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Old paper samples are bleached using pulsed laser radiation with a wavelength of 532 nm. The ablation products of five paper samples that differ by composition and production dates are studied using Raman microspectroscopy. Cellulose, protein, calcite, titanium dioxide (anatase, rutile, and brookite), quartz, lazurite, bonattite, and dolomite are identified as ablation products. [ABSTRACT FROM AUTHOR]

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B In this issue... b Papers in this thematic issue focus on Zechstein petroleum system elements in the North Sea and adjacent areas. The following three papers report on Z2 (Hauptdolomit) Zechstein carbonate platforms in and around the Mid North Sea High (MNSH), a Variscan uplift offshore eastern England, and its extension to the SE in Dutch waters known as the Elbow Spit High. However a separate Zechstein reservoir unit at the Jarvis structure consists of Z2 and Z3 dolomites which contain oil whose origin has not been studied before in detail. [Extracted from the article]

In the paper “Formation mechanism of deep Cambrian dolomite reservoirs in the Tarim basin, northwestern China” ( Zhu et al., 2015 ), we concluded that hydrothermal alteration further enhanced porosity in the deep Cambrian dolomite reservoirs in the Tarim Basin, NW China. Professor Ehrenberg and Bjørlykke made comments that the hydrothermal dolomitization and increase in porosity were not well supported and casted doubt on the exploration potential. We insist the influence of hydrothermal alteration on and large exploration potential in the deep Cambrian dolomite reservoirs due to the unique geological conditions and the recent exploration results. [ABSTRACT FROM AUTHOR]

This paper presents a gravimetric method for the quantification of total organic carbon by ignition at 1100°C and carbonates by acid dissolution in rock samples containing coal. Two minerals (CM-1 and CM-2) and a subbituminous coal (SBC) were used in the study. The mineralogical characterization of the samples was performed by X-ray diffraction and scanning electron microscopy. This revealed the presence of calcite in samples CM-1 (20.4%) and CM-2 (74.7%), dolomite in CM-2 (0.7%), and graphite in sample SBC (42.6%). To eliminate carbonates, the samples were treated with 4 mol/L HCl, which allowed quantification. Results of the carbonate gravimetric quantification were compared with those obtained with a calcimeter. A significant difference was observed for the sample CM-2 (70.3% versus 63.4% by calcimetry, p-value = 0.0042). For the sample without carbonates, no differences were observed for loss on ignition without and with the acid treatment, so this is not necessary for this type of sample. A morphological study showed no significant surface change after acid treatment, but fracture of iron oxide particles was observed in CM-1 and CM-2 after heat treatment. In this study it was demonstrated that rock mineralogy is essential to correctly analyze organic and inorganic carbon content. [ABSTRACT FROM AUTHOR]

The Lower Ordovician Tongzi Formation containing abundant shoal sediments is the most promising stratum for the petroleum exploration in the Sichuan Basin. However, the current studies mainly focus on the central part of the Basin, the systematic analysis of the southeastern part with well-developed shoal facies is lacking. This paper aims to clarify the characteristics and genesis of the Tongzi Formation reservoir in Southeastern Sichuan Basin, following an analysis of sedimentary facies within the sequence stratigraphic framework. The research shows that the main types of reservoir rocks are oolitic, intraclastic and bioclastic dolostones. And the reservoir spaces consist mainly of intergranular (dissolved) pores, inter-crystalline (dissolved) pores, intragranular dissolved pores and fractures. Among them, intergranular pores account for the highest proportion, which is followed by intragranular dissolved pores. In addition, most throats are necking and flaky which mainly connect intergranular and inter-crystalline pores, respectively. The diagenetic sequence shows that penecontemporaneous karst well improved the porosity of the reservoir in the early-stage although the cementation and compaction reduced parts of pores. The reservoir formation is associated with the tectonic-depositional settings, diageneses and terrigenous contamination. Paleohighlands and submerged uplifts, forming in the early Ordovician amalgamation between Yangtze and Cathaysia blocks, accumulated shoal sediments as the material basis for the reservoir formation. Penecontemporaneous karst forming intragranular dissolved pores and the dolomitization aiding grainstones to resist the pressure solution are the key to increasing porosity and preserving pores. The absence of terrigenous contamination prevented intergranular pores from being strongly cemented, which resulted in the reservoir difference between the central and southeastern Sichuan Basin. The study can be used as a reference for the further exploration of Ordovician petroleum in the Sichuan Basin and other regions owning similar geological settings. [ABSTRACT FROM AUTHOR]

The marine carbonates in the Ordovician Majiagou Formation in the Ordos Basin have significant exploration potential. Research has focused on their thermal history and hydrocarbon accumulation stages, as these are essential for guiding the exploration and development of hydrocarbons. In this paper, we study the thermal evolution history of the carbonate reservoirs of the Ordovician Majiagou Formation in the east-central Ordos Basin. Furthermore, petrographic and homogenization temperature studies of fluid inclusions were carried out to further reveal the hydrocarbon accumulation stages. The results demonstrate that the degree of thermal evolution of the Ordovician carbonate reservoirs is predominantly influenced by the deep thermal structure, exhibiting a trend of high to low values from south to north in the central region of the basin. The Fuxian area is located in the center of the Early Cretaceous thermal anomalies, with the maturity degree of the organic matter ranging from 1 to 3.2%, with a maximum value of 3.2%. The present geothermal gradient of the Ordovician Formation exhibits the characteristics of east–high and west–low, with an average of 28.6 °C/km. The average paleo-geotemperature gradient is 54.2 °C/km, the paleoheat flux is 55 mW/m2, and the maximum paleo-geotemperature reaches up to 270 °C. The thermal history recovery indicates that the Ordovician in the central part of the basin underwent three thermal evolution stages: (i) a slow warming stage before the Late Permian; (ii) a rapid warming stage from the end of the Late Permian to the end of the Early Cretaceous; (iii) a cooling stage after the Early Cretaceous, with the hydrocarbon production of hydrocarbon source rocks weakening. In the central part of the basin, the carbonate rock strata of the Majiagou Formation mainly developed asphalt inclusions, natural gas inclusions, and aqueous inclusions. The fluid inclusions can be classified into two stages. The early-stage fluid inclusions are mainly present in dissolution holes. The homogenization temperature is 110–130 °C; this coincides with the hydrocarbon charging period of 210–165 Ma, which corresponds to the end of the Triassic to the end of the Middle Jurassic. The late-stage fluid inclusions are in the dolomite vein or late calcite that filled the gypsum-model pores. The homogenization temperature is 160–170 °C; this coincides with the hydrocarbon charging period of 123–97 Ma, which corresponds to the late Early Cretaceous. Both hydrocarbon charging periods are in the rapid stratigraphic warming stage. [ABSTRACT FROM AUTHOR]

