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This paper deals with the results of a study of the thermodestruction of the earlywood and latewood in the 1988-1998 growth rings of Gmelin larch ( Larix gmelinii (Rupr.) Rupr.) trees growing along the polar tree line (7052′53″N, 102°58′26″E, Taimyr Peninsula). The study used methods of thermogravimetry (TG/DTG) and differential scanning calorimetry (DSC). Thermogravimetric data obtained were analyzed by Ozawa-Flynn-Wall kinetic model. We determined macrokinetic parameters of thermodestruction. Earlywood and latewood showed no significant difference in cellulose/hemicellulose/lignin ratio, whereas they differed significantly in destruction average value of activation energy (197.55 and 55.90 kJ mol, respectively). Our analysis of the correlation of thermodestruction values with mean monthly air temperature and precipitation revealed that component composition of both earlywood and latewood was influenced more by the weather conditions at the beginning of the growing season (April-June). Air temperature had markable influence on the wood component composition during cell wall synthesis only in latewood, whereas precipitation influenced the composition in both latewood and earlywood. TG/DTG and DSC methods were found to be promising for developing information on biochemical composition of early and latewood tracheids in stems and for identifying the extent of the influence of climatic changes on cell wall synthesis. [ABSTRACT FROM AUTHOR]

Wood modification is an efficient method to improve wood performance and expand the applications of wood material. In this study, a combination modification method of aluminum sol-gel and furfurylation was developed to improve the performance of poplar wood. Wood samples were characterized by Fourier transform infrared spectroscopy and field emission scanning electron microscopy. The properties of the treated wood, including thermal stability, water uptake, dimensional stability, and dynamic wettability were also evaluated. The thermogravimetric analysis results indicated that the incorporation of an aluminum-based gel could prevent furfurylated wood from thermal degradation by converting the gel into nano-Al2O3. The aluminum-based sol-gel apparently hindered furfuryl alcohol polymerization and reduced the weight percent gain of the samples; the anti-swelling efficiency of the treated wood was over 57% (with little decrease) due to crosslinking between the wood and aluminum-based gel. The water uptake and hydrophobicity of the modified samples were improved significantly in comparison to the control samples. [ABSTRACT FROM AUTHOR]

In this study, silica sol (SiO sol) and KCO were used as flame retardants for wood. The synergistic effect of SiO sol and KCO on the flame retardancy, leaching resistance, and thermal properties of wood was investigated. The limiting oxygen index results revealed a significant improvement in the flame retardancy and leaching resistance of the wood sample treated with KCO and SiO sol using the double bath technique. The thermal analysis results showed that the synergistic effect of KCO and the SiO sol effectively prolonged the degradation of the wood sample during the charring stage and improved the stability of the char residue. The thermogravimetry-mass spectrometry analysis and scanning electron microscopy results showed that KCO catalyzed the degradation reaction of the wood sample at lower temperatures resulting in an increase in the water and carbon dioxide output, and the SiO sol formed a compact and melted barrier on the surface of the char residue, which hindered the transfer of heat and combustible gases in the condensed phase. Thus, the combination of KCO and SiO sol proves to be a promising flame-retardant system for wood. [ABSTRACT FROM AUTHOR]

Key message: An efficient use of thermal treatment of wood requires a depth understanding of the chemical modifications induced. This is a prerequisite to avoid problems of process control, and to provide high quality treated wood with accurately assessed properties to the market. Properties and structural anatomy of thermally modified woods are slightly different than un-processed woods from a same wood species. So it is necessary to create or adapt new analytical methods to control their quality. Context: Heat treatment as a wood modification process is based on chemical degradation of wood polymer by heat transfer. It improves mainly the resistance of wood to decay and provides dimensional stability. These improvements, which come at the expense of a weakening of mechanical properties, have been extensively studied. Since a decade, researches focused mainly on the understanding of wood thermal degradation, on modelling, on quality prediction and quality control. Aims: We aimed at reviewing the recent advances about (i) the analytical methods used to control thermal treatment; (ii) the effects on wood decay resistance and (iii) the advantages and drawbacks of a potential industrial use of wood heating. Methods: We carried out a literature review of the main industrial methods used to evaluate the conferred wood properties, by thermal treatment. We used papers and reports published between 1970 and 2015, identified in the web of science data base.. Results: Approximately 100 papers mostly published after 2000 were retrieved. They concentrated on: (i) wood mass loss due to thermal degradation determination, (ii) spectroscopic analyses of wood properties, (iii) colour measurements, (iv) chemical composition, (v) non-destructive mechanical assessments and (vi) use of industrial data. Conclusions: One of most interesting property of heat-treated wood remains its decay resistance. Durability test with modified wood in laboratory are expensive and time-consuming. This review displays data from different analytical methods, such as spectroscopy, thermogravimetry, chemical analyses or mechanical tests that have the potential to be valuable indicators to assess the durability of heat treated wood at industrial scale. However, each method has its limits and drawbacks, such as the required investment for the equipment, reliability and accuracy of the results and ease of use at industrial scale. [ABSTRACT FROM AUTHOR]

To upgrade the utilization of kraft lignin (KL) for high-performance lignin-based materials (e.g., carbon fiber), the purity, molecular mass distribution (MMD), and thermal properties need to be improved and adjusted to target values. Therefore, different methods, such as ultrasonic extraction (UE), solvent extraction, dialysis, and hot water treatment (HWT), were applied for the purification of KL. The chemical and thermal properties of purified lignin have been characterized by nuclear magnetic resonance, Fourier transform infrared, gel permeation chromatography, elemental analysis, differential scanning calorimetry, and thermogravimetric analysis. The lignin fractions obtained by UE with ethanol/acetone (E/A) mixture (9:1) revealed a very narrow MMD and were nearly free of inorganic compounds and carbohydrates. Further, the E/A-extracted lignin showed a lower glass transition temperature ( Tg) and a clearly detectable melting temperature ( Tm). Dialysis followed by HWT at 220°C is an efficient method for the removal of inorganics and carbohydrates; however, lignin was partly forming condensed structures during the treatment. [ABSTRACT FROM AUTHOR]