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Old paper samples are bleached using pulsed laser radiation with a wavelength of 532 nm. The ablation products of five paper samples that differ by composition and production dates are studied using Raman microspectroscopy. Cellulose, protein, calcite, titanium dioxide (anatase, rutile, and brookite), quartz, lazurite, bonattite, and dolomite are identified as ablation products. [ABSTRACT FROM AUTHOR]

Medium-coarse-crystalline dolomite is a major variant of dolomite, and its structural heterogeneity inside and outside the crystals makes it an ideal vehicle for studies of dolomite genesis, fluid evolution and elemental migration. In this paper, the medium-coarse crystalline dolomite from the fifth section of the Majiagou Formation of the Lower Ordos Basin was systematically studied by petrographic, cathodoluminescence and related geochemical methods. The rock is developed in the context of mud powder crystal dolomite and granular dolomite, possessing significant ring band structure, fluorite and quartz intergrowth. Compared with other dolomites, it is characterized by Fe and Mn enrichment and low Na and Sr contents, as well as a negative δEu anomaly and a strong negative δ18 O offset. Combined with the evolutionary history of diagenesis, it is believed that the medium-coarse-crystal dolomite is the end product of a series of diagenetic effects such as early dolomitization-atmospheric freshwater leaching-secondary burial recrystallization-deep burial dissolution. Electron microprobe analysis reveals the structural and compositional heterogeneity inside and outside the crystals. The formation of mediumcoarse- crystalline dolomite is associated with an increase in Fe-Mn content, a rise in the Mn/Sr ratio, a decrease in Sr, and a first rise and then a fall in Na concentration. This study provides a valuable reference for further research on the genesis of the medium-coarse crystalline dolomite. [ABSTRACT FROM AUTHOR]

Natural aggregates from sedimentary rock, like limestone and dolomite, are of a great use in various practical applications. To evaluate their quality, among others, the test of methylene blue adsorption (MB value) using a filter paper is recommended. However, one can consider it as a rough test. In this paper we wished to evaluate its quality by comparison with a more precise spectrophotometric method, i.e., to perform adsorption isotherms of methylene blue from aqueous solutions, as well as determine other parameters characterizing the aggregates. For this purpose, methylene blue adsorption on samples of limestone and dolomite natural aggregates having various grain sizes were studied to assess quality (fine particles content) of the manufactured aggregates. To determine the amount of adsorbed dye two methods were used: the methylene blue stain test and the dye adsorption from its solutions at various concentrations under static conditions. From the linear form of Langmuir adsorption isotherms of methylene blue, the monolayer capacity was determined, and then the specific surface areas of all fractions of aggregates. The structural (N2 adsorption/desorption), textural (SEM/EDS) and crystallographic structure of the aggregates were studied. It was determined that the MB values for 0–2 and MBF for 0–0.125 mm aggregates fractions fulfill the criteria set out in the specifications required for pavement construction. A very good repeatability of the adsorbed amount of methylene blue on the dolomite and limestone aggregates were obtained by these two different methods. These results confirm the reliability of the method blue test used typically in industrial conditions. The measured specific surface areas of limestone and dolomite using N2 adsorption (SBET) are smaller than SMB determined by methylene blue adsorption from aqueous solutions. This is because in aggregates, apart from calcite and dolomite, there is a small admixture of quartz and clay minerals. During N2 adsorption in dry condition, the external surface of the grains is determined, while in the aqueous solution of methylene blue, both the external and inner surfaces of clay minerals are determined. [ABSTRACT FROM AUTHOR]

Under tectonic stresses, shale in different stress–strain environments will undergo structural deformation of varying mechanisms and intensities, forming various types of tectonically deformed shales (TDSs). By changing pore structures, structural deformation significantly influences shale's reservoir properties and then the resource potentials. This paper aims to reveal the evolution rules and mechanisms of micro- and mesopore structures of various TDSs. We first propose a TDS classification scheme according to the differences in deformation features and deformation mechanisms. Then, N2 and CO2 adsorption tests were conducted on the whole rock and kerogen samples of various TDSs to reveal the pore structure evolutions of shale during structural deformations and investigate the contributions of organic pore changes. Finally, we studied the mineral composition differences between various TDSs and their effects on the evolutions of shale's micro- and mesopores. Results showed that compared with undeformed shale, weakly brittle deformed shale (BDS) experienced a significant reduction in micro- and mesopores, mainly resulting from the decrease of organic matter content caused by the development of tectonic fractures and the filling of hydrothermal minerals. In strongly BDSs, there was a noticeable decrease in micro- and mesopores from undeformed shale as well. Apart from the negative effects of increasing carbonate minerals, the increased clay minerals also caused a decrease in kerogen content and organic pores. The limited increases of pores from weakly BDSs to strongly BDSs is mainly due to the emerged interparticle pores during shale fragmentation. Ductile deformed shale showed a significant decrease in micro- and mesopores; the collapse of organic pores is the dominant mechanism, with the mixing of clay minerals being an important reason as well. As for the brittle–ductile deformed shale, the evolution of micro- and mesopores is the result of the increase of carbonate minerals and the compression of kerogen. [ABSTRACT FROM AUTHOR]

