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In this work, four different techniques were concurrently applied to study the interplay between local electroactivity and electrode surface characteristics of free-standing, polycrystalline boron-doped diamond (BDD). Scanning electron microscopy, electron back-scatter diffraction, Raman mapping and scanning electrochemical microscopy were used to probe the electrode morphology, grain orientation and boundaries, composition, and local electrochemical activity, respectively. Both nucleation and growth BDD surfaces together with the cross-section area were carefully investigated for the first time in a single study using the combination of all four techniques. This enabled us to obtain significant insights into the highly heterogeneous nature of the polycrystalline BDD material. Notably, boron dopants were confirmed to be non-uniformly distributed over the BDD material, which is characterized by a distinct columnar structure and composition of grains of various orientations. Particularly, the highest electrochemical activity was recorded on the highest doped (111) crystal orientation. In contrast, the averagely boron-doped (100)-oriented facet showed non-conductive nature. This highlights that the local electrochemical activity of the BDD surface is strongly grain-dependent and the most significant factors governing the obtained responses are crystallographic orientation and boron doping. Moreover, increased boron and sp2 carbon content in the boundary regions was recognized by Raman mapping. However, such localized enrichment in impurities did not translate into enhanced electrochemical activity, which implies that boron atoms at the inter-grain areas are predominantly inactive. Finally, it is crucial to consider all characteristics of the polycrystalline BDD including crystal orientation, which is particularly relevant if micro- and nanoscale probing is intended., Micro and Nano Engineering, Team Arjan Mol, Team Yaiza Gonzalez Garcia

Integrated single-molecule force-fluorescence spectroscopy setups allow for simultaneous fluorescence imaging and mechanical force manipulation and measurements on individual molecules, providing comprehensive dynamic and spatiotemporal information. Dual-beam optical tweezers (OT) combined with a confocal scanning microscope form a force-fluorescence spectroscopy apparatus broadly used to investigate various biological processes, in particular, protein:DNA interactions. Such experiments typically involve imaging of fluorescently labeled proteins bound to DNA and force spectroscopy measurements of trapped individual DNA molecules. Here, we present a versatile state-of-the-art toolbox including the preparation of protein:DNA complex samples, design of a microfluidic flow cell incorporated with OT, automation of OT-confocal scanning measurements, and the development and implementation of a streamlined data analysis package for force and fluorescence spectroscopy data processing. Its components can be adapted to any commercialized or home-built dual-beam OT setup equipped with a confocal scanning microscope, which will facilitate single-molecule force-fluorescence spectroscopy studies on a large variety of biological systems., BN/Nynke Dekker Lab

Catch bonds are a rare class of protein-protein interactions where the bond lifetime increases under an external pulling force. Here, we report how modification of anchor geometry generates catch bonding behavior for the mechanostable Dockerin G:Cohesin E (DocG:CohE) adhesion complex found on human gut bacteria. Using AFM single-molecule force spectroscopy in combination with bioorthogonal click chemistry, we mechanically dissociate the complex using five precisely controlled anchor geometries. When tension is applied between residue #13 on CohE and the N-terminus of DocG, the complex behaves as a two-state catch bond, while in all other tested pulling geometries, including the native configuration, it behaves as a slip bond. We use a kinetic Monte Carlo model with experimentally derived parameters to simulate rupture force and lifetime distributions, achieving strong agreement with experiments. Single-molecule FRET measurements further demonstrate that the complex does not exhibit dual binding mode behavior at equilibrium but unbinds along multiple pathways under force. Together, these results show how mechanical anisotropy and anchor point selection can be used to engineer artificial catch bonds., BN/Nynke Dekker Lab

Chromatin replication involves the assembly and activity of the replisome within the nucleosomal landscape. At the core of the replisome is the Mcm2-7 complex (MCM), which is loaded onto DNA after binding to the Origin Recognition Complex (ORC). In yeast, ORC is a dynamic protein that diffuses rapidly along DNA, unless halted by origin recognition sequences. However, less is known about the dynamics of ORC proteins in the presence of nucleosomes and attendant consequences for MCM loading. To address this, we harnessed an in vitro single-molecule approach to interrogate a chromatinized origin of replication. We find that ORC binds the origin of replication with similar efficiency independently of whether the origin is chromatinized, despite ORC mobility being reduced by the presence of nucleosomes. Recruitment of MCM also proceeds efficiently on a chromatinized origin, but subsequent movement of MCM away from the origin is severely constrained. These findings suggest that chromatinized origins in yeast are essential for the local retention of MCM, which may facilitate subsequent assembly of the replisome., BN/Nynke Dekker Lab

The inclusion of the informal recycling sector (IRS) in a circular economy (CE) is challenging and it is gaining increasing attention by the academic community in an exponential yet fragmented way. In this narrative review, we demarcate the direct and indirect contributions of the IRS to various domains of the CE by drawing knowledge from relevant literature. First, we capture the modi operandi of different forms of recycling value chains into a typology. We do so based on distinct foci and policy approaches towards the IRS which have been adopted across different countries. Second, we synthesize various threads of information on reported forms of collaboration, tensions, and challenges in the context of urban waste management, into a conceptual framework to facilitate transitions towards circular and inclusive wise-waste systems. Finally, we discuss important aspects related to circular business models and integration approaches towards the IRS, and we propose avenues for further research., Integral Design & Management

In this paper, we propose a method to reconstruct a digital 3D model of a stolen/damaged statue using photogrammetric methods. This task is challenging because the number of available photos for a stolen statue is in general very limited – especially the side/back view photos. Besides using standard structure-from-motion and multi-view stereo methods, we match image pairs with low overlap using sliding windows and maximize the normalized cross-correlation (NCC) based patch-consistency so that the image pairs can be well aligned into a complete model to build the 3D mesh surface. Our method is based on the prior of the planar side on the statue’s pedestal, which can cover a large range of statues. We hope this work will motivate more research efforts for the reconstruction of those stolen/damaged statues and heritage preservation., Mechatronic Design, Emerging Materials

Realizing a circular economy (CE) has been widely recognized by practitioners and researchers as the key to the transition toward sustainability. Thus far the academic emphasis has been predominantly on economic and environmental aspects. However, the development and implementation of CE initiatives actually rely on extensive collaboration at the societal level. Hence, an understanding of how a more inclusive society can strengthen the transition is warranted. By systematically and critically reviewing the related academic literature, the results of this paper show that sensitivity to inclusion aspects is crucial to alleviate the transitional burdens on society. Seven main aspects were discerned on inclusion: (1) informal waste pickers, (2) e-waste and health risks, (3) accessibility of services/materials/facilities, (4) consumer behavior, (5) corporate and institutional involvement, (6) technology application, and (7) governance measures. Following these insights, a strong sustainability perspective and agenda on the CE transition are proposed by identifying key actors and structuring their interrelationships as an inclusive system., Integral Design & Management