The ash generated by Circulating Fluidized Bed (CFB) boilers is featured by its looseness and porosity, low content of glassy substances, and high contents of calcium (Ca) and sulfur (S), thus resulting in a low comprehensive utilization rate. Currently, the predominant treatment approach for CFB ash and slag is stacking, which may give rise to issues like environmental pollution. In this paper, CFB ash (with a CaO content of 7.64% and an SO3 content of 1.77%) was used as the main raw material. The high-temperature melting characteristics, viscosity–temperature characteristics, and initial crystallization temperature of samples with different acidity coefficients were investigated. The final drawing temperature range of the samples was determined, and mechanical property tests were conducted on the prepared inorganic fibers. The results show that the addition of dolomite powder has a significant reducing effect on the complete liquid phase temperature. The final drawing temperatures of the samples with different acidity coefficients range as follows: 1270–1318 °C; 1272–1351 °C; 1250–1372 °C; 1280–1380 °C; 1300–1382 °C; and 1310–1384 °C. The drawing temperature of this system is slightly lower than that of basalt fibers. Based on the test results of the mechanical properties of inorganic fibers, the Young's modulus of the inorganic fibers prepared through the experiment lies between 55 GPa and 74 GPa, which basically meets the performance requirements of inorganic fibers. Consequently, the method of preparing inorganic fibers by using CFB ash and dolomite powder is entirely feasible. [ABSTRACT FROM AUTHOR]

Copyright of Natural Gas Industry is the property of Natural Gas Industry Journal Agency and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

Reactive transport modeling (RTM) is an emerging method used to address geological issues in diagenesis research. However, the extrapolation of RTM results to practical reservoir prediction is not sufficiently understood. This paper presents a case study of the Eocene Qaidam Basin that combines RTM results with petrological and mineralogical evidence. The results show that the Eocene Xiaganchaigou Formation is characterized by mixed siliciclastic-carbonate-evaporite sedimentation in a semiclosed saline lacustrine environment. Periodic evaporation and salinization processes during the syngeneticpenecontemporaneous stage gave rise to the replacive genesis of dolomites and the cyclic enrichment of dolomite in the middle-upper parts of the meter-scale depositional sequences. The successive change in mineral paragenesis from terrigenous clastics to carbonates to evaporites was reconstructed using RTM simulations. Parametric uncertainty analyses further suggest that the evaporation intensity (brine salinity) and particle size of sediments (reactive surface area) were important rate-determining factors in the dolomitization, as shown by the relatively higher reaction rates under conditions of higher brine salinity and fine-grained sediments. Combining the simulation results with measured mineralogical and reservoir physical property data indicates that the preservation of original intergranular pores and the generation of porosity via replacive dolomitization were the major formation mechanisms of the distinctive lacustrine dolomite reservoirs (widespread submicron intercrystalline micropores) in the Eocene Qaidam Basin. The results confirm that RTM can be effectively used in geological studies, can provide a better general understanding of the dolomitizing fluid-rock interactions, and can shed light on the spatiotemporal evolution of mineralogy and porosity during dolomitization and the formation of lacustrine dolomite reservoirs. [ABSTRACT FROM AUTHOR]

AG-MP-1M anion exchange resin is commonly used to separate and purify Cd from geological and environmental samples. However, a second column using anion exchange, TRU Spec, or BPHA extraction resins is also required to further purify Cd from the residual Sn for high-precision Cd isotope ratio measurements. In this study, a new and efficient single-stage separation method using AG-MP-1M (100–200 mesh) anion exchange resin was developed to separate Cd from geological and environmental samples for high-precision Cd isotope ratio measurements. Most of the Sn (>99%) is effectively stripped from the resin using a 2 M HCl + 4 M HF mixed eluent, unlike commonly used separation protocols with AG-MP-1M anion exchange resin, which only removes ∼65% of the Sn using HCl eluent. Furthermore, potential residual Sn is retained on the resin by elution of 0.04 M HCl + 2 M HF and 0.005 M HCl + 2 M HF, which allows quantitative collection of the Cd fraction (∼99.5%) without Sn tailing. The single-stage purification procedure takes advantage of the different affinities of Sn on AG-MP-1M anion exchange resin at different HCl and HF concentrations in mixed HCl + HF solutions, which allows direct and effective separation of Cd from Sn and other complex sample matrices. We used this procedure and the double-spike MC-ICP-MS method to determine the δ114/110CdNIST SRM 3108 values for Mn nodule, igneous rock, shale, soil, and sediment reference materials, and obtained results that agree within analytical uncertainty with the values reported in previous studies. In addition, the δ114/110CdNIST SRM 3108 values of soil (GSS-1a), sediment (GSD-4a), and dolomite (GSR-12) standard reference materials are reported for the first time in this paper. The described purification procedure allows efficient and rapid Cd isotopic analysis in different types of geological and environmental samples. [ABSTRACT FROM AUTHOR]