Deep and ultra-deep carbonate reservoirs are the focus of exploration and development in future. However, the problems of high pressures in the treatment process, a limited effective etching distance of acid, great acid leak-off, and poor adaptability of the acid system are encountered in this type of oil and gas reservoir. The mechanism of acid fracturing stimulation under different processes and parameters is not clear. Aiming at these issues, the treatment schemes, process optimization, parameter optimization, and liquid system screening are studied in this paper, try to clarify the acid fracturing stimulation mechanism, and the following conclusions are drawn: The acid network fracturing could activate natural fracture to generate a complex fracture network to the greatest extent, and thereby a high output could be achieved; By using of weighted fracturing fluid, the wellhead injection pressure, as well as the performance of equipment required, could be effectively reduced; With 20% gelling acid and 20% retarded acid system, the non-uniform etching could be realized to improve the effective etching distance of acid liquid. The conclusions in this paper shed light on the acid fracturing treatment of deep and ultra-deep carbonate rocks. [ABSTRACT FROM AUTHOR]

On 12th August 2015, a massive rapid long run-out rock landslide occurred in the Shanyang Vanadium Mine in Shaanxi Province, China, which claimed the lives of 65 miners. No heavy rainfalls, earthquakes, and mining blasts were recorded before the incident. Therefore, the failure mechanism and the cause of the long run-out movement are always in arguments. In this paper, we conducted a detailed field investigation, laboratory tests, block theory analysis, and numerical simulation to investigate the failure and long run-out mechanisms of the landslide. The field investigation results show that the source material of the rock landslide is a huge dolomite wedge block bedding on siliceous shale layers. Uniaxial compression tests indicate that the uniaxial compression strength of the intact dolomite is 130–140MPa and the dolomite shows a brittle failure mode. Due to the progressive downward erosion of the gully, the dolomite rock bridge at the slope toe became thinner. As the compression stress in the dolomite bridge increased to surpass its strength, the brittle failure of the bridge occurred. Then huge potential energy was released following the disintegration of the landslide, which led to the high acceleration of this rock landslide. The 3D discrete element simulation results suggest that the low intergranular friction contributes to the long run-out movement of this rock landslide. [ABSTRACT FROM AUTHOR]

Rock and gas outbursts occur most frequently in coal mining. Gas-induced geodynamic events in dolomite are a new and unexplored phenomenon. In the last time, two outbursts of gas and dolomite have occurred in the Legnica-Głogów Copper Region in southwestern Poland, which is one of the world's largest copper ore mining regions. Gas-induced geodynamic events are dependent on the co-occurrence of two factors: rock porosity, and the presence of gas under significant pressure in the pores and crevices of the rock. This paper presents a condensed energy balance for the phenomenon of outbursts of dolomites and gases. The quantity of energy depends on the type of transformation taking place during decompression. The work produced enables first the disintegration of the rock, and then its transportation along the mine working space. This paper has focused on the estimation of the energy required to disintegrate the rock. It has been estimated that 0.38 MJ is needed for the size reduction of 1 m3 of ejected mass. Highlights: In the case of a dolomite outburst, the energy is accumulated primarily in the form of compressed gas present in the porous structure of the rock and causes the rock to disintegrate and its transport along the mine working space. Gas decompression during a gas-induced geodynamic phenomena can be between isothermal and adiabatic. Existing disintegration theories: Rittinger's, Kick's and Bond's are based consists chiefly of crushing, compression or abrasion, caused by the action of external factors. Author's theory of disintegration of research on tensile stress and is based on Brazilian tests. The disintegration of 1 m3 of rock requires the production of energy of approximately 0.38 MJ. [ABSTRACT FROM AUTHOR]

