1. Synthesis and structure of tri(p-tolyl)antimony diaroxides
- Author
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T. P. Platonova, O. K. Sharutina, A. P. Pakusina, V. K. Bel'skii, and Vladimir V. Sharutin
- Subjects
Stibine ,Chlorine atom ,Inorganic chemistry ,chemistry.chemical_element ,General Chemistry ,010402 general chemistry ,010403 inorganic & nuclear chemistry ,01 natural sciences ,Copper ,Medicinal chemistry ,Chloride ,0104 chemical sciences ,Trigonal bipyramidal molecular geometry ,chemistry.chemical_compound ,chemistry ,Antimony ,medicine ,Chlorine ,medicine.drug - Abstract
Tri(p-tolyl)antimony dichloride was prepared by oxidation of tri(p-tolyl)stibine with chlorine or copper(II) chloride. As found by X-ray diffraction analysis, the antimony atom in tri(p-tolyl)antimony dichloride has the configuration of trigonal bipyramid with axially located chlorine atoms. The Sb-Cl and Sb-C distances are 2.476(2) and 2.104(7) A, and the CSbC and ClSbCl angles are 120 and 180°, respectively.
- Published
- 2016
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