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Electrochemical water splitting is considered to be an important method for efficient hydrogen production to alleviate energy shortage and environmental pollution, but its development is currently limited by the slow oxygen evolution reaction (OER). To solve the sluggish reaction kinetics of OER, the focus is on the exploration of low-cost and efficient electrocatalysts, which is quite significant for the development of electrochemical water splitting. Herein, a NiFe layered double hydroxides (LDH) electrocatalyst (denoted as FNH) is achieved by a simple one-step hydrothermal method. The experimental results show that due to the synergistic interaction of introduced Fe species, the FNH possesses a special three-dimensional (3D) vertical nanosheet array structure, which results in efficient ion access. More importantly, the strong electronic interaction between Fe and Ni sites results in the optimized electronic structure of the Ni sites, which not only generates abundant Ni3+ sites as optimized active sites for OER, but also decrease the charge transfer resistance. Thus, the FNH catalyst exhibits an extraordinary overpotential of 386.8 mV to deliver 100 mA cm−2, showing better activity than that of RuO2, and satisfactory cycling stability after continuous operation for 28 h. Our work provides an easy-to-implement method to obtain high-efficiency OER electrocatalysts. [ABSTRACT FROM AUTHOR]

In order to study the characteristics of fire smoke spread and temperature distribution of a large indoor pedestrian street under different heat release rates and smoke exhaust modes, this paper focuses on the analysis of fire smoke spread, visibility, smoke temperature distribution and variation curves in an atrium. This paper uses a numerical simulation method to conduct research. PyroSim fire simulation software is used to calculate this project, which is based on a full-scale experimental design scheme. The numerical simulation results show that under the conditions of higher heat release rate, the smoke spread rate is greater than that under the conditions of lower heat release rate. Furthermore, the average temperature of smoke in the atrium is also greater, up to about 400 °C. The conditions of a higher heat release rate also show the characteristics of faster generation, faster spread and a larger volume of smoke. When the smoke exhaust system is turned on, the thickness of the smoke layer and the smoke temperature decrease. There then comes a situation where the stabile section of the fire ends in advance. The simulation results of vertical temperature distribution in an atrium can fit the modified McCaffrey plume model in any case. Under all cases, the smoke temperature reaches the maximum directly above the fire source. The horizontal dimensionless smoke temperature rises under the atrium roof, and decreases exponentially with the dimensionless distance from the fire source. The greater the heat release rate of fire source is, the smaller the attenuation coefficient is, with a more than 50% change. When the smoke exhaust system is turned on, the smoke flow accelerates and the smoke is cooled rapidly. Thus, the attenuation coefficient increases. Additionally, the effect of mechanical smoke exhaust is better than natural smoke exhaust, because mechanical smoke exhaust makes air flow and heat exchange more intense. The variation amplitudes of the attenuation coefficient under natural smoke exhaust and mechanical smoke exhaust are 13% and 22%, respectively. [ABSTRACT FROM AUTHOR]

In this study, a series of numerical simulations were carried out to investigate the effect of fire shutter descending height on the smoke extraction efficiency in a large space atrium. Based on the full-scale fire experiments, this paper carried out more numerical simulations to explore factors affecting the smoke extraction efficiency in the atrium. The smoke flow characteristics, temperature distribution law and smoke extraction efficiency of natural and mechanical smoke exhaust systems were discussed under different heat release rates and fire shutter descending heights. The results show that the smoke spread rate and the average temperature of the smoke are higher with a greater heat release rate. After the mechanical smoke exhaust system is activated, the smoke layer thickness and smoke temperature decrease, and the stable period of heat release rate is shorter. In the condition of natural smoke exhaust, the smoke extraction efficiency increases exponentially with the increase of heat release rate and the descending height of the fire shutter, and the maximum smoke extraction efficiency is 48.8%. In the condition of mechanical smoke exhaust, the smoke extraction efficiency increases with the increase of mechanical exhaust velocity. When the velocity increases to the critical value (8 m/s), the smoke extraction efficiency is essentially stable. The smoke extraction efficiency is increased first with the increase of fire shutter descending height and then has a downward trend when the descending height drops to half, and the maximum smoke extraction efficiency is 70.3% in the condition of mechanical smoke exhaust. Empirical correlations between the smoke extraction efficiency and the dimensionless fire shutter descending height, the dimensionless heat release rate and the dimensionless smoke exhaust velocity have been established. The results of this study can provide a reference for the design of smoke prevention and exhaust systems in the atrium. [ABSTRACT FROM AUTHOR]

The deterioration of a composite insulator's mandrel will cause a serious power-grid accident, so it is necessary to find the defect as soon as possible. Infrared imaging is an effective means to detect mandrel-deterioration defects, but sheath-aging defects will cause trouble to screen mandrel deterioration. Therefore, it is urgent to distinguish the two defects. In this paper, two composite insulators that are out of service with different heating characteristics are tested and analyzed, and the temperature-rise characteristics are analyzed by building a simulation model. The results show that the temperature rise of composite insulators with oxidative decomposition of epoxy resin is large, and the range usually extends from the hardware of the high-voltage side to several umbrella skirts. The temperature rise caused by the composite insulator with the fiber completely wrapped by epoxy resin is small, which mainly occurs from the hardware to the first umbrella skirt. The simulation model constructed in this paper is consistent with the experimental results, which verifies the accuracy of the model. The model can distinguish the mandrel-deterioration defect and sheath-aging defect, and has guiding significance and important reference value for the detection rate of the mandrel-deterioration composite insulator and ensuring the safe and stable operation of the power grid. [ABSTRACT FROM AUTHOR]