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The impact of heat treatment and wetting–drying cycles on the wetting properties of sandy forest soils was explored. Topsoil and upper subsoil were sampled at three beech forest sites in northern Germany. The air-dried soils were treated at 20, 40 and 80°C for 24 h, with materials treated at 20°C serving as reference. After wetting, materials were air-dried or shock-frozen in liquid N2 and freeze-dried. Interfacial properties were monitored by sessile drop contact angles (CAs) and X-ray photoelectron spectroscopy (XPS), which provide physical and chemical information on the outermost particle interface layer. CAs of reference samples were around 90° and significantly increased after 80°C-treatment to >90°, whereas 40°C-treatment had in comparison to reference soils no distinct impact on CA. Depending on the initial temperature treatment, air-drying after wetting decreased CA to 60–80% and shock-freezing and freeze-drying decreased CA to 10–50% of the reference value. Results suggest that shock-freezing may preserve the organic matter molecular structure that prevails during contact with water at the solid–liquid interface, thus indicating the wettability of the wet surface. Generally, wetting–drying cycles had the least impact on 80°C-treated material. XPS analysis confirmed dynamic interfacial molecular restructuring processes by changes in O and C content and the content of non-polar C compounds. A second heat treatment after two wetting–drying cycles again proved the distinct and pronounced impact of 80°C-treatment on CA, especially with prior shock-freezing and freeze-drying. In conclusion, the findings of our study indicate a sensitive and partly reversible reorganization of the solid interfacial wetting properties. Results may conceptually be used to develop dynamic wettability models, which are needed to simulate the sensitive interplay between wettability and dynamic soil hydraulic functions at sites that are exposed to intensive and periodic moisture fluctu

Absorptive fine roots are an important driver of soil biogeochemical cycles. Yet, the spatio-temporal dynamics of those roots in the presence of neighboring species remain poorly understood. The aim of this study was to analyze shifts in absorptive fine-root traits in monoculture or mixtures of Fagus sylvatica [L.] and Picea abies [L.] Karst. We hypothesized that root competition would be higher under single-species than mixed-species interactions, leading to changes in (i) root survivorship, diameter and respiration and (ii) spatio-temporal patterns of root growth and death. Using minirhizotron methods, we monitored the timing and location of absorptive fine-root growth and death at an experimental forest in southern Germany from 2011 to 2013. We also measured root respiration in the spring and fall seasons of 2012 and 2013. Our findings show that the absorptive fine roots of F. sylvatica had a 50% higher risk of root mortality and higher respiration rates in the single-species compared to mixed-species zones. These results support our hypothesis that root competition is less intense for F. sylvatica in mixture versus monoculture. We were unable to find confirmation for the same hypothesis for P. abies. To analyze spatio-temporal patterns of absorptive fine-root production and mortality, we used a mixed-effects model considering root depth (space) and seasons (time) simultaneously. This analysis showed that F. sylvatica shifts root production towards shallower soil layers in mixed-species stands, besides significant seasonal fluctuations in root production depths for both species. Ultimately, the impact of neighbor species identity on root traits observed in this study has important implications for where, when and how fast root-facilitated carbon cycling takes place in single-species versus mixed-species forests. In addition, our study highlights the need for inclusion of absorptive fine-root spatio-temporal dynamics when examining belowground plant interactions a

Soil wettability (quantified in terms of contact angle, CA) is crucial for physical, chemical, and biological soil functioning. As the CA is determined by components present within the outmost nanometer of particles, this study applied X-ray photoelectron spectroscopy (XPS) with a maximum analysis depth of 10 nm to test the relationship between CA and surface elemental composition, using soil samples from a chronosequence where CA increased from 0° (0 yrs) to about 98° (120 yrs). Concurrently, as seen by XPS, C and N content increased and the content of O and the mineral-derived cations (Si, Al, K, Na, Ca, Mg, Fe) decreased. The C content was positively correlated with CA and least squares fitting indicated increasing amounts of non-polar C species with soil age. The contents of O and the mineral-derived cations were negatively correlated with CA, suggesting an increasing organic coating of the minerals that progressively masked the underlying mineral phase. The atomic O/C ratio was found to show a close negative relationship with CA, which applied as well to further sample sets of different texture and origin. This suggests the surface O/C ratio to be a general parameter linking surface wettability and surface elemental composition.

Different physical properties of volcanic ash soils were investigated along a transect of 120 km from the western slope of the Central Cordilleras (40°20’S, 72°06’W) to the eastern slope of the Costal Cordillera (39°39’S, 73°11’W) in southern Chile with respect to the degree of soil development (Arenosol versus Andosol stage; Arenosol: young volcanic ash soil, free of clay, tephric properties, Andosol: older volcanic soil, clayey). The Andosols show a higher total pore volume and a higher field capacity, especially due to an increase in fine pores, than the Arenosols. Furthermore, the precompression stress (Pc) as a parameter for the mechanical soil strength is higher for Andosols despite of a lower bulk density. A land use (cropland, meadow, forest) dependent variation of the investigated parameters was less distinct for Andosols. A reduction of macropores and saturated hydraulic conductivity (ks) due to agriculture could be determined in the field, but in general the values are still on a high level with ks-values >100 cm d-1. However, at higher stresses using an oedometer test the ks-values of the Andosols are highly negatively affected with values <10 cm d-1. Aggregation is of major importance for soil stability of Andosols, whereas a homogenization of soil structure will lead to a distinct decrease of Pc of approx. 50%.

Most recent studies on soil water repellency (WR) were limited to the humous topsoil or to shallow subsoil layers slightly below the main root zone to approximately 0.5 m depth. Hence, the main objective of the present study was to investigate the wettability pattern of a forest soil including the deeper subsoil. The selected site was a 100 years old beech forest on a well-drained sandy Cambisol in northern Germany which showed moderate to partly extended acidification. Results obtained from three sampling transects (3 m length, 2 m depth; sampling grid 8 × 8 samples per transect; minimum distance of sampling locations to nearest tree about 0.5 m) show that contact angles (CA) were always in the subcritical WR range (0° < CA < 90°). Significant impact of the tree distance on WR was not observed for any of the transects. A prominent feature of two transects was the minimum WR level (CA < 10°) for samples with soil organic carbon (SOC) contents around 0.25–0.4%. For the topsoils it was observed that CA increased with SOC content from that minimum to a maximum CA of 60–75° for transects 1 and 2 with mean pH values < 3.5. For transect 3 with slightly higher average pH close to 4.0, average CA of samples were always < 10° and showed no trend to increase with increasing SOC content or other soil parameters like N content or C/N ratio. Subsoil samples, however, behave differently with respect to SOC: for these samples, generally low in SOC, the CA increase with decreasing SOC occurred at all transects for approximately 50% of the samples but did not show any clear tendencies with respect to further parameters like texture, pH or N content. We conclude that the SOC content is the most prominent parameter determining wettability, either positively correlated with WR for topsoils or negatively correlated for subsoil samples very low in SOC. We finally conclude for moderately acid beech forest stands that emerging WR starts in the A horizon after reaching a pH lower than 3.5