1. A cobalt-coordination polymer as a highly selective and sensitive luminescent sensor for detecting 2,4,6-trinitrophenol.
- Author
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Wang, Cuiping, Sheng, Wenwen, Sun, Chen, Lei, Jie, and Hu, Jinsong
- Subjects
COORDINATION polymers ,PICRIC acid ,PHENYL ethers ,POLYMERS ,POLYMER networks ,DETECTORS - Abstract
In this paper, a new three-dimensional network coordination polymer {[Co(TPTC)(HBPDPE)
2 ·2H2 O]·3H2 O}n [[[(1:1′:4′,1″-terphenyl)-3,3″,5,5″-tetracarboxylic cobalt (II)] dipyridine dihydrate] trihydrate] (Complex 1) was generated under solvothermal synthesis by rigid conjugated ligand H4 TPTC ([1:1′:4′,1″-terphengl]-3,3″,5,5″-tetracarboxylic), V-shaped BPDPE (4,4′-bis (pyridyl) diphenyl ether) and Co(II) ion. In complex 1, the neighboring Co(II) ions are linked by deprotonated TPTC4- to achieve a 1D zigzag chain [Co(TPTC)(HBPDPE)2 ]n , then the adjacent [Co(TPTC)(HBPDPE)2 ]n chains linked each other by various H-bondings to extend the structure from 1D chain to 3D network. Complex 1 has excellent fluorescence sensing performance and exhibits high sensitivity and selectivity for detecting 2,4,6-trinitrophenol (TNP), the quenching constant Ksv is up to 2.08 × 105 M−1 along with the correlation coefficient R2 of 0.993. Furthermore, the quench mechanisms of this Co-MOF as a sensor to detect nitro- aromatic explosives were studied as well. A new three-dimensional coordination polymer {[Co(TPTC)(HBPDPE)2 ·2H2 O]·3H2 O}n (1), constructed by 1D zigzag chains and H-bondings interactions, was synthesized under solvothermal condition by a rigid conjugated ligand H4 TPTC ([1:1′:4′,1″-terphengl]-3,3″,5,5″-tetracarboxylic), BPDPE (4,4′-bis (pyridyl) diphenyl) and Co(II) ion. Complex 1 has excellent fluorescence sensing performance for detecting Nitroaromatic explosive (NAE) 2,4,6-trinitrophenol (TNP), the quenching constant Ksv is up to 2.08 × 105 M−1 , and the quenching mechanism was studied as well. [ABSTRACT FROM AUTHOR]- Published
- 2024
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