There are concerns that Mg-calcite crustose coralline algae (CCA), which are key reef builders on coral reefs, will be most susceptible to increased rates of dissolution under higher pCO2 and ocean acidification. Due to the higher solubility of Mg-calcite, it has been hypothesized that magnesium concentrations in CCA Mg-calcite will decrease as the ocean acidifies, and that this decrease will make their skeletons more chemically stable. In addition to Mg-calcite, CCA Porolithon onkodes the predominant encrusting species on tropical reefs, can have dolomite (Ca0.5Mg0.5CO3) infilling cell spaces which increases their stability. However, nothing is known about how bio-mineralised dolomite formation responds to higher pCO2. Using P. onkodes grown for 3 and 6 months in tank experiments, we aimed to determine (1) if mol%MgCO3 in new crust and new settlement affected by increasing pCO2 levels (365, 444, 676 and 904 ppm), (2) whether bio-mineralised dolomite formed within these time frames, and (3) if so, whether this was effected by pCO2. Our results show there was no significant effect of pCO2 on mol%MgCO3 in any sample set, indicating an absence of a plastic response under a wide range of experimental conditions. Dolomite within the CCA cells formed within 3 months and dolomite abundance did not vary significantly with pCO2 treatment. While evidence mounts that climate change will impact many sensitive coral and CCA species, the results from this study indicate that reef-building P. onkodes will continue to form stabilising dolomite infill under near-future acidification conditions, thereby re- taining its higher resistance to dissolution. [ABSTRACT FROM AUTHOR]

The Cambrian pre-salt dolomite sequence in the Tarim Basin is a target zone of great strategic significance for hydrocarbon exploration in the basin. Using the results of the interpretation of 3D seismic data from Lunnan and 2D seismic data covering the whole basin, and based on a synthesis of outcrop data, drilling data, well logs, core data, and thin-section data, and the findings from previous studies, this paper studies the characteristics of the facies of the Middle–Lower Cambrian in the platform area in the Tarim Basin, the formation and evolution of platform margins, and the sedimentary characteristics, lithofacies, and paleogeographic characteristics of the Middle–Lower Cambrian series. Based on the types of lithofacies and the seismic facies analysis, the sedimentary facies of the Middle–Lower Cambrian strata can be classified into the five types. From bottom to top, the Middle–Lower Cambrian have experienced several development stages, including the deposition of continental shelf sediments of the Yuertusi Formation, gently sloping non-rimmed platform margin sediments of the Xiaoerbulake Formation, weakly rimmed platform margin sediments of the Wusongger and Shayilike formations, and strongly rimmed platform margin sediments of the Awatage Formation. In each stage, the platform margin shifted further east relative to its location in the previous stage. Based on these results and previous studies, the lithofacies and paleogeography maps of the Middle–Lower Cambrian in the Tarim Basin are modified, and the implications for hydrocarbon exploration in this area are discussed. [ABSTRACT FROM AUTHOR]

Copyright of Journal of Forestry Society of Croatia / Sumarski List Hrvatskoga Sumarskoga Drustva is the property of Forestry Society of Croatia and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

Medium-coarse-crystalline dolomite is a major variant of dolomite, and its structural heterogeneity inside and outside the crystals makes it an ideal vehicle for studies of dolomite genesis, fluid evolution and elemental migration. In this paper, the medium-coarse crystalline dolomite from the fifth section of the Majiagou Formation of the Lower Ordos Basin was systematically studied by petrographic, cathodoluminescence and related geochemical methods. The rock is developed in the context of mud powder crystal dolomite and granular dolomite, possessing significant ring band structure, fluorite and quartz intergrowth. Compared with other dolomites, it is characterized by Fe and Mn enrichment and low Na and Sr contents, as well as a negative δEu anomaly and a strong negative δ18 O offset. Combined with the evolutionary history of diagenesis, it is believed that the medium-coarse-crystal dolomite is the end product of a series of diagenetic effects such as early dolomitization-atmospheric freshwater leaching-secondary burial recrystallization-deep burial dissolution. Electron microprobe analysis reveals the structural and compositional heterogeneity inside and outside the crystals. The formation of mediumcoarse- crystalline dolomite is associated with an increase in Fe-Mn content, a rise in the Mn/Sr ratio, a decrease in Sr, and a first rise and then a fall in Na concentration. This study provides a valuable reference for further research on the genesis of the medium-coarse crystalline dolomite. [ABSTRACT FROM AUTHOR]

Hydraulic fracturing (HF) is the primary choice for stimulating petroleum reservoirs. Rock tensile strength and brittleness are crucial parameters required for screening candidate reservoirs and in designing successful HF operations. However, in situ and laboratory determinations of the hydraulic tensile strength (HTS) of rock can prove problematic. Alternatively, the HTS could be estimated from the rock brittleness once a reliable relationship has been established between them. Accordingly, this paper investigates the correlations between the HTS, as measured using laboratory hydraulic fracture tests, and ten strength-based brittleness indices (BIs) selected from the research literature. The primary inputs for computing these BIs are uniaxial compressive strength (UCS) and the Brazilian tensile strength (BTS), which are typically measured for most projects using standard laboratory rock mechanics tests or obtained from log data. For the purposes of this experimental investigation, intact rock core samples were obtained from a carbonate–dolomite formation in Iran, comprising eight distinct geomechanical units, with measured values of UCS, BTS, and HTS ranging 29.7–162.2, 1.93–12.23, and 7.20–20.63 MPa, respectively. The measured HTS was found to directly correlate with the UCS, BTS, and Young's modulus, and inversely correlated with the rock porosity. Seven of the ten investigated BIs correlated with the measured HTS over 69% (R2 ≥ 0.69). In particular, the BI expressions developed by Yagiz and Gokceoglu, Ghadernejad et al., and Khandelwal et al. exhibited relatively strong correlations with the measured HTS (producing R2 values of 0.94, 0.87, and 0.86, respectively), suggesting that these three HTS–BI correlations could be used to provide preliminary HTS estimates for the investigated carbonate–dolomite formation in Iran. This work adds to a database that can be expanded to include other geographical regions for providing useful information about the selection of a suitable site or reserve for conducting HF operations. [ABSTRACT FROM AUTHOR]

