous rocks of the SCS and its adjacent areas. This paper also presents an analysis of geological survey and published data in terms of seismic profiles, ages, geochemistry and isotopic systematics of the Mesozoic igneous complexes of the SCS and its adjacent areas. Three periods of igneous activity can be distinguished: (1) Permian – Triassic that spans from 250–201 Ma; (2) Jurassic (201–145 Ma); and (3) Latest Jurassic/Cretaceous to Maastrichtian (145–66 Ma), of which the Cretaceous is the best preserved and could possibly be the most widespread. Triassic igneous rocks are distributed in the northwestern and southern SCS (Qiongdongnan Basin, Yinggehai-Song Hong Basin, Beibu Gulf Basin, the Dangerous Grounds, and the Reed Bank); Jurassic igneous rocks are distributed in the northern and southern SCS (Pearl River Mouth Basin, Qiongdongnan Basin, Yinggehai-Song Hong Basin, Beibu Gulf Basin, and the Reed Bank); and Cretaceous igneous rocks are distributed in the northern, western and southern SCS. The igneous activity of the SCS is mostly distributed in the continent slope. Mesozoic igneous rocks of the SCS include at least 350 rock masses: the smallest being 0.182 km2, the largest being 5,5,502 km2, and the total area covering 688,539 km2. Mesozoic magmatism in the SCS and its adjacent areas migrated oceanward (southeastward). Our new seismic profiles and the wells from the literature highlight that Jurassic granites occur not only inland of South China but also in coastal South China and the northern and southern SCS. The YING6 well in the northern SCS encountered andesite with an age of 68.24 Ma, which is the youngest age found for the SCS Mesozoic volcanic rocks. The XY1 well in the western SCS encountered granite with an age of 68.9 Ma, which is the youngest age found for the SCS Mesozoic intrusive rocks. The WZ12-3-1 well in the northern SCS encountered granite with an age of 243.3 Ma, which is the oldest age found for the SCS Mesozoic intrusive rocks. The encountered dacite ages (219.1 ± 1.4 Ma) of the NK-1 well in the southern SCS were the oldest ages found for the SCS Mesozoic volcanic rocks. The thickest Mesozoic igneous rocks (>1022.5 m) were encountered in the NK-1 well. Igneous rocks in the SCS and its adjacent areas are closely related to tectonic movements such as faults, plate movement, and mantle-derived igneous fluid ascent. They are controlled by the subduction of the Tethys lithospheric and Paleo-Pacific domains. [ABSTRACT FROM AUTHOR]

The West Junggar terrain (WJT), as a crucial part of the Central Asian Orogenic Belt (CAOB), is distributed with numerous igneous rocks, which provide critical information for crustal growth. However, the closure of the Junggar Ocean (JO) and the beginning of the postcollisional tectonic stage of the WJT have been controversial. This study delimited the regional lithologic units based on remote sensing geological mapping and recognized a series of bimodal volcanic rocks (BVR) in Hala'alate Mountain of the WJT. LA-ICP‒MS zircon U‒Pb geochronology and geochemistry were used to discuss the petrogenesis of the BVR and determine the stage of regional tectonic evolution. Geochronological results yield crystallization ages of 302 ± 4 Ma, 298 ± 2 Ma, 304 ± 1 Ma, and 303 Ma± 2 Ma for the basaltic andesite, basalt, and two rhyolitic samples, respectively. Basalts and basaltic andesites are calc-alkaline, and display enrichment in light rare earth elements (LREEs) and large ion lithophile elements (LILEs) and depletion in high field strength elements (HFSEs). Notably, basaltic andesites in this area were once misjudged as sanukitoids owing to their low contents of Mg#, Ni, Cr, and other characteristics that are inconsistent with the typical definition of sanukitoids. The rhyolites are A2-type granitoids with high SiO2 contents and are depleted in Nb, Ta, P, Ti, and Sr, showing enriched LREE patterns with negative Eu anomalies. These features indicate that the magma of the mafic end-member of the BVR is derived from the partial melting of the depleted lithospheric mantle, whereas the felsic end-member magma can be associated with the remelting of the lower crust due to the upwelling and underplating of mafic magma. In combination with previous studies of simultaneous basic dikes and felsic rocks, a postcollisional tectonic stage was proposed for the WTJ during the late Carboniferous, suggesting that the JO was closed. [ABSTRACT FROM AUTHOR]

In this paper, we present an integrated study of petrology, zircon U–Pb geochronology, whole-rock geochemistry, and zircon Lu–Hf isotopes for the basic–intermediate dykes in the western Gonghe basin, northeastern Qinghai–Tibetan Plateau. LA–MC–ICP–MS zircon U–Pb dating indicates that these dykes were emplaced in the Middle Triassic (240 ± 1.6 Ma). Geochemically, these basic–intermediate dykes are characterized by enrichments in light rare earth elements (LREEs) and large-ion lithophile elements (LILEs; e.g. K, Rb, and Pb), coupled with depletions in high-field-strength elements (HFSEs; e.g. Nb, Ta, and Ti). These geochemical features, along with the relatively low zircon εHf values (−7.2 to 1.6), suggest that these mafic dykes were originated from enriched mantle metasomatized by subduction-related fluids in a back-arc extensional environment. Literature investigations indicate that Middle Triassic mafic dykes are widespread in central China and are geochemically of arc affinities. Therefore, a regional back-arc extensional event occurred in central China during Middle Triassic time, which was likely caused by rollback of the subducting Kunlun–Animaqin Paleo-Tethyan slab. [ABSTRACT FROM AUTHOR]