Rapid global urbanization, urban renewal and changes in people's lifestyles have led to both an increase in waste generation and more complex waste types. In response to these changes, many local governments have invested in municipal solid waste infrastructure (MSWI) to implement circular strategies. However, matching and bridging the costly and logistically complex MSWI with the dynamic social context is a central challenge. In this paper we aim to explore the interdependencies between MSWI and the local social system, and then conceptualize and empirically validate the systemic nature of MSWI. We first review the current MSW treatment methods, corresponding infrastructure, and the challenges facing them. Then, we interrogate system-oriented concepts and use two key insights to set up a conceptual model for mapping the interdependencies in a MSWI system (MSWIS). Finally, a case study of the Dutch city of Almere is used to empirically validate the MSWIS model and identify the social systems that contribute to the development of the MSWIS. The analysis reveals that the development of MSWIS is beyond the municipality's control: efficient resource recovery facilities established by businesses under market rules and waste reuse facilities constructed by social organizations/individuals based on their own needs are key pieces of the puzzle to complete the MSWIS. This highlights the ability of the framework to capture interdependencies that go further than just the formal municipal sphere of influence., Integral Design & Management, Real Estate Management

As an effective way to facilitate the increasing demand for reliable infrastructure, energy supply and sustainable urban development, underground utility tunnels have been developed rapidly in recent years. Due to the widespread distribution of utility tunnels, the safe operation of natural gas pipelines accommodated in utility tunnels has caused great concern considering fire, explosion, and other coupling consequences induced by the gas pipeline leakage. However, the limited information on leakage source terms in accidental leakage scenarios could preclude timely consequence assessment and effective emergency response. In this study, a BI-IEnKF coupling source term estimation (STE) model is developed, with the combination of gas dispersion model, Bayesian inference (BI) and iterative ensemble Kalman filter (IEnKF) method, to achieve the effective source term estimation (including leakage location and leakage rate) and gas concentration distribution prediction. The newly developed model is first evaluated by the twin experiment with good reliability and accuracy. Furthermore, three contributing factors affecting the performance of the developed BI-IEnKF coupling STE model were investigated to assist parameter selection for practical use. Additionally, the novel application of mobile sensors serving as an alternative for fixed sensors is explored, and an application framework is sequentially given to guide the deployment of the developed coupling model in utility tunnels. The results show that the developed model has great performance in accuracy, efficiency and robustness, as well as the potential to be applied in actual utility tunnel scenarios. This study can provide technical supports for safety control and emergency response in the case of natural gas pipeline leakage accidents in utility tunnels. Also, it could be helpful to reasonable references for gas lekage monitoring system design., Green Open Access added to TU Delft Institutional Repository ‘You share, we take care!’ – Taverne project https://www.openaccess.nl/en/you-share-we-take-care Otherwise as indicated in the copyright section: the publisher is the copyright holder of this work and the author uses the Dutch legislation to make this work public., Civil Engineering & Geosciences, Safety and Security Science

Hydrate dissociation is often accompanied by the formation of nanobubbles. Knowledge of the effects of nanobubbles on hydrate dissociation is essential for understanding the dynamic behavior of the hydrate phase change and improving the gas production efficiency. Here, molecular dynamics simulations were performed to study the methane hydrate dissociation kinetics with and without a pre-existing methane nanobubble. The results show that the hydrate cluster in the liquid phase dissociates layer-by-layer. This process is shown to be independent of the temperature and nanobubble presence at the simulation conditions. Hydrate dissociation does not always lead to nanobubble formation because the supersaturated methane solution can be stable for a long time. A steep methane concentration gradient was observed between the hydrate cluster surface and the methane nanobubble, which can enhance the directional migration of methane and effectively minimize the methane concentration in the liquid phase, thereby increasing the driving force for the hydrate dissociation. Our findings indicate that the presence of a nanobubble near the hydrate surface does not decrease the activation energy of hydrate dissociation, but it can increase the intrinsic decomposition rate. The average hydrate dissociation rate is linearly correlated with the mass flow rate towards the nanobubble. The mass flow rate is determined by the nanobubble size and hydrate-nanobubble distance. Our findings contribute to the fundamental understanding of the dissociation mechanism of gas hydrates in the liquid phase, which is crucial for the design and optimization of efficient gas hydrate production techniques., Engineering Thermodynamics

Garments, one of the human basic needs, were customized and handmade before the Industrial Revolution. After the realization of mass production, the cost of a piece of clothing became lower, but some disadvantages arose. Garments were no longer made to measure and overproduction caused environmental problems. The new developments in digital garment design and digital customization target addressing these limitations. The computational design of knitting attracted increased attention in recent years. In this dissertation, we consider the customized design and fabrication of 3D and 4D garments as knitwears. The 3D knitwear fits the target human body, and the 4D knitwear also considers comfort during body movement. The main research question (RQ) is: How to design customized 3D and 4D knitwear and generate instructions for a digital knitting machine? In this dissertation, we researched computational knitwear design methods. We considered not only 3D fitting but also comfort during motion (4D). Our research can be applied in garment production (especially mass customization) or other knitting applications. Garment designers and other industrial designers can use the proposed methods to generate knitting instructions for free-form 3D surfaces. Our 4D design method helps designers place elastic or other varied knitting structures while keeping the intended 3D shape. This dissertation presents new perspectives on computational approaches to existing manufacturing techniques. It also provides enough details to further develop such design systems to be applied in practice., Emerging Materials

Diamond nanostructures are mostly produced from bulk diamond (single- or polycrystalline) by using time-consuming and/or costly subtractive manufacturing methods. In this study, we report the bottom-up synthesis of ordered diamond nanopillar arrays by using porous anodic aluminium oxide (AAO). Commercial ultrathin AAO membranes were adopted as the growth template in a straightforward, three-step fabrication process involving chemical vapor deposition (CVD) and the transfer and removal of the alumina foils. Two types of AAO membranes with distinct nominal pore size were employed and transferred onto the nucleation side of CVD diamond sheets. Subsequently, diamond nanopillars were grown directly on these sheets. After removal of the AAO template by chemical etching, ordered arrays of submicron and nanoscale diamond pillars with ~325 nm and ~85 nm diameters were successfully released., Micro and Nano Engineering

As the use of distributed energy resources increases, peer-to-peer (P2P) energy trading is becoming a promising way to harmonize the decarbonization and decentralization transformations in the energy sector. P2P markets give households the autonomy to make individual decisions and thus they may cooperate with each other to obtain economic benefits. However, existing studies on cooperative behaviors in P2P markets focus mostly on the electricity sector and P2P multi-energy markets are rarely studied. In fact, other energy carriers not only constitute a large part of the total energy demand, but their coupling can potentially benefit the system as well as the end-users. In this paper, we propose a P2P multi-energy market mechanism that allows peers to trade both electricity and heat. Two trading coalitions, i.e., an electricity-only trading coalition and an electricity–heat trading coalition, are predefined. The peers will join one of the coalitions based on their potential benefits and will trade energy inside the coalition. The energy markets are cleared separately per coalition and per energy carrier and hence, multi-energy markets are modeled. The proposed mechanism is a first-of-its-kind that explores the integrated effects of the multi-energy coupling and the cooperative behaviors in the P2P market. It is illustrated by a case study on a neighborhood in the Netherlands using realistic data. Results show that the mechanism is prosumer-centric as peers choose to join different coalitions at different time steps which benefit them the most. Compared to the reference scenario where there is no P2P trading, the P2P multi-energy market leads to higher economic benefits for all the peers altogether and benefits most individuals. The case study also demonstrates a benefit transfer from service-sector peers to residential peers., Energy & Industry, Multi Actor Systems