Owing to the deep concave mining in Bayan Obo stope, the slope angle is steep, the terrain is high, the outcrop width of the crushing belt is large, the stability of many slopes is poor, and there are potential sliding surfaces. In this paper, through on-site investigation and sampling, the main factors affecting the landslide of the high and steep slopes of Bayan Obo are analyzed. Uniaxial compression tests were carried out to obtain the mechanical parameters of dolomite and slate. With the help of the three-dimensional digital speckle system, the whole process of slope landslide under rainfall conditions was studied through similar simulation and numerical simulation experiments. The influence of rainfall on the slope of Bayan Obo and the induced pattern of landslide were revealed. The experimental results show that rainfall is the key to inducing instability, the slippage at the edge of the slope is obvious, and there is seepage in the depths but the effect is not significant. The landslide can be roughly divided into the damage accumulation stage; the deformation development and expansion stage; and the unstable slip stage. [ABSTRACT FROM AUTHOR]

Under tectonic stresses, shale in different stress–strain environments will undergo structural deformation of varying mechanisms and intensities, forming various types of tectonically deformed shales (TDSs). By changing pore structures, structural deformation significantly influences shale's reservoir properties and then the resource potentials. This paper aims to reveal the evolution rules and mechanisms of micro- and mesopore structures of various TDSs. We first propose a TDS classification scheme according to the differences in deformation features and deformation mechanisms. Then, N2 and CO2 adsorption tests were conducted on the whole rock and kerogen samples of various TDSs to reveal the pore structure evolutions of shale during structural deformations and investigate the contributions of organic pore changes. Finally, we studied the mineral composition differences between various TDSs and their effects on the evolutions of shale's micro- and mesopores. Results showed that compared with undeformed shale, weakly brittle deformed shale (BDS) experienced a significant reduction in micro- and mesopores, mainly resulting from the decrease of organic matter content caused by the development of tectonic fractures and the filling of hydrothermal minerals. In strongly BDSs, there was a noticeable decrease in micro- and mesopores from undeformed shale as well. Apart from the negative effects of increasing carbonate minerals, the increased clay minerals also caused a decrease in kerogen content and organic pores. The limited increases of pores from weakly BDSs to strongly BDSs is mainly due to the emerged interparticle pores during shale fragmentation. Ductile deformed shale showed a significant decrease in micro- and mesopores; the collapse of organic pores is the dominant mechanism, with the mixing of clay minerals being an important reason as well. As for the brittle–ductile deformed shale, the evolution of micro- and mesopores is the result of the increase of carbonate minerals and the compression of kerogen. [ABSTRACT FROM AUTHOR]

This paper presents the results of detailed geological investigations of the Middle Triassic dolomite deposit of Nikolin Potok, which is located west of Bugojno. Based on the established borders of surface distribution and research results, geological reserves of about 4.6 million m³ have been determined in the wider area of the deposit. The dolomite reserves that have been established so far in this area are at a low level of geological exploration. For this reason, the level of research should be significantly increased, because the calculated and confirmed reserves are very modest compared to the potential possibilities. The paper contains a description of the geological characteristics of the area and the qualitativequantitative characteristics of dolomite. The results of the conducted research point that the general geological and technical-exploitation factors are favorable and indicate profitable exploitation of the deposit in the coming period as well. Taking into account the significant raw material potential, and the possibility of expanding the existing raw material base, this area has a special significance for the perspective development of dolomite exploitation and its use in the production of technical-building stone. [ABSTRACT FROM AUTHOR]

This paper provides an updated understanding of the reservoir stratigraphy, sedimentology, palaeogeography and diagenesis of the Upper Permian Hauptdolomit Formation of the Zechstein Supergroup ("Hauptdolomit") in a study area on the southern margin of the Mid North Sea High. The paper is based on the examination and description of core and cuttings data from 25 wells which were integrated with observations based on existing and new 3D seismic. Based on thin‐section petrography of cuttings and core from the wells studied, it is evident that Hauptdolomit microfacies are distributed in a relatively predictable way, and well‐defined platform interior, platform margin, slope and basin settings can be distinguished. Platform margins are typically characterised by the development of ooid shoals and, to a lesser‐extent, by microbial build‐ups. High‐energy back‐shoal settings are characterised by a more complex combination of peloid grainstones, thrombolitic and microbial build‐ups, and fine crystalline dolomites. Lower energy lagoons which developed further behind the platform margin are characterised by a variety of microfacies types; fine crystalline dolomites are common in this setting as well as peloidal facies and local microbial build‐ups. Intertidal and supratidal settings are typified by increased proportions of anhydrite and the development of laminated microbial bindstones (stromatolites). Platform margins are in general relatively steep and pass into slope and basinal settings. Only a few wells have penetrated Hauptdolomit successions deposited in a slope setting, and these successions are characterised by a range of resedimented shallow‐water facies together with low‐energy laminated dolomicrites and fine crystalline dolomites. Slope zones in the study area are interpreted from seismic data to be typically 1‐1.5 km in width. Basinal Hauptdolomit deposits have been strongly affected by post‐depositional diagenesis and are dedolomitised to variable degrees. The original depositional facies are rarely preserved. Diagenetic studies show that dolomitisation has affected almost the entire Hauptdolomit Formation throughout the study area in both basinal and platform settings. The dolomite is considered to result from seepage‐reflux processes and is an early diagenetic phase. Mouldic porosity is present in many facies types as a result of dissolution, especially in ooid grainstones, thrombolitic build‐ups and peloidal facies. The dissolution cannot be associated with any one diagenetic phase but was most likely a result of the dolomitisation process itself. Stable isotope analyses indicate that all dolomites were precipitated from Permian marine‐derived pore fluids. Fluid inclusion analyses of dolomite cements indicate that cementation continued into the burial realm. Anhydrite cementation occurs in two phases: early anhydrite precipitation was associated with dolomitisation, and can be distinguished from a later, pore‐filling cement which is highly detrimental to reservoir quality. The Hauptdolomit succession in basinal wells (and in some slope wells) in the study area has undergone significant dedolomitisation. Dedolomitisation was a shallow burial process which affected precursor dolomites, whereby excess calcium from the transition of gypsum to anhydrite during burial combined with CO2 and organic acids derived from basinal sediments. The process was triggered by excess calcium reacting with excess carbonate ions from dissolution. 3D seismic volumes supplemented by numerous 2D lines were available in the study area and allowed an interpretation to be made of Hauptdolomit gross depositional settings; platform margins and base‐of‐slope polygons were mapped, with the greatest confidence in areas of 3D seismic. The basin, slope and platform settings were distinguished using seismic data integrated with the results of micro‐facies analysis and incorporating seismic‐to‐well ties. The data shows that large parts of the study area are characterised by the presence of polyhalites within the overlying (Z2) Stassfurt Halite Formation, which may create particular seismic geometries at the Hauptdolomit slope. These are interpreted to be intra‐Stassfurt Halite features, providing an alternative model to the thickened, prograded Hauptdolomit which has been suggested in previous publications. Because few wells drilled in the study area had the Hauptdolomit as the primary target, cores were limited but significant data was obtained from cuttings analyses. More than 400 thin sections were evaluated, allowing depositional models based on microfacies observations to be developed, verifying the seismic‐scale observations. [ABSTRACT FROM AUTHOR]

