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Herein, an efficient one-dimensional (1D) N-doped Co/C nanotube absorber was designed by a cobalt source and solvent ratio comodulation strategy. First, we explored the influences of different cobalt sources (CoCl2, Co-(OAc)2, Co-(NO3)2, and CoSO4) on the morphology and microwave absorption (MA) property, which showed that CoCl2 facilitated the formation of nanotubes with a relatively uniform diameter and length. Notably, the Co/C nanotubes displayed an ultrawide effective absorption bandwidth (EAB) of 6.885 GHz at 2.2 mm when the filling ratio was only 8 wt %. Then, by adjusting the solvent ratio of isopropanol (IPA) and water, Co/C showed a strong absorption of −44.51 dB with an EAB of 5.44 GHz at 2.35 mm. The outstanding MA performance is ascribed to the synergistic effect of dielectric and magnetic components, which is conducive to optimizing the impedance matching, thus broadening the EAB. In addition, the 1D nanostructure is good for constructing three-dimensional (3D) conductive networks and enhancing conductive loss. Since Co nanoparticles are wrapped in carbon nanotubes (CNTs), the confinement effect can effectively prevent the agglomeration of ferromagnetic nanoparticles, adjusting the MA performance. It is worth mentioning that the maximum Radar cross section (RCS) value of Co/C can be reduced by 28.8 dB m2. Furthermore, the RCS values are all lower than −10 dB m2 from −90 to 90° and the minimum RCS value can reach −46.8 dB m2. This work provides a strategy for designing lightweight MA absorbers with strong RL and ultrawide EAB. [ABSTRACT FROM AUTHOR]

The separation of CO2 from flue gases presents a crucial challenge that needs to be addressed. However, membrane processes offer a promising alternative solution. Polysulfone (PSF)membranes were prepared using N-methyl-2-pyrrolidone (NMP) and tetrahydrofuran (THF) using a dry–wet phase inversion technique. The membranes were fabricated with the selection of casting parameters, PSF concentration (20–30 wt%), solvent ratio of THF/NMP (0/100–35/65), and evaporation time (0–4 min). In this work, the interaction between these influencing factors during preparation and membrane performance was studied. Scanning electron microscopy (SEM) was used to characterize the membranes for morphological investigation. Taguchi statistical analysis was employed in the Minitab-19 software used for the design of the experiments in this study, and the responses of the CO2 permeance and CO2/N2 separation factor were analyzed and optimized based on the casting parameters. The results showed the CO2 permeance of the membranes was determined between 1.25 ± 0.04 and 8.47 ± 0.51GPU and selectivity was between 2.95 and 8.92.The statistical analysis indicated that casting conditions affect membrane performance in the following order: PSF concentration > solvent ratio > evaporation time. The optimum parameters for casting solution were the PSF concentration of 20 wt%, THF/NMP ratio of 17.5/82.5, and evaporation time of 4 min. The selected method also reinforces the connection between membrane casting parameters and the observed outcomes in terms of permeation and morphology.

Metal sulfide is often utilized as a catalyzed material to form colorimetric response system for some heavy metal detection. While the aggregation effect and conventional morphology limited the catalyzed efficiency. Herein, a robust method based on morphology adjustment was proposed to improve the dispersibility and catalytic performance of CuS. The results demonstrated when the solvent ratio of ethylene glycol and dimethyl sulfoxide arrived at 3:1, it displayed an optimal structure which is like a patulous flower. Meanwhile, an optimal surface binding energy (ΔE) of 120.1 kcal/mol was obtained via theoretical calculation model. The flower-like structure caused a 2-fold increase in the catalytic level. Subsequently, the CuS was employed to make colorimetric detection of Cr(VI) in water. The assay results exhibited a linear range of the Cr(VI) from 60 to 340 nM, the limit of detection was 1.07 nM. In the practical tests for Qianhu lake water, the spiked recoveries were 93.6% and 104% with the RSD of 4.71% and 3.08%. Therefore, this CuS-based colorimetric method possesses a satisfactory application prospect for the Cr(VI) determination in water. [ABSTRACT FROM AUTHOR]

