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The Role Model Moms (RMM) program supports low-income mothers completing their General Equivalency Diplomas. Postsecondary education (PSE) can break cycles of intergenerational poverty; however, existing PSE orientation resources were not designed for this group. A need existed for a new university resource utilizing a collaborative and community-engagement approach to provide tailored information on PSE for RMM participants. The RMM Post-Secondary Academy was developed to bridge this gap. It was evaluated via facilitator debriefing sessions, post-event surveys, and participant interviews, with results analyzed using basic statistics and descriptive thematic analysis. The event has run for three iterations, inviting 42, 45, and 38 women, respectively. Participants improved their understanding of and outlook on PSE. Their PSE concerns included family, financial, and academic barriers. This event provides a replicable model for responsive and cost-effective community programming. Community engagement ensured the content was relevant and applicable to the target audience.

Severe photogenerated charge carrier recombination involved in photocatalytic CO2 reduction leads to low photocatalytic efficiency. Here we demonstrate that a chiral hierarchical structure could facilitate charge separation in BiOBr, thus suppressing charge recombination and enhancing photocatalytic performance. Chiral helical flower-like BiOBr nanospheres were prepared via a D / L -sorbitol-assisted hydrothermal process, exhibiting a 1.1-fold increase in photocatalytic CO2 reduction activity compared to the achiral counterparts. This enhancement is attributed to the chiral-induced electron spin polarization regulation, as confirmed by photoluminescence and electrochemical characterizations. This work opens an alternative avenue for the design of high-performance photocatalysts. [ABSTRACT FROM AUTHOR]

Tin halide perovskites are the most promising candidate materials for lead‐free perovskite solar cells (PSCs) thanks to their low toxicity and ideal band gap energies. The introduction of 2D/3D mixed perovskite phases in tin‐based PSCs (TPSCs) has proven to be the most effective approach to improving device efficiency and stability. However, a 2D perovskite phase normally shows relatively low carrier mobility, which will be unfavorable for carrier transfer in the devices. In this work, we used a thiophene‐based cation 2‐(thiophen‐3‐yl)ethan‐1‐aminium (3‐TEA) as a spacer to form a novel 2D perovskite phase in TPSCs, which shows the most promising effect on the performance enhancement in comparison with other cations like 2‐(thiophen‐2‐yl)ethan‐1‐aminium (2‐TEA) and benzene‐based 2‐phenylethan‐1‐aminium (PEA). Theoretical calculations reveal that 3‐TEA enables the most compact crystal packing of [SnI6]4− octahedral layers, resulting in the lowest hole effective mass and formation energy in the 2D phase. This effect significantly enhances device efficiency and stability by facilitating more efficient carrier transfer within the 2D phase. These findings indicate that thiophene‐based 2D perovskites are well‐suited for high‐performance TPSCs. [ABSTRACT FROM AUTHOR]

The digital capabilities driven by Internet of Things and affiliated techniques have enabled the prevailing service-oriented business models, among which servitization has been well recognised as one of the most competitive strategies for manufacturing companies. However, manufacturing companies usually show a lack of knowledge regarding the service offering associated to their manufactured products. Acquiring external knowledge from service providers is one effective way to tackle this problem, but due to the information asymmetry, the process of knowledge sharing between the two is often faced with a prisoner's dilemma game. Meanwhile, the company's game strategy will change with the evolution of the knowledge sharing network structure. We therefore consider the influence of group spatial structure on individual game strategy, marry a canonical evolutionary game model on the decision-making mechanism of individuals to the complex network theory on the interaction behaviour among individuals in the groups. By analysing the model, we reveal the influence of various factors under the dimensions of ability and benefit on the willingness of companies to share knowledge. We also demonstrate the divergence in the influence of various factors on different types of companies. [ABSTRACT FROM AUTHOR]

Endoscopic antireflux therapy is widely used in clinical practice. Peroral endoscopic cardial constriction (PECC), antireflux mucosal intervention (ARMI), and radiofrequency ablation (RF) possess analogous antireflux mechanisms. This comprehensive systematic review and meta-analysis aimed to evaluate and compare the safety and effectiveness of antireflux therapy during endoscopic cardia peripheral tissue scar formation (ECSF) procedures. We comprehensively searched the Web of Science, PubMed, Embase, China National Knowledge Infrastructure, and Wan-Fang databases for articles published from January 1990 to January 2024. Network meta-analysis (NMA) was used to assess the outcomes, with outcome metrics including the Gastroesophageal Reflux Questionnaire (GERD-Q) score, proton pump inhibitor discontinuation rate, pH <4.2 percent acid reflux time (AET), lower esophageal pressure (LES pressure), DeMeester score, adverse events, and patient satisfaction. Twenty studies involving 1219 patients were included. PECC was significantly superior to RF in lowering the patients' postoperative GERD-Q scores(MD = -2.34, 95% confidence interval (CI): [-3.02, -1.66]), augmentation of LES pressures(MD = 3.22, 95% CI: [1.21, 5.23]), and having a lower incidence of serious adverse events. ARMI was preferable to PECC (MD = -2.87, 95% CI [-4.23, -1.51])and RF (MD = -1.12, 95% CI [-1.79, -0.54]) in reducing the AET percentage, but was not as effective as PECC in lowering GERD-Q scores(MD = -1.50, 95% CI [-2.47, -0.53]). The incidence of adverse effects was less than 10% for all interventions, with most of them mildly self-resolving. Each ECSF procedure resulted in a favorable outcome in patients with GERD. Considering the safety and efficacy of treatment, PECC was the most favorable choice among ECSF procedures. [ABSTRACT FROM AUTHOR]

Connectives are crucial in constructing coherent discourse by signalling relationships across sentences and triggering presuppositions. This event-related potential study investigated how the type and presence of connectives influence sentence processing. Participants read sentences with because, although, or no connective, where critical words were either congruent or incongruent with the clausal relation specified by connectives. Incongruent words elicited a larger N400 than congruent words, regardless of the connective type or its presence. In later processing stages, incongruency induced an extended N400 effect in concessive contexts but a P600 effect in causal and no-connective contexts. Additionally, a larger P600 was observed in concessive-congruent versus causal-congruent conditions, indicating a greater effort to reconcile the concessive-triggered presupposition with the proposition. These findings suggest that connective-triggered presuppositions constrain both the initial evaluation of language input against broad contextual knowledge and the subsequent integration into discourse representation, supporting an Evaluation and Integration model of presupposition processing. [ABSTRACT FROM AUTHOR]