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We compute the radiative ro-vibrational emission spectrum of H2 involving quasibound states via a simple numerical method of resolution of the Schr\"odinger equation by introducing a modifed effective molecular potential. The comparison of the eigenvalues obtained with our approximation and other theoretical methods based on scattering resonance properties is excellent. Electric quadrupole and magnetic dipole contributions are calculated and we confirm the previous computations of Forrey of the electric quadrupole transition Einstein coeffcients. The astrophysical relevance of such quasibound levels is emphasized, Comment: 10 pages,1 figure, 4 tables. Molecular Physics

The FUV continuum spectrum of many accreting pre-main sequence stars, Classical T Tauri Stars (CTTSs), does not continue smoothly from the well-studied Balmer continuum emission in the NUV, suggesting that additional processes contribute to the short-wavelength emission in these objects. The most notable spectral feature in the FUV continuum of some CTTSs is a broad emission approximately centered at 1600~��, which has been referred to as the "1600 A Bump". The origin of this feature remains unclear. We have assembled archival FUV spectra of 37 disk-hosting systems observed by the {\it Hubble Space Telescope}. Clear 1600 A Bump emission is observed above the smooth, underlying 1100-1800 A continuum spectrum in 19/37 Classical T Tauri disks in the HST sample, with the detection rate in transition disks (8/8) being much higher than in primordial or non-transition sources (11/29). We describe a spectral deconvolution analysis to separate the Bump (spanning 1490~--~1690 A) from the underlying FUV continuum, finding an average Bump luminosity, $L$(Bump7 x 10^{29} erg s^{-1}. We find that the 1600 A Bump is characterized by a peak wavelength of 1598.6 +/- 3.3 A. Contrary to previous studies, we find that this feature is inconsistent with models of H2 excited by electron-impact. We show that this Bump emits roughly 10-80% of the total fluorescent H2 luminosity for stars with well-defined Bump features. Energetically, this suggests that the carrier of the 1600 A Bump emission is powered by Ly-a photons. We argue that the most likely mechanism is Ly-a-driven dissociation of H2O in the inner disk, r < 2 AU. We demonstrate that non-thermally populated H2O fragments can qualitatively account for the observed emission (discrete and continuum), and find that the average Ly-a-driven H2O dissociation rate is 1.7x 10^{42} water molecules s^{-1}., 28 pages, 17 figures. Accepted for publication in the Astrophysical Journal