Inulin is one of many functional food components that becomes a trend nowadays. Inulin can be found in the stems and roots/tubers of plants. Yellow sweet potato (Ipomea batatas L.) is a widespread species of sweet potato with abundant availabilty in Indonesia, where it is exploited only as a source of carbohydrate. From the previous study, it was stated that sweet potato can be used as an alternative resource of inulin besides dahlia and Dioscorea spp. tubers. This study aimed at extracting and isolating inulin from aqueous extract of yellow sweet potato with 3 different ratio (1:1, 1:2, 1:3) and 3 different time (6, 12, 18 hours) to determine its effect on the yield of inulin. After preparation of extracts, crude inulin was precipitated in 96% ethanol. The free reducing sugar from sweet potato flour was tested using Dinitrosalisylic Acid Method (DNS). After precipitation, inulin powder was obtained by an overnight drying process using oven at 60ºC and characterized by color, solubility, water absorption, moisture content and ash content. Its inulin structure was analyzed and confirmed by Fourier Transformed Infrared (FT-IR) spectroscopy. The results showed that different ethanol ratio and precipitating time has effect on the yield of inulin. The highest yield of inulin were 8.80% obtained from solvent ratio 1:3 with 18 hours of precipitating time. It can be concluded that yield of inulin were affected by solvent ratio, precipitating time and degree of polymerization (DP). Higher solvent ratio and precipitating time could obtain higher yield of inulin.

Understanding the phase regulation mechanism of BaTiO 3 synthesized by a hydrothermal method is a complicated and challenging task. Here, we successfully prepared cubic and tetragonal BaTiO 3 single nanocrystals by changing the ratio of water and ethanol in the solvent. We confirm that the BaTiO 3 phase is mainly affected by the hydroxylation process due to the reaction with solvent. In particular, ethanol can be catalytically oxidized by titanium atoms, cause BaTiO 3 hydroxylation and promote the formation of a cubic phase. In the mixed solution of ethanol and water, the hydroxylation process is suppressed, which facilitates the formation of the tetragonal phase. The relationship framework between the solvent ratio, phase structure and hydroxyl defects of BaTiO 3 is established. Tetragonal BaTiO 3 with fewer hydroxyl defects can promote charge transfer and surface reaction after polarization, thereby enhancing their photoelectric catalytic performance. This work provides references for the controllable synthesis of ferroelectric nanocrystals by hydrothermal methods and new insight for the utilization of polarization in photoelectrocatalysis applications. [Display omitted] • Cubic BaTiO 3 were prepared in pure ethanol or water solution due to the hydroxylation effect in the hydrothermal process. • In the mixed solution of ethanol and water, the hydroxylation process was suppressed and tetragonal BaTiO 3 were generated. • The polarization electric field of tetragonal BaTiO 3 has a significant imapct on their photoelectrocatalytic performance. [ABSTRACT FROM AUTHOR]

Lignin is recommended to a tempting alternative precursor of petroleum for fabricating carbon nanofibers (CNFs) due to its high carbon content, low-cost and renewable resources. However, the property of lignin-based carbon nanofibers (LCNFs) is inferior owing to the heterogeneity and 3D-network structure of lignin, which hinders its application in supercapacitors. The latest developments in fractionation technology have shown great potential for overcoming the aforementioned shortcomings. However, most of fractionation methods mainly rely on expensive chemicals and complex reaction process, such as enzymes, multiple solvents, membranes, and dialysis tubes. Herein, we proposed a controllable and effective strategy to fractionate lignin by only changing the ratio of ethanol/water (V/V) as mixture solvent. This gradient extraction method effectively removed the part of lignin with small molecular and branching structure, thus selectively getting the fractionated lignin with high molecular weight, narrow polydispersity index, and good linear structure. Fortunately, when the ratio of ethanol/water was 6:4, the corresponding LCNFs (LCNFs-L60) was obtained with large specific surface area, independent filamentous morphology networks and excellent electrochemical property. Its specific capacitance was up to 405.8 F/g. This way features controllable and sustainable for preparing high-quality LCNFs supercapacitors. [Display omitted] • The high linear structure of sugarcane bagasse lignin was obtained through different solvent ratio fractionation way. • The heterogeneity of fractionated lignin was decreased by screening large molecular weight sugarcane bagasse lignin. • L60 with more β-O-4 structural units and smaller homogeneity was more suitable for fabricating high performance LCNFs. • The LCNFs-L60 showed independent morphology, uniform diameter, large surface area and excellent power storage capacity. • This method was an effective strategy for preparing low-cost and high-quality LCNFs supercapacitors electrodes. [ABSTRACT FROM AUTHOR]