During weathering and pedogenesis of carbonate rock with poor-uranium (U) and thorium (Th), U and Th present the characteristics of strong leaching (especially U) and significant residual enrichment, the cause of which is still unclear. In this paper, a weathering profile developed by dolomite in karst area of Guizhou province in southwest China was selected, which showed zonation characteristics of bedrock (Y), powdery rock (Yf), and soil layer (T1 to T12) from the bottom to up. Through the determination of the occurrence speciation of U and Th in Y and weathering profile, combined with mineralogical, geochemical characteristics, and element mass balance calculation, the constraints of U and Th speciation on the geochemical behavior of U and Th during the weathering of carbonate rock were revealed. The results proved that U and Th in Y preferentially existed in acid insoluble phase, for example, the contents of U and Th in Y were 0.90 mg·kg−1 and 0.28 mg·kg−1, respectively, while those in acid insoluble matter were 2.34 mg·kg−1 and 2.57 mg·kg−1, respectively, but because the mass percentage of acid insoluble matter was extremely low (0.95%), the mass percentages of U and Th in the acid soluble phase in the whole rock were absolutely superior (96% of U and 86% Th). The U and Th in the acid soluble phase of Y were mainly adsorbed on the crystal surface of carbonate minerals or existed in the cement, and the U and Th in the carbonate lattice only accounted for a small proportion. From Y to Yf with the initial dissolution, U and Th released from the surface of carbonate minerals and cements were in carbonate-rich alkaline environment, and these portions of U and Th were leached out, resulting in strong loss of U and Th in the Yf (the loss rates are 83% of U and 65% of Th, respectively). From the Yf to the overlying soil layer T1, the carbonate components were completely dissolved, and the U and Th released from the carbonate lattice showed different behaviors, where U was completely leached and Th tended to stay in the weathered residue. Thus, in the soil layer T1 formed by Y or Yf , the residual U was the inheritance of the U in the acid insoluble phase of Y; For Th, it not only inherited the Th of acid insoluble phase of Y, but also superimposed the Th from carbonate lattice in Y. On the other hand, during the evolution process from Y to Yf and to soil layer T1, with the dissolution of carbonate, the acid insoluble phase also showed a significant tendency of chemical weathering. However, the U and Th in the Y acid insoluble phase were not leached with the decomposition of the acid insoluble phase but were redistributed among the residual phases. For the geochemical behaviors of U and Th in the evolution of soil profile (T1~T12), they were subjected to the occurrence speciation of U and Th in T1 and the change of U and Th occurrence speciation with the upward direction of soil profile. The U and Th released from the carrier minerals were mainly redistributed among the residual solid phases, which weakened the intensity of their further loss. This study deepens the understanding of the geochemical behavior of radionuclides in karst environment and provides reference for the treatment of radioactive pollution in karst areas. [ABSTRACT FROM AUTHOR]

The Guizhou Province is located in karst mountainous area, so it is very important for the future layout and planning of the city to study the underground geological structure of the city based on seismic detection technology. In this paper, taking the underground active fault detection in the Liupanshui City, Guizhou Province, China as an example, a set of appropriate evaluation techniques for the accurate spatial location, structural characteristics and latest activities of the fault suit for mountainous area are proposed. Through pre-stack noise suppression, amplitude fidelity and consistency processing, and multiple iterative analysis of velocity residual statics, the resolution of the geological structure of the underground rock has been significantly improved. Based on the detailed interpretation of the shallow seismic data and the regional geological analysis, it is concluded that the main fault strike of the Weining – Shuicheng section of the Weining - Shuicheng fault is NW, mainly normal fault, the dip direction is mainly southwest, partly northeast and the dip angle is 60-70°. The strata of the two fault plates are strongly compressed and broken, and the limestone and dolomite are generally recrystallized, and calcite veins and masses can be seen. [ABSTRACT FROM AUTHOR]

Pore fluids control the diagenetic processes and storage spaces of deep clastic rock reservoirs and have become a major area of interest within the fields of sedimentology and petroleum geology. This paper aims to relate the diagenetic processes of the Oligocene Zhuhai sandstones in the Baiyun Sag to pore fluids varying with burial depth. The types and distribution patterns of authigenic minerals are investigated through analysis of petrographic, mineralogical, and geochemical features to illustrate the origin and flow patterns of pore fluids and their influences on reservoir diagenesis. Strong cementation of eogenetic carbonate cement near the sandstone–mudstone interface was a consequence of material migration from adjacent mudstones on a large scale. The pore fluids were mainly affected by microbial methanogenesis and carbonate mineral dissolution in adjacent mudstones during eogenesis. The pore fluids were diffusively transported in a relatively open geochemical system within a local range. Support for this model is provided by the heavier stable isotopic values present in eogenetic calcite and dolomite. Feldspar dissolution during early mesogenesis was spatially accompanied by the precipitation of authigenic quartz and ferroan carbonate cement. Pore fluids in this period were rich in organic acids and CO2, and their migration mechanism was diffusive transport. The obviously lighter carbon and oxygen isotopic compositions of the ferroan calcite support this inference. During late mesogenesis, the input of deep hydrothermal fluid might have been partly responsible for the precipitation of ankerite, barite and authigenic albite. Oil charging may have inhibited carbonate cementation and compaction, accordingly preserving porosity, and together with authigenic kaolinite, might have promoted the transition of the reservoir from water wet to oil wet to the benefit of oil entrapment. The findings reported here shed new light on the evaluation and prediction of sandstone reservoirs that have experienced multiple periods of fluid flow. [ABSTRACT FROM AUTHOR]

