Search

The sealing capacities of shale, roof, and floor strata are essential for the preservation of shale gas. Sealing capacity development and its influence on shale gas composition and organic matter pore development are important but have not been addressed by existing studies. In this paper, the Upper Ordovician Wufeng-the first member of the Lower Silurian Longmaxi Fm. in the Yangtze region is selected as the study object. We dissected the J1 well in the Jiaoshiba block inside the Sichuan Basin and the Y6 well in the Youyang block outside the Sichuan Basin to analyze the gas components and carbon isotopes in recovered shale gas. In this study, two microscope techniques (i.e., FIB-SEM and FIB-HIM), porosity measurement, TOC content analysis, permeability tests, isothermal adsorption measurements, are utilized. The analytical results show that both the roof and floor strata have vertical sealing effects on the organic-rich shale due to their different physical properties compared to the shale. The shale overburden pressure increases with burial depth, and the adsorbed gas increases with increasing TOC content and thickness: all of these can lead to a decrease in permeability and an increase in self-sealing capacity. This paper determined the formation mechanism of the sealing capacity for shale, roof and floor strata. Furthermore, the control patterns of "sealing capacity strength" on the shale gas source and organic matter pore development are clarified. The main findings are as follows: when the shale, roof, and floor strata have a strong sealing capacity, only a small amount of liquid hydrocarbons can be discharged from the shale, but the natural gas formed due to liquid hydrocarbon cracking is abundant. Under such circumstances, shale gas has a mixed origin of liquid hydrocarbon cracked gas and kerogen cracked gas; the carbon isotopes are inverted; abundant pyrobitumen pores with high porosity and good connectivity are developed. When the sealing capacities are weak, the amount of liquid hydrocarbons discharged from the shale are high, and the amount of natural gas is low. The shale gas is mainly derived from kerogen cracking with weak or no carbon isotope inversion, and kerogen pores are small with poor connectivity. These findings will advance the study of shale gas formation mechanisms and provide a scientific basis for selecting shale gas exploration area. • Due to different physical properties, the roof and floor strata provide a seal for the organic-rich shale. • As the burial depth, TOC content, and the shale thickness increase, the shale has a stronger sealing capacity. • Sealing capacity plays an important role in the characteristics of shale gas and organic matter pore development. [ABSTRACT FROM AUTHOR]

Breakthroughs in shale gas exploration in the Upper Ordovician-Lower Silurian strata of the Upper Yangtze Platform have attracted interest in its sedimentary-tectonic evolution, but the tectonic background of the northern margin of the Upper Yangtze Platform remains unclear. In this paper, the Wufeng-Longmaxi formations on the northern margin of the Upper Yangtze Platform were investigated. Based on geochemical and mineralogical analyses of the tuffs/K-bentonites of the Wufeng Formation and the barite in the Longmaxi Formation, as well as previous research results, it was concluded that the northern margin of the Upper Yangtze Platform was in an extensional tectonic background during the Late Ordovician-Early Silurian. Detailed analysis revealed that, (1) the U–Pb zircon age of the tuff in the Bajiaokou section in South Qinling is 443.91 ± 0.92 Ma. The Zr/TiO 2 –Nb/Y diagram of the tuffs/K-bentonites indicates that their protoliths were alkaline-subalkaline basalt and andesite series rock. Based on the Th–Hf/3-Ta, Th–Tb*3-Ta*2, and TiO 2 –Nb/3-Th diagrams, there are undiscovered intraplate tension calc-alkaline basalts in the northern Yangtze Platform or the southern Qinling region, which provided volcanic clastic materials to the Ziyang, Lan'gao, Chengkou, Yichang and other regions. (2) Scanning electron microscopy revealed that the barite crystals in the Longmaxi Formation exhibit dissolution features and have a large particle size. Energy spectrum analysis of these barite crystals revealed that they have C, O, S, and Ba contents of 8.48 wt%, 22.98 wt%, 13.09 wt% and 55.44 wt%, so they are speculated to have been formed via cold methane seep genesis in a weak extensional tectonic setting. The 87Sr/86Sr ratios of the barite revealed that different types of barite were simultaneously formed in this area under the influences of hydrothermal and cold methane seeps. (3) The analysis of the heavy minerals in the Lower Silurian strata in the Bajiaokou section revealed that the provenance in the South Qinling area changed significantly during the late Early Silurian. Based on the above analyses, the northern margin of the Upper Yangtze Platform was in an extensional tectonic setting during the Late Ordovician-Early Silurian. The distribution of the total organic carbon content indicated that the extensional tectonic background provided good conditions for the enrichment and preservation of organic matter. The results of this study provide an understanding of the regional sedimentary-tectonic pattern and evolution of the Yangtze Platform during this period, as well as a reference for future shale gas exploration in this region. • The tectonic background of the Late Ordovician-Early Silurian was studied. • The northern margin of the Upper Yangtze Platform is an extensional background. • The extensional tectonics caused the cold seepage events. • The extensional fault controlled the distribution of volcanic clastic sediments. • Organic matter accumulation was influenced by the extensional fault depression. [ABSTRACT FROM AUTHOR]