RST/Reactor Physics and Nuclear Materials

The use of natural ventilation in buildings to reduce the energy consumption and CO2 emission has been widely investigated and practiced, but few existing studies have considered the exploration and assessment of natural ventilation in different location patterns of rural residential buildings in the mountainous terrain of China. In this paper, the representative rural residential buildings are firstly selected in Huarong, Pingjiang and Liuyang regions of northern Hunan Province to carry out on-site survey works to determine building types, physical parameters and layout forms. Then, the wind tunnel experiments are carried out to investigate the effectiveness of natural ventilation under different location patterns, and the monitored results are compared with simulated data. The results show that the experiments and simulations are in satisfactory agreement. The experimental data also indicate that when the modelled distance of 120 mm (i.e. 12 m between the building and hilly terrain in practical application) is the best option for building natural ventilation. Based on the investigation and statistical data, the natural ventilation effectiveness under different location patterns and operational conditions is simulated using CFD methods, and it is obtained the most favourable location pattern for natural ventilation. The results show that the winter ventilation of buildings in the existing location pattern is significantly obstructed in the hilly terrain, which is favourable to the indoor thermal environment, however, the natural ventilation is compromised to a certain extent in summer. Furthermore, the findings also show that, regardless of the hilly terrain's height at 50 m or 150 m, the buildings are able to avoid natural ventilation in winter to the maximum extent when the distance between the buildings and the frontier of the hilly terrain is double that of the building height (i.e. 12 m). This study could contribute to theoretical instructions fo, Design & Construction Management

Gordon et al. (TCC 2015) systematically studied the security of Multi-client Verifiable Computation (MVC), in which a set of computationally-weak clients outsource the computation of a general function f over their private inputs to an untrusted server. They introduced the universally composable (UC) security of MVC and proposed a scheme achieving UC-security, where the protocol remains secure after arbitrarily composed with other UC-secure instances. However, the clients in their scheme have to undertake the heavy computation overhead caused by fully homomorphic encryption (FHE) and further, the plaintext size is linear to the function input size. In this work, we propose a more efficient UC-secure multi-client privacy-preserving verifiable computation protocol, called MVOC, that sharply reduces amortized overheads for clients, in both semi-honest and malicious settings. In particular, our protocol achieves stronger outsourcability by outsourcing more computation to the server, so that it may be more friendly to those lightweight clients. More specifically, we revisit the definition of garbling scheme, and propose a novel garbled circuit protocol whose circuit randomness is non-interactively provided by multiple parties. We also realize the idea of hybrid homomorphic encryption, which makes the FHE plaintext size independent of the input size. We present the detailed proof and analyze the theoretical complexity of MVOC. We further implement our protocol and evaluate the performance, and the results show that, after adopting our new techniques, the computation and communication overheads during input phase can be decreased by 55.15%–68.05% and 62.55%–75% respectively., Green Open Access added to TU Delft Institutional Repository ‘You share, we take care!’ – Taverne project https://www.openaccess.nl/en/you-share-we-take-care Otherwise as indicated in the copyright section: the publisher is the copyright holder of this work and the author uses the Dutch legislation to make this work public., Cyber Security

Operation risk (OR) has affected sustainable development of urban rail transit (URT) public–private partnership (PPP) projects in China. Balanced distribution of operational risks among stakeholders (the public, government, and private companies) involved in URT PPP projects can maximize overall profit. Quantitative analysis of operational risk allocation of urban rail transit PPP project is the key to achieve balance. Few existing studies have quantitatively analyzed operation risk allocation (ORA) in URT PPP project. The objective of this research is to construct a quantitative risk allocation model among three participants by using cooperative game theory. The risk allocation model was modified based on the consideration of four factors affecting the allocation of operational risks: controllability, risk loss, affordability, and handling cost. A case was used as an empirical example, and possible problems were illustrated. The result shows it is necessary and feasible to let the public bear part of the operational risk of the project by raising ticket prices. The results reveal that the public will play an important role in balancing risk allocation. This study shows that an ORA model can suggest how to make the risk allocation process more reasonable, fair, and stable. Meanwhile, the quantitative approach proposed can also be used by stakeholders in achieving fairness and stability of the partnership., Integral Design & Management

Chemical loss such as surfactants and alkalis by adsorption to reservoir rock surface is an important issue in enhanced oil recovery (EOR). Here, we investigated the adsorption behaviors of anionic surfactants and alkalis on silica for the first time as a function of temperature using quartz crystal microbalance with dissipation (QCM-D). The results demonstrated that the temperature dependent critical micelle concentration of alcohol alkoxy sulfate (AAS) surfactant can be quantitatively described by the thermodynamics parameters of micellization, showing a mainly entropy-driven process. AAS adsorption was mediated under varying temperature conditions, by divalent cations for bridging effect, monovalent cations competitive for adsorption sites but not giving cation bridging, pH regulation of deprotonated sites of silica, presence of alkoxy groups in the surfactants, and synergistic effect of surfactant co-injection. The addition of organic alkalis can enhance the overall adsorption of the species with AAS, whereas inorganic alkali of Na2CO3 had capability of the sequestration of the divalent ions, whose addition would reduce AAS adsorption. The typical AAS adsorption indicated a non-rigid multilayer, estimated to have between 2 and 5 layers, with a likely compact bilayer followed by disorganized and unstable further layering. The new fundamental understanding about temperature effect on surfactants and alkalis adsorption contributes to optimizing the flooding conditions of chemicals and developing more efficient mitigation strategies., ChemE/Advanced Soft Matter, OLD ChemE/Organic Materials and Interfaces

RST/Reactor Physics and Nuclear Materials

As the use of distributed energy resources increases, peer-to-peer (P2P) energy trading is becoming a promising way to harmonize the decarbonization and decentralization transformations in the energy sector. P2P markets give households the autonomy to make individual decisions and thus they may cooperate with each other to obtain economic benefits. However, existing studies on cooperative behaviors in P2P markets focus mostly on the electricity sector and P2P multi-energy markets are rarely studied. In fact, other energy carriers not only constitute a large part of the total energy demand, but their coupling can potentially benefit the system as well as the end-users. In this paper, we propose a P2P multi-energy market mechanism that allows peers to trade both electricity and heat. Two trading coalitions, i.e., an electricity-only trading coalition and an electricity–heat trading coalition, are predefined. The peers will join one of the coalitions based on their potential benefits and will trade energy inside the coalition. The energy markets are cleared separately per coalition and per energy carrier and hence, multi-energy markets are modeled. The proposed mechanism is a first-of-its-kind that explores the integrated effects of the multi-energy coupling and the cooperative behaviors in the P2P market. It is illustrated by a case study on a neighborhood in the Netherlands using realistic data. Results show that the mechanism is prosumer-centric as peers choose to join different coalitions at different time steps which benefit them the most. Compared to the reference scenario where there is no P2P trading, the P2P multi-energy market leads to higher economic benefits for all the peers altogether and benefits most individuals. The case study also demonstrates a benefit transfer from service-sector peers to residential peers., Energie and Industrie, Multi Actor Systems