Metal sulfide is often utilized as a catalyzed material to form colorimetric response system for some heavy metal detection. While the aggregation effect and conventional morphology limited the catalyzed efficiency. Herein, a robust method based on morphology adjustment was proposed to improve the dispersibility and catalytic performance of CuS. The results demonstrated when the solvent ratio of ethylene glycol and dimethyl sulfoxide arrived at 3:1, it displayed an optimal structure which is like a patulous flower. Meanwhile, an optimal surface binding energy (ΔE) of 120.1 kcal/mol was obtained via theoretical calculation model. The flower-like structure caused a 2-fold increase in the catalytic level. Subsequently, the CuS was employed to make colorimetric detection of Cr(VI) in water. The assay results exhibited a linear range of the Cr(VI) from 60 to 340 nM, the limit of detection was 1.07 nM. In the practical tests for Qianhu lake water, the spiked recoveries were 93.6% and 104% with the RSD of 4.71% and 3.08%. Therefore, this CuS-based colorimetric method possesses a satisfactory application prospect for the Cr(VI) determination in water.

The separation of CO 2 from flue gases presents a crucial challenge that needs to be addressed. However, membrane processes offer a promising alternative solution. Polysulfone (PSF)membranes were prepared using N -methyl-2-pyrrolidone (NMP) and tetrahydrofuran (THF) using a dry-wet phase inversion technique. The membranes were fabricated with the selection of casting parameters, PSF concentration (20-30 wt%), solvent ratio of THF/NMP (0/100-35/65), and evaporation time (0-4 min). In this work, the interaction between these influencing factors during preparation and membrane performance was studied. Scanning electron microscopy (SEM) was used to characterize the membranes for morphological investigation. Taguchi statistical analysis was employed in the Minitab-19 software used for the design of the experiments in this study, and the responses of the CO 2 permeance and CO 2 /N 2 separation factor were analyzed and optimized based on the casting parameters. The results showed the CO 2 permeance of the membranes was determined between 1.25 ± 0.04 and 8.47 ± 0.51GPU and selectivity was between 2.95 and 8.92. The statistical analysis indicated that casting conditions affect membrane performance in the following order: PSF concentration > solvent ratio > evaporation time. The optimum parameters for casting solution were the PSF concentration of 20 wt%, THF/NMP ratio of 17.5/82.5, and evaporation time of 4 min. The selected method also reinforces the connection between membrane casting parameters and the observed outcomes in terms of permeation and morphology., Competing Interests: The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (© 2024 Published by Elsevier Ltd.)

Highlights • The effect of solvent ratio on Co 2 (OH) 3 Cl was studied for the first time. • The highest capacitance of 321.79 F g−1 was got when V water :V glycol = 1:2. • No obvious capacitance decay was observed after 10,000 cycles. Abstract Co 2 (OH) 3 Cl was synthesized by a facile solvothermal method with different solvent ratios of water/glycol (V water :V glycol). The Co 2 (OH) 3 Cl prepared at the ratio of 1:2 showed uniform cubic nanostructure and provided the highest specific capacitance of 321.79 F g−1 at 0.5 A g−1. The capacitance retention and the Coulombic efficiency were both kept at 100% without obvious decay after continuous 10,000 charge-discharge cycles, demonstrating the durability and eximious stability of the Co 2 (OH) 3 Cl when utilized as the supercapacitor electrode material. [ABSTRACT FROM AUTHOR]

Two new coordination polymers (CPs), namely, [Cu(4-bptzp)(BDC)] ( 1 ) and [Cu 2 (4-bptzp) 2 (BDC)Cl 2 ] ( 2 ) (4-bptzp = 1,4-bis(5-(4-pyridyl)tetrazolyl)propane, H 2 BDC = 1,3-benzenedicarboxylic acid) were synthesized by changing the proportion of the solvents under the solvothermal conditions, and structurally characterized by single crystal X-ray diffraction, infrared spectroscopy (IR), powder X-ray diffraction (PXRD), elemental analyses and thermogravimetric analyses (TGA). The 4-bptzp was firstly introduced into the CPs. Complexes 1 and 2 show two kinds of 1D chain structures. Complex 1 contains the 1D ladder-like [Cu(BDC)] n chains and Cu 2 (4-bptzp) 2 rings, while complex 2 consists of the 1D linear [Cu 2 (BDC)Cl 2 ] n chain containing the bridging Cl − ions and Cu 2 (4-bptzp) 2 rings. The adjacent 1D chains in 1 and 2 are extended to 2D supramolecular layers by the hydrogen bonding interactions, respectively. In addition, the electrochemical properties and dye adsorption properties of complexes 1 and 2 have been investigated. The solvent ratio plays a key role in adjusting their structures and adsorption property. [ABSTRACT FROM AUTHOR]

