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The Smith-Purcell effect allows for coherent free-electron-driven compact light sources over the entire electromagnetic spectrum. Intriguing interaction regimes, with prospects for quantum optical applications, are expected when the driving free electron enters the sub-keV range, though this has until now remained an experimental challenge. Here, we demonstrate the Smith-Purcell light emission from UV to visible using engineerable, fabricated gratings with periodicities as low as 19 nm and with electron energies as low as 300 eV. Our findings constitute a major step toward broadband, highly tunable, on-chip light sources, observation of quantum recoil effects, and tunable EUV and x ray sources from swift electrons.

This study examines the fundamental feasibility of sequential metal-powder solidification by localized microwave-heating (LMH) provided by a scanning, all-solid-state microwave applicator. This continuous process is considered for the additive manufacturing (AM) and 3D printing (3DP) applications of metal parts. In previous studies, we employed LMH for the incremental solidification of small batches of metal powder in a stepwise vertical manner. Here, we study a continuous lateral LMH process, layer by layer, in a fashion similar to laser scanning in powder beds, as performed in common laser-based AM systems. LMH solidification at scanning rates of ~1 mm 3 /s is obtained in bronze powder using ~0.25-kW microwave power. The effect is studied here by LMH scanning in one lateral dimension (~20-mm long) in layers, each of ~1-4 mm thickness and ~2-4 mm width (mechanically confined). Imperfect solid bars of ~20×4×5 mm 3 are obtained with rough surfaces. Their joining in an L shape is also demonstrated. The experimental solidified products are tested, and their hardness and density properties are found to be comparable to laser-based AM products. The capabilities and limitations of the LMH scanning concept for metal-powder solidification are evaluated. The potential feasibility of a solid-state LMH-AM technology is discussed.

Additively manufactured (AM) materials and hot rolled materials are typically orthotropic, and exhibit anisotropic elastic properties. This paper elucidates the anisotropic elastic properties (Young's modulus, shear modulus, and Poisson's ratio) of Ti6Al4V alloy in four different conditions: three AM (by selective laser melting, SLM, electron beam melting, EBM, and directed energy deposition, DED, processes) and one wrought alloy (for comparison). A specially designed polygon sample allowed measurement of 12 sound wave velocities (SWVs), employing the dynamic pulse-echo ultrasonic technique. In conjunction with the measured density values, these SWVs enabled deriving of the tensor of elastic constants ( C ij ) and the three-dimensional (3D) Young's moduli maps. Electron backscatter diffraction (EBSD) and micro-computed tomography (μCT) were employed to characterize the grain size and orientation as well as porosity and other defects which could explain the difference in the measured elastic constants of the four materials. All three types of AM materials showed only minor anisotropy. The wrought (hot rolled) alloy exhibited the highest density, virtually pore-free μCT images, and the highest ultrasonic anisotropy and polarity behavior. EBSD analysis revealed that a thin β-phase layer that formed along the elongated grain boundaries caused the ultrasonic polarity behavior. The finding that the elastic properties depend on the manufacturing process and on the angle relative to either the rolling direction or the AM build direction should be taken into account in the design of products. The data reported herein is valuable for materials selection and finite element analyses in mechanical design. The pulse-echo measurement procedure employed in this study may be further adapted and used for quality control of AM materials and parts.

Soft electronics based on various rubbers have lately been needed in many advanced applications such as soft robotics, wearable electronics, and remote health monitoring. The ability of a self-sensing material to be monitored in use provides a significant advantage. However, conductive fillers usually used to increase conductivity also change mechanical properties. Most importantly, the initial sought-after properties of rubber, namely softness and long elastic deformation, are usually compromised. This work presents full mechanical and electro-mechanical characterization, together with self-sensing abilities of a vinyl methyl silicone rubber (VMQ) and multi-walled carbon nanotubes (MWCNTs) composite, featuring conductivity while maintaining low hardness. The research demonstrates that MWCNT/VMQ with just 4 wt.% of MWCNT are as conductive as commercial conductive VMQ based on Carbon Black, while exhibiting lower hardness and higher elastic recovery (~20% plastic deformation, similar to pure rubber). The research also demonstrates piezo-resistivity and Raman-sensitivity, allowing for self-sensing. Using morphological data, proposed mechanisms for the superior electrical and mechanical behavior, as well as the in-situ fingerprint for the composite conditions are presented. This research novelty is in the full MWCNT/VMQ mechanical and electro-mechanical characterization, thus demonstrating its ability to serve as a sensor over large local strains, multiple straining cycles, and environmental damage., Competing Interests: The authors declare no conflict of interest. The funders had no role in the design of the study; in the collection, analyses, or interpretation of data; in the writing of the manuscript, or in the decision to publish the results.

