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Based on the comparison of zircon ages with source terranes, they inferred that the likely source for Cenozoic zircon grains was the Eastern Alkaline Province of Mexico, which comprises various volcanic fields of Cenozoic age. Armstrong-Altrin et al. (2021) reported the detrital zircon grain surface features, chemistry, and U-Pb ages in the Chachalacas beach sediments, Gulf of Mexico. Armstrong-Altrin et al. (2020) discussed the U-Pb ages of detrital zircon grains, which we reported from the Chachalacas beach in the western Gulf of Mexico. [Extracted from the article]

We thank Patil Pillai et al. for preparing a critique on our article (Joy et al., 2018). Patil Pillai et al. contest the analytical procedure utilized for the carbonates and "geological information" documented in our research article and raise concerns on our conclusions. We hereby provide our reply to each of their comments. [ABSTRACT FROM AUTHOR]

The Klamath Mountains Province of Northern California and southern Oregon, USA, consists of generally east-dipping terranes assembled via Paleozoic to Mesozoic subduction along the western margin of North America. The Klamath Mountains Province more than doubled in mass from Middle Jurassic to Early Cretaceous time, due to alternating episodes of extension (e.g., rifting and formation of the Josephine ophiolite) and shortening (e.g., Siskiyou and Nevadan events). However, the tectonic mechanisms driving this profound Mesozoic growth of the Klamath Mountains Province are poorly understood. In this paper, we show that formation of the Condrey Mountain schist (CMS) of the central Klamath Mountains Province spanned this critical time period and use the archive contained within the CMS as a key to deciphering the Mesozoic tectonics of the Klamath Mountains Province. Igneous samples from the outer CMS subunit yield U-Pb zircon ages of ca. 175–170 Ma, which reflect volcanic protolith eruptive timing. One detrital sample from the same subunit contains abundant (~54% of zircon grains analyzed) Middle Jurassic ages with Paleozoic and Proterozoic grains comprising the remainder and yields a maximum depositional age (MDA) of ca. 170 Ma. These ages, in the context of lithologic and thermochronologic relations, suggest that outer CMS protoliths accumulated in an outboard rift basin and subsequently underthrust the Klamath Mountains Province during the Late Jurassic Nevadan orogeny. Five samples of the chiefly metasedimentary inner CMS yield MDAs ranging from 160 Ma to 130 Ma, with younger ages corresponding to deeper structural levels. Such inverted age zonation is common in subduction complexes and, considering existing K-Ar ages, suggests that the inner CMS was assembled by progressive underplating over a >10 m.y. timespan. Despite this age zonation, age spectra derived from structurally shallow and deep portions of the inner CMS closely overlap those derived from the oldest section of the Franciscan subduction complex (South Fork Mountain schist). These relations suggest that the inner CMS is a composite of South Fork Mountain schist slices that were sequentially underplated beneath the Klamath Mountains Province. The age, inboard position, and structural position (i.e., the CMS resides directly beneath Jurassic arc assemblages with no intervening mantle) of the CMS suggest that these rocks were emplaced during one or more previously unrecognized episodes of shallow-angle subduction restricted to the Klamath Mountains Province. Furthermore, emplacement of the deepest portions of the CMS corresponds with the ca. 136 Ma termination of magmatism in the Klamath Mountains Province, which we relate to the disruption of asthenospheric flow during slab shallowing. The timing of shallow-angle subduction shortly precedes that of the westward translation of the Klamath Mountains Province relative to correlative rocks in the northern Sierra Nevada Range, which suggests that subduction dynamics were responsible for relocating the Klamath Mountains Province from the arc to the forearc. In aggregate, the above relations require at least three distinct phases of extension and/or rifting, each followed by an episode of shallow-angle underthrusting. The dynamic upper-plate deformation envisioned here is best interpreted in the context of tectonic switching, whereby slab steepening and trench retreat alternate with slab shallowing due to recurrent subduction of buoyant oceanic features [ABSTRACT FROM AUTHOR]

The paper presents new isotopic U–Pb data (LA-ICP-MS method) of zircon from the main types of intrusive rocks at the Kuru-Tegerek gold-copper-molybdenum skarn deposit situated in the Chatkal segment of the Middle Tien Shan. This and other gold, copper, tungsten and molybdenum deposits are parts of the extended Late Paleozoic metallogenic belt of Tien Shan. The concordant isotopic U–Pb values obtained for zircon autocrysts from the rocks of sequential intrusive phases span over the interval from approximately 323 to 311 Ma. This interval comprises the crystallization of gabbro-diorite (from 323.5 ± 2.5 Ma to 323.2 ± 6.8 Ma) and tonalite (from 321.4 ± 3.8 Ma to 311 ± 3.8 Ma). The age dates obtained for these zircon autocrysts correspond to the emplacement of these moderate-potassic intrusions in the Late Carboniferous and are almost coincident with the isotopic dates previously known for the high-potassic intrusions of the porphyry Cu–Au–Mo deposits of the Almalyk mineralized cluster (Kurama segment of the Middle Tien Shan), which were also emplaced in the Late Carboniferous (about 330–310 Ma). This corresponds to the subduction tectonic regime occurred in this region in relation to the steep-dipping (in the Kurama segment) or flat (in the Chatkal segment) subduction of a tectonic plate toward the north, under the structures of the Kazakhstan–North Tien Shan continental massif and accreted segments of the Middle Tien Shan. The intrusive rocks studied at the Kuru-Tegerek deposit contain also zircon xenocrysts (including these in the core of complex crystals) with the isotopic U–Pb age of some 1.9–2.1 Ga. These dates are in agreement with the age of metamorphic rocks in the Tarim craton basement and indicate the presence of the ancient continental crust in this segment of the Middle Tien Shan. [ABSTRACT FROM AUTHOR]

Comprehensive U-Pb detrital zircon geochronology of Ediacaran sandstones from Oman indicates that they originated from Neoproterozoic basement with a peak magmatic age of ca. 850-780 Ma (Tonian), with lesser Paleoproterozoic and Ediacaran sources and renewed magmatic input starting at ca. 550 Ma. Comparison with detrital zircons from the Arabian-Nubian and NW Indian Shields supports an eastern Gondwana affinity for the Ediacaran succession of Oman. Tonian basement sediment sources are present in Oman. Sources for older Paleoproterozoic zircons (ca. 2500 and 1800 Ma) are not found in Oman but are known from the cratonic Indian Shield. The signal of the main magmatic events of the juvenile Arabian-Nubian Shield, peaking at ca. 640-620 Ma, is rare or absent in the Ediacaran rock succession of Oman. However, deformed Ediacaran clastic units with an Arabian-Nubian Shield affinity occur in western Oman. Influx of latest Ediacaran-early Cambrian zircons (550-525 Ma) is interpreted as due to final Cambrian Angudan/Malagasy orogeny-related magmatism. These results, together with new ages for volcano-sedimentary terranes in the subsurface of SW Oman and seismic observations, support the interpretation that the Ediacaran succession of Oman was deposited along the western, passive margin of the Greater Indian Shield, on the eastern (east and west in this paper refer to present-day coordinates) side of the Mozambique Ocean. Oman then collided with the Arabian-Nubian Shield in the early Cambrian, when the Angudan/Malagasy orogeny led to final consolidation of Gondwana. Our data support the inference that the youngest and final suture between the Indian and Arabian Shields lies in the subsurface of Oman along the early Cambrian western deformation front. [ABSTRACT FROM AUTHOR]

How and when sedimentary rocks record Earth's magnetic field is complex. Most studies assume a time‐progressive lock‐in mechanism during sediment deposition called depositional remanent magnetization (DRM). However, magnetic minerals can also form in situ, recording a chemical remanent magnetization (CRM) that is discontinuous in time. Disentangling the two mechanisms represents a major hurdle, and differences in their recording efficiencies remain unexplored. Here, our theoretical solutions demonstrate that CRM intensities exceed DRM by a factor of six when acquired in the same magnetic field. Novel experiments growing greigite (Fe3S4) in sediments and subsequent redeposition under identical magnetic field conditions confirm the predicted difference in recording efficiency. Thus, if left unrecognized, CRM leads to overestimated paleointensity and deserves more attention when interpreting Earth's magnetic history from sedimentary records. Recognition of fundamental differences between CRM and DRM characteristics provide a way forward to distinguish the recording mechanisms through routine laboratory protocols. Plain Language Summary: Remanent magnetizations preserved in sedimentary rocks serve as a continuous record of Earth's magnetic field history and play a fundamental role in understanding the Earth system. It is commonly assumed that magnetic minerals align with the magnetic field as a particle settles through the water column, known as a depositional remanent magnetization (DRM). However, diagenesis can lead to chemical growth of magnetic minerals, known as a chemical remanent magnetization (CRM). CRM lacks stratigraphic continuity and can obscure or completely overprint the original magnetization any time after sediment deposition, leading to a magnetic record that is uncorrelated with the age of the rock. Yet, CRMs go largely unrecognized. Theory and experiments in our paper document that CRMs record the magnetic field six times more efficiently than DRMs. Our work provides a way to distinguish the two through routine laboratory protocols. Key Points: Recording efficiency of chemical remanent magnetization (CRM) is six times higher than depositional remanent magnetization (DRM)Undetected chemical remanences lead to overestimated relative paleointensity estimatesComparison of natural and laboratory magnetization and demagnetization behavior help identify chemical remanent magnetizations in sediments [ABSTRACT FROM AUTHOR]

The North Qinling Orogenic Belt (NQB) records the pivotal geological information for understanding the Palaeozoic evolution of the Qinling Orogenic Belt (QOB). Previous studies mainly focused on the subduction–collision process along the Shangdan suture zone before the Early Devonian. However, as the significant interim period between the Early Palaeozoic and Mesozoic orogeny, the Late Palaeozoic tectonic evolution of the NQB remains poorly understood. Fortunately, the Carboniferous magmatic rocks discovered this time provide substantial geological evidence for revealing the Late Palaeozoic tectonic history of the Qinling Orogenic Belt. This paper will provide a detailed analysis of zircon U–Pb ages, geochemical characteristics and Sr‐Nd‐Hf isotopic compositions of Carboniferous rocks. The Carboniferous magmatic rocks are categorized as highly differentiated S‐type granite and monzodiorite, formed at 350 ± 2.4 Ma and 353 ± 5.2 Ma, respectively. The granite shows weak peraluminous (A/CNK = 1.02–1.11) and shoshonite nature. Based on the isotopic composition and trace element characteristics, we propose that the Qinling Group paragneiss is the primary source of the Carboniferous granite. Monzodiorite is characterized by enriched LREEs and LILEs (Ba, K and Pb), depleted HFSEs (Th, Nb, Ta and Ti) and enriched Sr‐Nd isotopic composition. Monzodiorite magma source region consists of continental crustal material and lithospheric metasomatized mantle. Carboniferous magmatic rocks are the product of an extensional tectonic setting, which indicates the NQB tectonic regimes transition from compression to extension during the Carboniferous. [ABSTRACT FROM AUTHOR]