The upper Permian Longtan Formation (LTF) shale is a new shale gas exploration and development focus in China, which was formed in a transitional depositional environment. Because of the difference in the sedimentary environment between marine-continental transitional shale and marine shale, the enrichment characteristics and mechanism of organic matter (OM) are very different. Because of a weak research foundation, the enrichment mechanism of OM in the LTF shale in the Sichuan Basin is still unclear. In this paper, shale samples of the upper Permian LTF from the Well F5 were collected, and the abundance, source and sedimentary environment of organic matter were studied by using paleoclimate, detrital input, redox, paleoproductivity and sedimentation rate parameters. The results show that the TOC content of the LTF shale is high (average = 3.04%) and reaches the high to overmature stage (average = 2.46%), indicating a favorable source rock. The LTF shale was deposited in a humid and hot climate, which was conducive to the growth and prosperity of a large number of plants. The source of organic matter was mainly terrestrial plant fragments. The sedimentary environment of the LTF shale was oxic, it had a high sedimentation rate, which reduced the oxidation rate of OM, promoted the rapid deposition of OM, and ensured the preservation of organic matter. In summary, the enrichment of OM of LTF shale in the Sichuan Basin was affected by the sedimentary environment, which was complicated. The main controlling factors were detrital input, redox conditions and sedimentation rate. • The geochemical characteristics of Permian Longtan Formation (PLTF) shale in eastern Sichuan are analyzed. • The sedimentary paleoenvironment of PLTF shale in eastern Sichuan is reconstructed. • The main controlling factors of organic matter enrichment of PLTF in eastern Sichuan are studied for the first time. [ABSTRACT FROM AUTHOR]

In this paper, the original nature of organic matters is introduced for the first time to reevaluate the lower Permian (P 1) source rocks. The carbonate rocks in Maokou Formation (P 1 m) whose high organic carbon values were caused by external asphalt have poor hydrocarbon generation ability, but the argillaceous rocks in P 1 m have some, especially the recent discovered black shale in Gufeng deep-water facies in the north have good hydrocarbon generation ability. The black shale is 5–20 m thick and the measured average value of organic carbon can reach up to 7.24 wt%, which can greatly increase the hydrocarbon generation capacity in the north; The studies of natural gas sources of the lower Permian in eastern Sichuan basin show that the contribution of gas source is mainly Silurian. In the north, the lower Permian source rock is supplemented, while in the south, it's greatly affected by the coal-measure source rocks of Longtan Formation (P 2 l); Take the Wutan-1 well in Tanmuchang as an example to dissect the reservoir in syncline area. The Wutan-1 well has a tested daily production of more than 80 × 104 m3, and the paleotectonic evolution history shows that it was in the high position of the structure during the generation and expulsion peak of hydrocarbon. The fracture-vuggy lithologic reservoir of Wutan-1 well is favorable for hydrocarbon capture and later preservation. According to the above, the Tanmuchang syncline has a good spatio-temporal matching relationship, which is the key to hydrocarbon accumulation and exploration. This knowledge has expanded the exploration area of the Lower Permian Maokou Formation in eastern Sichuan, and more importantly, it brings much enlightenment to the exploration of the syncline areas in Sichuan basin and other basins at home and abroad. • The original nature of organic matters is introduced for the first time to reevaluate the lower Permian source rocks. • The black shale in Gufeng deep-water facies has hydrocarbon generation capacity in the north of the eastern Sichuan Basin. • The sources of natural gas in Maokou Formation are different between the north and the south in the eastern Sichuan Basin. • The syncline area of the Lower Permian Maokou Formation in eastern Sichuan has the potential for gas accumulation. [ABSTRACT FROM AUTHOR]

Details of the Lower Cambrian succession of the newly-discovered intraplatfrom basin of the Yangtze Platform (South China), source rocks of the giant Ediacaran-Cambrian gasfields of the Sichuan Basin, including its stratigraphic framework, redox and organic matter accumulation histories, remain unresolved. This paper describes results of a petrological and geochemical investigation of Lower Cambrian strata near the center of the Sichuan Basin with the goal of elucidating those processes that controlled the sedimentary history of the succession. We recognize two intervals of organic-rich source rocks deposited in the intraplatfrom basin, including the Maidiping Formation and overlying Qiongzhusi Formation. The Maidiping accumulated in a carbonate platform setting during Fortunian-Early Stage 2 time (~541–526.5 Ma) and comprises a variety of rock types, including carbonate, chert, phosphorite, shale, and Mn-ore layers. Total organic carbon (TOC) value ranges from 0.47 to 5.06 wt.%; the highest quality source rocks are found in its lower member. The Qiongzhusi Formation was deposited as part of a clastic shelf during Middle Stage 2-Middle Stage 3 (~526.5–515 Ma) time. This unit is dominated by shale and argillaceous siltstone and displays TOC values varying from 0.30 to 4.28 wt.%. The most organic-rich deposits are found in its lower and upper members. Redox and hydrographic proxies suggest that the intraplatfrom basin was dominated by a strongly restricted environment and anoxic bottom water conditions that experienced intermittent episodes of euxinic or dysoxic-oxic conditions during the Fortunian-Middle Stage 3 time. However, bottom water conditions appear to have been oxic during Late Stage 2 time. Accumulation of Lower Cambrian source rocks across the Yangtze Platform appears to have been closely linked to depositional setting. Our findings suggest that organic matter accumulation in the intraplatfrom basin was fundamentally redox-controlled whereas productivity exerted the greatest control on deposition of organic matter near the slope-deep basin of the Yangtze Platform. In summary, Early Cambrian high-quality source rocks preferentially accumulated in topographic lows, including the intraplatfrom basin and slope-deep basin, an association useful to targeting conventional and unconventional hydrocarbons in the Sichuan Basin. • Stratigraphic framework of the Lower Cambrian deposits in an intraplatfrom basin on the Yangtze Platform were established. • The intraplatfrom basin was dominated by anoxic bottom water with intermittent episodes of euxinic/dysoxic-oxic conditions. • A model depicting controls on OM accumulation across the Yangtze Block during the Early Cambrian was proposed. [ABSTRACT FROM AUTHOR]