Cleaner power production, distributed renewable generation, building-vehicle integration, hydrogen storage and associated infrastructures are promising for transformation towards a carbon–neutral community, whereas the academia provides limited information through integrated solutions, like intermittent renewable integration, hydrogen sharing network, smart operation on electrolyzer and fuel cell, seasonal hydrogen storage and advanced heat recovery. This study proposes a hybrid electricity-hydrogen sharing system in California, United States, with synergistic electric, thermal and hydrogen interactions, including low-rise houses, rooftop photovoltaic panels, hydrogen vehicles, a hydrogen station, micro and utility power grid and hydrogen pipelines. Advanced energy management strategies were proposed to enhance energy flexibility and grid stability. Besides, simulation-based optimizations on smart power flows of vehicle-to-grid interaction and electrolyzer are conducted for further seasonal grid stability and annual cost saving. The obtained results indicate that, the green renewable-to-hydrogen can effectively reduce reliance on pipelines delivered hydrogen, and the hydrogen station is effective to address security concerns of high-pressure hydrogen and improve participators’ acceptance. Microgrid peer-to-peer sharing can improve hydrogen system efficiency under idling modes. Furthermore, the integrated system can reduce the annual net hydrogen consumption in transportation from 127.0 to 1.2 kg/vehicle. The smart operation (minimum input power of electrolyzer and fuel cell at 65 and 80 kW) can reduce the maximum mean hourly grid power to 78.2 kW by 24.2% and the annual energy cost to 1228.5 $/household by 38.9%. The proposed district hydrogen-based community framework can provide cutting-edge techno-economic guidelines for carbon-neutral transition with district peer-to-peer energy sharing, zero-energy buildings, hydrogen-based transportations together with smar, Green Open Access added to TU Delft Institutional Repository 'You share, we take care!' - Taverne project https://www.openaccess.nl/en/you-share-we-take-care Otherwise as indicated in the copyright section: the publisher is the copyright holder of this work and the author uses the Dutch legislation to make this work public., Housing Quality and Process Innovation

Hydrogen-based (H2-based) interactive energy networks for buildings and transportations provide novel solutions for carbon-neutrality transition, regional energy flexibility and independence on fossil fuel consumption, where vehicle fuel cells are key components for H2-electricity conversion and clean power supply. However, due to the complexity in thermodynamic working environments and frequent on/off operations, the proton exchange membrane fuel cells (PEMFCs) suffer from performance degradation, depending on cabin heat balance and power requirements, and the ignorance of the degradation may lead to the performance overestimation. In order to quantify fuel cell degradation in both daily cruise and vehicle-to-grid (V2G) interactions, this study firstly proposes a two-space cabin thermal model to quantify the ambient temperature of vehicle PEMFCs and the power supply from PEMFCs to vehicle HVAC systems. Afterwards, a stack voltage model is proposed to quantify the fuel cell degradation for multiple purposes, such as daily transportation and V2G interactions. Afterwards, the two models are coupled in a community-level based building-vehicle energy network, consisting of twenty single residential buildings, rooftop PV systems, four hydrogen vehicles (HVs), a H2 station, community-served micro power grid, local main power grid, and local H2 pipelines, located in California, U.S.A. Comparative analysis with and without fuel cell degradation is conducted to study the impact of dynamic fuel cell degradation on the energy flexibility and operating cost. Furthermore, a parametrical analysis is conducted on the integrated HV quantity and the grid feed-in tariff to reach trade-off strategies between associated fuel cell degradation costs and grid import cost savings. The results indicate that, in the proposed hydrogen-based building-vehicle energy network, the total fuel cell degradation is 3.16% per vehicle within one year, wher, Green Open Access added to TU Delft Institutional Repository 'You share, we take care!' - Taverne project https://www.openaccess.nl/en/you-share-we-take-care Otherwise as indicated in the copyright section: the publisher is the copyright holder of this work and the author uses the Dutch legislation to make this work public., Housing Quality and Process Innovation

In this paper, we present a new computational pipeline for designing and fabricating 4D garments as knitwear that considers comfort during body movement. This is achieved by careful control of elasticity distribution to reduce uncomfortable pressure and unwanted sliding caused by body motion. We exploit the ability to knit patterns in different elastic levels by single-jersey jacquard (SJJ) with two yarns. We design the distribution of elasticity for a garment by physics-based computation, the optimized elasticity on the garment is then converted into instructions for a digital knitting machine by two algorithms proposed in this paper. Specifically, a graph-based algorithm is proposed to generate knittable stitch meshes that can accurately capture the 3D shape of a garment, and a tiling algorithm is employed to assign SJJ patterns on the stitch mesh to realize the designed distribution of elasticity. The effectiveness of our approach is verified on simulation results and on specimens physically fabricated by knitting machines., Accepted Author Manuscript, Materials and Manufacturing, Mechatronic Design

Boron-doped diamond (BDD) is of increasing interest for applications in electrochemical sensing. It is well known that the sp2 carbon content in BDD influences its electrochemical properties as electrode material. In this work, evidence is provided that the surface sp2 carbon content plays a crucial role in the electrochemical sensitivity of BDD towards glucose. Single-crystal BDD, freestanding polycrystalline BDD and glassy carbon (sp2 carbon reference material) were examined by voltammetry. Neither single-crystal BDD, which is free of sp2 carbon, nor pure sp2 glassy carbon could detect glucose in the range of 0.2–1.0 V. On the other hand, glucose oxidation was observed on polycrystalline BDD, and with increasing intensity with increase of sp2 carbon content. Thus, an optimum amount of (B-doped) sp2 carbon in the BDD electrode is needed for best sensing performance. Understanding this, and being able to control the composition of BDD, are not only important to glucose detection but to any electrochemical sensing application involving BDD., Micro and Nano Engineering

Mega infrastructure projects (MIPs) have become increasingly important to the realization of sustainable development in China. Sustainable development is a process of dynamic balance, and coordinating the triple bottom line (the environmental, social, and economic dimensions) will enable more sustainable development of MIPs. However, previous studies have lacked consideration of coordination when applying sustainable development principles to the systematic identification of risks to MIPs. The goals of this study were to clarify the definition and dimensions of the sustainable development of MIPs and to identify the key risks of MIPs. A literature review was performed to extend the definition of sustainable development of MIPs by combining the triple bottom line with a fourth coordination dimension. A conceptual model of MIP risk identification was then proposed from an extended sustainable development perspective, 22 sustainability elements and 75 risk factors were identified, and the key risk factors were determined based on the interview responses and fuzzy set theory. The results show that economic risks have a high probability, social risks have a high loss, environmental risks have an intermediate probability and loss, and coordination risks have the greatest impact. In addition, the three most important key risk factors were found to be construction and installation cost overruns, land acquisition and resettling cost overruns, and information sharing with the public. Identifying key risk factors can provide information to help stakeholders understand the risk factors associated with MIPs and formulate reasonable risk response strategies., Integral Design and Management

The concept of circular economy (CE) offers an innovative and systematical approach to address a number of urban sustainability issues, via exploring symbiotic ways to design circular urban systems and optimizing the materials and energy metabolism of cities, so as to mitigate environmental footprints. Urban sustainability is highlighted as a critical issue in the Sustainable Development Goals (SDGs) proposed by United Nations; hence, in nature, circular economy could offer a number of solutions towards SDGs in urban scope. As trade-offs, circular economy also potentially causes negative impacts to business-as-usual scenario, which is easily to be ignored. To highlight this scientific issue, this paper identified and matched the role of circular economy in realizing 17 SDGs in urban scope. How circular economy strategy could potentially affect the SDGs, whether positive or negative, were comprehensively evaluated. We expect such findings could support an equilibrium decision-making on circular economy promotion in cities, rather than an optimum solution to a single target under the triple bottom line of sustainability., Accepted Author Manuscript, Integral Design and Management