Shoshonitic rocks are widely distributed in post-collisional settings and provide key information on deep geodynamic mechanisms and magmatic evolution. In this paper, we present petrographic, zircon U-Pb age-related, trace elemental, Hf isotopic, bulk-rock elemental, and Sr-Nd isotopic data of the Dalongtan shoshonitic syenite porphyries (DSSPs) in central Yunnan, southeastern Tibet. The DSSPs formed at 33.2 ± 0.3 Ma in a post-collisional setting. They define linear trends on Harker diagrams, and they display similar trace element patterns and enriched bulk-rock Sr-Nd isotopes [(87Sr/86Sr)i = 0.70964–0.70968, εNd(t) = −12.9 to −12.7] and zircon Hf isotopes (εHf(t) = −15.7 to −13.1) to the coeval mantle-derived potassic mafic rocks. This suggests that the DSSPs were fractionated from the lithospheric mantle-derived mafic magmas. The DSSPs, along with the coeval felsic and mafic magmatic rocks (37.2–32.3 Ma), exhibit a planar distribution on the SE Tibet and predate the left-lateral shearing of the Ailaoshan–Red River shear zone (ARSZ) (32–22 Ma), suggesting that there are no genetic relationships between them. The DSSPs have geochemical characteristics similar to those of A-type granites, with high total alkalinity (10.39–11.17 wt.%), HFSE concentrations (Zr + Nb + Ce + Y = 890.2–1054.3 ppm), Ga/Al ratios (10,000 × Ga/Al = 2.95–3.46), whole-rock zircon saturation temperatures (906–947 °C), and oxygen fugacity (ΔFMQ = +3.30–+4.65), indicating that they are products of the high-temperature melting of the lithosphere as a result of asthenosphere upwelling in extensional settings. Based on our data and regional observations, it is proposed that the generation of the DSSPs may be linked to the convective thinning of the thickened lithospheric mantle following the India–Asia collision. [ABSTRACT FROM AUTHOR]

To assess whether life existed on Mars, it is crucial to identify geochemical biosignatures that are relevant to specific Martian environments. In this paper, thermochemical modeling was used to investigate fluid chemistries and secondary minerals that would have evolved biotically over geological time scales in Martian fluvio‐lacustrine and evaporitic settings, and that could be used as potential inorganic biosignatures for life detection on Mars. Modeling was performed using fluid and rock chemistries relevant to Gale crater aqueous environments. Potential inorganic biosignatures were identified investigating alteration deposits found at the surface of a simulant exposed to short‐term bio‐mediated weathering and comparing experimental and modeling results. In a fluvio‐lacustrine setting (water/rock of 2000–278), models suggest that less complex mineral assemblages form during biotic basalt dissolution and subsequent brine evaporation compared to what would happen in an abiotic system. Mainly nontronite, kaolinite, and quartz form under biotic conditions, whereas celadonite, talc, and goethite would also precipitate abiotically. Quartz, sepiolite, and gypsum would precipitate from the evaporation of fluids evolved biotically, whereas nontronite, talc, zeolite, and gypsum would form in an abiotic evaporitic environment. These results could be used to distinguish products of abiotic and biotic processes, aiding the interpretation of data from Mars exploration missions. [ABSTRACT FROM AUTHOR]

Accurately determining the timing and mechanism of metallogenesis of ore deposits is essential for developing a robust genetic model for their exploration. In this paper, we analyze the formation conditions of cassiterite in five major deposits of southern Hunan Province, one of the most important tungsten-tin (W-Sn) provinces in South China, using a combination of cathodoluminescence imaging, in situ U-Pb geochronology, and trace-element concentration data. In situ cassiterite U-Pb geochronology constrains the main period of Sn mineralization to between 155.4 and 142.0 Ma, demonstrating a temporal and genetic relationship to silicic intrusive magmatism in the same area. Three stages of magmatic activity and metallogenic evolution are recognized: (1) Early Paleozoic and Triassic: the initial enrichment stage of tungsten and tin; (2) Jurassic: the metasomatic mineralization stage; and (3) Cretaceous: the magmatic-hydrothermal superposition stage. The cassiterite in these deposits takes four forms, i.e., quartz vein-type, greisen-skarn-type, greisen-type, and granite-type, representing a progression characterized by the increasing content and decreasing range of variation of high field strength elements (HFSEs), and reflecting a general increase in the degree of evolution of the associated granites. Rare earth element (REE) concentrations suggest that precipitation of cassiterite was insensitive to the redox state of the fluid and that precipitation of cassiterite in the southern Hunan Sn deposits did not require a high-fO2 environment. These findings provide new insights into tin mineralization processes and exploration strategies. [ABSTRACT FROM AUTHOR]

This paper presents new zircon U–Pb–Hf isotopic and whole‐rock geochemical data for early Paleozoic–early Mesozoic igneous rocks from the Zhangguangcai Range, which are used to provide constraints on the petrogenesis and tectonic setting of these rocks and on the tectonic evolution of the eastern Songnen Massif. We dated five igneous rocks from the Zhangguangcai Range of the eastern Songnen Massif, namely, a late Cambrian (~489 Ma) syenogranite, a middle Silurian (~431 Ma) dacite, a Middle Triassic (~247 Ma) gabbro‐diorite and two Late Triassic (214–210 Ma) rhyolites. The late Cambrian syenogranite, middle Silurian dacite and Late Triassic rhyolites have high SiO2 and (Na2O + K2O) contents and low Mg# values. These four rocks are enriched in light rare earth elements (LREEs) and large‐ion lithophile elements (LILEs) but depleted in heavy REEs (HREEs) and high‐field‐strength elements (HFSEs). In addition, the εHf(t) values and TDM2 ages of zircons from these rocks range from −1.31 to +5.88 and from 1264 to 896 Ma, respectively. These data suggest that their primary magma was derived from partial melting of the juvenile mafic lower crust that was generated during the Mesoproterozoic–Neoproterozoic. The Middle Triassic gabbro‐diorite has low SiO2 and high MgO, Sc, Co, Cr and Ni contents and is enriched in LILEs and LREEs but depleted in HREEs and HFSEs such as Nb and Ta. Combining these features with the zircon εHf(t) values of the gabbro‐diorite, which range from +0.02 to +1.79, the primary magma of this rock is inferred to have been derived from partial melting of an isotopically depleted lithospheric mantle. The late Cambrian syenogranites and the middle Silurian dacites are weakly peraluminous and are classified as medium‐ to high‐K calc‐alkaline series, indicating that they formed in an active‐continental‐margin setting. The Middle–Late Triassic igneous rocks exhibit a bimodal igneous rock association, suggesting that they formed within an extensional environment. Combining our new results with previous findings, the early Paleozoic–early Mesozoic tectonic evolution of the eastern Songnen Massif is revealed. During the early Cambrian–early Silurian, the oceanic plate between the southern Songnen and southern Jiamusi massifs subducted westward beneath the Songnen Massif. The amalgamation between the southern Songnen and southern Jiamusi massifs occurred during the middle Silurian, and the southeastern Songnen Massif was in a post‐collisional extensional setting during the Devonian. During the late Carboniferous–Triassic, the Zhangguangcai Range was in an extensional environment, and the Mudanjiang Ocean started to open along the Jiayin–Mudanjiang Fault, separating the Songnen and Jiamusi massifs during the Middle–Late Triassic. [ABSTRACT FROM AUTHOR]

The gabbro-dioritoid rocks from Veľké Železné (Nízke Tatry Mts., Western Carpathians, Slovakia) were recently studied in order to better understand the age, origin, and evolution of the basic/intermediate magmas associated with Variscan granitic rocks. Their genesis was investigated from the points of view of petrology, whole-rock geochemistry (including Sr, Nd, and Pb isotopic characteristics), as well as U-Th-Pb zircon and apatite dating. The Famennian magmatic crystallization age of ca. 360 Ma (determined from zircon: 362.4 ± 2.9 Ma and apatite: 358.4 ± 2.8 Ma) is older than the Tournaisian-Visean ages for granite intrusions in the Tatric Unit. Geochemically, the studied rocks have an affinity to arc-related basalts, consisting of a metaluminous, magnesian, and high-potassium calc-alkaline character. Isotope data (i.e., (87Sr/86Sr)360 = 0.7035-0.7044 and εNd360 = +1.4 to +1.6) demonstrate that these gabbro-dioritoids were formed from the mantle-influenced, lower crustal and/or sub-continental lithospheric mantle (SCLM) sources, whereas the unsystematic increase of Pb isotope ratios indicate either the melting of an ancient Enriched mantle-II (EM-II) reservoir or the upper crustal assimilation and/or local fluid alteration. The data presented in this paper favour the origin of the studied gabbro-dioritoids at a continental arc, although we cannot rule out their genesis as a result of the subsequent slab break-off. [ABSTRACT FROM AUTHOR]

The Kresty volcano–plutonic complex (KVPC) is one of the representatives of the alkaline–ultrabasic magmatism in the Maymecha-Kotuy Alkaline Province in Polar Siberia. The geological structure of the KVPC consists of intrusive formations of olivinite–pyroxenite and melilitolite–monticellitolite bodies, a series of rocks that break through dikes of trachydolerites, syenites, granosyenites, alkaline picrites and lamprophyres. This paper summarizes the results of the authors' long-term research on the geological structure and features of the material composition of the intrusive magmatic rocks, including geochemistry, mineralogy, distribution of rare earth elements (REE), as well as the results of isotope studies. The multielement composition of the KVPC intrusions demonstrates a complex geodynamic paleoenvironment of the formation as plume nature with signs of subduction and collision. For the ultrabasic series with normal alkalinity from the first phase of the KVPC, a Sm-Nd isochron age yielded an Early Triassic (T1) result of 251 ± 25 Ma. Here, we present U-Pb dating of zircons and perovskite of high-calcium intrusive formations and a dyke complex of alkaline syenites. Thus, for the intrusion of kugdite (according to perovskite), the age determination was 249 ± 4 Ma, and for the crosscutting KVPC dykes of syenites (according to zircon) 249 ± 1 Ma and 252 ± 1 Ma. The age of the most recent dike is almost identical to the age of the main intrusive phases of the KVPC (T1), which corresponds to a larger regional event of the Siberian LIP—251 Ma. According to isotopic Sr-Nd parameters, the main source of KVPC magmas is a PREMA-type material. For dyke varieties, we assume there was an interaction of plume melts with the continental crust. The new age results obtained allow us to further constrain the episodes of alkaline–ultrabasic intrusions in Polar Siberia, taking into account the interaction of mantle plume matter and crustal material. [ABSTRACT FROM AUTHOR]