In response to the challenges of karst geophysical exploration in an environment with strong external interference, this paper proposes a new method, namely the frequency-Bessel transform method, for extracting multi-order dispersion curves of surface waves from background noise to characterize karst. The observation noise data of the Wuhan karst development area are used as an example, where the dolomitic limestone and limestone mixed with dolomite of the Jialing River Formation of the middle lower Triassic are widely developed in the observation area. The frequency-Bessel transform method involves performing a Bessel integral transformation on the cross-correlation coefficient of background noise in the frequency domain. Firstly, by synthesizing theoretical noise data and comparing it with the spatial autocorrelation method—which is currently the main method for extracting the fundamental dispersion curve of surface waves—it is verified that the frequency-Bessel transform method can extract the higher-mode dispersion curve. Then, by taking the actual measured single-point noise data as an example, the effect of applying the frequency-Bessel transform to the actual noise data is tested, and the inversion of the fine structure of the strata by the addition of higher-mode dispersion, the use of the damped least squares inversion method, and the joint inversion of fundamental and higher-mode dispersion curves are analyzed. The higher-mode dispersion curve of Rayleigh surface wave extracted by the frequency-Bessel transform is much clearer, and the 2D shear wave velocity structure profile obtained from inversion explains the karst development area, karst strip area, and thickness of the Quaternary overburden. The inferred results match with the actual borehole data. Multi-mode imaging of background noise based on the frequency-Bessel method can be applied to depict karst in complex backgrounds, and has significant potentiality in the field of ambient seismic noise tomography, providing a new idea and method for karst detection in near-surface engineering. [ABSTRACT FROM AUTHOR]

Deep and ultra-deep carbonate reservoirs are the focus of exploration and development in future. However, the problems of high pressures in the treatment process, a limited effective etching distance of acid, great acid leak-off, and poor adaptability of the acid system are encountered in this type of oil and gas reservoir. The mechanism of acid fracturing stimulation under different processes and parameters is not clear. Aiming at these issues, the treatment schemes, process optimization, parameter optimization, and liquid system screening are studied in this paper, try to clarify the acid fracturing stimulation mechanism, and the following conclusions are drawn: The acid network fracturing could activate natural fracture to generate a complex fracture network to the greatest extent, and thereby a high output could be achieved; By using of weighted fracturing fluid, the wellhead injection pressure, as well as the performance of equipment required, could be effectively reduced; With 20% gelling acid and 20% retarded acid system, the non-uniform etching could be realized to improve the effective etching distance of acid liquid. The conclusions in this paper shed light on the acid fracturing treatment of deep and ultra-deep carbonate rocks. [ABSTRACT FROM AUTHOR]

Copyright of Natural Gas Geoscience is the property of Natural Gas Geoscience and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

Ultra-High Molecular Weight Polyethylene (UHMWPE) polymers have been used in biomedical applications due to its biocompatibility, durability, toughness and high wear resistance. To enhance the mechanical properties, various types of minerals are commonly utilized as fillers in UHMWPE. One of the minerals is dolomite, which has been recognized as a valuable mineral with versatile applications, particularly in the field of biomedical applications. This paper presents the tensile properties of UHMWPE composites that filled with dolomite and treated-dolomite at various filler loading (i.e., 1-5 wt.%). Nitric acid and diammonium phosphate were used to treat the dolomite. From the results, the peaks of the FTIR spectrum displays carbonate (CO3-2), phosphate (PO4-3) and hydroxyl (OH-) groups in the ct-dolomite powder sample while the XRD pattern reveals that using dolomite treated with 1M nitric acid resulted in the presence of calcium hydroxide phosphate (Ca10(PO4)5(OH)) and MgO. For tensile strength, UHMWPE/ct-dolomite composites show better tensile strength than the pure UHMWPE composites. Treated improve the dolomite filler and resulted in significantly better matrix-filler interfacial interactions and improve the properties. [ABSTRACT FROM AUTHOR]

Siliceous minerals of the Dengying Formation in the Gaoshiti–Moxi area in the central Sichuan Basin exhibit four types of quartz crystals (cryptocrystalline quartz, chalcedony, microcrystalline quartz, and megacrystalline quartz) and three structural types: cryptocrystalline, microcrystalline, and mosaic (laminated mosaic, window-hole interrupted mosaic, and arc-laminated mosaic). Siliceous minerals have a great influence on the storage performance of the reservoirs in the Dengying Formation. According to the petrophysical parameters of the Dengying Formation and porosity intersection diagrams, the siliceous dolomite and the reservoirs have low impedance characteristics, which makes it difficult to distinguish between them and leads to difficulties in the characterization and prediction of the reservoirs. The transverse wave velocity is favorable for reservoir characterization. Currently, the main method used to estimate the transverse wave velocity is petrophysical modeling, which establishes a relationship between the elastic and physical parameters of the reservoir. In this paper, the siliceous minerals in the dolomite in the study area are regarded as solid inclusions, and the calculation method of the rock matrix modulus is improved by using solid replacement. Then, an improved petrophysical model is constructed by combining the KT (Kuster–Toksöz) model, the DEM (Discrete Element Method) model, the Gassmann equation, and the Wood equation. The transverse wave velocity is estimated using the improved model under the constraint of the longitudinal wave velocity. The shapes of the transverse wave velocity curves obtained by the improved model and the deviations from the measured velocities are significantly better than those of the Xu–Payne model and other models. The results show that the improved model can effectively estimate the transverse wave velocity of the reservoir in this area, which provides a basis for future reservoir predictions in this area. [ABSTRACT FROM AUTHOR]