This paper investigates the origin of ultra-deep dolostone and the factors influencing large-scale dolostone reservoirs, focusing on the Sinian Dengying Formation and the Cambrian Longwangmiao Formation in the Sichuan Basin. The study involves petrology, microscale X-ray diffraction, trace element analysis, and C-O-Sr-Mg isotope experiments to provide a detailed analysis. The research findings indicate that the Dengying and Longwangmiao formations comprise six types of matrix dolostone and four types of cement. The Dengying Formation, which developed under a sedimentary background of a restricted platform, contains special microbial and microcrystalline dolostones. The dolomite grains are small (<30 µm) and have a low order degree (Min=0.55), with large unit cell parameters and an extremely high Na content (Max=788 ppm). The 87Sr/86Sr value of the dolostone is consistent with contemporaneous seawater, while the δ13C and δ18O values are lower than those of the contemporaneous seawater. The δ26Mg value is small (Min=−2.31‰). Powder crystal, fine-crystalline, and calcite dolostones with coarser and more ordered crystals exhibit similar δ13C and 87Sr/86Sr values to microbial and microcrystalline dolostone. During the sedimentary period of the Dengying Formation, ancient marine conditions were favorable for microbial survival. Microorganisms induced the direct precipitation of primary dolomite in seawater, forming microbial and microcrystalline dolostones during the seawater diagenesis period. During the subsequent diagenesis period, dolostones underwent the effects of dissolution-recrystallization, structures, and hydrothermal fluids. This resulted in the formation of dolostone with coarser crystals, a higher degree of order, and various types of cement. The Longwangmiao Formation was developed in an inter-platform beach characterized by special particle dolostone. The particle dolostone has a large grain size (>30 µm), high order degree (Min=0.7), small unit cell parameters, high Na content (Max=432 ppm), and low Fe and Mn content. The δ26Mg and δ13C values are consistent with the contemporaneous seawater, while the δ18O and 87Sr/86Sr values are higher than those of the contemporaneous seawater. There is mutual coupling between multiple-period varying δ26Mg values and sedimentary cycles. The dolostone in the Longwangmiao Formation resulted from the metasomatism of limestone by evaporated seawater. The thickness and scale of the dolostone in the Longwangmiao Formation are controlled by the periodic changes in sea level. The period of dolostone development from the Sinian to the Cambrian coincides with the transition from Rodinia's breakup to Gondwana's convergence. These events have resulted in vastly different marine properties, microbial activities, and sedimentary climate backgrounds between the Sinian and the Cambrian. These differences may be the fundamental factors leading to the distinct origins of dolostone formed in the two periods. The distribution of sedimentary facies and deep tectonic activities in the Sichuan Basin from the Sinian to the Cambrian is influenced by the breakup and convergence of the supercontinent. This process plays a key role in determining the distribution, pore formation, preservation, and adjustment mechanisms of ultra-deep dolostone reservoirs. To effectively analyze the genesis and reservoir mechanisms of ultra-deep dolostone in other regions or layers, especially during the specific period of supercontinent breakup and convergence, it is crucial to consider the comprehensive characteristics of seawater properties, microbial activities, sedimentary environment, and fault systems driven by tectonic activities. This can help predict the distribution of high-quality and large-scale ultra-deep dolostone reservoirs. [ABSTRACT FROM AUTHOR]

The use of the calcareous soil as a backfill material in ocean constructions faces pervasive challenges due to the significant rate of particle fracture. To meet the requirements of marine ecological protection, a bio-cementing technique, microbially induced carbonate precipitation (MICP), has emerged as a green method for improving the soil properties of calcareous sands. This paper presents a detailed study on the effect of MICP on the fracture behaviours of calcareous particles and its treating mechanism at microscopic scale level. First, individual calcareous and dolomite particles were treated by MICP for different numbers of rounds. The increase ratio of the particle mass and the filling degree of the intra-particle pores were then measured to evaluate the treatment effect of MICP on individual sand particles. Combining with scanning electron microscopy measurements of the evolution of the particle morphology and internal microstructures of the calcareous particles, the intra-particle pore filling effect as well as the surface coating effect induced by MICP treatment were directly observed. Finally, a series of single-particle crushing tests indicated that the intra-particle pore filling effect of MICP rather than the surface coating effect played the dominant role in improving the fracture pattern and fracture strength of calcareous sand particles. [ABSTRACT FROM AUTHOR]

In this paper, we present mineralogical, whole-rock geochemical, Sr and Pb isotopic, and zircon trace elemental and U–Pb geochronological data for the newly-discovered Pengco listvenite in central Tibet, in an attempt to probe the petrogenesis of listvenite and the tectonic environment. The listvenite is composed of magnesite, quartz and minor dolomite and Cr-spinel. Chemistry of abundant protogenetic Cr-spinel in the Pengco listvenite as well as the whole-rock Cr and Ni concentrations and low rare-earth element contents indicates the harzburgite protolith. Addition of Ca and K and redistribution of Si at sample scale suggest that the formation of Pengco listvenite was not an isochemical process. Serpentinization could partly accounts for the enrichments in some fluid mobile elements before listvenitization. The εHf(t) values of xenocrystic zircons in the Pengco listvenite are dominantly negative, suggesting a continental crustal source. The zircon age spectra and high whole-rock initial 87Sr/86Sr values (0.7094–0.7107, and one up to 0.7193) and high 207Pb/204Pb (15.750–15.759), 208Pb/204Pb (39.145–39.215) and 206Pb/204Pb (18.542–18.567) of the Pengco listvenite are similar to those of the Qiangtang continental sediments/upper crust, indicating the terrigenous source of reactant fluids and fluid-assisted solid-state transfer during the formation of listvenite. The Pengco listvenite is likely formed in the forearc extensional environment of the Bangong Meso-Tethyan ocean during the Late Jurassic. [ABSTRACT FROM AUTHOR]