A search has been carried out for Magnetized Quark Nuggets (MQNs) accumulating in iron ore over geologic time. MQNs, which are theoretically consistent with the Standard Models of Physics and of Cosmology, have been suggested as dark-matter candidates. Indirect evidence of MQNs has been previously inferred from observations of magnetars and of non-meteorite impact craters. It is shown in this paper that MQNs can accumulate in taconite (iron ore) and be transferred into ferromagnetic rod-mill liners during processing of the ore. When the liners are recycled to make fresh steel, they are heated to higher than the Curie temperature so that their ferromagnetic properties are destroyed. The MQNs would then be released and fall into the ferromagnetic furnace bottom where they would be trapped. Three such furnace bottoms have been magnetically scanned to search for the magnetic anomalies consistent with trapped MQNs. The observed magnetic anomalies are equivalent to an accumulation rate of ~1 kg of MQNs per 1.2 × 108 kg of taconite ore processed. The results are consistent with MQNs but there could be other, unknown explanations. We propose an experiment and calculations to definitively test the MQN hypothesis for dark matter. [ABSTRACT FROM AUTHOR]

Speleothems are unique archives of information on climate, geomagnetism, and environmental conditions of the past, and have been successfully used for paleoclimatic and paleomagnetic studies in the last two decades. The uniqueness of these geological objects lies in the peculiarities of their formation and preservation of a wide range of geochemical, geological and geophysical proxies, and, most importantly, in the ability to obtain time series of the corresponding characteristics in an unprecedentedly accurate resolution using isotope-geochronological dating methods and incremental chronology. This paper presents the first results of dating the Vor speleothem from the Vorontsovskaya Cave (Krasnodar region), which preserved a record of the geomagnetic excursion, obtained by 230Th/U α-spectrometry, 14C dating, and incremental chronology. Such studies have been carried out in Russia for the first time. Despite the limitations of using the methods of isotope geochronology, it was possible to obtain an upper limit on the age of the excursion, which probably occurred no earlier than 5500–6000 years ago. By the method of incremental chronology, the duration of the main phase of the excursion Vor – 871 ± 16 years – was determined with great accuracy. [ABSTRACT FROM AUTHOR]

The southern Great Xing'an Range is located in the eastern Central Asian Orogenic Belt, where voluminous igneous rocks developed during the Late Mesozoic period. The east slope of the southern Great Xing'an Range has been the topic of numerous debates on the level of influence of the Mongol-Okhotsk and the Paleo-Pacific regimes in the Late Mesozoic period. Therefore, this area is a suitable region in which to study the temporal changes in magma sources and tectono-magmatic evolution. In this paper, whole-rock geochemical data, zircon U-Pb geochronology, and zircon Hf isotope studies were carried out on the granitoids in the east slope area of the southern Great Xing'an Range. LA-ICP-MS zircon U-Pb dating revealed the ages of four granitoid samples: 135.0 ± 0.6 Ma, 130.7 ± 1.4 Ma, 130.4 ± 1.0 Ma, and 127.6 ± 0.8 Ma, respectively. The Hf isotope values 176Hf/177Hf = 0.282751–0.283015, εHf (t) = +2.0~+11.5, and T2DM = 583~1442 Ma suggest that the magma was generated by partial melting of Meso- and Neoproterozoic accreted and thickened low crust. The whole-rock geochemical data implied that these granitoids are A-type granite and their formation is closely linked to the subduction of the Paleo-Pacific Ocean plate. These geochemical, isotopic, and geochronological data suggest that the Early Cretaceous magmatism in the east slope area of the southern Great Xing'an Range formed in an extensional back-arc tectonic setting associated with the slab roll-back of the Paleo-Pacific plate subduction. [ABSTRACT FROM AUTHOR]

Since the start of the 21st century, the widespread application of ion probes has promoted the mass output of highprecision and high-accuracy U‒Th‒Pb geochronology data. Zircon, as a commonly used mineral for U‒Th‒Pb dating, widely exists in the continental crust and records a variety of geological activities. Due to the universality and stability of zircons and the long half-lives of U and Th isotopes, zircon U‒Th‒Pb geochronology can provide nearly continuous records for almost the entire history of Earth and is thus essential to studying the growth and evolution of the continental crust and even Earth system evolution. Here, we present a database of zircon U‒Th‒Pb geochronology that samples the global continental crust and spans nearly all of Earth's history. This database collects ~2,000,000 geochronology records from ~12,000 papers and theses and is by far the largest geochronology database to our knowledge. This paper describes the complied raw data, presents the relationship between dating error and zircon age, compares the error levels of different dating methods, and discusses the impact of sampling bias on data analysis as well as how to evaluate and weaken this impact. In addition, we provide an overview of the temporal and spatial distribution of global zircon ages and provide key insights into the potential research value of zircon ages for Earth system science, such as crustal evolution, supercontinent cycles, plate tectonics, paleoclimate changes, biological extinction, as well as commercial use in mining and energy. Overall, this collection not only provides us with a comprehensive platform with which to study zircon chronological data in deep time and space but also makes it possible to explore the underlying geodynamic mechanisms and evolution of Earth's system and its astronomical environment. [ABSTRACT FROM AUTHOR]

The availability of remote sensing imagery at high spatiotemporal resolutions presents the opportunity to monitor the surface motion of rock glaciers, a key constraint for characterizing the dynamics of their evolution. In this paper, we investigate four North American rock glaciers by automatically measuring their horizontal surface displacement using photogrammetric data acquired with crewed and uncrewed aircraft along with orbital spacecraft over monitoring periods of up to eight years. We estimate vertical surface changes on these rock glaciers with photogrammetrically generated digital elevation models (DEM) and digitized topographic maps. Uncertainty analysis shows that the imagery with the highest resolution and most precise positioning have the best performance when used with the automated change detection algorithm. This investigation produces gridded velocity fields over the entire surface area of each study site, from which we estimate the age of rock glacier formation using along-flow velocity integration. Though the age estimates vary, the ice within the modern extent of these landforms began flowing between 3000 and 7000 years before present, postdating the last glacial maximum. Surface elevation change maps indicate present-day thinning at the lower latitude/higher elevation sites in Wyoming, while the higher latitude/lower elevation sites in Alaska exhibit relatively stable surface elevations. [ABSTRACT FROM AUTHOR]

El Olivo Cave (Pruvia de Arriba, Llanera, Asturias, Spain) is a small karst cave located in the Aboño River basin and formed in the Cretaceous limestone of the Mesozoic cover of the Cantabrian Mountains (north of the Iberian Peninsula). It contains an important upper Pleistocene sedimentary, archaeological, and paleontological record, with abundant technological evidence and faunal remains. The archaeological record shows a first occupation that could correspond to the Middle Paleolithic and a second occupation in the Middle Magdalenian. The stratigraphic sequence inside and outside the cave was studied with geoarchaeological methodology. In this paper, the lithostratigraphic sequence is analyzed, and the data from the granulometric, mineralogical, edaphological, and radiometric analyses are presented. The results of these analyses enable an accurate interpretation of both the lithostratigraphy of the deposit and the processes responsible for its formation and subsequent evolution. The available numerical dates allow us to locate the first sedimentation episode in the cave in OIS 7a, in the Middle Pleistocene, the base of the outer fluvial sedimentation in the cold OIS 3a stage of the Upper Pleistocene and the Magdalenian occupation in the Last Glacial Maximum (OIS 2) at the end of the Late Pleistocene. [ABSTRACT FROM AUTHOR]

Within the Himalayan collisional belt, granites occur along two subparallel belts, namely, the Tethyan Himalayan Sequence (THS) and the Greater Himalayan Crystalline Complex (GHC). In this study, Eocene adakitic rocks and leucogranite are found only in the northern Himalayas, so further research is required to constrain their origin. Here, we present zircon U–Pb and monazite U–Th–Pb ages, Sr–Nd–Pb and Hf isotopes, and whole-rock major and trace elements for Liemai muscovite granite in the eastern Himalayan region. The U–(Th)–Pb results show that Liemai muscovite granite was emplaced at 43 Ma, and that its geochemical characteristics are similar to those of adakitic rocks of the same age (Dala, Quedang, Ridang, etc.). Combined with previous studies, both Eocene adakitic rocks and leucogranite are high-potassium calc-alkaline peraluminous granites. The former is relatively rich in large-ion lithophile elements (LILEs), such as Ba and Sr, and relatively deficient in high-field-strength elements (HFSEs), such as Nb, Ta, Zr, and Y, with weak or no Eu anomalies, and the average light rare earth element (LREE)/heavy rare earth element (HREE) ratio is 17.8. The latter is enriched in LILEs (such as Rb) and U, Ta, and Pb, and depleted in HFSEs (such as Nb and Zr), La, and Nd, with obvious negative Sr, Ba, and Eu anomalies and a mean LREE/HREE ratio of 10.7. The 87Sr/86Sr of the former is in the range of 0.707517–0.725100, εNd (t) ranged from −1.2 to −14.7, the average is −11.6, εHf (t) ranged from −0.5 to −65, the average is −12.2. The average values of (206Pb/204Pb) i, (207Pb/204Pb) i and (208Pb/204Pb) i are 18.788, 15.712 and 39.221, respectively; The 87Sr/86Sr of the latter is in the range of 0.711049~0.720429, εNd (t) ranged from −9.8 to −13.8, the average is −12.3, εHf (t) ranged from −4.2 to −10, the average is −6.7. The isotopic characteristics indicate that adakitic rocks and leucogranites are derived from the ancient lower crust, and both may be derived from metamorphic rocks of the GHC. In this paper, the origin of the two is associated with the transformation of the Himalayan tectonic system during the Eocene, and it is inferred that the deep crust may have altered the tectonic environment (temperature and pressure), resulting in an obvious episodic growth trend of leucogranite and significant development of adakitic rocks from 51 to 40 Ma. From 40 to 35 Ma, the development of Eocene magmatic rocks was hindered, and adakitic rocks disappeared. It is proposed that the genetic difference is related to the transition from high to low angles of the subducting plate in the crustal thickening process. [ABSTRACT FROM AUTHOR]