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In the field of mineral processing, the successful flotation of target minerals requires sufficient liberation through grinding. The aim of this paper is to compare and evaluate the performance of ball versus short cylindrical media for comminution of dolomite by point and line contact, respectively. The results of the grinding experiments indicate that short cylinders generate more angular particles with intermediate sizes and exhibit a higher grinding efficiency compared to balls. The Population Balance Model demonstrates the distribution of broken fragment sizes during the breaking stage for each size range. The results of the DEM (discrete element method) grinding simulation are consistent with the experimental findings in terms of the distribution of particle sizes, the shape of the particles, and the distribution of broken fragment sizes. Furthermore, short cylinders selectively produce more active {104} crystal surface of dolomite, which possess a higher adsorption capacity with collectors and are preferentially floated as the concentrate. In reverse flotation for removal of dolomite, tests confirm that the products obtained from grinding with short cylinders exhibit a higher flotation recovery of dolomite compared to those obtained from ball grinding. This study provides a reference scheme for optimizing the grinding and flotation processes of valuable minerals. [ABSTRACT FROM AUTHOR]

Smithsonite, dolomite, and calcite are carbonate minerals. The crystal structures and spatial distribution characteristics of their common surface metal sites are similar, leading to difficulty in the flotation separation of smithsonite from these carbonate gangues. In this paper, the floatability of smithsonite, dolomite, and calcite in sodium oleate, salicylhydroxamic acid, and their combined-collector system were systematically studied through single-mineral flotation tests, respectively. The results showed that it was difficult to obtain a noticeable recovery difference between smithsonite–calcite and smithsonite–dolomite in a single-collector system of sodium oleate and salicylhydroxamic acid, both at the same time. In the combined-collector system of salicylhydroxamic acid and sodium oleate with total dosage of 6 × 10−4 mol/L, molar ratio of 3:1, and pH of 8.0, the recovery difference of smithsonite–calcite and smithsonite–dolomite could reach the highest values of 38.46% and 37.98%, respectively, while obtaining the highest smithsonite recovery of 88.19%. The adsorption mechanism of the combined collectors was investigated via Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, a collector adsorption test, and zeta potential measurements, respectively. [ABSTRACT FROM AUTHOR]

The paper presents experimental results obtained in the manufacturing process of porous high-strength glass foam for thermal insulation in buildings made of glass waste and kaolin clay as raw materials and dolomite as a foaming agent. The paper’s originality is the use of the unconventional microwave heating technique. The best product manufactured by this technique was that sintered at 1050 ºC using 18 wt.% kaolin clay and 3.5 wt.% dolomite. The product characteristics were: the apparent density of 0.66 g·cm-3, the thermal conductivity of 0.155 W/m·K, the compressive strength of 5.3 MPa and a microstructural homogeneity with pore size between 0.20-0.50 mm. [ABSTRACT FROM AUTHOR]

In order to enhance the development efficiency of thick and complex carbonate reservoirs in the Middle East, a case study was conducted on M oilfield in Iraq. This study focused on reservoir characterization, injection-production modes, well pattern optimization, and other related topics. As a result, key techniques for the high-efficiency development of thick carbonate reservoirs were established. The research findings include the following: (1) the discovery of hidden "low-velocity" features within the thick gypsum-salt layer, which led to the development of a new seismic velocity model; (2) the differential dissolution of grain-supported limestones is controlled by lithofacies and petrophysical properties, resulting in the occurrence of "porphyritic" phenomena in core sections. The genetic mechanism responsible for reversing petrophysical properties in dolostones is attributed to "big hole filling and small hole preservation" caused by dense brine refluxing; (3) fracture evaluation technology based on anisotropy and dipole shear wave long-distance imaging was developed to address challenges associated with quantitatively assessing micro-fractures; (4) through large-scale three-dimensional physical models and numerical simulations, it was revealed that water–oil displacement mechanisms involving "horizontal breakthrough via hyper-permeability" combined with vertical differentiation due to gravity occur in thick and heterogeneous reservoirs under spatial injection-production modes; (5) a relationship model linking economic profit with well pattern density was established for technical service contracts in the Middle East. Additionally, an innovative stepwise conversion composite well patterns approach was introduced for thick reservoirs to meet production ramp-up requirements while delaying water cut rise; (6) a prediction technology for the oilfield development index, considering asphaltene precipitation, has been successfully developed. These research findings provide robust support for the efficient development of the M oilfield in Iraq, while also serving as a valuable reference for similar reservoirs' development in the Middle East. [ABSTRACT FROM AUTHOR]

On 12th August 2015, a massive rapid long run-out rock landslide occurred in the Shanyang Vanadium Mine in Shaanxi Province, China, which claimed the lives of 65 miners. No heavy rainfalls, earthquakes, and mining blasts were recorded before the incident. Therefore, the failure mechanism and the cause of the long run-out movement are always in arguments. In this paper, we conducted a detailed field investigation, laboratory tests, block theory analysis, and numerical simulation to investigate the failure and long run-out mechanisms of the landslide. The field investigation results show that the source material of the rock landslide is a huge dolomite wedge block bedding on siliceous shale layers. Uniaxial compression tests indicate that the uniaxial compression strength of the intact dolomite is 130–140MPa and the dolomite shows a brittle failure mode. Due to the progressive downward erosion of the gully, the dolomite rock bridge at the slope toe became thinner. As the compression stress in the dolomite bridge increased to surpass its strength, the brittle failure of the bridge occurred. Then huge potential energy was released following the disintegration of the landslide, which led to the high acceleration of this rock landslide. The 3D discrete element simulation results suggest that the low intergranular friction contributes to the long run-out movement of this rock landslide. [ABSTRACT FROM AUTHOR]