The deep-burial Ordovician carbonate reservoirs in the Yangshuiwu area (Jizhong Depression) have shown significant hydrocarbon potential since 2016. In this paper, based on the systematic investigation of characteristics and diagenesis of the reservoirs using cores, thin sections, logging, drilling, and geochemical analysis, their controlling factors and formation mechanism were discussed. The three high-quality reservoir belts (RBs) developed in the Ordovician strata are named RB1 (karst reservoirs), RB2 and RB3 (dolostone reservoirs) from top to bottom, each with its own set of pores, vugs, caves, and fractures. The results show that dolostones have relatively higher porosity and permeability than limestones and breccias. Unfilled and partly filled fractures, in particular, multiply enhance reservoir permeability. Additionally, the diagenetic paragenesis developed in marine, meteoric, and burial environments leads to the porosity evolution of Ordovician carbonates, mainly including compaction, calcite cementation, dolomitization, dissolution, and fracturing. Notably, sedimentation and dolomitization controlled by sea-level fluctuations are critical for the reservoirs formation. The tidal-flat sequence of each cycle of sea-level fluctuations influences their distribution. Subaerial meteoric water dissolution triggered by the Late Ordovician uplift plays an important role in the RB1, but has a negligible effect on the RB2 and RB3. Most importantly, the conductive high-angle fractures induced by the activities of the Yangshuiwu and Hexiwu faults from the Eocene to Pliocene can enhance all RBs potential, contributing to the ultimate reservoir quality. Therefore, a four-stage theoretical development model of the Ordovician reservoirs was established in combination with the tectonic background. [ABSTRACT FROM AUTHOR]

Limestone is a widely used natural building material, and its physical and mechanical properties can change greatly when exposed to high-temperature heat sources. In this paper, limestone samples from Linyi City, Shandong Province, were selected and some of them were heated to 650 °C at different heating rates (4, 6, and 8 °C min−1), while the rest of the samples were heated cyclically (200, 300, 400, 500, 600, and 650 °C) at a heating rate of 8 °C min−1, and the acoustic emission (AE) signals were recorded throughout. The results show that the AE signal rate increases with increases in temperature, and the AE signal increases rapidly at 300 °C and 500 °C because of the thermal decomposition of dolomite and calcite. There is a negative correlation between the heating rate and the AE signal rate. The high-frequency data and high-amplitude data generated by AE are negatively correlated with the heating rate. With the increase in the heating rate, AE counts and cumulative AE counts decrease significantly. [ABSTRACT FROM AUTHOR]

This paper describes the stratiform fluorite and fluorite–base-metal mineralization within the Baikal area, Aldan Shield, Sette-Daban Ridge, and Omulyovka uplift in the Kolyma region. It is assumed to have developed in the Bureya, Khanka, and East Chukchi massifs. Fluorite was concentrated in terrigenous–carbonate rocks of the predominant dolomite range, in the shallow shelf zones separated from the open sea by coral reefs. The fluorite accumulation within layers and horizons at the diagenesis stage was followed by its redistribution with the formation of commercial ore bodies at the catagenesis stage. The Baikal stratiform fluorite mineralization is typical for stratiform deposits of fluorite–base-metal ores. The Aldan type occurs as deposits of high-quality fluorite ores in the carbonate cover of the Siberian Platform. The examples of typical deposits are considered and the forecast fluorite resources are estimated. [ABSTRACT FROM AUTHOR]

The purpose of this paper was to propose a method to predict shear-wave velocities in the process of AVO (amplitude variation with offset) inversion, to interpret seismic converted-wave data, and to match reservoir engineering information with seismic data in regions without shear-wave velocities. During CO2 flooding and sequestration, the shear-wave velocity varies with the pressure that is caused by fluid injection. Predictions of how the shear-wave velocity changes with pressure can be used to interpret 4D seismic monitoring data during different stages of CO2 injection. To verify the calculations, the authors used the characteristic parameters of the Marly dolomite and Vuggy limestone units of the Weyburn Oilfield reservoir in Canada. The Digby's model and Gassmann's equation were used to evaluate the dependence of the shear-wave velocity on the pressure in the carbonate rock formation. The authors have developed a new method for calculating the coordination number of the model and supplement the results with a shale correction, enabling the prediction to match the measured shear-wave velocities more closely. Our method is verified by dipole sonic logging data and petrophysical test data from the Weyburn Oilfield. When applied to petrophysical test data, the average error is below 5%. When the method is applied to well log data, the average error in the porous media is 3.014% in the Marly unit and 6.288% in the Vuggy unit. [ABSTRACT FROM AUTHOR]