Detrital single‐grain zircon U–Pb geochronology is a powerful tool for provenance studies if information on the source rocks is available. This paper proposes a new source‐rock classification tool that uses the degree of annealing of radiation damage in detrital zircon; the annealing is expressed by the relationship between the width (full‐width at half‐maximum; FWHM) of the v3[SiO4] Raman band at ~1008 cm−1 and the calculated α‐dose. The host rocks of the zircons are classified into three types according to their emplacement process and/or thermal history: volcanic and rapidly cooled plutonic and high‐grade metamorphic rocks (type 1); rocks with hydrothermal zircons (type 2); slowly cooled igneous and metamorphic rocks (type 3). We construct a naive Bayes prediction model by training it with a collection of zircons of known types. The unknown zircons are assigned a probability of derivation from a specific host‐rock type. This classification scheme is best used as an accessory tool in provenance studies that apply detrital zircon U–Pb geochronology. [ABSTRACT FROM AUTHOR]

This paper reports two types of basalt that have different ages (Carboniferous and Permian) but occur next to each other in the northern part of the Changning–Menglian accretionary wedge, southwestern China. We use the geochronology and geochemical data to evaluate the tectonic evolution of the Palaeo‐Tethys during this period. Zircon grains from the mafic‐ultramafic rocks associated with the Permian basalts in the Xiaomengtai area yield a U–Pb age of 281 Ma and εHf(t) values from +9.2 to +12.8. The Permian mafic‐ultramafic rocks and the associated basalts are all characterized by normal mid‐ocean ridge basalt (N‐MORB)‐like chondrite‐normalized rare earth elements patterns, moderately negative Nb‐Ta anomalies in the mantle‐normalized immobile incompatible trace element patterns, and positive εNd(t) values from +4.2 to +6.5, which are consistent with the geochemical characteristics of mafic‐ultramafic rocks in supra‐subduction zone (SSZ)‐type ophiolite. On the contrary, the Carboniferous basalts, which are associated with marine carbonates, are characterized by light REE enrichments, slightly positive Nb‐Ta anomalies, and εNd(t) values from +2.8 to +4.0. These features are similar to those of typical oceanic island basalts (OIBs) worldwide. Modelling results using REEs show that the parental magmas for the Carboniferous OIBs and the Permian basalts were likely derived from mantle peridotites at the depths of garnet and spinel stability, respectively, consistent with the formation depth of these two different types of basalt globally. The occurrence of these two different types of mafic‐ultramafic rocks with significantly different ages in the same area supports the view that they are the remnants of the accreted Palaeo‐Tethys oceanic crust. The Carboniferous OIBs are considered to be parts of an OIB‐carbonate seamount chain that originally formed in the southern part of the Palaeo‐Tethys. The Permian mafic‐ultramafic rocks are regarded as fragments of SSZ‐type ophiolites that were present in the northern part of the Palaeo‐Tethys. These different pieces of oceanic crust were accreted to the Simao–Indochina continental Block by subduction between the Late Permian and the Triassic. [ABSTRACT FROM AUTHOR]

The Gacun deposit is a typical Volcanic Hosted Massive Sulfide (VHMS) associated with Late Triassic seafloor calc-alkaline felsic volcanics. Studies of zircon ages, petrology, major and trace element geochemistry, and Sr-Nd-Hf isotope geochemistry of volcanic rocks from the Northern Yidun arc were undertaken in this paper. We reshaped the Gacun magmatic system activity time, defined the origin of magma evolution, and proposed a metallogenic model of the deposit. Whole-rock major element compositions of the magmatic rocks in the Northern Yidun island arc indicate that they are a complete basalt–andesite–dacite–rhyolite assemblage, showing three obvious stages of composition evolution. They are enriched in large-ion lithophile and light rare earth elements, but depleted in high field-strength and heavy rare earth elements, with weak-to-negligible Eu anomalies (obvious in rhyolite). These geochemical features indicate that the Northern Yidun island arc is a magmatic arc based on ancient continental crust. The Ganzi–Litang oceanic subduction induced mantle melting and produced calc-alkaline basaltic magma, while the MASH processes at the bottom of the crust produced andesitic magma. Part of the andesite magma erupted to form andesite lava. The remaining part was mixed with magma produced via anatexis of ancient crust (approximately 20%–40% of the ancient crustal component), forming the ore-bearing rhyolite. Zircon U-Pb age data defines Gacun magmatic–hydrothermal mineralization sequence of events: At 238 Ma, arc magmatism led to the formation of andesite in the eastern part of the deposit. At 233 Ma, in the arc zone (the western part of Gacun deposit), a large-scale bimodal magmatism formed the main ore-bearing rock series of Gacun deposit, rhyolitic volcanic rocks. At 221 Ma, volcanic eruptions tended to end and sub-volcanic intrusion occurred, forming a lava dome, which was located under the ore-bearing rhyolitic volcanic rocks. The lava dome acted as a thermal engine and promoted hydrothermal circulation. The hydrothermal activity reached a peak at 217 ± 1 Ma, and the Gacun VHMS deposit was formed. [ABSTRACT FROM AUTHOR]

The Mesoproterozoic Husky Creek Formation is an interlayered redbed and basalt package that overlies a ca. 2.5 km thick, regionally extensive basaltic plateau linked to the 1.27 Ga Mackenzie Large Igneous Province. This succession provides an opportunity to study the interaction between contemporaneous fluvial sedimentation and flood basalt volcanism. The Husky Creek Formation is approximately 1900 m thick, consisting predominantly of fluvial channel and subordinate floodplain and eolian strata dominated by lithic detritus intercalated with basalt flows. U–Pb dating of detrital zircon grains collected from four stratigraphic levels in the Husky Creek Formation reveals two main age groupings: (1) a 1270 Ma peak attributed to the Mackenzie Large Igneous Province; and (2) Pre-1.6 Ga detrital zircon ages, which reflect sources from a broad region of northwestern Laurentia and are interpreted to be recycled from underlying sedimentary rocks of the Hornby Bay Basin. An upsection decrease in the proportion of ca. 1270 Ma zircon grains, coupled with increasing sandstone compositional maturity, reflects the expansion of the drainage basin during burial of a volcanic pile, with recycling becoming more dominant as the Husky Creek Formation accumulated. The Husky Creek Formation was deposited in the waning stages of the Mackenzie Igneous Event by west-flowing rivers into a geographically restricted basin above an extensive mafic volcanic plateau. This paper provides insight into fluvial basin development during the aftermath of one of Earth's largest igneous events. [ABSTRACT FROM AUTHOR]

Appinite–granite suites commonly occur in the final stage of collisional orogenic processes, providing a unique opportunity to reveal the properties of continental lithospheric mantle and crust–mantle geodynamics. In this paper, we present a systematic study of the petrology, mineral chemistry, whole-rock geochemistry and geochronology of the Xiong'erling pluton and adjacent appinite dikes in the northern margin of the North Qinling orogenic belt. The pluton is mainly composed of diorites, quartz monzonites and minor granites. The diorites and appinites have LA-ICP-MS zircon U–Pb ages of c. 389 Ma with variable εHf(t) values of −5.58 to +3.36 and TDM1 model ages peaking at c. 1133 Ma. These rocks belong to the shoshonitic series with high Ba–Sr content and were emplaced in an intraplate extensional environment. The quartz monzonites and granites are oxidized A-type granites and have zircon U–Pb ages of c. 396 and c. 378 Ma with negative εHf(t) values of −11.99 to −1.18 and TDM2 model age peaks at 1434, 1720, and 1888 Ma. The in situ 87Sr/86Sr ratios of plagioclase from the mafic and felsic rocks are 0.70565-0.70752 and 0.70695-0.71008, respectively. The Xiong'erling pluton and the coeval appinite dikes represent a Devonian appinite–granite suite in the North Qinling orogenic belt. Asthenospheric upwelling during the intraplate extension triggered partial melting of a phlogopite- and amphibole-bearing garnet lherzolite mantle source that had been previously metasomatized by the subducted oceanic slab, leading to the formation of a primitive hydrous mafic magma. The rapid ascent of the water-rich magma along deep-seated active faults with fast crystallization of amphibole resulted in emplacement of the c. 389 Ma appinite dikes. Replacement of anhydrous minerals by amphibole and biotite via hydrous reaction during magma cooling resulted in the formation of the coeval diorites. The mafic magma underplating triggered episodic remelting of a late Paleoproterozoic to early Mesoproterozoic crustal source, leading to the generation of the c. 396–378 Ma quartz monzonites and granites. Combining our results with existing data, we identify a sequence of (1) northward subduction of the Shangdan oceanic crust beneath the Qinling block at c. 524–438 Ma resulting in island-arc calc-alkaline magmatism, (2) closure of the Shangdan Ocean indicated by collision between the Qinling block and the South Qinling terrane and slab failure magmatism at c. 438–410 Ma, and (3) post-collisional to intraplate extension with alkaline magmatism at c. 410–370 Ma. The Devonian extensive intraplate magmatism marks the end of the Paleozoic orogenesis in the North Qinling belt. [ABSTRACT FROM AUTHOR]

Controversy over the geodynamic interpretation of the early Paleozoic granites in the South China Block constrains understanding of tectonic–magmatic evolution. In this paper, we present zircon U-Pb age, Hf isotope, and major and trace element data of the early Paleozoic granites in the Jilongjie region, south-central Hunan Province. A sample that yielded a weighted average 206Pb/238U age of 425 ± 3 Ma falls into the post-collisional granite field in the classification discriminant of magmatic rocks. Geochemical features indicate that the Jilongjie pluton is a shoshonitic metaluminous rock. The Jilongjie pluton's chondrite-normalized rare earth element patterns exhibit a slight enrichment of light rare earth elements (LREEs) relative to heavy rare earth elements (HREEs) with (La/Yb)N ratios of 15.1–23.7 and weak Eu anomalies (Eu/Eu* = 0.68–0.78). Zircon Hf isotope results show εHf(t) ranging from −9.94 to −0.69. Jilongjie granite's parent magma originated from a mixing of crust-derived felsic and mantle-derived mafic magmas, which then underwent fractional crystallization during its ascent. Jilongjie granite was generated through a post-collisional extensional setting associated with delamination of the thickened lithosphere. [ABSTRACT FROM AUTHOR]

