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Coupled Thermal-Hydraulic-Mechanical-Chemical (THMC) approaches may be important for assessing the long-term durability of cementitious materials. We present a multiphysics approach to overcome past limitations of THMC modelling and validate it based on experimental results of accelerated carbonation tests. Our numerical approach rests on a sequential coupling between Hytec and Cast3m. Hytec computes the evolution of hydraulic and mineralogical fields allowing to compute the micromechanical properties (e.g. Young's modulus). The mineral reactions generate tensile stresses and Cast3M computes the associated strain tensors and the damage evolution represented by the opening or sealing of cracks, impacting subsequent reactive transport processes. Our approach manages to qualitatively represent the crack patterns and non-uniform degradation depths observed on microtomographic images of carbonated cement samples, which can only be explained by the coupled dynamics of chemical and mechanical processes. Our approach can be extended to a wide range of cement-concrete pathologies and contexts. [ABSTRACT FROM AUTHOR]

The geologic disposal of radioactive waste could lead to confined conditions in which cementitious materials impose a moderate alkaline pH, in which the rocks supply sulfate ions at rather low concentrations. In this context, the purpose of this work was to study the degradation of cement pastes under such conditions using a non-renewed 30 mmol/L Na2SO4 solution without pH regulation. Samples were investigated through laboratory testing and numerical modeling. XRD, SEM–EDS, and micro-indentation acquisitions were performed to follow the evolution of chemical, mineralogical, and mechanical properties during the weak external sulfate attack. Reactive transport modeling was performed with the HYTEC code. Based on these results, the Young's moduli of the degraded zones were estimated using analytical homogenization. Decalcification occurred despite the high pH value of the solution and significantly affected the mechanical properties. Macroscopic swelling and cracking were caused by the formation of expansive sulfate minerals after 60 days, despite the low sulfate content of the tank solution. The modeling supported the discussion on the evolution of the mineral fronts (ettringite, portlandite, and gypsum). [ABSTRACT FROM AUTHOR]

Durability of concrete exposed to an external sulfate attack is a great concern for the long-term reliability of nuclear waste containment. This paper presents experimental results obtained on cement paste subjected to a low concentration (30 ×10−3 mol/L) external sulfate attack. Samples were characterized with complementary methods (XRD, SEM-EDS, microtomography, microindentation, autoradiography) to follow the evolution of chemical, mineralogical, microstructural and mechanical properties during 8 months. Cement pastes of different C 3 A contents were used to boost either ettringite or gypsum formation during the sulfate attack to assess their respective impact on the degradation. Cracks parallel to the attacked surface occurred in the zone of gypsum formation and portlandite dissolution, which suggests that gypsum has a key effect on the expansion. Reactive transport modeling supported the discussion on the competition between hydrolysis, gypsum and ettringite precipitation as well as the analytical homogenization to estimate Young's moduli. • Multiple characterization tools were used including a synchrotron radiation CT. • Contributions of hydrolysis and sulfate attack on damage were discriminated. • Expansion occurred even for low C3A content and groundwater SO 4 concentration. • Cracking was initiated in the gypsum formation zone. • Ettringite formation was identified by microindentation and homogenization. [ABSTRACT FROM AUTHOR]