We have investigated the formation of pixelated red inkjetprinted QDs film in high resolution pixels. We targeted the 60 inch sized 4K UHD format of 73 pixel per inch (ppi), which is 3840 pixels width and 2160 pixels tall. By controlling proper solvent ratio of toluene and 1,2-dichlorobenzene (DCB), we found feasibility to fabricate inkjet-printed QDs film of high resolution and reduce coffee ring effect of inkjet-printed QDs film. [ABSTRACT FROM AUTHOR]

Three groups of polypyrrole (PPy) were synthesised at different mole ratio of FeCl3 to pyrrole of 0·5∶1, 0·75∶1 and 1∶1, and were marked as N-PPy, H-PPy and M-PPy respectively. The effects of oxidant dosage on morphologies, chemical structures, conductivities and especially dielectric properties were contrastively studied, and the influences of solvent ratio (volume ratio of acetonitrile to water) on permittivity and dielectric loss of PPy were also studied for. The results indicate that the variation law and mechanism of morphology of H-PPy and M-PPy are unchanged when compared with N-PPy, as we have reported before. H-PPy shows the highest conductivity and dielectric loss among the three groups of PPy, which can be attributed to the most suitable oxidation and doping degree. As to the solvent ratio effect, we find that all the dielectric parameters decrease with the increase in the volume ratio of acetonitrile to water, which is due to the solvent effect. [ABSTRACT FROM AUTHOR]

• Control of microscopic morphology by modulation of the water-to-alcohol ratio. • The high capacitance of NCS-3 (857C/g) and the capacitance retention rate is 80% (20 A g−1). • Asymmetric supercapacitor shows high energy density 48.7 Wh kg−1 at a power density of 801 W kg−1. Because of high electrical conductivity, theoretical capacity, and numerous redox pairs, NiCo 2 S 4 has sparked a lot of interest in energy storage. In the paper, with citric acid as inductive agent, NiCo 2 S 4 mesoporous microspheres have been successfully prepared via solvothermal approach by regulating the solvent ratio (water/ethanol ratio = 1/3). It reveals that citric acid dominate in the nucleation and orientated growth of NiCo 2 S 4 and the morphology of NiCo 2 S 4 with different submicron structures can be tuned by the ratio of water/ethanol. The morphology, structure, and electrochemical properties of all NiCo 2 S 4 samples have been investigated. Among these samples, NiCo 2 S 4 mesoporous microspheres display the best electrochemical properties due to their unique mesoporous structure and high specific area. It has a high discharge capacity of 857C/g at a current density of 1 A/g, and exhibit exceptional rate capability (80 % retention even at 20 A/g). Additionally, when employed as positive of an asymmetric NiCo 2 S 4 //active carbon (AC) supercapacitor, it yields an energy density of 48.7 Wh kg−1 at 801 W kg−1 and 81 % capacity retention after 10,000 cycles at a current density of 5 A/g. The work describes a quick and easy way to increase the performance of NiCo 2 S 4 electrode materials and demonstrates its potential in practical application. [ABSTRACT FROM AUTHOR]

The YAFAF-based hydrogel was a three-dimensional network cross-linked by grooved fiber bundles. The fiber bundles were formed by entanglement of fibrils with a diameter of 2 nm, and the surface of the fibrils also presented grooves. Spectroscopic analysis revealed that the main secondary structures were β-sheets and β-turns, which led to the grooved feature of fibrils. In comparison of the nuclear magnetic resonance spectra of peptide solutions at 313 and 277 K, the nuclear Overhauser effects can be clearly observed, indicating that hydrogen-bondings and π-π stacking interactions play important roles in self-assembly. The micro-organization of the self-assemblies was affected by the ratio of solvents ( x A ) remarkably. Unexpectedly, x A of 0.05 produced hollow spherical aggregates. The result of these investigations on the mechanism and organization of the YAFAF-based hydrogel can contribute to the development of strategies using hydrogels in the food industry.