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In this study, the simultaneous atmospheric circulation system configuration characteristics of the four rainfall patterns (FRP) over the East China during the period 1951–2015 are analyzed in order to investigate their formation mechanisms. The results confirm that the FRP possess obvious differences in the upper-level, middle-level, and lower-level troposphere. In northern China rainfall pattern (NCP) years, the East Asian subtropical westerly jet stream (EAJS) shows a northward trend, with a higher intensity than normal; the blocking high (BH) in the mid-high latitudes is inactive; and the western Pacific subtropical high (WPSH) tends to be stronger, with a location to the north of its normal position. The East Asian summer monsoon (EASM) is stronger, which promotes vapor transport to northern China, and this leads to increased rainfall. In intermediate rainfall pattern (IRP) years, the EAJS position is close to that in normal years; the BH is inactive; the WPSH tends to be weaker, with a location to the east of its normal position; and the EASM is stronger, which is conducive to increased rainfall over the Huaihe River Basin. In Yangtze River rainfall pattern (YRP) years, the circulations are found to be almost opposite in their features to those in NCP years. In South China rainfall pattern (SCP) years, the circulations are found to be almost opposite in their features to those in IRP years. This leads to increased rainfall over South China. Therefore, the different circulation system configuration characteristics lead to the different rainfall patterns. [ABSTRACT FROM AUTHOR]

Transition metal doped WO 3 mixed oxides (named as W-M-O, M = Nb, Fe, Cr, Cu, Ti or Sn, respectively) with high structure stability were synthesized by modified sol-gel method using citric acid as organic crosslinking agent, and were evaluated for catalytic elimination of low-concentration toluene, monochlorobenzene and 1,2-dichloroethance with high toxicity and relatively stable molecule structure, as the typical examples for the pollutants of various volatile organic compounds (VOCs). Results of the structure-property-performance relationship research showed that mesoporous structure and nanocrystalline/amorphous state were formed, and binary metal components were dispersed into each other, which contributed to promoting the metal/metal electron interaction and adjusting the physicochemical properties of mixed metal oxides. The sequence of apparent catalytic activity for toluene degradation was: W-Nb-O＞W-Fe-O＞W-Cr-O, W-Cu-O＞W-Ti-O＞W-Sn-O＞WO 3 , and the sequence for monochlorobenzene degradation was: W-Nb-O＞W-Fe-O＞W-Cr-O, W-Ti-O＞W-Cu-O＞W-Sn-O＞WO 3 . There existed cooperative catalytic effect: mesopore and surface acid sites of catalysts facilitated adsorption, activation and breakage of the C-X bond, and then redox sites of catalysts promoted deep oxidation of a series of reaction intermediates to transform into CO 2 and H 2 O. Especially, the optimized W-Nb-O catalyst deserved more attention, since it represented remarkable catalytic activity, selectivity and durability for three typical VOCs degradation along with good resistance to water vapor and corrosion of HCl., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)