Rock and gas outbursts occur most frequently in coal mining. Gas-induced geodynamic events in dolomite are a new and unexplored phenomenon. In the last time, two outbursts of gas and dolomite have occurred in the Legnica-Głogów Copper Region in southwestern Poland, which is one of the world's largest copper ore mining regions. Gas-induced geodynamic events are dependent on the co-occurrence of two factors: rock porosity, and the presence of gas under significant pressure in the pores and crevices of the rock. This paper presents a condensed energy balance for the phenomenon of outbursts of dolomites and gases. The quantity of energy depends on the type of transformation taking place during decompression. The work produced enables first the disintegration of the rock, and then its transportation along the mine working space. This paper has focused on the estimation of the energy required to disintegrate the rock. It has been estimated that 0.38 MJ is needed for the size reduction of 1 m3 of ejected mass. Highlights: In the case of a dolomite outburst, the energy is accumulated primarily in the form of compressed gas present in the porous structure of the rock and causes the rock to disintegrate and its transport along the mine working space. Gas decompression during a gas-induced geodynamic phenomena can be between isothermal and adiabatic. Existing disintegration theories: Rittinger's, Kick's and Bond's are based consists chiefly of crushing, compression or abrasion, caused by the action of external factors. Author's theory of disintegration of research on tensile stress and is based on Brazilian tests. The disintegration of 1 m3 of rock requires the production of energy of approximately 0.38 MJ. [ABSTRACT FROM AUTHOR]

Lower Cretaceous carbonates of the Fahliyan Formation form prolific reservoir rocks at oilfields in the Dezful Embayment, central Zagros fold‐thrust belt, SW Iran. The carbonates have undergone significant diagenetic alteration in phases which can in general be linked to the pre‐, syn‐ and post‐tectonic evolution of the fold‐thrust belt. This paper investigates the impact of diagenetic processes on the reservoir quality of the carbonates using integrated petrographic, geochemical and sedimentological analyses of subsurface and outcrop samples of the formation. Diagenetic alterations include: (i) pre‐tectonic eogenesis in the marine and shallow‐burial realm, which resulted in micritization of allochems and cementation by equant and isopachous calcite rims and framboidal pyrite together with limited dolomitization and dissolution of metastable bioclasts. The isotopic compositions of micrite and early calcite cement depart from postulated values of Lower Cretaceous marine carbonates, signifying early stabilization of precursor metastable carbonate minerals and the possible effects of the incursion of meteoric waters and/or increasing burial temperatures; (ii) mesogenesis during the subsequent syn‐tectonic phase, which included Late Cretaceous ophiolite obduction at the northern margin of the Arabian Plate and the later Zagros orogeny in the Miocene‐Pliocene. Diagenetic modifications included the emplacement of hydrocarbons, the development of stylolites and fractures, and the precipitation of saddle dolomite, replacive rhombic dolomite, discrete pyrite, microcrystalline quartz, kaolin and anhydrite. The average stable isotope compositions of saddle dolomite (δ18O: ‐6.9 ‰ ±.9 and δ13C 0.5 ‰ ± 1.6, respectively) also reflects the influence of high temprature basinal fluids; and (iii) "late" (telogenetic, post‐tectonic) uplift‐related modification starting in the Pliocene, when the incursion of meteoric waters resulted in the formation of vugs, the calcitization of dolomite, and cementation by fracture‐filling blocky calcite. The negative δ18O and δ13C stable isotope values (average: ‐5.5 ‰ ± 1.5; and ‐3.6 ‰ ± 5.9, respectively) of late blocky calcite cement suggest the incursion of meteoric water into the system. This study demonstrates that diagenetic processes in carbonates in the Fahliyan Formation, which exerted a significant control on the distribution of secondary porosity, can be related to the tectonic evolution of the central Zagros fold‐thrust belt. Thus, constraining the diagenetic history of carbonate successions within the context of their wider tectonic evolution is important for the prediction of the spatial and temporal distribution of reservoir quality. [ABSTRACT FROM AUTHOR]

Crushed dolomite stone can be used as a part of concrete for hot weather. Fine dolomite as a filler is not commonly included in Portland cement. In this paper, the properties of a blended binder based on Portland cement and dolomite filler are presented. Dolomite filler was obtained from dust grains by mechanical activation in a laboratory ball mill to increase the specific surface area and its chemical activity. It is shown that the impact of mechanical activation allows to obtain dolomite filler with a median particle size of 1.4 μm and a specific surface area of 639.9 m2/kg. The content of dolomite filler in Portland cement was 10, 30 and 50%. The main properties of blended cements, i.e., the standard consistency, setting time, compressive strength, average density, and drying shrinkage, were determined on pastes. The mineralogical composition of the hydrated pastes was determined by XRD at 28 days. The presence of dolomite filler at levels higher than 10% decreases the compressive strength of blended cements. The dolomite filler decreases the water demand, shortens the setting time, and mitigates the development of drying shrinkage in the blended binder. To prevent concrete cracking, the application of dolomite filler in blended cement is relevant in hot weather due to its reduced drying shrinkage. [ABSTRACT FROM AUTHOR]

