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Comparative experiments investigating the dissipation of four nursery-box-applied pesticides and three foliar-applied pesticides were conducted using lysimeters and in actual paddy fields. In the lysimeter experiments, there were test plots for submerged application for both application types. Analytical concentrations of the pesticides in paddy water were evaluated using appropriate kinetic models. The detection levels of pesticides in the paddy water for the nursery-box and foliar applications were 10–77% and 42–79% of the submerged application, respectively. The times required for 50% dissipation (DT(50)s) in case of the nursery-box and foliar applications were 0.8–10.4 days and 0.5–2.7 days, respectively. Although overall dissipations were affected by the physicochemical properties of the pesticide and the experimental design in the test plots, the initial detection levels in the lysimeters, governed by the runoff at transplanting and the deposition at spraying, were comparable with those in the actual paddy fields.

Antarctica is one of the most rapidly mass changing areas with poor ground observation data on Earth. Considering the dominant uncertainty in Glacial Isostatic Adjustment (GIA) effects for the Antarctic Ice Sheet (AIS) mass balance, we analyze mass change patterns of Antarctica qualitatively using a statistics-based blind source separation method named Independent Component Analysis (ICA). We extract the 6 leading independent components using gravimetric data derived from the Gravity Recovery and Climate Experiment (GRACE) mission and GRACE Follow-On (GRACE-FO) mission. The results show that the whole continental mass changes can be effectively separated into several spatial patterns that could be dominated by different physical processes. Although the hidden independent physical processes cannot be completely separated, some significant signals such as glacial melting components, snow accumulation components, periodic climatic components, and GIA effects could be determined without introducing any external information. We also found that the time period of the employed data sets has a direct impact on ICA results. This suggested that some impacts of extreme events, such as rapid increases of snowfall in the late 2000s might cause dramatic changes spatially and temporally. In general, ICA provides a special view for a better understanding of AIS mass changes and specific regional researches.

The 11th Symposium on Polar Science/Ordinary sessions: [OG] Polar Geosciences, Poster presentations, Mon. 16 Nov. - Fri. 18 Dec.

Three-year comprehensive experiments were conducted to compare the dissipation patterns of a total of 16 pesticides, including 3 metabolites, as granular formulations applied in lysimeters and paddy fields with two soil types. Analytical concentrations of the target pesticides in paddy water were analyzed using a granular kinetic model consisting of the following parameters: release rate, decrease rate, and dissolved concentration. Results of parameter grouping analyses of the kinetic models showed that 56% of data reproducibility (entire grouping) was obtained between replicates for the lysimeters. In comparisons between the lysimeters and paddy fields, 48% of decrease rates and 34% of release rates were grouped, although significant differences were observed with a nearly 90% difference for dissolved concentrations. These differences might be attributed to the hydrological components such as water management and meteorological covariates in paddy fields, the daily percolation in lysimeters and the adsorption-desorption kinetics between paddy water and soil.

The Ninth Symposium on Polar Science/Special session: [S] Antarctic ice-ocean interaction ～observation, reconstruction, and modeling～, Tue. 4 Dec. / Entrance Hall (1st floor) at National Institute of Polar Research