This paper presents new age estimates and results obtained by the chemostratigraphic study of dolostones of the Billyakh Group, which consists of the Kotuikan and the Yusmastakh formations. The Billyakh Group forms the upper part of the Riphean section of the Anabar uplift in northern Siberia. The stepwise dissolution technique was used for the first time to determine the 87Sr/86Sr, 206Pb/204Pb, and 207Pb/204Pb isotopic ratios in dolostones. The Rb‒Sr systematics was studied by the chemical removal of about a third of the crushed sample (fraction L1) by the preliminary acid leaching in 0.2 N CH3COOH and the subsequent partial dissolution (fraction L2) of the remaining part of the sample in CH3COOH with the same concentration. The Pb‒Pb isotope systematics of dolostones was studied by the six-step dissolution of crushed samples in 0.5 N HBr. These procedures led to the removal of secondary carbonate material and greatly improved the quality of Sr chemostratigraphic and geochronological information. The initial 87Sr/86Sr ratios of the least altered carbonate material (fraction L2) of the Billyakh Group dolostones are 0.70502 ± 0.00029 in the Kotuikan Formation, 0.70519 ± 0.00026 in the lower subformation of the Yusmastakh Formation, and 0.70511 ± 0.00018 in the upper subformation of the Yusmastakh Formation. The Pb‒Pb age of early diagenesis of Kotuikan and Yusmastakh dolostones (1519 ± 18 Ma at MSWD = 1.8) was calculated from the results obtained for carbonate fractions L3–L6. Secondary carbonate fractions L1‒L2 are characterized by a Pb‒Pb age of 1466 ± 54 Ma at MSWD = 0.6. The δ13C values vary from ‒1 to ‒0.4‰ in dolostones of the Kotuikan Formation and from ‒0.4 to +0.8‰ in those of the Yusmastakh Formation (from ‒0.1 to +0.4‰ in the lower subformation and from ‒0.4 to +0.8‰ in the upper subformation). Comparison of these variations, as well as variations in the initial 87Sr/86Sr ratios in dolostones of the Kotuikan Formation and the Lower and Upper Yusmastakh subformations (0.70460‒0.70499, 0.70450‒0.70525, and 0.70462‒0.70523, respectively), does not make it possible to distinguish these units on the basis of chemostratigraphic characteristics. [ABSTRACT FROM AUTHOR]

In the Transdanubian Range (Hungary), a wide spectrum of Triassic dolomites is known. Mechanism of dolomitization of the platform carbonate successions was subject of a number of studies but the study of dolomitization of basinal carbonates is very limited. Petrographical and isotope–geochemical characteristics of the Upper Triassic dolomitized carbonate deposits, formed in a fault-controlled intraplatform basin, and interpretation of the dolomite-forming processes are presented in the current paper. From the latest Carnian to Middle Norian under semi-arid climatic conditions density-driven flux of seawater derived mesohaline fluids was the dominant mechanism of the near-surface pervasive dolomitization of the thick platform carbonate succession. In the late Middle Norian incipient rifting of the Alpine Tethys led to establishment of an extensional structural regime and onset of the formation of the Kössen Basin. In the study area, above the dolomitized platform carbonate succession, platform-derived carbonate sediments were accumulated in a fault-bounded, semi-restricted sub-basin of the Kössen Basin, whereas talus breccias and debrites were deposited near a basin-bounding master fault. The basin deposits (lower and upper members of the Rezi Dolomite Formation) were subject of early diagenetic dolomitization in shallow burial setting. Enhanced salinity seawater was the dolomitizing fluid; the synsedimentary fracturing may have promoted the fluid flow and thereby the dolomitization. Thick-bedded carbonates (middle member of the Rezi Dolomite Formation) representing a progradational tongue of the ambient platform are intercalated between the basin deposits. The dolomitization of this unit can be explained by the reflux model. [ABSTRACT FROM AUTHOR]

To characterize the polyphase palaeokarst development of Wumishan formation in Jizhong depression, the data of outcrops, cores, thin sections, SEM, core plugs, drilling relief and leakage, and carbon isotope have been analyzed in this paper. The results reveal that the polyphase palaeokarst was petrography controlled of microbial dolostone and grain dolostone, and was identified as three phases: (1) poly-period eogenetic karst during Wumishan depositional environment, (2) two-period telogenetic karst in Triassic and Cretaceous, and (3) hydrothermal karst in Paleogene. The eogenetic karst was related to high frequent sea level fluctuations with development of vugs and selective dissolution porosities which distributed at the top of microbial dolostone and grain dolostone layers. The origin of the telogenetic karst was related to Indosinian and Yanshan orogeny which formed widespread fold belts and thrust faults, and provided the endokinetic force and a strong topography difference. Each period's telogenetic karst was characteristic of one-period fracture-cave system, and the Cretaceous telogenetic karst was stronger than the Triassic telogenetic karst in karst intensity. Moreover, the karst intensity increased downward in superimposed telogenetic karst zones. Hydrothermal karst was related to volcanic activities and provided the hydrothermal environment for its formation. It was featured by solution-enlarged porosities and new forming porosities. The microbial dolostone and grain dolostone layers with three-phase palaeokarst were the best exploration targets for high-quality reservoirs. This paper rebuilds a suitable karst model to show the palaeokarst evolution process. [ABSTRACT FROM AUTHOR]