The Meghalaya Gneissic Complex (MGC) of northeast India is a little-studied high-grade metamorphic terrain, located close to the Late Palaeoproterozoic to early Neoproterozoic orogenic front. We include mapping, petrography, mineral chemistry, geochemistry, phase equilibria modelling, and U-Th-total Pb monazite geochronology to investigate the evolutionary history of deformed and metamorphosed ortho- and para-gneisses from the central MGC. The metapelite and metamafic rocks of the MGC are folded to E-W upright, antiforms-synforms; and intruded by charnockites during progressive deformations. Reconstructing the metamorphic history of pelite (garnet-cordierite granulite) and two pyroxene granulite, using a TiMnNCKFMASH and TiNCKFMASHO system, reveals a clockwise P–T path where the peak metamorphism was associated with mid crustal burial heating to granulite facies (~825°C and 5.5 to 6.5 kbar) and subsequent cooling with a minor decompression (~ 816°C and 5.3 kbar). Chemically zoned monazites were grown episodically during 1035 ± 13 Ma (n = 21), 976 ± 14 Ma (n = 16), and 494 ± 14 Ma (n = 26). The granulite metamorphism here initiated at 1035 ± 13 Ma and reached thermal peak at 976 ± 14 Ma. This contribution emphasizes the importance of late Mesoproterozoic to early Neoproterozoic metamorphic evolution of the MGC related to the collision of North and South Indian cratonic blocks. The studied P-T path differs from the previously reported Meso- to early Neoproterozoic paths of Central and Western India and close to Western Australia. This finding further explains the change in the early Neoproterozoic collisional pattern of the Central Indian Suture in extreme east (near MGC) and its significance in reconstructing the western Rodinia. [ABSTRACT FROM AUTHOR]

Seagrasses provide crucial ecosystem services in the coastal environment, but are under increasing threat associated with anthropogenic activities. Seagrass meadows effectively trap suspended sediment, a key vector for trace metal transport, by altering local hydrodynamic conditions around their leaves and stems. As a result, seagrass meadows often have different geochemical sediment characteristics compared to adjacent bare sediments and may accumulate higher concentrations of trace metals. The aim of this systematic review was to identify research trends and knowledge gaps in the relationships between metals and seagrasses. The systematic search of the literature identified a total of 191 relevant articles. Although seagrasses have a broad geographic distribution, the highest diversity and endemism exists in the Indo-Pacific region, yet most studies (40%) were conducted in the Mediterranean Sea. There were also taxonomic gaps with some common species groups, including Amphibolis and Thalassodendron spp., being poorly studied. The reviewed studies examined the relationship between seagrass and 39 metal elements. There were no studies examining rare-earth elements (REEs) or platinum-group elements (PGEs), both of which are critical classes of metals in emerging technologies. Furthermore, the review determined that all 191 studies focused on the impact of metals on seagrasses, while only six also considered the effect of seagrasses on metal geochemistry in sediments. We conclude that further research is necessary to address these key gaps in knowledge to better understand the role(s) of seagrasses in the distribution, immobilization, and release of trace metals in coastal ecosystems. [ABSTRACT FROM AUTHOR]

Although the intensity of mining and the amount of opal produced have greatly diminished in comparison to the 1890s, White Cliffs remains the only known locality for "opal pineapples", an apparently unique occurrence of glendonite pseudomorphs (calcite after ikaite) that have subsequently been replaced by opaline silica. Broken precious opal pineapple showing banded opal structure, 9.4 cm. Red Earth Opals specimen, Malcolm Southwood photo. The final arrangement and size of these silica spheres determine whether the resultant opal displays a vivid range of colors (i.e., precious opal) or lacks a play of colors (i.e., common opal or "potch"). Opal pineapple composed of precious opal, 10.7 cm. Red Earth Opals specimen, Malcolm Southwood photo. [Extracted from the article]

The Naxiguole Banded Iron Formation (BIF), located in the Eastern Kunlun Orogenic Belt, Northwest China, is hosted by the Jinshuikou Group and has a Fe of 75 Mt at a grade of 15–28.83 wt.% Fe. In this paper, we use integrated petrological, geochemical, and geochronological data to limit the age and origin of the Naxiguole BIF. Country rocks mainly comprise marble, felsic paragneiss, plagioclase amphibolite schist, and biotite plagioclase gneiss. The features of sedimentary structure (blastopsammitic texture and blastobedding structure) and trace elements (e.g. La, Ni, Zr) from the country rock indicate that their protoliths are sedimentary rock. The 141 detrital zircons from the Jinshuikou Group yield a minimum age of 908 Ma, which can be considered the upper limit for the Naxiguole BIF. According to the age (602 Ma) of the mafic rocks intruding into the Jinshuikou Group, it is reasonable to assume that the formation age of BIF can be limited at 908–602 Ma (i.e. Neoproterozoic). The high contents of Al2O3 + TiO2 (3–6 wt.%), ΣREE (36–135 ppm) for BIF samples suggest that terrestrial clastic material contributed to BIF formation. The BIF samples show seawater-like features, such as depletion in LREEs, positive Y anomaly and high Y/Ho ratios (30.7–57.5, average = 42.5), implying that the Naxiguole BIF precipitated from seawater. The positive Eu/Eu*PAAS anomalies (average 1.52) suggest the influence of high-T hydrothermal fluids. Based on positive Eu anomalies and high terrestrial clastic components and no obvious Ce anomalies, the Naxiguole BIF was formed in an anoxic or suboxic sedimentary basin within active continental island arc, and is similar to Superior-type BIFs worldwide. [ABSTRACT FROM AUTHOR]