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• Geochemical subdivision of mafic-intermediate volcanic rocks based on immobile element ratios. • Blake River Group geochemical diversity is mostly caused by crustal interaction with TTG-like contaminant. • VMS deposits in the Blake River Group show a potential relationship with crustal assimilation. • Composition of mafic to intermediate volcanic rocks has potential for VMS vectoring. Volcanogenic massive sulfide (VMS) deposits, prevalent since the Archean, constitute a well-explored ore deposit type. Nonetheless, the factors contributing to variations in fertility among volcanic centers, assemblages within greenstone belts, or entire greenstone belts remain unclear. For instance, the Blake River Group (BRG) of Ontario and Quebec, Canada, hosts almost half of the total VMS tonnage of the entire Abitibi greenstone belt, yet represents less than 10 % of its map surface. This study utilizes a large dataset (n = 2271) of whole-rock geochemistry for mafic to intermediate volcanic rocks to understand the BRG petrogenesis, and its implications for VMS endowment in the Abitibi. Principal Component Analysis shows that Ti, Th, and Yb are the primary contributors to the dataset's variation. This yields a two-ratio diagram (Th/Yb versus Zr/Ti) revealing seven geochemical groups with coherent map patterns referenced as tholeiitic basalts, tholeiitic intermediate rocks, medium-Th basalts, transitional intermediate rocks, high-Th basalts, calc-alkaline intermediate rocks and low-Zr basalts. A least altered subset of the data is used to analyze major element patterns. BRG mafic to intermediate magmas show variable degrees of Fe-Ti enrichment/depletion during their evolution, with simultaneous Al 2 O 3 depletion or lack thereof. Utilizing a single parental mafic tholeiitic magma, the Magma Chamber Simulator enables the modeling of major and trace element compositions for each geochemical group. Fractional crystallization (FC) models with variable initial water contents can explain the range of the tholeiitic basalt and tholeiitic intermediate compositions. Assimilation fractional crystallization (AFC) models successfully replicate most of the geochemical groups using a TTG average composition for the assimilant. While mafic-intermediate host rock geochemical signatures are not the sole factor influencing VMS endowment in volcanic belts, regional analysis reveals that the vast majority of volcanic rocks in geological formations bearing VMS deposits in the BRG are crustally contaminated lacking tholeiitic geochemical groups. Conversely, poorly endowed formation consistently contain samples from these groups. Moreover, the Bousquet formation, which hosts several world-class gold-rich VMS deposits, displays the highest rates of crustal assimilation, further suggesting that petrogenesis of mafic-intermediate volcanic rocks is linked to VMS metallogenesis in the BRG. [ABSTRACT FROM AUTHOR]

[Display omitted] • Mineral prospectivty mapping for Au. • Random forest algorithm for integrating geoscience data. • Knowledge-based algorithms. • Superior tectonic province. This paper uses the random forest (RF) algorithm to produce two maps of orogenic gold prospectivity (MPM) across the entire Superior geologic province of Ontario and Quebec, Canada. One MPM of this entire study area is based on a compilation of mapped faults while the other is based on a manual interpretation of lineaments from airborne magnetic data. In addition, we have created four MPMs over the Abitibi region as the MPM map of the entire Superior is characterized by a mapping bias due to more intense mapping of faults over the Abitibi portion of the study area with respect to the rest of the Superior province. There are three RF maps generated over the Abitibi region based on faults, fault density and fault intersection density, faults + magnetic data and faults + gravity + magnetic data. To reduce the effect of the fault mapping bias, we developed a fourth map based on a knowledge driven (weighted sum technique). Statistically the best MPM is based on the faults, gravity and magnetic data. The major predictors of gold are NW-SE, NE-SW, EW trending faults, fault intersection density between EW and NW trending faults and to a lesser extent fault density and a magnetic vertical gradient image. In addition, we compare two greenstone belts in three dimensions with respect to their potential for gold exploration. We conclude that the Larder Lake greenstone belt is more fertile with respect to gold mineralization than the Swayze greenstone belt due to deeper penetrating faults which have greater potential for tapping gold mineralized fluid from the mantle or lower crust. Our final MPM map has identified prospective areas that contain known gold mines as well as areas that do not contain any known gold mines. These prospective areas may be prime for orogenic gold exploration. [ABSTRACT FROM AUTHOR]

In Archean greenstone belts, magmatism is dominated by intrusive and volcanic rocks with tholeiitic affinities, as well as tonalite- and granodiorite-dominated large-volume batholiths, i.e., tonalite–trondhjemite–granodiorite (TTG) suites. These intrusions are associated with poorly documented mineralization (Cu-Au porphyries) that, in the Neoarchean Abitibi Subprovince (>2.79 to ~2.65 Ga), Superior Province, Canada, are associated with diorite bearing plutons, i.e., tonalite–trondhjemite–diorite (TTD) suites. The importance of TTG versus TTD suites in the evolution of greenstone belts and of their magmatic-hydrothermal systems and related mineralization is unconstrained. The aim of this study was to portray the chemistry and distribution of these suites in the Abitibi Subprovince. The study used data compiled by the geological surveys of Québec and Ontario to evaluate the chemistry of TTG and TTD suites and uncovered two coeval magmas that significantly differentiated (fractional crystallization mostly): 1) a heavy rare earth elements (HREE)-depleted tonalitic magma from high pressure melting of an hydrated basalt source; and 2) a hybrid HREE-undepleted magma that may be a mixture of mantle-derived (tholeiite) and tonalitic melts. The HREE-depleted rocks (mostly tonalite and granodiorite) display chemical characteristics of TTG suites (HREE, Ti, Nb, Ta, Y, and Sr depletion, lack of mafic unit, Na-rich), while the other rocks (tonalite and diorite) formed TTD suites. Tonalite-dominated magmatism, in the Abitibi Subprovince, comprises crustal melts as well as a significant proportion of mantle-derived magmas and this may be essential for Cu-Au magmatic-hydrothermal mineralizing systems. [ABSTRACT FROM AUTHOR]