Search

In this paper, we investigate the problem of optimal supervisory control for the discrete event systems under energy constraints. We consider that the execution of events consumes energy and the energy can be replenished at specific reload states. When the energy level drops below zero, the system will be crashed. To capture the above scenario, we introduce a new model, called consumption discrete event system (cDES). Our objective is to find the minimal initial energy value and synthesize an optimal supervisor ensuring that the energy will never be exhausted. To solve this problem, we propose a game-theoretical approach by converting the cDES as a consumption two-player graph game (cTPG) and reformulate the optimal supervisory control problem in game theory. In particular, we demonstrate that the converted game can be decomposed into independent reachability games related to reload vertices, which can be solved by a fixed point iterative algorithm proposed in this paper. Through iteratively removing unsafe reload vertices and solving reachability games for the remaining reload vertices, a solution can be found., Comment: We will add richer content

Symmetry engineering is explicitly effective to manipulate and even create phases and orderings in strongly correlated materials. Flexural stress is universally practical to break the space-inversion or time-reversal symmetry. Here, by introducing strain gradient in a centrosymmetric antiferromagnet Sr2IrO4, the space-inversion symmetry is broken accompanying a non-equivalent O p-Ir d orbital hybridization along z axis. Thus, emergent polar phase and out-of-plane magnetic moment have been simultaneously observed in these asymmetric Sr2IrO4 thin films, which both are absent in its ground state. Furthermore, upon the application of magnetic field, such polarization can be controlled by modifying the occupied d orbitals through spin-orbit interaction, giving rise to a flexomagnetoelectric effect. This work provides a general strategy to artificially design multiple symmetries and ferroic orderings in strongly correlated systems.

Mapping the electrostatic potential (ESP) distribution around ions in electrolyte solution is crucial for the establishment of a microscopic understanding of electrolyte solution properties. For solutions in the bulk phase, it has not been possible to measure the ESP distribution on Angstrom scale. Here we show that liquid electron scattering experiment using state-of-the-art relativistic electron beam can be used to measure the Debye screening length of aqueous LiCl, KCl, and KI solutions across a wide range of concentrations. We observe that the Debye screening length is long-ranged at low concentration and short-ranged at high concentration, providing key insight into the decades-long debate over whether the impact of ions in water is long-ranged or short-ranged. In addition, we show that the measured ESP can be used to retrieve the non-local dielectric function of electrolyte solution, which can serve as a promising route to investigate the electrostatic origin of special ion effects. Our observations show that, interaction, as one of the two fundamental perspectives for understanding electrolyte solution, can provide much richer information than structure., Comment: The small-angle signal in Fig. 2 C-H is highly likely to be an experimental artifact, due to that the electron beam is placed too close to the edge of the liquid sheet. This artifact invalidates the main conclusion of the paper

One of the great challenges facing atomically dispersed catalysts, including single-atom catalyst (SAC) and double-atom catalyst (DAC) is their ultra-low metal loading (typically less than 5 wt%), basically limiting the practical catalytic application, such as oxygen reduction reaction (ORR) crucial to hydrogen fuel cell and metal-air battery. Although some important progresses have been achieved on ultra-high-density (UHD) SACs, the reports on UHD-DACs with stable uniform dispersion is still lacking. Herein, based on the experimentally synthesized M2N6 motif (M = Sc-Zn), we theoretically demonstrated the existence of the UHD-DACs with the metal loading > 40 wt%, which were confirmed by systematic analysis of dynamic, thermal, mechanical, thermodynamic, and electrochemical stabilities. Furthermore, ORR activities of the UHD-DACs are comparable with or even better than those of the experimentally synthesized low-density (LD) counterparts, and the Fe2N6 and Co2N6 UHD-DACs locate at the peak of the activity volcano with ultra-low overpotentials of 0.31 and 0.33 V, respectively. Finally, spin magnetic moment of active center is found to be a catalytic descriptor for ORR on the DACs. Our work will stimulate the experimental exploration of the ultra-high-density DACs and provides the novel insight into the relationship between ORR activity of the DACs and their spin states., Comment: Accept; Physical Review Applied, online https://journals.aps.org/prapplied/accepted/6e070Ad3M481130513b194765dfdaa4e7c6b6b46d

Nucleus is a typical many-body quantum system. Full calculation of a nuclear system in a classical computer is far beyond the capacity of current classical computers. With fast development of hardware, the prospect of using quantum computers in nuclear physics is closing. Here, we report a full quantum package, QCSH, for solving nuclear shell-model in a quantum computer. QCSH uses the linear combination of unitaries formalism of quantum computing, and performs all calculations in a quantum computer. The complexities of qubit resource, number of basic gates of QCSH, are both polynomial to the nuclear size. QCSH can already provide meaningful results in the near term. As examples, the binding energies of twelve light nuclei, $^{2}$H, $^{3}$H, $^{3}$He, $^{4}$He, $^{6}$Li, $^{7}$Li, $^{12}$C, $^{14}$N, $^{16}$O, $^{17}$O, $^{23}$Na and $^{40}$Ca are calculated using QCSH in a classical quantum emulator. The binding energy of Deuteron has already been experimentally studied using QCSH on a superconducting quantum computing device. QCSH not only works in near-term quantum devices, but also in future large-scale quantum computers. With the development of quantum devices, nuclear system constitutes another promising area for demonstrating practical quantum advantage.

Fundamental symmetry breaking and relativistic spin-orbit coupling give rise to fascinating phenomena in quantum materials. Of particular interest are the interfaces between ferromagnets and common s-wave superconductors, where the emergent spin-orbit fields support elusive spin-triplet superconductivity, crucial for superconducting spintronics and topologically-protected Majorana bound states. Here, we report the observation of large magnetoresistances at the interface between a quasi-two-dimensional van der Waals ferromagnet Fe0.29TaS2 and a conventional s-wave superconductor NbN, which provides the possible experimental evidence for the spin triplet Andreev reflection and induced spin-triplet superconductivity at ferromagnet/superconductor interface arising from Rashba spin-orbit coupling. The temperature, voltage, and interfacial barrier dependences of the magnetoresistance further support the induced spin-triplet superconductivity and spin-triplet Andreev reflection. This discovery, together with the impressive advances in two-dimensional van der Waals ferromagnets, opens an important opportunity to design and probe superconducting interfaces with exotic properties.