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1. Study region The Clare Valley region of South Australia. 2. Study focus Continuing extraction of groundwater threatens pools in seasonal and permanent streams. In order to determine this groundwater dependence, the pools and groundwater from corresponding fractured rock aquifers were investigated using environmental tracers (δD, δ18O, 87Sr/86Sr, and major and minor elements). For the 11 paired pool-groundwater sites in the four different catchments, groundwater dependence was evaluated over a four season sampling period. 3. New hydrological insights In this Mediterranean climate with cool wet winters and dry hot summers strong salinity changes (up to 2.5 times) due to seasonal cycles of wetting and drying were observed in surface water. Oxygen and hydrogen isotope values from pool sites showed strong evaporative enrichment during the dry season with up to 50% net evaporation calculated. Water isotopes from groundwater, however, cluster at the depleted end of the local meteoric water line and most do not show change despite significant seasonal salinity changes. Strontium isotope values and concentrations from the pools over the one year period do not define a mixing relationship. Instead, most pool sites have unchanging strontium isotope values despite the large seasonal change in salinity indicating strong evaporation of groundwater fed pools during this drought year.

1. The dissolved organic matter (DOM) biogeochemistry of intermittent rivers is affected by periods of disconnection and drying after cessation of surface flow, with a pronounced concentra tion of solutes as pools evaporate and contract. However, inputs of alluvial ground water to stream pools may offset the effects of evaporation and influence the quantity and composition of DOM. 2. We used δ18 O and δℑ²H values of surface water and alluvial ground water (AW) together with DOM fluorescence excitation-emission spectroscopy to investigate changes in DOM biogeochemistry of pools from four intermittent streams in semi-arid north-west Australia. Our objective was to deter mine whether the fluorescence characteristics of DOM in pools are driven by their connectivity to alluvial ground water. 3. Pool water δ18O values ranged from -8 to 13.1‰ & and showed progressive enrichment as pools became disconnected from AW and subsequently evaporated. Parallel factor analysis of DOM fluo rescence revealed that DOM in pools was generally dominated by humic-like components, with les ser contributions from tryptophan-like and tyrosine-like components. 4. DOC concentrations were higher in more evaporated pools. Humic-like and tryptophan-like DOM were also highest in pools isolated from AW, suggesting that inputs of AW had a dilution effect while also moderating evaporative concentration of solutes. In contrast, tyrosine-like DOM was only weakly correlated with the hydrological status of pools. 5. The proportion that each component contributed to total DOM fluorescence remained mostly consistent across both AW-connected and evaporating pools. However, some pools with AW through-flow had higher contributions from tyrosine-like fluorescence and lower contributions from humic-like fluorescence. 6. Disconnection from AW and subsequent evaporative concentration of solutes is an important control on DOM fluorescence characteristics in these intermittent streams. However, production and removal of DOM were only rarely influenced by AW connectivity, likely reflecting the high hydrological variability of intermittent rivers, even following cessation of surface flow. [ABSTRACT FROM AUTHOR]