The controllability of mining is a key factor affecting the commercial application of methane hydrates, and the addition of chemical additives can significantly accelerate the mining process. However, the effect of additive concentration on hydrate decomposition is not yet well understood. In this study, we systematically investigate the effect of ethanol concentration on the decomposition of methane hydrate under varying thermodynamic conditions using molecular dynamics (MD) simulations. To quantitatively characterize the decomposition process and mechanism of methane hydrates, the combination of angular order parameter (AOP), radial distribution function (RDF), mean square displacement (MSD), diffusion coefficients and system energy was for the first time used. The results showed that the addition of ethanol contributed to the formation of methane bubbles and accelerated the decomposition of hydrates. The mass transfer effect of ethanol molecules and the reconstruction of the hydrogen bond network of water molecules determined the stability of hydrates. From 0 to 40 mol% ethanol concentration, the hydrate decomposition increased with increasing the concentration of ethanol. Both increasing the temperature and decreasing the pressure are beneficial to the decomposition of the hydrate system. These results provide the selection of optimal ethanol concentration for the decomposition of methane hydrate and reveal its decomposition mechanism, and shed important light for the controllable production of gas hydrates., ChemE/Advanced Soft Matter

BACKGROUND: Staggered seats are a solution for the Flying-V aircraft, where the cabin's longitudinal axis has a 26 degrees angle with respect to the direction of flight, to compensate for an otherwise oblique sitting position. However, little is known on acceptable pitches in this staggered configuration. OBJECTIVE: The goal of this research is to evaluate the comfort of different pitches for seats that are staggered relative to the cabin's longitudinal axis. METHODS: Two rows of staggered seats are positioned at three different pitches (27, 29 and 31 inches). 53 participants were seated in each setup. For each, a questionnaire was completed including questions on comfort and discomfort, top view photos were taken to analyse postures and physical dimensions were recorded to define passengers' space. RESULTS: Comfort as well as discomfort were significantly different for the three setups. The comfort at 27 inches was seen as unacceptably low. The 29 and 31-inch configurations showed to result in acceptable levels of comfort, comparable to higher-end seating layouts. There were very little complaints about space in lateral direction (elbow and seat width), showing the advantage of having your won armrest and shoulder space in the staggered configuration. Interesting was that at larger pitches more complaints were found for the seat characteristics, probably in the shorter pitch the other discomfort was overruling this. CONCLUSION: The 26-degree staggered configuration offers improvements in shoulder- and elbow-space. The results for the 29- and 31-inch are expected to allow enough design freedom for further exploration of such a configuration for the Flying-V cabin interior., Mechatronic Design, Applied Ergonomics and Design, Materials and Manufacturing

With the increasing demand for efficient extraction of residual oil, enhanced oil recovery (EOR) offers prospects for producing more reservoirs’ original oil in place. As one of the most promising methods, chemical EOR (cEOR) is the process of injecting chemicals (polymers, alkalis, and surfactants) into reservoirs. However, the main issue that influences the recovery efficiency in surfactant flooding of cEOR is surfactant losses through adsorption to the reservoir rocks. This review focuses on the key issue of surfactant adsorption in cEOR and addresses major concerns regarding surfactant adsorption processes. We first describe the adsorption behavior of surfactants with particular emphasis on adsorption mechanisms, isotherms, kinetics, thermodynamics, and adsorption structures. Factors that affect surfactant adsorption such as surfactant characteristics, solution chemistry, rock mineralogy, and temperature were discussed systematically. To minimize surfactant adsorption, the chemical additives of alkalis, polymers, nanoparticles, co-solvents, and ionic liquids are highlighted as well as implementing with salinity gradient and low salinity water flooding strategies. Finally, current trends and future challenges related to the harsh conditions in surfactant based EOR are outlined. It is expected to provide solid knowledge to understand surfactant adsorption involved in cEOR and contribute to improved flooding strategies with reduced surfactant loss., Accepted Author Manuscript, ChemE/Advanced Soft Matter, OLD ChemE/Organic Materials and Interfaces

The concept of circular economy (CE) offers an innovative and systematical approach to address a number of urban sustainability issues, via exploring symbiotic ways to design circular urban systems and optimizing the materials and energy metabolism of cities, so as to mitigate environmental footprints. Urban sustainability is highlighted as a critical issue in the Sustainable Development Goals (SDGs) proposed by United Nations; hence, in nature, circular economy could offer a number of solutions towards SDGs in urban scope. As trade-offs, circular economy also potentially causes negative impacts to business-as-usual scenario, which is easily to be ignored. To highlight this scientific issue, this paper identified and matched the role of circular economy in realizing 17 SDGs in urban scope. How circular economy strategy could potentially affect the SDGs, whether positive or negative, were comprehensively evaluated. We expect such findings could support an equilibrium decision-making on circular economy promotion in cities, rather than an optimum solution to a single target under the triple bottom line of sustainability., Accepted Author Manuscript, Integral Design & Management

In this paper, we present a new computational pipeline for designing and fabricating 4D garments as knitwear that considers comfort during body movement. This is achieved by careful control of elasticity distribution to reduce uncomfortable pressure and unwanted sliding caused by body motion. We exploit the ability to knit patterns in different elastic levels by single-jersey jacquard (SJJ) with two yarns. We design the distribution of elasticity for a garment by physics-based computation, the optimized elasticity on the garment is then converted into instructions for a digital knitting machine by two algorithms proposed in this paper. Specifically, a graph-based algorithm is proposed to generate knittable stitch meshes that can accurately capture the 3D shape of a garment, and a tiling algorithm is employed to assign SJJ patterns on the stitch mesh to realize the designed distribution of elasticity. The effectiveness of our approach is verified on simulation results and on specimens physically fabricated by knitting machines., Accepted Author Manuscript, Materials and Manufacturing, Mechatronic Design

Boron-doped diamond (BDD) is of increasing interest for applications in electrochemical sensing. It is well known that the sp2 carbon content in BDD influences its electrochemical properties as electrode material. In this work, evidence is provided that the surface sp2 carbon content plays a crucial role in the electrochemical sensitivity of BDD towards glucose. Single-crystal BDD, freestanding polycrystalline BDD and glassy carbon (sp2 carbon reference material) were examined by voltammetry. Neither single-crystal BDD, which is free of sp2 carbon, nor pure sp2 glassy carbon could detect glucose in the range of 0.2–1.0 V. On the other hand, glucose oxidation was observed on polycrystalline BDD, and with increasing intensity with increase of sp2 carbon content. Thus, an optimum amount of (B-doped) sp2 carbon in the BDD electrode is needed for best sensing performance. Understanding this, and being able to control the composition of BDD, are not only important to glucose detection but to any electrochemical sensing application involving BDD., Micro and Nano Engineering