The development of trench-arc-backarc (TABA) systems is uniquely associated with modern-style plate tectonics on Earth. The Qilian orogenic belt in NW China records the evolution history of the Proto-Tethys Ocean at the transition time from the Proterozoic to Phanerozoic. This paper presents systematic studies of petrography, U–Pb chronology and geochemistry on various rocks from a middle-ocean ridge (MOR)-type ophiolite belt, active continental margin and back-arc basin in the Qilian orogenic belt to address the development of a modern-style TABA system. Arc magmas include felsic intrusions with ages of 531 to 477 Ma and felsic-mafic arc volcanic rocks with ages of 506 to 439 Ma, showing distinctive features of typical magmatic rocks formed at an Andean-type continental margin. The back-arc basin is recorded by a 490- to 448-Ma suprasubduction zone (SSZ)-type ophiolite with boninite, and Silurian turbidite flysch formation. We establish a three-stage tectonic history from the initiation of subduction to the formation of a mature Japan-Sea-type back-arc basin at the active continental margin in the Early Paleozoic era. (1) Northward subduction of Proto-Tethys Ocean initiated and the Andean-type continental arc developed at ~530 to 500 Ma with continual crustal thickening; (2) a tectonic transition occurred from an Andean-type active continental margin to a West Pacific-type active continental margin at ~500 to 490 Ma with rapid thinning of crust to ~35 km; and (3) mature ocean basins and back-arc-basin (BAB) ophiolites were formed in the back-arc extensional environment at ~490 to 450 Ma. [ABSTRACT FROM AUTHOR]

The Zhaojinggou Nb–Ta deposit is one of large rare metal deposits newly discovered in the northern margin of the North China Craton in recent years. This paper reports petrography, petrochemistry, columbite‐group minerals U–Pb chronology study of the amazonite granitic pegmatite (AGP) exposed in this deposit, and composition of columbite‐group minerals and biotite are obtained by electron probe microanalyzer and LA‐ICP‐MS. Eighteen analyses of columbite‐group minerals yielded weighted mean 206Pb/238U age of 116.9 ± 1.4 Ma. The crystallization temperature of biotite is 630–650°C, and the oxygen fugacity is 10−17–10−18 bars. The biotite has low MgO contents and high Rb, Rb/Sr, and FeOT/(FeOT + MgO) ratios. The AGP has extremely low MgO, Cr, Co and Ni contents, with Nb/Ta ratios range from 1.63 to 9.05 and Rb/Sr ratios range from 303.30 to 648.90, and obvious 'M' type tetrad effect of rare earth element indicating that the formation of the AGP is related to crust‐derived magma. The contents of Nb2O5 and FeO decrease, while the Ta2O5 and WO3 contents, Mn# and Ta# values increase gradually from the core to the rim of columbite‐group minerals. Some columbite‐group minerals have unobvious oscillatory zoning, and some have a clear bright zoing with high Ta contents on the rim, indicating that the genesis of Zhaojinggou Nb–Ta deposit is mainly magmatic crystallization differentiation, accompanied by hydrothermal autometasomatism in the late stage. [ABSTRACT FROM AUTHOR]

The North China Block and the South China Block collided in the Middle Triassic, but there is still a lack of consensus regarding the end of collisional orogeny and the closure time of the Paleo-Tethys. In this paper, we report zircon U–Pb ages and geochemistry for the Shimen pluton in the northern margin of the West Qinling Orogenic Belt to investigate its genesis and tectonic environment. The new findings allow to constrain the end time of the Triassic orogeny in the Qinling Orogenic Belt and the closure time of the Paleo-Tethys. The weighted average 206Pb/238U ages of the Shimen pluton are 218.6 ± 1.5 Ma and 221.0 ± 1.7 Ma. Thus, we suggest that the Shimen pluton crystallized at the 218.6 Ma and 221.0 Ma and was formed during the Late Triassic (Norian). The Shimen pluton is mainly syenogranite and has alkaline dark minerals aegirine–augite. It is composed of 73.45 to 77.80 wt.% SiO2, 8.28 to 9.76 wt.% alkali, and 11.35 to 13.58 wt.% Al2O3, with A/CNK ranging from 0.91 to 1.02 and 10,000 Ga/Al ranging from 2.39 to 3.15. These findings indicate that the Shimen pluton is typical A-type granite. The plutons have low rare earth element contents, ranging from 73.92 to 203.58 ppm, with a moderate negative Eu anomaly. All the samples are enriched in large-ion lithophile elements, such as Rb, Nd, Th and U, and light rare earth elements, and are depleted in high field strength elements, such as Nb, P, Zr, Ba, and Sr. The depletion of Ba, Sr, and Zr may be related to the fractionation and evolution of the granite. According to the petrological and geochemical characteristics, the Shimen pluton is an A1-type granite formed in an anorogenic extensional environment. Combined with its tectonic characteristics and petrogenesis, the Shimen pluton was probably formed by the partial melting of the crust under high temperature and low pressure in the intraplate environment after the subduction of the South China Block beneath the North China Block. This observation indicates that the Triassic orogeny in the Qinling Orogenic Belt had ended and the Paleo-Tethys-Mianlve Ocean had also closed by the Late Triassic (Norian). [ABSTRACT FROM AUTHOR]

Dongcao muscovite granite, as the product of the second stage of the magmatic intrusion of the Ganfang composite pluton, is closely related to the mineralization of Li–Nb–Ta rare metals in the Yifeng area. This paper aims to discuss the diagenetic age, evolutionary process, and relationship with the rare metal mineralization of Dongcao muscovite granite by using petrographic, cassiterite U–Pb dating and geochemical analyses. Petrographic analysis shows that the lithology of the Dongcao muscovite granite is medium– to fine–grained muscovite monzogranite. The cassiterite U–Pb dating results show that the diagenetic age of the Dongcao muscovite granite is 139.7 ± 6.7 Ma, which is Early Cretaceous. The geochemical analysis indicates that the rock is characterized by high Si, abundant aluminum alkalis, low Ca and Fe, and low Mg, which indicates that this granite is a strongly peraluminous rock. Moreover, the Dongcao muscovite granite is enriched with Rb, U, Ta, Pb, P, and Hf and depleted of Ba, Sr, Ti, and rare earth elements (REEs), with a tetrad effect of REEs. Based on this analysis, the Dongcao muscovite granite is a highly differentiated granite that formed in the tectonic transition from continental collisional to post–collisional settings related to the subduction of the Paleo–Pacific plate. A high degree of crystallization differentiation occurred at the early stage of magmatic evolution, resulting in the initial enrichment of Li–Nb–Ta–Sn. The melt–fluid interaction in the late stage is significant to the high enrichment of Li–Nb–Ta–Sn until the final mineralization. [ABSTRACT FROM AUTHOR]

The Ailaoshan orogenic belt is one of the most significant orogenic belts in the southeastern margin of the Qinghai–Tibet Plateau. The widely developed magmatic rocks in this belt preserve the multi-stage tectonic evolution records of the South China Plate. As an important response to the Rodinia breakup tectonic event, the study of Neoproterozoic magmatic rocks in the area is of great significance for reconstructing the Neoproterozoic tectonic process of the Ailaoshan orogenic belt and the tectonic evolution of the South China Plate. Petrology, geochemistry, zircon U-Pb, and Lu-Hf isotopes of the Daping pluton in the Ailaoshan orogenic belt are studied in this paper. The Daping pluton is mainly divided into gabbros and granites. Gabbros and granites belong to the sub-alkaline series, which are relatively enriched in large ion lithophilic elements and depleted in high-field strength elements. The ΣREE contents of the gabbro are low with enrichment in LREEs and depletion in HREEs, and the degree of differentiation of light and heavy rare earth is low, with positive δEu and weak negative δCe anomalies. The ΣREE contents of the granite are low with enrichment in LREEs and depletion in HREEs, and the degree of light and heavy rare earth differentiation is high, with medium–weak negative δEu and weak positive δCe anomalies, suggesting an A2-type granite with A1-A2 transition characteristics. The weighted average age of the gabbro is 816.1 ± 4.1 Ma (MSWD = 0.11), with zircon εHf(t) values of −7.5–5.5. The magma source is a mixture of an ancient crust source and a new mantle source; the weighted average age of the syenogranite is 783.7 ± 8.1 Ma (MSWD = 1.4), with zircon εHf(t) values of −4.3–0.4. The magma source is mainly ancient crustal material (Ailaoshan Group), mixed with a small amount of mantle-derived material; the weighted average age of the monzogranite is 754.8 ± 6.1 Ma (MSWD = 3.0), with positive zircon εHf(t) values of 1.65–10.36. The magma source is a mixture of a large number of mantle-derived materials and a small number of crust-derived materials (Ailaoshan Group). The Daping pluton was formed in the transitional tectonic environment from post-collision to intraplate continental margin rift, corresponding to the Rodinia breakup process in the western margin of the South China Plate. [ABSTRACT FROM AUTHOR]

Reconstructing the tectonic architecture of the southern Altaids is of great importance to piece together the continental growth history of the Central Asian continent. In this paper, we address the subduction‐accretion process of the Paleo‐Tianshan Ocean, one branch of the South Tianshan Ocean, in the southern Altaids, through a detailed geological and geochemical investigation of the Wulanmoren Accretionary Complex (WAC). The WAC is composed of ophiolitic mélanges, ocean plate stratigraphy mélanges, and turbiditic coherent units. In this study, we present key geological, petrological, and geochemical evidence indicating back‐arc and ocean island affinity of the igneous rocks of the WAC. Zircon U‐Pb dates of these rocks ages range between 380.2 ± 1.3 and 302.0 ± 5.3 Ma. The sedimentary matrix units of the mélanges were deposited in the Early Devonian (∼405 Ma) to the Late Triassic (∼222 Ma), rather than Silurian strata as previously thought. However, the ages of some detrital zircons in the sedimentary matrix are Precambrian, pointing to a complex evolution involving multiple ocean island terrains and island arcs of different ages that accreted from the mid‐Paleozoic to the Early Mesozoic. Plain Language Summary: Well‐exposed rock outcrops of the Wulanmoren Accretionary Complex (WAC) offer an ideal opportunity to solve the enigma of the evolutionary history of the Paleo‐Tianshan Ocean (PTO) of Central Asia. We report field observations, geochemistry, and geochronology of the WAC in the southern Altaids, pointing to multiple tectonic settings of ages spanning from the Early Devonian (∼405 Ma) to the Late Triassic (∼222 Ma). These reconstructions suggest closure time of the PTO occurred post‐Triassic. Based on detrital zircons provenance analysis, we propose a multi‐island ocean model to explain the tectonic evolution of the PTO in the time period studied. Key Points: The Wulanmoren Accretionary Complex was composed of ophiolitic mélanges, ocean plate stratigraphy mélanges, and coherent unitsThe Late Paleozoic MORB‐like and OIB‐type basalts, and ∼222 Ma coherent units indicate closure of the Paleo‐Tianshan Ocean occurred post‐TriassicThe southern Paleo‐Asian Ocean was an archipelago with several subduction systems which is similar to the modern southwest Pacific [ABSTRACT FROM AUTHOR]

