1. Experimental and Theoretical Studies of Two New Trinuclear Ni(II) Asymmetric Salamo-Based Complexes.
- Author
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Ding, Y.-F., La, Y.-T., Li, W.-D., Yao, G.-X., Wang, L., and Dong, W.-K.
- Subjects
CHEMICAL bonds ,CHEMICAL stability ,X-ray crystallography ,DENSITY functional theory ,SURFACE analysis ,COORDINATION compounds ,CHELATING agents - Abstract
Two new trinuclear Ni(II) complexes, [{Ni(L)(DMF)(μ-OAc)}
2 Ni] (1) and [{Ni(L)(EtOH)(μ-OAc)}2 Ni]·2CH2 Cl2 (2), have been successfully synthesized from a new asymmetric salamo-based hexa-dentate chelating ligand (H2 L) and Ni(OAc)2 ·4H2 O, and characterized by elemental analysis, IR and UV-Vis spectra, and X-ray crystallography. The binding ratio of H2 L and Ni(II) ion has been confirmed by UV-Vis titration. All Ni(II) atoms are hexa-coordinated, and the complexes have octahedral configuration, though with difference in the solvent molecules (DMF/EtOH) involved in the coordination, composition of the hydrogen bond and chemical stability. This conclusion is confirmed by Hirshfeld surfaces analyses and Density Functional Theory (DFT). [ABSTRACT FROM AUTHOR]- Published
- 2021
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