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This investigation presents a new approach for evaluating soil organic carbon (SOC) content in farming soils using a photocatalytic chemical oxygen demand (PeCOD) analyzer combined with geographic information system (GIS) technology for spatial analysis. Soil samples were collected at various sites throughout Canada and were analyzed using sieve analysis, followed by further SOC evaluation using three distinct techniques: loss on ignition (LOI), Walkley-Black, and PeCOD. The PeCOD system, which relies on the photochemical oxidation of organic carbon, showed an exciting correlation between its evaluations and SOC content, making it a prompt and reliable method to evaluate SOC. In this investigation, finer materials such as clayey soils (soil fractions of (<50 µm)) demonstrated high SOC content compared to coarser ones (soil fractions of (>75 µm)) and decreased SOC content with increased soil depth, generally below the 30 cm mark. It should be noted that this investigation revealed that other variables, such as land management practices, precipitation, and atmospheric temperature, have drastic effects on the formation and residence time of SOC. GIS georeferencing еnablеd mapping of the SOC distribution and identification of hotspot areas with high SOC content. The results of this study have implications for sustainable farming, climate change mitigation, and soil health operations by providing farmers with schemes that amplify carbon sequestration while simultaneously improving soil health. [ABSTRACT FROM AUTHOR]

• Soil acidification rates and dissolved organic C fluxes were quantified on permafrost. • Fluxes of dissolved organic C were higher in clayey soils with shallow active layer. • Nitrate-N fluxes were higher at lower slope position even in arctic soils. • Cation uptake by lichen and moss as well as higher plants leads to soil acidification. • Climate warming has potential to increase active layer thickness and soil acidification. Climate warming is predicted to change the fluxes of dissolved organic matter and nitrate by increasing active layer thickness, plant productivity, and organic matter decomposition. These changes are hypothesized to increase mineral weathering and soil acidification rates. We investigated whether acidification rates and solute leaching fluxes are variable between permafrost-affected soils with different active layer thicknesses. We compared the fluxes of dissolved organic carbon (DOC) and total dissolved N and the ion fluxes associated with solute leaching and plant uptake to calculate proton budgets in the soils that differed in slope positions (upper slope and lower slope) and soil texture (clayey and sandy soils) in NW Canada. We found the wide variation in DOC and nitrate-N fluxes, depending on slope positions and soil texture. The nitrate-N fluxes were higher at the lower slope position of the sandy soil, compared to the upper slope position. Compared to sandy soils, the DOC fluxes from the organic horizons were higher in the clayey soils on shallower permafrost table. Organic acids were major proton sources in the organic horizons at all sites, but acidity was also contributed by nitrate (sandy and clayey soils at lower slope position) and carbonic acid (clayey soil at upper slope position). The weathering by carbonic acid lead to accumulation of short-range-order minerals in the clayey soils, while incipient podzolization of the sandy soils included the weathering of illite to vermiculite and the dissolution of short-range-order minerals. The shallower active layer thickness at the lower slope position resulted in lower plant productivity and acidification rates. In the permafrost-affected soils, the active layer thickness, the DOC and nitrate-N fluxes, and their contribution to acidification are dependent on the local variation in slope position and soil texture, as well as climate change. [ABSTRACT FROM AUTHOR]

Knowledge is lacking on the factors controlling the structure and spatial distribution of earthworm communities within agroecosystems. We first hypothesized that forested riparian buffer strips (FRBS) within agricultural landscapes would be a refuge for earthworms, as we predicted higher soil moisture and organic matter inputs in FRBS than in adjacent agricultural fields (treatments = FRBS vs. Field). We further hypothesized that earthworms would be most abundant where the chemical quality of above- and belowground plant litter is high, or where soil disturbance is low. We conducted a field survey to quantify earthworm species abundances in FRBS and adjacent agricultural fields in two bioregions, namely Eastern Canada and Central Europe. At each of 77 sites, we collected and identified earthworms from three plots within FRBS and within adjacent agricultural fields. In each plot, we identified the tree species, understory vegetation, soil drainage class, agricultural crop as well as five soil physicochemical properties. In each bioregion and treatment, we found proportionately more endogeic than anecic or epigeic earthworm species. In Eastern Canada, there were proportionately fewer anecic and more epigeic individuals in FRBS than in fields; in Central Europe there were fewer endogeic and more anecic earthworms in FRBS than in fields. We found significant bioregion × treatment interactions on earthworm abundance and soil moisture. More specifically, in Eastern Canada we found higher earthworm abundance and soil moisture in FRBS, whereas in Central Europe we found higher earthworm abundance in fields and no treatment effect on soil moisture. In both bioregions, we found higher organic matter in FRBS than in fields. In Eastern Canada, earthworm abundance in deciduous and mixedwood stands were higher than in coniferous stands; in Central Europe, earthworm abundance was highest in deciduous stands only. Within FRBS in Eastern Canada, the abundance of the prominent endogeic species, Apporectodea rosea , was correlated with herbaceous plants, notably ferns and graminoids. Conditional regression tree analysis revealed positive relationships between earthworms and soil clay content, pH, moisture and organic matter. Our results suggest that local and landscape patterns in earthworm diversity can be predicted by soil and vegetation attributes, however the relative importance of these factors changes across continental scales due to differences in precipitation patterns and soil moisture availability. Comparing the distributions of earthworms across different scales provides insights into the potential of different species to spread into new habitats with climate change. • In Canada, earthworms were more abundant in forested riparian strips than in fields • In Central Europe, the opposite pattern was observed • Differences across continents were ascribed to precipitation patterns • Earthworms were more abundant under deciduous tree canopies • Endogeic species were more abundant with herbaceous plants [ABSTRACT FROM AUTHOR]

While it is generally understood that conservation tillage in heavy soils under a cool, wet climate increases N2O fluxes compared with inversion tillage, the interaction between tillage and manure type on soil N2O fluxes in different textured soils is not well understood. To investigate how long-term applications of different manures interact with tillage effects on N2O fluxes, we established a long-term trial in 2009 in eastern Canada, using two tillage (conventional: inversion at 25 cm in autumn; conservation: harrow at 5 cm in spring) and three fertilizer types (liquid swine manure, liquid dairy manure and a 0-N control) arranged in a split-plot design with 3 replications. The experiment is reproduced on two contrasting soil textures (silty clay and sandy loam) located approximately 800m apart in a wheat-maize-soybean rotation. During 2016 (wheat – Triticum aestivum), 2017 (maize – Zea mays) and 2018 (soybean – Glycine max), we measured the N2O fluxes from each plot using standard non-flow through, non-steady state, manual chambers for the snow-free period (1 April through 30 November). Cumulative fluxes for the snow free periods ranged from 0.4 kg N2O-N ha-1 for the inversion tillage on the sandy loam soil during the third year when soybean was grown without fertilizer, to 7.6 kg N2O-N ha-1 for the cattle manure/conservation tillage on the silty clay soil. Conservation tillage increased soil N2O fluxes for both manure types and the 0-N control in the clay soil (mean flux for all fertilizer treatments over all three seasons were 4.7 and 2.3 kg N2O-N ha-1 season-1 for the conservation and inversion tillage, respectively); while on the sandy loam the N2O flux was similar between the conservation and inversion tillage systems (mean flux for all fertilizer treatments over both seasons were 1.1 kg N2O-N ha-1 season-1 for both the conservation and inversion tillage). Considering that soil organic C may not increase in fine-textured soils under conservation tillage in temperate, humid areas such as eastern Canada, our findings suggest that conservation tillage in fine-textured soils in the region may lead to a net decrease in the GHG balance. [ABSTRACT FROM AUTHOR]