The effectiveness of Carbon Capture and Storage (CCS) as an imperative decarbonization technology relies on the sealing capacity of a fine‐grained caprock to permanently store CO2 deep underground. Uncertainties in assessing the caprock sealing capacity increase with the spatial and temporal scales and may delay CCS deployment at the gigatonne scale. We have developed a computationally efficient transport model to capture the dynamics of basin‐wide upward CO2 migration in a multi‐layered setting over geological time scales. We find that massive capillary breakthrough and viscous flow of CO2, even through pervasively fractured caprocks, are unlikely to occur and compromise the storage security. Potential leakage from the injection reservoir is hampered by repetitive layering of overlying caprocks. This finding agrees with geologic intuition and should be understandable by the public, contributing to the development of climate policies around this technology with increased confidence that CO2 will be indefinitely contained in the subsurface. Plain Language Summary: Massive and timely deployment of Carbon Capture and Storage (CCS) at the gigatonne scale is a critical component of the majority of pathways toward reaching the Paris Agreement emissions abatement targets to mitigate climate change. Although CCS has been successfully deployed at multiple sites around the world, concerns about long‐term containment, especially for gigatonne‐scale storage, are causing uncertainty about the ability of geological layers to permanently store CO2 underground. This uncertainty is delaying the widespread deployment of CCS. This paper focuses on assessing the possibility of basin‐wide CO2 leakage through a typical multi‐layered geological setting with a sequence of aquifers and fine‐grained caprocks (e.g., shales). Numerical transport models, constrained by hydraulic properties of intact and pervasively fractured caprocks (as the best‐ and worst‐case scenarios, respectively), enable us to draw unambiguous limits on the CO2 leakage rates over previously unexplored temporal and spatial scales. We show that CO2 leakage to shallow sediments in both extreme scenarios is quite unlikely and the injected CO2 will be contained in the subsurface over millions of years. These findings should offer confidence to industrial developers, policy‐makers, investors, and most importantly, the public that CCS provides a secure and environmentally sound carbon removal option. Key Points: We develop a numerical transport model to understand the long‐term fate of CO2 in gigatonne‐scale geologic carbon storageCO2 leakage is dominated by molecular diffusion at inherently slow rates, hardly approaching a meter per several thousands of yearsThe long‐term potential for CO2 leakage from a multi‐layered system is low, making geologic storage a secure decarbonization technology [ABSTRACT FROM AUTHOR]

One was the Planetary Boundaries framework, introduced by Johan Rockström and colleagues in 2009, which aims to provide a natural-science based framework for describing a Holocene-like state of the Earth System and the intrinsic boundaries of the Earth System that should not be transgressed if such a stable state is to be maintained (Rockström et al. [10]). Introducing the Anthropocene: The human epoch: This article belongs to Ambio's 50th Anniversary Collection. The other is the polycentric governance systems approach introduced by the late Elinor Ostrom ([9]), which, in the context of the S et al. paper, was proposed as a more appropriate governance system for the Anthropocene than the present governance systems that are driving us deeper towards a planetary crisis. The SCM paper foreshadowed the debate on the start date for the Anthropocene, which became prominent from 2009 with the formation then of the Anthropocene Working Group to explore the Anthropocene as a potential new interval in the Geologic Time Scale (AWG [1]). [Extracted from the article]

A quantitative analysis of any environment older than the instrumental record relies on proxies. Uncertainties associated with proxy reconstructions are often underestimated, which can lead to artificial conflict between different proxies, and between data and models. In this paper, using ordinary least squares linear regression as a common example, we describe a simple, robust and generalizable method for quantifying uncertainty in proxy reconstructions. We highlight the primary controls on the magnitude of uncertainty, and compare this simple estimate to equivalent estimates from Bayesian, nonparametric and fiducial statistical frameworks. We discuss when it may be possible to reduce uncertainties, and conclude that the unexplained variance in the calibration must always feature in the uncertainty in the reconstruction. This directs future research toward explaining as much of the variance in the calibration data as possible. We also advocate for a "data‐forward" approach, that clearly decouples the presentation of proxy data from plausible environmental inferences. Plain Language Summary: Earth's surface environments have varied significantly throughout geologic time. Accurate quantification of these ancient environmental changes relies on proxies—materials that are known to change composition or morphology with the ambient environment. These approaches have provided insight into important questions across the Earth sciences, from the context and consequences of biological evolution and volcanic eruptions, to threshold behavior and long‐term feedbacks within the modern climate system. Although the uncertainty associated with an estimate of an environmental change is of equal importance to the estimate itself, uncertainties are widely either underestimated or else rely on proxy‐specific statistical models. Fortunately, a very good, and broadly applicable, estimate of uncertainty is extremely simple to calculate. In this paper we show that statistical uncertainty in proxy reconstructions is mostly due to the magnitude of scatter around the calibration line. We furthermore attempt to give the reader an intuition for how large reported uncertainties in proxy reconstructions should be, how and when they can be reduced, and where future efforts to reduce uncertainty should be directed. Key Points: Statistical uncertainties in proxy reconstructions are dominated by unexplained variance in the calibrationProxy data should be presented as explicitly distinct from environmental interpretationsFuture efforts should prioritize collection of multiple explanatory variables for calibrations, and true replicate paleoanalyses [ABSTRACT FROM AUTHOR]

Field exposures are often used to provide useful information about sub-surface reservoirs. This paper discusses general lessons learnt about the use of deformed Devonian and Carboniferous meta-sedimentary rocks in the Harz Mountains, Germany, as analogues for a proposed enhanced geothermal reservoir (EGS) at Göttingen. The aims of any analogue study must be clarified, including agreeing with people from other disciplines (especially reservoir modellers) about the information that can and cannot be obtained from surface exposures. Choice of an analogue may not simply involve selection of the nearest exposures of rocks of a similar age and type, but should involve consideration of such factors as the quality and geological setting of the analogue and reservoir, and of any processes that need to be understood. Fieldwork should focus on solving particular problems relating to understanding the EGS, with care being needed to avoid becoming distracted by broader geological issues. It is suggested that appropriate questions should be asked and appropriate analyses used when planning a study of a geothermal reservoir, including studies of exposed analogues. [ABSTRACT FROM AUTHOR]

This paper studies the mineralization process and the ore-forming setting of the Kantian fluorite deposit in South China through the zircon U-Pb chronology, quartz Rb-Sr dating, whole rock geochemistry, H-O isotope and fluid inclusions. A mineralization model for the Kantian fluorite deposit is proposed as follows: The subduction of the Pacific plate during the late mid-Jurassic and late Jurassic led to the formation of several fault zones. As the subduction gradually decelerated and eventually ceased, continental extension and lithosphere thinning occurred, accompanied by upwelling of the asthenosphere. This asthenosphere upwelling facilitated melting of the lithospheric mantle, resulting in the ascent of magma into the lower crust. Consequently, the intrusion of magma into the lower crust caused substantial heat, triggering partial melting of the lower crust. The molten material then ascended along faults, generating a significant quantity of granites. During the Early Cretaceous period, the Yanshan cycle witnessed another notable phase of magmatic activity. The residual magmatic hydrothermal fluid from this period served as a source of heating, while the pre-existing fault structures provided favorable pathways and storage space. Atmospheric precipitation infiltrated into the depth along these faults, and the deep-seated residual magmatic hydrothermal fluid heated the infiltrated atmospheric water, inducing cyclic upwelling. The upward migration of hydrothermal fluid continuously extracted Ca and F elements from the granites. Ongoing interaction between the fluid and the surrounding rocks led to changes in pH, coupled with alterations in temperature and pressure, ultimately resulting in the precipitation of fluorite with associated alteration zones in the surrounding rocks. [Display omitted] • Ca and F element in the fluorite were derived through the surrounding rocks. • The ore-forming fluids belong to the NaCl-H 2 O system and exhibit characteristics of medium–low temperature, low salinity, and low density, and were derived from meteoric water. • The intrusion age of surrounding rock in Kantian fluorite deposit was 159.4 ± 2.2 Ma, and the ore-forming of fluorite was 135.6 ± 0.7 Ma. • The tectonic setting responsible for the diagenesis and mineralization processes is believed to be an intracontinental stretching environment associated with the subduction of the Pacific plate. The Yanshanian events have led to the development of South China as a unique granite province globally. Within South Jiangxi, numerous metallic and non-metallic deposits have a close association with Mesozoic granite formations. The Kantian fluorite deposit, a newly discovered non-metallic deposit in southern Jiangxi Province, is one such deposit that is linked to Mesozoic granites. The orebody at the Kantian fluorite deposit is identified as occurring in veined structures within the silicification fracture zone of Mesozoic granites, with strict control exerted by fault systems. Fluorite ore can be classified into two categories based on the amount of quartz and fluorite. The first category is the fluorite quartz type, which has a higher amount of quartz than fluorite. The second category is quartz fluorite type, which has more fluorite than quartz. Among these two categories, the quartz fluorite type is precipitated during the primary mineralization stage. Through the analysis of fluid inclusions within the fluorite, it was determined that the homogenization temperature is relatively low, ranging from 133 to 236℃. The fluid inclusions also display low salinity (0.18–3.39 wt% NaCl eqv.) and low density (0.75–0.96 g/cm3). Laser Raman spectroscopy revealed that the primary components of the fluid inclusions are H 2 O, with minor C 3 H 6. Isotope analysis indicated δD VSMOW values of fluorite ranging from −61.9 ‰ to −54.8 ‰ (average −59.8 ‰), while δ18O VSMOW values varied from 1.3 ‰ to 3.1 ‰ (average 2.0 ‰). This study presents chronological, petrological and geochemical data that suggest several processes. The metallogenic age is 135.6 ± 0.7 Ma. The mineralizing fluids were identified to the NaCl-H 2 O system, with heated meteoric water identified as the primary source; The ore-forming materials originated from the granite, and water–rock interactions are proposed as the primary mechanism for fluorite precipitation. Based on a tectonic setting characterized by stretching, which is closely linked to the subduction of the Pacific plate, we proposed a model for the Kantian fluorite deposit. [ABSTRACT FROM AUTHOR]