Mega infrastructure projects (MIPs) have become increasingly important to the realization of sustainable development in China. Sustainable development is a process of dynamic balance, and coordinating the triple bottom line (the environmental, social, and economic dimensions) will enable more sustainable development of MIPs. However, previous studies have lacked consideration of coordination when applying sustainable development principles to the systematic identification of risks to MIPs. The goals of this study were to clarify the definition and dimensions of the sustainable development of MIPs and to identify the key risks of MIPs. A literature review was performed to extend the definition of sustainable development of MIPs by combining the triple bottom line with a fourth coordination dimension. A conceptual model of MIP risk identification was then proposed from an extended sustainable development perspective, 22 sustainability elements and 75 risk factors were identified, and the key risk factors were determined based on the interview responses and fuzzy set theory. The results show that economic risks have a high probability, social risks have a high loss, environmental risks have an intermediate probability and loss, and coordination risks have the greatest impact. In addition, the three most important key risk factors were found to be construction and installation cost overruns, land acquisition and resettling cost overruns, and information sharing with the public. Identifying key risk factors can provide information to help stakeholders understand the risk factors associated with MIPs and formulate reasonable risk response strategies., Integral Design & Management

The controllability of mining is a key factor affecting the commercial application of methane hydrates, and the addition of chemical additives can significantly accelerate the mining process. However, the effect of additive concentration on hydrate decomposition is not yet well understood. In this study, we systematically investigate the effect of ethanol concentration on the decomposition of methane hydrate under varying thermodynamic conditions using molecular dynamics (MD) simulations. To quantitatively characterize the decomposition process and mechanism of methane hydrates, the combination of angular order parameter (AOP), radial distribution function (RDF), mean square displacement (MSD), diffusion coefficients and system energy was for the first time used. The results showed that the addition of ethanol contributed to the formation of methane bubbles and accelerated the decomposition of hydrates. The mass transfer effect of ethanol molecules and the reconstruction of the hydrogen bond network of water molecules determined the stability of hydrates. From 0 to 40 mol% ethanol concentration, the hydrate decomposition increased with increasing the concentration of ethanol. Both increasing the temperature and decreasing the pressure are beneficial to the decomposition of the hydrate system. These results provide the selection of optimal ethanol concentration for the decomposition of methane hydrate and reveal its decomposition mechanism, and shed important light for the controllable production of gas hydrates., ChemE/Advanced Soft Matter

BACKGROUND: Staggered seats are a solution for the Flying-V aircraft, where the cabin's longitudinal axis has a 26 degrees angle with respect to the direction of flight, to compensate for an otherwise oblique sitting position. However, little is known on acceptable pitches in this staggered configuration. OBJECTIVE: The goal of this research is to evaluate the comfort of different pitches for seats that are staggered relative to the cabin's longitudinal axis. METHODS: Two rows of staggered seats are positioned at three different pitches (27, 29 and 31 inches). 53 participants were seated in each setup. For each, a questionnaire was completed including questions on comfort and discomfort, top view photos were taken to analyse postures and physical dimensions were recorded to define passengers' space. RESULTS: Comfort as well as discomfort were significantly different for the three setups. The comfort at 27 inches was seen as unacceptably low. The 29 and 31-inch configurations showed to result in acceptable levels of comfort, comparable to higher-end seating layouts. There were very little complaints about space in lateral direction (elbow and seat width), showing the advantage of having your won armrest and shoulder space in the staggered configuration. Interesting was that at larger pitches more complaints were found for the seat characteristics, probably in the shorter pitch the other discomfort was overruling this. CONCLUSION: The 26-degree staggered configuration offers improvements in shoulder- and elbow-space. The results for the 29- and 31-inch are expected to allow enough design freedom for further exploration of such a configuration for the Flying-V cabin interior., Mechatronic Design, Applied Ergonomics and Design, Materials and Manufacturing

Surfactant losses by adsorption to rock surfaces make surfactant-based enhanced oil recovery economically less feasible. We investigated polyacrylate (PA) as a sacrificial agent in the reduction of anionic surfactant adsorption with focus on calcite surfaces by using quartz crystal microbalance with dissipation monitoring. It was found that the adsorption of the anionic surfactant alcohol alkoxy sulfate (AAS) followed a Langmuir adsorption isotherm, and the adsorbed amount reached saturation above its critical micellar concentration. Adsorption of PA was a much slower process compared to AAS adsorption. Increasing the calcium ion concentration also increased the amount of AAS adsorbed as well as the mass increase rate of PA adsorption. Experimental results combined with density functional theory calculations indicated that calcium cation bridging was important for anionic surfactant AAS and PA adsorption to calcite surfaces. To effectively reduce the amount of surfactant adsorption, it was needed to preflush with PA, rather than by a simultaneous injection. Preflushing with 30 ppm of PA gave a reduction of AAS adsorption of 30% under high salinity (HS, 31,800 ppm) conditions, compared to 8% reduction under low salinity (LS, 3180 ppm) conditions. In the absence of PA, the amount of adsorbed AAS was reduced by already 50% upon changing from HS to LS conditions. Lower calcium ion concentrations, as under LS conditions, contributed to this observation. On different mineral surfaces, PA reduced the AAS adsorption in the order of alumina > calcite > silica. These results offer important insights into mitigating surfactant adsorption using PA polyelectrolyte as sacrificial agent and contribute to improved flooding strategies with reduced surfactant loss., ChemE/Advanced Soft Matter, OLD ChemE/Organic Materials and Interfaces, Micro and Nano Engineering

Water ice and gas hydrates can coexist in the permafrost and polar regions on Earth and in the universe. However, the role of ice in the mechanical response of ice-contained methane hydrates is still unclear. Here, we conduct direct million-atom molecular simulations of ice-contained polycrystalline methane hydrates and identify a crossover in the tensile strength and average compressive flow stress due to the presence of ice. The average mechanical shear strengths of hydrate-hydrate bicrystals are about three times as large as those of hydrate-ice bicrystals. The ice content, especially below 70%, shows a significant effect on the mechanical strengths of the polycrystals, which is mainly governed by the proportions of the hydrate-hydrate grain boundaries (HHGBs), the hydrate-ice grain boundaries (HIGBs), and the ice-ice grain boundaries (IIGBs). Quantitative analysis of the microstructure of the water cages in the polycrystals reveals the dissociation and reformation of various water cages due to mechanical deformation. These findings provide molecular insights into the mechanical behavior and microscopic deformation mechanisms of ice-contained methane hydrate systems on Earth and in the universe., Accepted Author Manuscript, Engineering Thermodynamics

Mega infrastructure projects provide a basic guarantee for social development, economic construction, and livelihood improvement. Their operation and maintenance (O&M) management are of great significance for the smooth operation and the realization of the value created by the projects. In order to provide an approach for effectively evaluating O&M management, this study develops a holistic indicator system using a mixed-review method from the national macro perspective in China. In this study, literature analysis, policy texts, expert interviews, and grounded theory were used to collect relevant data at home and abroad, and establish an initial evaluation indicator system with 23 indicators covering two dimensions and five aspects. Then the questionnaire survey and factor analysis were used to score and categorize the indicators, and finally an evaluation indicator system for O&M management of mega infrastructure projects was formed. The results show that social relations, environmental benefits, macro policy, and operational capacities play an important role in the evaluation of the O&M of mega infrastructure projects. This study helps the management team to avoid negative impacts in the O&M management of mega infrastructure projects and lays a theoretical foundation for future research. The indicator system in this study is based on the Chinese context, and it remains to be verified whether the indicator system is applicable to other countries due to the differences in political and cultural backgrounds in different regions., Integral Design and Management