Dolomites are well-known minerals; belonging to the Infra-Cambrian Hormuz Series lies within the salt domes of southern Iran. In this paper, the origin and alteration of dolomitic rocks of Paskhand and Deh-kuyeh salt diapirs in the area of Larestan (southern Iran) are investigated. Based on petrographic (size and fabric) studies, we recognize four dolomite types that consist of very fine-to-fine crystalline dolomite (D1), neomorphic dolomite (D2), fine-to-medium crystalline euhedral-to-subhedral dolomite (D3), and pore- and fracture-filling dolomite (D4). The dolomite samples with up to 26% iron can be called ferruginous dolomites. Some igneous rock patches to gehter with hydrothermal iron veins are observable in the salt domes of Larestan. Oxygen and carbon isotope values of black and white, and altered red dolomite of Paskhand and Deh-kuyeh salt domes, are equal to − 12.35 to − 18.78 for δ18OPDB and − 5.48 to − 8.49 for δ13CPDB; values enriched δ180 with low-temperature (~ 70 °C) conditions are related to D1 dolomites and values depleted δ180 with higher temperatures (~ 270 °C) are related to D3 and D4 dolomites. The most important source for secondary dolomites is deeper hydrothermal and catchment sources, which ascended through faults during the intrusion. Meteoric waters can be mentioned as less important sources for these types of dolomites. We reported sassolite B(OH)3 mineral in Deh-kuyeh salt diapir for the first time in this paper. This mineral is only observed in the areas which have famous riftings Fumarol. Therefore, in this paper, the existence of sassolite in the studied area could be considered one of the most important the origin of the composing elements of Hormuz rocks from fumarols which are formed in an extensional regime. [ABSTRACT FROM AUTHOR]

The Upper Permian Changhsing Formation is one of the most important gas-bearing formations in the Eastern Sichuan Basin. Nonetheless, the primary factors controlling the reef-shoal gas reservoirs of different regions are diverse. Clarifying the controlling factors for the formation of intra-platform reef-shoal reservoirs will promote the exploration and development process of the Changhsing Formation. By using outcrop data, core observation, thin section identification, scanning electron microscope analysis, physical property study, and logging interpretation, this paper analyse the characteristics and factors controlling the reef-shoal reservoir in Dianjiang area of the Eastern Sichuan Basin. The results show that the reef cap and reef base microfacies fine-to-medium crystalline dolomite reservoir have the best physical properties, and the reservoir spaces are primarily composed of intercrystalline pores, intercrystalline solution pores, karst caves, and fractures. The main lithology of reservoir formation is reef-shoal facies. The results for the carbon and oxygen isotopes show that dolomites of different particle sizes are formed in three environments. Affected by regression in the late Changhsingian Age, the reef-shoal of the Changhsing Formation were subaerially exposed to meteoric water diagenesis environments, resulting in the highly dispersed particles in rocks that formed a honeycomb karst system, which greatly improved the physical properties of the reservoirs. After reflux dolomitization, the honeycomb karst system was well preserved due to strong resistance to pressure and dissolution of dolomite. Therefore, dolomitization in the Changhsing formation contributed to reservoir porosity. Later, tectonic fracturing has adjusted and modified the reef-shoal reservoir. In summary, penecontemporaneous karstification was the key to the formation of the reef-shoal reservoir. [ABSTRACT FROM AUTHOR]

The dolomite explosion in the terminal Ediacaran period has great geological significance for understanding the paleoenvironmental evolution of the Precambrian-Cambrian transition. However, dolomite origins remain controversial. Abundant dolomites in the Ediacaran Dengying Formation in the northern Yangtze Block provide a window for solving the problem. In this paper, the genesis of dolomites and the paleoenvironment of the terminal Ediacaran were studied by facies, trace elements (including rare earth elements, REEs), and carbon, oxygen, and strontium isotopes of the Dengying Formation in the Xichuan area of South Qinling, Northern Yangtze Block. The results indicate that the Dengying Formation was deposited on a carbonate platform, and four types of dolomite (i.e., micro-crystalline dolomite, fine-medium crystalline dolomite, brecciated dolomite, and saddle dolomite) are identified. According to the differences in the ∑REEs, δ13C, Z value and 87Sr/86Sr values in different types of dolomite, it is concluded that micro-crystalline dolomite mainly formed in the early diagenetic stage, fine-medium crystalline dolomite in the middle diagenetic stage, and saddle dolomite in the late diagenetic stage, while brecciated dolomite formed in the epigenetic stage. Moreover, it is determined that the dolomitization models for the Dengying Formation include the seepage-reflux, mixed water, burial, and hydrothermal dolomitization models. In addition, micro-crystalline dolomite has a Sr/Ba value far greater than 1, the Z value is usually greater than 125, δEu is positive, V/(V + Ni) is less than 0.74, and δ13C is positive, indicating that the Dengying Formation dolomite was deposited in a shallow water environment with high salinity, weak oxidation, and dry and warm climate. By comparing the characteristics of dolomite in other parts of the world in the same period, it indicates that the global climate warmed up, the ocean appeared oxygenation process, and extensive retrogression events occurred in the Precambrian-Cambrian boundary. [ABSTRACT FROM AUTHOR]