[Display omitted] • The hydrothermal titanite associated with Au mineralization was formed at 130.8 ± 0.63 Ma. • The early Cretaceous Au mineralization overprinted the Triassic and late Jurassic Mo-Pb mineralization in Huangshui'an. • The gold precipitation mechanisms are sulfidation, collection-redissolution by LMCE melt, and changes in f Te 2 and f S 2. Huangshui'an deposit, situated in the Xiong'ershan area of Qinling orogenic belt (QOB) in China, is a globally rare carbonatite-type molybdenum polymetallic deposit that contains economic Mo, Au, Pb, and REE mineralization. The molybdenite Re-Os ages (Ca. 213.5–209.2 Ma) indicates that Huangshui'an Mo mineralization formed at Late Triassic. However, it is still unclear whether the Au mineralization is related to carbonatite dykes, and the formation age and genesis mechanism of Au mineralization remain poorly understood at Huangshui'an. This paper presents a comprehensive investigation of the Au mineralization events at the Huangshui'an deposit, including geology, mineralogy, and geochronology. The aim is to provide insights into its formation and mineralization processes and offer a broader understanding of regional Au metallogeny. Based on petrographic investigations, four stages are identified in the Au mineralization as follows: (I) quartz-K-feldspar stage; (II) quartz-pyrite-gold stage, including (IIA) pyrite-native gold sub-stage and (IIB) gold-tellurite-bismuthide sub-stage; (III) quartz-pyrite-polymetallic sulphide-oxide stage; and (IV) calcite-quartz-chlorite stage. The LA-ICP-MS titanite U-Pb dating yields a weighted mean age of 130.8 ± 0.63 Ma which determined that the Au mineralization at Huangshui'an was in the Early Cretaceous and was an independent mineralization event, which may be related to the lithosphere's destructive effect on the North China Craton (NCC). Combined with mineralography by automatic quantitative mineral analysis and testing system (TIMA), we consider that tellurium-bismuth minerals are closely associated with Au mineralization. The sulfur and tellurium fugacity of the ore-forming fluids in each stage were calculated using metal sulfide-oxides and tellurium-bismuth minerals. It was concluded that the precipitation of Au in the Huangshui'an deposit was mainly due to the combined effects of sulfidation, gold collection-redissolution by the low-melting point chalcophile elements (LMCE) melts, and the variation of sulfur fugacity and tellurium fugacity. [ABSTRACT FROM AUTHOR]

The paper presents new petrographic and geochemical data from terrigenous rocks and first U–Pb ages of detrital zircons from sandstones of the Tekturmas zone of Junggar-Balkhash suture zone (central Kazakhstan). Petrographically and chemically the samples under study are greywacke sandstones. We performed U–Pb isotope dating of detrital zircons separated from two sandstones sampled in the northern (TK-17) and southern (TK-27) parts at the periphery of the Tekturmas zone. The distribution of U–Pb ages of zircons from sample TK-27 (northern Tekturmas zone) is unimodal with a major peak at 453 Ma. The distribution of U–Pb ages of detrital zircons from TK-17 sample (southern Tekturmas zone) has a bimodal character peaked at 510 and 450 Ma. Both samples contain a small amount of Precambrian zircons. The most probable sources of ca. 450 Ma zircons are andesitic to volcanic rocks of Tekturmas supra-subduction ophiolites. The ca. 500 Ma zircons are also low-rounded like those younger, but no igneous rocks of that age have been identified in the study area. The youngest U–Pb ages of zircons from both samples are similar (438–437 Ma), suggesting the beginning of sedimentation after the Llandovery. The greywacke composition and the poorly sorted, poorly rounded and immature characteristics of the sandstones under study and the clear major peaks of U–Pb detrital zircon ages at an extremely low amount of old zircons suggest their derivation from short-distant sources dominated by Late Cambrian-Early Ordovician and Middle-Late Ordovician supra-subduction igneous complexes. A very limited amount of oldest zircons could come from Precambrian complexes present at the periphery of both sedimentation basins. [ABSTRACT FROM AUTHOR]

The Jiao-Liao-Ji belt (JLJB), in the Eastern Block of the North China Craton, is a major Paleoproterozoic orogen and underwent a complicated tectonic evolution during 2.2–1.8 Ga. The Liaohe Group, an important stratigraphic unit in the JLJB, is key to understanding the complex evolution of this belt. In this paper, we present new detrital zircon U–Pb ages and Hf isotope data for meta-sedimentary rocks from the Gaixian Formation in different areas of the JLJB, in addition to compiled data for other formations of the Liaohe Group, to establish the depositional age and source of detrital materials of the group. U–Pb age results show that the age ranges of zircons from the different samples are broadly similar. The youngest zircon group is ca. 2.06 Ga, and the youngest single-grain age is ca. 2.0 Ga, constraining the depositional age of the Gaixian Formation to between 2.0 Ga and the metamorphic age of ca. 1.9 Ga. The zircon age data indicate that the provenance was primarily Archaean basement of the Nangrim Block and Paleoproterozoic volcanic rocks of the Li'eryu Formation. On the basis of the new geochronological data and results from previous studies, it is inferred that the JLJB underwent a successive process of rifting–subduction–collision, with the different formations of the Liaohe Group being deposited in different stages from rift to passive continental margin and then to active continental margin. Zircon Hf isotope data from the JLJB and adjoining Longgang and Nangrim blocks indicate that a major crustal growth event occurred at 2.9–2.5 Ga, followed by crustal growth and intense recycling of ancient crust at ca. 2.2 Ga. [ABSTRACT FROM AUTHOR]

Jinling complex pluton is a key part of the Mesozoic magmatic belt in the eastern North China Craton. However, its petrogenesis is still being debated. The Jinling complex, mainly composed of biotite diorites, hornblende diorite, augite diorites, (quartz) monzonites, and quartz diorites, is outcropped in Huashan and Heitieshan. This paper studies the zircon geochronology, zircon Hf isotope, and Sr-Nd-Pb isotope of quartz monzonites. The samples have high contents of Cr, Ni, V, Al2O3, Ba, Sr, and are enriched in LREEs, LILEs (K, Ba, Sr), depleted in HREEs, and HFSEs (Nb, Ta, Ti). The samples with captured zircons of ~2.5 Ga yield a weighted mean age of ~127 Ma, and the zircons have negative values of εHf(t) from −3.2 to −9.4 while the ratios of 208Pb/204Pb, 207Pb/204Pb, 206Pb/204Pb 37.75~38.15, 15.41~15.43, 17.59~17.98, respectively. The ratios of Th/U are from 3.77 to 3.82, while the values of μ and ω are 9.18 and from 35.72 to 36.15. Meanwhile, the ratios of 87Sr/86Sr are higher than the ones of the mantle. Geochemical and isotopic features indicate that the quartz monzonites derived from the subcontinental lithospheric mantle that probably assimilated ancient NCC upper crust materials (~15–20%) during the magma ascent in a lithospheric extension setting. [ABSTRACT FROM AUTHOR]

The Zhashui-Shanyang ore cluster area is one of the most important gold polymetallic ones in northwestern China. The Qinglingou gold deposit is a newly discovered small-scale deposit in the Zhashui-Shanyang area. Gold mineralization closely related to acid intrusive rocks has been found for the first time in this area. In this paper, the geochronology, whole-rock geochemistry, and isotope signature of the granite porphyries in the deposit are studied. They are characterized by variable medium SiO2 (67.22–71.72 wt.%), high K2O + Na2O contents (6.54–10.34 wt.%), and variable Al2O3 (14.47–15.10 wt.%) values. The A/CNK ratios range from 0.90 to 1.23, and the A/NK ratios vary from 1.14 to 1.48. These rocks also contain biotite and amphiboles and are similar to peraluminous and high-K calc-alkaline I-type granites. The Qinglingou granite porphyries show relative enrichment of Rb, Th, and K, and depletion of Nb, Ta, P, Ti, and other high field strength elements. These porphyries are enriched in light rare earth elements relative to heavy rare earth elements with weak negative Eu anomalies (δEu = 0.63–0.89), which is interpreted to be the best age of crystallization of the Qinglingou porphyries. LA–ICPMS zircon U–Pb dating yields an age of 211 ± 1.2 Ma (n = 16, MSWD = 0.39). The close spatial relationship between the ore bodies and granite porphyry dikes indicates that this age may represent the metallogenic age in this area. The zircons have 176Hf/177Hf ratios ranging from 0.282625 to 0.282702, the εHf(t) values are near 0 and the two-stage zircon Hf model ages range from 1121 to 1296 Ma. These data indicate that the Qinglingou granite porphyries were derived from the interplay between mantle- and crustal-derived magmas. We therefore propose that there is potential gold in carbonate rocks at the periphery of porphyry-skarn copper-molybdenum deposits. [ABSTRACT FROM AUTHOR]

This paper examines the way COVID-19-related rock art challenges popular assumptions about the information society and the digital age. Adopting a constructivist-based humanities approach, it explores the significance of rock art as an information practice that emerged in response to the pandemic. Specifically, this personal case study reflects on the way rock art encouraged people to practice "joyful attention" and "kind attention" during the 2020 spring restrictions in British Columbia. Analyzing the possible values associated with different rock designs, I suggest that this joy-oriented information practice presents an alternative narrative of the present time, one that is ultimately more positive in its representation of the world than the negative, technologically driven discourses that tend to dominate cultural narratives of information. [ABSTRACT FROM AUTHOR]

This paper reviews data from numerous publications focused on the physicochemical parameters and chemical composition of ore-forming fluids from orogenic gold deposits formed during various geological epochs. The paper presents analysis of the distribution of the principal parameters of mineralizing fluids depending on the age of the mineralization. Some parameters of the fluids (their salinity and pressure) at orogenic gold deposits are demonstrated to systematically vary from older (median salinity 6.1 wt.%, median pressure 1680 bar) to younger (median salinity 3.6 wt.%, median pressure 1305 bar) deposits. The detected statistically significant differences between some parameters of mineralizing fluids at orogenic gold deposits are principally new information. The parameters at which mineralization of various age was formed are demonstrated to pertain to different depth levels of similar mineralization-forming systems. The fluid parameters of the most ancient deposits (which are mostly deeply eroded) correspond to the deepest levels of orogenic fluid systems. Hence, the detected differences in the salinity and pressure of the mineralizing fluids at orogenic deposits of different age reflect the vertical zoning of the mineralizing fluid systems. [ABSTRACT FROM AUTHOR]