This paper presents our winning entry for the EVA 2019 data competition, the aim of which is to predict Red Sea surface temperature extremes over space and time. To achieve this, we used a stochastic partial differential equation (Poisson equation) based method, improved through a regularization to penalize large magnitudes of solutions. This approach is shown to be successful according to the competition’s evaluation criterion, i.e. a threshold-weighted continuous ranked probability score. Our stochastic Poisson equation and its boundary conditions resolve the data’s non-stationarity naturally and effectively. Meanwhile, our numerical method is computationally efficient at dealing with the data’s high dimensionality, without any parameter estimation. It demonstrates the usefulness of stochastic differential equations on spatio-temporal predictions, including the extremes of the process., Applied Probability, Materials and Manufacturing

We have investigated the conditions of colloidal stability of silica nanoparticles smaller than 100 nm for their applications in enhanced oil recovery (EOR), especially pertaining to chemical flooding processes. Using zeta sizer and dynamic light scattering techniques, the stability of silica nanoparticle (SNP) dispersions has been investigated by variation of the pH, composition of salt solutions, addition of surfactants and polyelectrolytes. Such conditions can be encountered in oil reservoirs. It was found that changing pH from 5 to 10 had a negligible effect on the size of SNPs, whereas its zeta potential increased with increasing pH. Aggregation of SNPs is a partially reversible process for low degrees of aggregation in 500 mM NaCl, whereas observed strong aggregation in 1000 mM NaCl was irreversible. A critical aggregation concentration (CAC) was defined for the different salts investigated, above which the SNP dispersion became unstable at a fixed pH of 9.5. The CAC for NaCl was approximately 200 times higher than for CaCl2 and MgCl2. Our observations could not be explained completely by the Derjaguin-Landau-Verwey-Overbeek (DLVO) theory. Therefore, we have included non-DLVO interactions such as cation bridging, hydration forces, and steric effects. The additional presence of anionic alcohol alkoxy sulfate (AAS) surfactant slightly destabilized the SNP solution, but by the addition of polyacrylate (PA) was effectively stabilized. With increasing PA concentration, the CAC for both CaCl2 and MgCl2 increased. Upon addition of 100 ppm PA, the CAC increased by a factor of five compared to the situation in the absence of PA. Reducing the solution pH below 8.5, SNP can be stabilized in higher salinity in the presence of PA. The obtained results contribute to a better fundamental understanding of the SNP stability mechanism and a guide to optimize the SNP injection process with EOR chemicals., ChemE/Advanced Soft Matter, OLD ChemE/Organic Materials and Interfaces

Along with unprecedented urbanization in the last few decades, cities have experienced rapid social and economic transformation in China. A major challenge facing urban authorities in the immediate future is how to plan and govern cities such that they can serve as inclusive systems where everyone is enabled and empowered to fully participate in and contribute to socioeconomic life. A first step towards realizing this is to conceptualize an integrated framework that allows analysts and decision-makers to delineate, evaluate, and guide the development of these cities towards inclusiveness. In this study, we conducted a conceptual analysis of urban inclusiveness and then proposed a multidimensional framework for the evaluation of inclusive development. This is followed by the presentation of the case of Xiong'an, for which inclusive development indicators (IDIs) were selected. By comparing the state before the establishment of Xiong'an with its current development progress, and analyzing the area's management structure and policy measures, the inclusive development challenges are identified. Subsequently, suggestions are given on how to direct Xiong'an toward higher levels of inclusiveness, including offering equal access to public services and employment opportunities, preserving environmental health and sustainable use of natural resources through waste recycling, and encouraging public participation in decision-making to bring higher levels of inclusion within reach., Integral Design and Management, Projects

eAssessment The application of multiterminal (MT), high-voltage dc (HVdc) (MTdc) grid technology requires test procedures for the operation and implementation of the protection solutions. The test procedures are usually derived from experience and from extensive measurement data, which, at present, are still not widely available. Based on a hardware-inthe- loop (HIL) method, advanced dc protection testing strategies, utilizing existing experience for ac grids and requirements for MTdc grids, may overcome this gap., Green Open Access added to TU Delft Institutional Repository ‘You share, we take care!’ – Taverne project https://www.openaccess.nl/en/you-share-we-take-care Otherwise as indicated in the copyright section: the publisher is the copyright holder of this work and the author uses the Dutch legislation to make this work public., Intelligent Electrical Power Grids

Surface cracked steel plates reinforced with single-side Fiber-Reinforced Polymer (FRP) subjected to cyclic tension are experimental studied. The main purpose is to analyze the effect of FRP reinforcement on the crack growth. The failure modes and their effects are analyzed as well. Given the single-side reinforcement, reinforcing the cracked surface significantly prolonged the fatigue life, while reinforcing the reversed side resulted in the opposite consequence. Most specimens did not encounter debonding failures, indicating such failures are avoidable by improving the reinforcement quality. The results also indicate the bond layer number is an insensitive factor–an optimum number is existed., Support Marine and Transport Techology, Transport Engineering and Logistics, Ship Design, Production and Operations

Due to their characteristics and multiple objectives, high-speed rail (HSR) projects carry more complex risks than conventional projects and high correlation and conductivity are among the associated risk factors. Previous risk assessment frameworks for rail infrastructure have ignored the effects of risk interactions that inflate risk levels, namely, risk coupling effects. Based on a system dynamics method, this paper develops a risk coupling model for HSR project risk assessments. A risk factor list is established from a literature review, and relationships analysed using a case study and expert interviews. System dynamics equations are constructed and their parameters obtained by expert evaluations of risk factors. The proposed model is applied to a real-world HSR project to demonstrate it in detail. The model can evaluate the risk levels of HSR projects during a simulation period. In particular, it can identify the key coupling effects that are the main increased risk. It provides a significant resource, using which HSR project managers can identify and mitigate risks., Integral Design and Management

Adsorption behavior of surfactants to rock surfaces is an important issue in oil recovery, especially in the process of surfactant flooding. The surfactant loss through adsorption to rock surfaces makes such process economically less feasible. Here, we investigated the adsorption behavior of anionic surfactants (alcohol alkoxy sulfate, AAS) onto silica with quartz crystal microbalance with dissipation monitoring. The results demonstrated that the surfactant adsorption followed the Langmuir adsorption isotherm. Up to solution pH 10, surfactant adsorption slightly increased with increasing pH. The higher pH leads to more anionic surface sites for binding with an anionic surfactant with the help of a calcium cation bridging. The amount of anionic surfactant binding also increases with increasing calcium ion concentration up to 50 mM. It was found that sodium ions were able to exchange calcium ions near the silica surface, which would reduce the affinity for surfactant adsorption. The effect of the polyanion polystyrene sulfonate (PSS) on the anionic AAS adsorption was investigated to learn the possible competitive adsorptions. Indeed, this was found. Upon addition of 50 ppm PSS to a 0.05 wt% AAS containing solution, the adsorption of AAS was reduced by about 85 %. The obtained results show the interplay of different interacting species affecting the overall degree of anionic surfactant adsorption to silica surfaces. Optimal tuning of the process conditions according to these results will contribute to a more efficient use of anionic surfactants in enhanced oil recovery., Accepted Author Manuscript, ChemE/Advanced Soft Matter, OLD ChemE/Organic Materials and Interfaces