This work describes a procedure for building a high-quality 3D model of a rocky pinnacle in the Dolomites, Italy, using Structure from Motion (SfM) techniques. The pinnacle, known as "Campanile di Val Montanaia", is challenging to survey due to its high elevation and sub-vertical cliffs. The construction of the 3D model is the first step in a multi-disciplinary approach to characterize the rock mass and understand its behavior and evolution. This paper discusses the surveying operations, which involved climbing the pinnacle to collect Ground Control Points (GCPs) and using a UAV to capture aerial imagery. The photographs were processed using SfM software to generate point clouds, mesh, and texture, which were then used for rock mass discontinuity mapping. The study compares models of different qualities and point densities to determine the optimal trade-off between processing time and accuracy in terms of discontinuity mapping. The results show that higher quality models allow for more detailed mapping of discontinuities, with some drawbacks due to noise in the case of the densest solution (e.g., increase in frequency of outliers across the point cloud). These pros and cons are also discussed in relation to the computational cost necessary to build the models. The study also examines the limitations and challenges of performing discontinuity mapping in the different models, including subjectivity in interpretation. A further element of interest is the publication of a high-quality 3D georeferenced model of the "Campanile di Val Montanaia" to be used for several potential further applications, such as stability analyses and numerical modeling. [ABSTRACT FROM AUTHOR]

During weathering and pedogenesis of carbonate rock with poor-uranium (U) and thorium (Th), U and Th present the characteristics of strong leaching (especially U) and significant residual enrichment, the cause of which is still unclear. In this paper, a weathering profile developed by dolomite in karst area of Guizhou province in southwest China was selected, which showed zonation characteristics of bedrock (Y), powdery rock (Yf), and soil layer (T1 to T12) from the bottom to up. Through the determination of the occurrence speciation of U and Th in Y and weathering profile, combined with mineralogical, geochemical characteristics, and element mass balance calculation, the constraints of U and Th speciation on the geochemical behavior of U and Th during the weathering of carbonate rock were revealed. The results proved that U and Th in Y preferentially existed in acid insoluble phase, for example, the contents of U and Th in Y were 0.90 mg·kg−1 and 0.28 mg·kg−1, respectively, while those in acid insoluble matter were 2.34 mg·kg−1 and 2.57 mg·kg−1, respectively, but because the mass percentage of acid insoluble matter was extremely low (0.95%), the mass percentages of U and Th in the acid soluble phase in the whole rock were absolutely superior (96% of U and 86% Th). The U and Th in the acid soluble phase of Y were mainly adsorbed on the crystal surface of carbonate minerals or existed in the cement, and the U and Th in the carbonate lattice only accounted for a small proportion. From Y to Yf with the initial dissolution, U and Th released from the surface of carbonate minerals and cements were in carbonate-rich alkaline environment, and these portions of U and Th were leached out, resulting in strong loss of U and Th in the Yf (the loss rates are 83% of U and 65% of Th, respectively). From the Yf to the overlying soil layer T1, the carbonate components were completely dissolved, and the U and Th released from the carbonate lattice showed different behaviors, where U was completely leached and Th tended to stay in the weathered residue. Thus, in the soil layer T1 formed by Y or Yf , the residual U was the inheritance of the U in the acid insoluble phase of Y; For Th, it not only inherited the Th of acid insoluble phase of Y, but also superimposed the Th from carbonate lattice in Y. On the other hand, during the evolution process from Y to Yf and to soil layer T1, with the dissolution of carbonate, the acid insoluble phase also showed a significant tendency of chemical weathering. However, the U and Th in the Y acid insoluble phase were not leached with the decomposition of the acid insoluble phase but were redistributed among the residual phases. For the geochemical behaviors of U and Th in the evolution of soil profile (T1~T12), they were subjected to the occurrence speciation of U and Th in T1 and the change of U and Th occurrence speciation with the upward direction of soil profile. The U and Th released from the carrier minerals were mainly redistributed among the residual solid phases, which weakened the intensity of their further loss. This study deepens the understanding of the geochemical behavior of radionuclides in karst environment and provides reference for the treatment of radioactive pollution in karst areas. [ABSTRACT FROM AUTHOR]

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Copyright of Natural Gas Industry is the property of Natural Gas Industry Journal Agency and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

Copyright of Natural Gas Industry is the property of Natural Gas Industry Journal Agency and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

Copyright of Iraqi Journal of Chemical & Petroleum Engineering is the property of Republic of Iraq Ministry of Higher Education & Scientific Research (MOHESR) and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

The Guizhou Province is located in karst mountainous area, so it is very important for the future layout and planning of the city to study the underground geological structure of the city based on seismic detection technology. In this paper, taking the underground active fault detection in the Liupanshui City, Guizhou Province, China as an example, a set of appropriate evaluation techniques for the accurate spatial location, structural characteristics and latest activities of the fault suit for mountainous area are proposed. Through pre-stack noise suppression, amplitude fidelity and consistency processing, and multiple iterative analysis of velocity residual statics, the resolution of the geological structure of the underground rock has been significantly improved. Based on the detailed interpretation of the shallow seismic data and the regional geological analysis, it is concluded that the main fault strike of the Weining – Shuicheng section of the Weining - Shuicheng fault is NW, mainly normal fault, the dip direction is mainly southwest, partly northeast and the dip angle is 60-70°. The strata of the two fault plates are strongly compressed and broken, and the limestone and dolomite are generally recrystallized, and calcite veins and masses can be seen. [ABSTRACT FROM AUTHOR]

Sandy dolomite, being a soluble rock, is prone to dissolution and erosion caused by groundwater, leading to the formation of underground caves and fractures. This may result in geological disasters such as ground subsidence and collapse. In this paper, the changes and mechanical properties of black sandy dolomite after hydrochemistry are studied. A semi-immersion test with different concentrations of iron sulfate solution was carried out to simulate the water-rock interaction in different water environments. After that, scanning electron microscope (SEM) results could reflect the dissolution and pore development of rock by the effect of water-rock interaction from the microscopic. Water-rock interaction enlarges cracks in rocks and dissolves pyrite, carbonate minerals, and other components, reducing the cementation between particles. The change in the mechanical properties of black sandy dolomite under water-rock chemical interaction was revealed by uniaxial compression test. The mechanical properties of the samples exhibit varying degrees of deterioration, with strain increased ranging from 4.96 to 29.58%. The brittleness index modified (BIM) values for each sample ranged from 5.20 to 6.20%, all of which are larger than 4.70% in the natural state. [ABSTRACT FROM AUTHOR]