[Display omitted] • Phlogopite 40Ar–39Ar dating constrains the age of the Baijian deposit at ca. 128 Ma. • Magnetite and its equilibrated fluid acquire high δ18O values through fluid-wall rock interaction. • Interaction of magmatic fluids with evaporate-bearing carbonates may play a vital role in the district-wide Fe skarn mineralization. The Handan-Xingtai district, situated in the central part of the North China craton, is one of the most important concentrations of Fe skarns in China. Baijian is the largest Fe skarn deposit in this district with significant Fe reserves being newly identified. This deposit is spatially related with a monzodiorite stock intruding the Middle Ordovician evaporate-bearing marine carbonates, with Fe mineralization occurring in the contact zone or within carbonate wall rocks. This paper conducts a comprehensive investigation encompassing geological, mineralogical, geochronological, and stable isotope analyses of the Baijian deposit. The goal is to provide insights into its formation and mineralization processes and offer a broader understanding of regional Fe metallogeny. The skarn mineralogy in the Baijian deposit is predominantly characterized by Mg-rich minerals such as diopside, tremolite, serpentine, and phlogopite. Magnetite is the dominant metallic mineral, featuring low Ti contents (<0.11 wt%) and high Fe concentrations (>66.59 wt%), indicative of a hydrothermal origin. The majority of the magnetite trace element data are plotted in the skarn field on the Al + Mn versus Ti + V diagram. Pyrite, a notable component in ores, exhibits considerable variations in Co and Ni concentrations, with Co/Ni ratio generally higher than unity. Phlogopite 40Ar–39Ar dating constrains the formation of the Baijian Fe skarn deposit at ca. 128 Ma, aligning with zircon U-Pb ages (128.8 ± 0.9 Ma) of the associated monzodiorite. This temporal congruence suggests a genetic relationship between the magmatism and skarn mineralization. Combined with previous published geochronological data, this study identifies an increasing trend in Fe mineralization intensity within the Handan-Xingtai district, spanning from ca. 137 to 128 Ma. Geological and oxygen isotopic evidence advocates for a magmatic origin of the ore-forming fluids at the Baijian deposit. The δ18O values of these fluids experience elevation through interaction with carbonate wall rocks. The pronouncedly high δ34S values of pyrite (>16.1 ‰) in the Baijian magnetite ores underscore a substantial sulfur contribution from sulfate in evaporate beds. Drawing on geological, mineralogical, and isotopic evidence, the study suggests that the interaction between magmatic fluids and evaporate-bearing carbonate rocks plays an important role in magnetite precipitation at the Baijian deposit. This interaction serves to reduce fluid acidity and facilitate the oxidation of ferrous iron (Fe2+). The Fe skarn deposits in Handan-Xingtai district are mostly hosted in middle Ordovician evaporite-bearing carbonate strata with ore-related sulfides exhibiting strong 34S enrichment (δ34S > 10 ‰). The interaction of magmatic fluids with evaporate-bearing carbonates is likely a common process responsible for magnetite deposition in the Fe skarn deposits. [ABSTRACT FROM AUTHOR]

The Trans‐North China Orogen (TNCO) is a part of the North China Craton (NCC) and together provides a classic example of lithospheric destruction. The Pandao granites outcropping in the Wutai Mountains area provide a window to investigate the Mesozoic magmatism in the TNCO. Here, this paper presents the new zircon geochronology, whole‐rock geochemistry, and zircon Hf isotope data for the Pandao granites to discuss their petrogenesis and tectonic implications. The Pandao granites are mainly composed of light‐red medium‐ to coarse‐grained biotite granite and light‐grey fine‐ to medium‐grained biotite granite. Zircon U–Pb ages of 110.05 ± 0.67 Ma and 108.35 ± 0.81 Ma suggest that the Pandao granites were crystallized in the Early Cretaceous. The Pandao granites are classified as high‐K calc‐alkaline and weak peraluminous series. The rocks display abundance in large‐ion lithophile elements (LILE) and light rare‐earth elements (LREE) but show depletion in high‐field‐strength elements (HFSE) and heavy rare‐earth elements (HREE), with strong negative Eu anomalies. The classification diagrams indicate that the Pandao granites are A‐type granites and thus belong to the A1 subtype, formed in an intraplate extensional environment. The Pandao granites have homogeneous zircon Hf isotopic compositions. Their zircons have negative εHf(t) values (−19.1 to −17.1) and old Hf isotope crustal model ages (2,250–2,375 Ma), suggesting that the Pandao granites were formed by partial melting of the Paleoproterozoic lower crustal material. Therefore, it is suggested that the Pandao granites were formed under an intraplate extensional tectonic environment of remote effect due to the ancient Pacific Plate subduction and retreat beneath the Eurasian continent. The TNCO was influenced by the subduction and retreat of the ancient Pacific Plate in the late Early Cretaceous. [ABSTRACT FROM AUTHOR]

The Compostela area is located in the western Trans‐Mexican Volcanic Belt, which consists of volcanic rocks that produced during the Pliocene to Recent volcanism. In this paper, we present petrography, whole‐rock major‐ and trace‐element concentrations, Ar–Ar ages, and Sr–Nd isotopic data of volcanic rocks from the Compostela area in the south of the city of Tepic, Nayarit, Mexico. These volcanic rocks are of intermediate composition and belong to the transitional series: basaltic trachyandesites [52.72–53.94 wt% SiO2; 0.69–2.53 wt% MgO] and subalkaline series: low‐Si [55.11–60.94 wt% SiO2; 0.79–2.74 wt% MgO] and high‐Si [61.60–62.71 wt% SiO2; 0.36–0.80 wt% MgO] andesites. The 40Ar/39Ar dating of two basaltic trachyandesites yields plateau ages of 1.05 ± 0.15 Ma and 1.07 ± 0.17 Ma and the andesites yielded a plateau age of 2.42 ± 0.36 Ma. These results indicate that the studied rocks were formed during the Pleistocene in two discrete episodes. The basaltic trachyandesites show enriched light rare earth elements patterns relative to high rare earth elements [(La/Yb)N = 5.81–8.07] with negligible Eu anomalies. The andesites display enriched large‐ion lithophile elements (Ba, K) with anomalies of Nb (Th/Ce) and Ti in the three groups identified in the subalkaline series. The basaltic trachyandesites appear in a tight cluster of initial 87Sr/86Sr ratios (0.703519–0.703882) as compared to the basaltic andesite 87Sr/86Sr (0.704073) and positive ɛNd(t) values of +5.6 to +3.4, respectively, indicating that the basaltic trachyandesites were derived from intermediate magmas from a shallow mantle source. Geochemical modelling reveals that both basaltic trachyandesite and andesite rocks were derived by a process of crystal fractionation accompanied by assimilation of crustal rocks at the lower or middle level. Geochemical ratios and multidimensional discrimination diagrams, combined with the cross‐section of the subduction zone indicates that basaltic trachyandesites were generated from a rift and/or Ocean Island Basalt‐type source, whereas andesites were generated from a slab‐derived source in a subduction environment. [ABSTRACT FROM AUTHOR]

This study, along with our previous studies (Yuguchi et al. 2015, 2019a), reveals the hydrothermal alteration processes in a pluton, with a focus on the mass transfer between minerals and hydrothermal fluid. It also depicts the sequential variations in fluid chemistry as alteration progresses. Hydrothermal alteration of the Toki granite in Tono, Japan--the study area of this research--progressed through the successive processes of chloritization, plagioclase alteration, and precipitation of a carbonate. This paper describes the alteration processes of hornblende chloritization, K-feldspar chloritization, and the formation of fracture-filling chlorite through petrography and mineral chemistry. A set of singular value decomposition analyses was conducted to obtain reaction equations for the chloritization processes, which facilitates the quantitative assessment of mass transfer between the reactant and product minerals, and the inflow and outflow of components through the hydrothermal fluid. Several types of chloritization reactions (including biotite chloritization) can be characterized by their reaction with the inflow of Al3+, Fe2+, Mn2+, and Mg2+ and the outflow of H4SiO4, Ca2+, K+, and F-. The age and thermal conditions of hornblende chloritization (64-54 Ma and 330-190 °C), K-feldspar chloritization (68-53 Ma and 350-210 °C), and precipitation of fracture-filling chlorite (66 and 63 Ma, 340 and 320 °C) overlap with those of biotite chloritization (68-51 Ma and 350-180 °C). The chloritization reactions (this study and Yuguchi et al. 2015) and plagioclase alteration (Yuguchi et al. 2019a) represent sequential variations in fluid chemistry at temporal conditions from 68 to 51 Ma as the temperature decreased from 350 to 180 °C. As the alteration proceeds, the concentrations of aluminum, iron, manganese, and magnesium ions in the hydrothermal fluid decrease gradually, and those of calcium, hydrogen, and fluorine ions increase gradually. Hornblende chloritization is associated with formation of magnetite and ilmenite. The thermal conditions of the hydrothermal fluid yielding the formation of magnetite and ilmenite can be interpreted by the chemical characteristics of chlorite around their associated minerals. The formation temperature of magnetite was higher than that of ilmenite, implying a decrease in oxygen fugacity in the hydrothermal fluid with the decrease in temperature from 280-310 to 220-250 °C. [ABSTRACT FROM AUTHOR]

The Lower Jurassic clastic rocks in the Qiangtang Basin, northern Tibet, are generally regarded as the early sediments of the new Mesozoic Qiangtang Basin (Late Triassic to Early Cretaceous). However, little attention has been paid to the palaeoenvironment, provenance, and tectonic setting of this unit. The QZ‐16 well, located in the east of the northern Qiangtang Basin, firstly recovered the Lower Jurassic strata (Quemo Co Formation) in the Qiangtang Basin. In this paper, the whole‐rock major‐trace elemental characteristics of 34 mudstone samples and detrital zircon geochronology of one sandstone, collected from the Quemo Co Formation of the QZ‐16 well, are reported in order to infer the palaeoenvironment, provenance, and tectonic setting. Quemo Co mudstones are dominated by SiO2 and Al2O3, while Fe2O3, CaO, K2O, and MgO are the second most abundant oxides. They are generally characterized by high REE concentrations, enrichment in light rare earth elements (LREEs), marked negative Eu and Ce anomalies. The REE contents of the mudstones are mainly controlled by terrigenous detrital minerals input. The Lower Jurassic mudstones have relatively high chemical index of alteration (79.1–83.6) values, indicating moderate to high degree of chemical weathering conditions of the source area. Sr/Ba and Rb/K ratios reflect that the marine transgression impact was limited and the mudstones were generally deposited in a brackish water environment. Major, trace, and REE contents indicate that the mudstones were mainly derived from intermediate igneous rocks with subordinate felsic igneous rocks. Prominent age peaks at ca. 200 ~ 400 Ma, 700 ~ 970 Ma, 1,700 ~ 1,900 Ma, and 2,100 ~ 2,700 Ma of the detrital zircon grains suggest that the Lower Jurassic clastic rocks were derived from the Central Qiangtang and Songpan–Ganzi complex. Moreover, tectonic discrimination diagrams based on major and trace elements show that the source of the Lower Jurassic sediments were most likely derived from a collision tectonic setting. [ABSTRACT FROM AUTHOR]