Urban-industrial symbiosis (UIS) is an important system innovation via sectors integration, and has been widely recognized as a novel pathway for achieving regional eco-industrial development. Eco-efficiency, as a mature approach and indicator, offers an effective tool to uncover both the status and trends of such a transformation. However, most studies have focused on the whole industry or city as a whole, which has meant that a view from the sectoral level focusing on UIS was missing. To fill this research gap, this paper applied a modified eco-efficiency approach using integrating input-output analysis (IOA) and carbon footprint (CFP) to identify the eco-efficiency benefits of UIS from a sectoral level. Specifically, sector-level economic data (as economic outputs) and CFP (as environmental impacts) are used to calculate the sectoral eco-efficiency. IOA helps to offer sectoral economic data, and, with integrating process-based inventory analysis, to conduct a CFP calculation at the sectoral level. To test the feasibility of the developed approach, urban industrial symbiosis scenarios in one typical industrial city of China were analyzed. This city is held up as the national pilot of the circular economy, low-carbon city, and ecological civilization in China. Scenarios analysis on a business as usual (no UIS) and with UIS implementation in 2012 were undertaken and compared with the change of sectoral CFP and eco-efficiency. The results highlighted a moderate increase in eco-efficiency and trade-offs in certain sectors, indicating that UIS was moderately effective in increasing the urban resource efficiency from a sectoral level, but a refined design was required. Policy recommendations are made based on the analytical results, to inform decision makers and urban and industrial managers seeking to improve the implementation of UIS as a means of achieving greater urban sustainability., Integral Design and Management

Water ice and gas hydrates can coexist in the permafrost and polar regions on Earth and in the universe. However, the role of ice in the mechanical response of ice-contained methane hydrates is still unclear. Here, we conduct direct million-atom molecular simulations of ice-contained polycrystalline methane hydrates and identify a crossover in the tensile strength and average compressive flow stress due to the presence of ice. The average mechanical shear strengths of hydrate-hydrate bicrystals are about three times as large as those of hydrate-ice bicrystals. The ice content, especially below 70%, shows a significant effect on the mechanical strengths of the polycrystals, which is mainly governed by the proportions of the hydrate-hydrate grain boundaries (HHGBs), the hydrate-ice grain boundaries (HIGBs), and the ice-ice grain boundaries (IIGBs). Quantitative analysis of the microstructure of the water cages in the polycrystals reveals the dissociation and reformation of various water cages due to mechanical deformation. These findings provide molecular insights into the mechanical behavior and microscopic deformation mechanisms of ice-contained methane hydrate systems on Earth and in the universe., Accepted Author Manuscript, Engineering Thermodynamics

Mega infrastructure projects provide a basic guarantee for social development, economic construction, and livelihood improvement. Their operation and maintenance (O&M) management are of great significance for the smooth operation and the realization of the value created by the projects. In order to provide an approach for effectively evaluating O&M management, this study develops a holistic indicator system using a mixed-review method from the national macro perspective in China. In this study, literature analysis, policy texts, expert interviews, and grounded theory were used to collect relevant data at home and abroad, and establish an initial evaluation indicator system with 23 indicators covering two dimensions and five aspects. Then the questionnaire survey and factor analysis were used to score and categorize the indicators, and finally an evaluation indicator system for O&M management of mega infrastructure projects was formed. The results show that social relations, environmental benefits, macro policy, and operational capacities play an important role in the evaluation of the O&M of mega infrastructure projects. This study helps the management team to avoid negative impacts in the O&M management of mega infrastructure projects and lays a theoretical foundation for future research. The indicator system in this study is based on the Chinese context, and it remains to be verified whether the indicator system is applicable to other countries due to the differences in political and cultural backgrounds in different regions., Integral Design & Management

We have investigated the conditions of colloidal stability of silica nanoparticles smaller than 100 nm for their applications in enhanced oil recovery (EOR), especially pertaining to chemical flooding processes. Using zeta sizer and dynamic light scattering techniques, the stability of silica nanoparticle (SNP) dispersions has been investigated by variation of the pH, composition of salt solutions, addition of surfactants and polyelectrolytes. Such conditions can be encountered in oil reservoirs. It was found that changing pH from 5 to 10 had a negligible effect on the size of SNPs, whereas its zeta potential increased with increasing pH. Aggregation of SNPs is a partially reversible process for low degrees of aggregation in 500 mM NaCl, whereas observed strong aggregation in 1000 mM NaCl was irreversible. A critical aggregation concentration (CAC) was defined for the different salts investigated, above which the SNP dispersion became unstable at a fixed pH of 9.5. The CAC for NaCl was approximately 200 times higher than for CaCl2 and MgCl2. Our observations could not be explained completely by the Derjaguin-Landau-Verwey-Overbeek (DLVO) theory. Therefore, we have included non-DLVO interactions such as cation bridging, hydration forces, and steric effects. The additional presence of anionic alcohol alkoxy sulfate (AAS) surfactant slightly destabilized the SNP solution, but by the addition of polyacrylate (PA) was effectively stabilized. With increasing PA concentration, the CAC for both CaCl2 and MgCl2 increased. Upon addition of 100 ppm PA, the CAC increased by a factor of five compared to the situation in the absence of PA. Reducing the solution pH below 8.5, SNP can be stabilized in higher salinity in the presence of PA. The obtained results contribute to a better fundamental understanding of the SNP stability mechanism and a guide to optimize the SNP injection process with EOR chemicals., ChemE/Advanced Soft Matter, OLD ChemE/Organic Materials and Interfaces

Adsorption behavior of surfactants to rock surfaces is an important issue in oil recovery, especially in the process of surfactant flooding. The surfactant loss through adsorption to rock surfaces makes such process economically less feasible. Here, we investigated the adsorption behavior of anionic surfactants (alcohol alkoxy sulfate, AAS) onto silica with quartz crystal microbalance with dissipation monitoring. The results demonstrated that the surfactant adsorption followed the Langmuir adsorption isotherm. Up to solution pH 10, surfactant adsorption slightly increased with increasing pH. The higher pH leads to more anionic surface sites for binding with an anionic surfactant with the help of a calcium cation bridging. The amount of anionic surfactant binding also increases with increasing calcium ion concentration up to 50 mM. It was found that sodium ions were able to exchange calcium ions near the silica surface, which would reduce the affinity for surfactant adsorption. The effect of the polyanion polystyrene sulfonate (PSS) on the anionic AAS adsorption was investigated to learn the possible competitive adsorptions. Indeed, this was found. Upon addition of 50 ppm PSS to a 0.05 wt% AAS containing solution, the adsorption of AAS was reduced by about 85 %. The obtained results show the interplay of different interacting species affecting the overall degree of anionic surfactant adsorption to silica surfaces. Optimal tuning of the process conditions according to these results will contribute to a more efficient use of anionic surfactants in enhanced oil recovery., Accepted Author Manuscript, ChemE/Advanced Soft Matter, OLD ChemE/Organic Materials and Interfaces