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Agricultural activity is a significant source of greenhouse gas emissions. The fertilizer production process emits N2O, CO2, and CH4, and fertilized croplands emit N2O. We present continuous airborne observations of these trace gases in the Lower Mississippi River Basin to quantify emissions from both fertilizer plants and croplands during the early growing season. Observed hourly emission rates from two fertilizer plants are compared with reported inventory values, showing agreement for N2O and CO2 emissions but large underestimation in reported CH4 emissions by up to a factor of 100. These CH4 emissions are consistent with loss rates of 0.6–1.2%. We quantify regional emission fluxes (100 km) of N2O using the airborne mass balance technique, a first application for N2O, and explore linkages to controlling processes. Finally, we demonstrate the ability to use airborne measurements to distinguish N2O emission differences between neighboring fields, determining we can distinguish different emission behaviors of regions on the order of 2.5 km2 with emissions differences of approximately 0.026 μmol m−2 s−1. This suggests airborne approaches such as outlined here could be used to evaluate the impact of different agricultural practices at critical field‐size spatial scales. Key Points: Reported N2O and CO2 emissions from fertilizer plants agree with observations, but CH4 is underestimated by orders of magnitudeWe demonstrate mass balance quantification of N2O emissions from agriculture at 10–100 km scalesAirborne measurements can observe and quantify N2O emission differences between agricultural fields of ∼2.5 km2 [ABSTRACT FROM AUTHOR]

This paper describes 10 core features of a neuropsychological assessment with the aim of helping neurologists understand the unique contribution the evaluation can make within the wider context of diagnostic methods in epilepsy. The possibilities, limitations and cautions associated with the investigation are discussed under the following headings. (1) A neuropsychological assessment is a collaborative investigation. (2) Assessment prior to treatment allows for the accurate assessment of treatment effects. (3) The nature of an underlying lesion and its neurodevelopmental context play an important role in shaping the associated neuropsychological deficit. (4) Cognitive and behavioural impairments result from the essential comorbidities of epilepsy which can be considered as much a disorder of cognition and behaviour as of seizures. (5) Patients' subjective complaints can help us understand objective cognitive impairments and their underlying neuroanatomy, resulting in improved patient care. At other times, patient complaints reflect other factors and require careful interpretation. (6) The results from a neuropsychological assessment can be used to maximize the educational and occupational potentials of people with epilepsy. (7) Not all patients are able to engage with a neuropsychological assessment. (8) There are limitations in assessments conducted in a second language with tests that have been standardized on different populations from that of the patient. (9) Adequate intervals between assessments maximize sensitivity to meaningful change. (10) Patients should be fully informed about the purpose of the assessment and have realistic expectations of the outcome prior to referral. [ABSTRACT FROM AUTHOR]

It is widely accepted that photosynthetic bacteria played a crucial role in Fe( II) oxidation and the precipitation of iron formations ( IF) during the Late Archean-Early Paleoproterozoic (2.7-2.4 Ga). It is less clear whether microbes similarly caused the deposition of the oldest IF at ca. 3.8 Ga, which would imply photosynthesis having already evolved by that time. Abiological alternatives, such as the direct oxidation of dissolved Fe( II) by ultraviolet radiation may have occurred, but its importance has been discounted in environments where the injection of high concentrations of dissolved iron directly into the photic zone led to chemical precipitation reactions that overwhelmed photooxidation rates. However, an outstanding possibility remains with respect to photochemical reactions occurring in the atmosphere that might generate hydrogen peroxide (H2O2), a recognized strong oxidant for ferrous iron. Here, we modeled the amount of H2O2 that could be produced in an Eoarchean atmosphere using updated solar fluxes and plausible CO2, O2, and CH4 mixing ratios. Irrespective of the atmospheric simulations, the upper limit of H2O2 rainout was calculated to be <106 molecules cm−2 s−1. Using conservative Fe( III) sedimentation rates predicted for submarine hydrothermal settings in the Eoarchean, we demonstrate that the flux of H2O2 was insufficient by several orders of magnitude to account for IF deposition (requiring ~1011 H2O2 molecules cm−2 s−1). This finding further constrains the plausible Fe( II) oxidation mechanisms in Eoarchean seawater, leaving, in our opinion, anoxygenic phototrophic Fe( II)-oxidizing micro-organisms the most likely mechanism responsible for Earth's oldest IF. [ABSTRACT FROM AUTHOR]