Surveys conducted in Eilat's upper mesophotic coral ecosystem (MCE) revealed protruding columnar calcareous structures with a Sinularia octocoral colony growing atop of each. The current study addressed the hypothesis that these colonies produce spiculites, and sought to determine (a) the spatial occurrence and dimensions of the spiculite-forming colonies and their species affiliation; (b) their microstructural features; and (c) the elemental composition of the columnar spiculites in comparison to the sclerites of the colonies. All the spiculite-forming colonies were exclusively found in the upper MCEs and produced by S. vrijmoethi. This type of spiculite, including its elemental analysis, is reported here for the first time for coral reefs in general and for the MCE in particular. Examination of the spiculites by scanning electron microscopy and energy-dispersive X-ray spectroscopy revealed spindle shaped-sclerites cemented by crystallites. The elemental composition of the sclerites differed from that of the cementing crystallites, in featuring ~8% Mg in the former and none in the latter. Inductively coupled plasma mass spectrometry revealed fragments of spiculite to be composed of 35% sclerites and 65% crystallites. X-ray powder diffraction analysis of individual sclerites indicated that they are composed exclusively of magnesium-calcite, and the spiculite fragments to also feature 9.3 ± 4% aragonite and 5-7% amorphous calcium carbonate. Consequently, it is proposed that the formation of the crystallites, which lithify the sclerites, is caused by a non-biogenic aragonite precipitation, and that the living colony might benefit from this protruding spiculite structure by means of enhanced exposure to water flow.

The highly controlled formation of "radial" silicon/NiSi  core-shell nanowire heterostructures has been demonstrated for the first time. Here, we investigated the "radial" diffusion of nickel atoms into crystalline nanoscale silicon pillar 11 cores, followed by nickel silicide phase formation and the creation of a well-defined shell structure. The described approach is based on a two-step thermal process, which involves metal diffusion at low temperatures in the range of 200-400 °C, followed by a thermal curing step at a higher temperature of 400 °C. In-depth crystallographic analysis was performed by nanosectioning the resulting silicide-shelled silicon nanopillar heterostructures, giving us the ability to study in detail the newly formed silicide shells. Remarkably, it was observed that the resulting silicide shell thickness has a self-limiting behavior, and can be tightly controlled by the modulation of the initial diffusion-step temperature. In addition, electrical measurements of the core-shell structures revealed that the resulting shells can serve as an embedded conductive layer in future optoelectronic applications. This research provides a broad insight into the Ni silicide "radial" diffusion process at the nanoscale regime, and offers a simple approach to form thickness-controlled metal silicide shells in the range of 5-100 nm around semiconductor nanowire core structures, regardless the diameter of the nanowire cores. These high quality Si/NiSi core-shell nanowire structures will be applied in the near future as building blocks for the creation of utrathin highly conductive optically transparent top electrodes, over vertical nanopillars-based solar cell devices, which may subsequently lead to significant performance improvements of these devices in terms of charge collection and reduced recombination.

Cold radiofrequency plasma treatment modified wetting and floating regimes of pepper seeds. The wetting regime of plasma-treated seeds was switched from the Wenzel-like partial wetting to the complete wetting. No hydrophobic recovery following the plasma treatment was registered. Environmental scanning electron microscopy of the fine structure of the (three-phase) triple line observed with virgin and plasma-treated seeds is reported. Plasma treatment promoted rapid sinking of pepper seeds placed on the water/air interface. Plasma treatment did not influence the surface topography of pepper seeds, while charged them electrically. Electrostatic repulsion of floating plasma-treated seeds was observed. The surface charge density was estimated from the data extracted from floating of charged seeds and independently with the electrostatic pendulum as σ≈1-2μC/m 2 ., (Copyright © 2017 Elsevier B.V. All rights reserved.)

The formation of intricately shaped crystalline minerals by organisms is orchestrated by specialized biomacromolecules. The macromolecules associated with coccoliths, nanometer-sized calcite crystal arrays produced by marine microalgae, can form a distinct calcium-rich phase via macromolecular recognition. Here, we show that this calcium-rich phase can be mineralized into a thin film of single-crystalline calcite by the balanced addition of carbonate ions. Such a crystallization process provides a strategy to direct crystalline products via local interactions between soluble macromolecules and compatible templates.

The fine structure of the three-phase (triple) line was studied for different liquids, various topographies of micro-rough substrates and various wetting regimes. Wetting of porous and pillar-based micro-scaled polymer surfaces was investigated. The triple line was visualized with the environmental scanning electron microscope and scanning electron microscope for the "frozen" triple lines. The value of the roughness exponent ζ for water (ice)/rough polymer systems was located within 0.55-0.63. For epoxy glue/rough polymer systems somewhat lower values of the exponent, 0.42 < ζ < 0.54, were established. The obtained values of ζ were close for the Cassie and Wenzel wetting regimes, different liquids, and different substrates' topographies. Thus, the above values of the exponent are to a great extent universal. The switch of the exponent, when the roughness size approaches to the correlation length of the defects, is also universal.