Search

Borylierung eines wolframgebundenen N2‐Liganden und anschließende Halogenidabstraktion ermöglichen den Zugang zu einem kationischen Komplex mit einem bisher beispiellosen linearen NNBR‐Liganden. Dieser Komplex geht [3+2] Cycloadditionen mit Aziden ein und eine unerwartete Kettenverlängerungsreaktion mit einem Iminoboran, was zu einem Komplex mit einer fünfatomigen B/N‐Kette führt. Diese beiden [NNBR]‐haltigen Komplexe, anorganische Analoga von E. O. Fischers Alkinylcarbinen, sind sehr seltene Beispiele für Moleküle, die rein anorganische Ketten von sp‐hybridisierten Atomen enthalten. [ABSTRACT FROM AUTHOR]

Copyright of Angewandte Chemie is the property of Wiley-Blackwell and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

Copyright of Angewandte Chemie is the property of Wiley-Blackwell and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

Copyright of Angewandte Chemie is the property of Wiley-Blackwell and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

Copyright of Angewandte Chemie is the property of Wiley-Blackwell and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)