Recently, special attention has been drawn to the high-salt argillaceous dolomite reservoir in Jianghan basin, China due to its abundant oil resources with complex geological conditions. However, the current production methods used to develop this reservoir are not efficient with low throughput. Hence, the purpose of this paper is to explore the main possible reasons affecting the oil well productivity and determine suitable field development method for the target oilfield through experimental and numerical simulation approaches. The mercury injection capillary pressure (MICP) test results indicate that the average pore radius of samples is 0.0144 μm, and pore size distribution (PSD) results from MICP indicate that single peaks appeared in the PSD curves of the pore type samples. Permeability peaks of the samples range from 0.01 to 0.03 μm, and mesopores make most of the permeability contribution of the samples, which also reveals the low-permeability and porosity characteristics of the target oilfield. The results of core stress sensitivity tests show that the largest permeability damage rate is 98.97% with an average permeability damage rate of 98.37% while the maximum porosity damage rate is less than 10% with an average damage rate of 5.57% during the process of depressurization. The results of Non-Darcy percolation experiment indicate that threshold pressure gradient testing by water is about 0.03 MPa/m, which is close to the actual situation of the target oilfield. Numerical simulation method that considers the impact of threshold pressure gradient and stress sensitivity were established to study flooding patterns deployment for the research area. The simulation results show that performing water alternating gas flooding (WAG) by using CO2 is recommended for the development of the high-salt reservoir with inverse five-spot flooding pattern made up of 400 m well spacing in X-direction and 150 m row spacing. [ABSTRACT FROM AUTHOR]

Enhanced oil recovery in carbonates due to wettability alteration has received much attention recently. In contrast to sandstones reservoirs, carbonates are neutralwet or preferentially oil-wet. The use of CO2 dissolved into water has emerged as an alternative method for EOR operations in carbonates reservoirs. In the present paper, oil recovery from two carbonate outcrop rocks was evaluated with different brines containing CO2. The evaluation included a qualitative approach by spontaneous imbibition tests and a quantitative assessment by the Amott-Harvey index. The rocks tested were limestone and dolomite samples known as analogous to Brazilian pre-salt reservoirs. The testing fluids were a medium gravity crude oil, seawater concentration brine, formation equivalent brine and the carbonated version of these brines. Results shown additional oil recovery directly associated with wettability alteration driven by brine concentration switches. Oil recovery increases were observed independently if the brine concentration decreased or increased over the water replacement process. Wettability alteration took place in both carbonate types starting at oil-wet to neutral-wet conditions. Similar tests carried out with equivalent carbonated brines showed similar alterations in the wetting properties, trending no dependence on salt concentration. However, CO2 and its derived ions dissolved in the brines seem to inhibit the wettability alteration mechanism. [ABSTRACT FROM AUTHOR]

The analysis of mechanisms which affect the formation of agglomerates and determine the granulation process in a broad sense encounters difficulties related to the many ways of the formation of granules. The aim of the study was to perform a qualitative and quantitative analysis of granulation mechanisms with special reference to agglomerates' disintegration in the disc granulation process. This paper contains an analysis of disintegration mechanisms (abrasion and crushing) of agglomerates during the disc granulation of dolomite. The analysis of the mechanisms taking place during the process concerns the granulation stage after wetting. During the research, each time after the wetting stage, the size fraction 10-12.5 mm was substituted with an analogous fraction wetted by means of an aqueous solution of a coloring agent and the process was continued. After the specified time of granulation, the obtained product was sieved through laboratory sieves and then the content of the provided coloring agent in different size fractions was analyzed by means of a spectrophotometer. Measuring the absorbance of the analyzed samples and granulometric composition of the bed, the level and cause of the migration of material of the tested fraction into other size classes were determined, and at the same time, the occurring granulation mechanisms were analyzed. The proposed model and measurement method consisting of determining the absorbance of the tested granulometric fraction enable the qualitative and quantitative analysis of granulation mechanisms are encountered during the carrying-out of the process after wetting the bed. [ABSTRACT FROM AUTHOR]

Many buried karst areas in Iran, and in other parts of the world have not yet been mapped using detailed geological or geophysical studies to delineate susceptibility to sinkhole development. The purpose of this paper is to investigate the possibility of using the results of hydrogeochemical analysis with routine measurements of physicochemical parameters to evaluate and detect areas prone to sinkhole develop. Sixteen spatial maps were prepared using analyzed data from 77 water samples from monitoring water wells in the Kabudar Ahang, Razan, and Qahavand (KRQ) sub-catchments of the Hamadan province, western Iran. By use of geographic information system tools 16 thematic maps for physicochemical parameters (EC, pH., TDS, and groundwater temperature), major cations (Ca2+, Mg2+, Na+, and K+), anions (HCO−3, SO42−, NO3−, and Cl−), and calcite, dolomite, gypsum, and partial pressure of CO2 saturation indices (SIC, SID, SIG, and SIpCO2) were prepared. It was hypothesized that the anomalies of each parameter concentration could be consistent with sinkhole prone areas. To evaluate this assumption, the area under the Receiver Operating Characteristic (ROC) curve was calculated by 100 points as a true sinkhole pixel (50 positive true) and non-sinkhole point (50 true negative). The areas under curve of ROC for these thematic maps were calculated for the 16 variables. Results show that the dolomite and calcite saturation indices (0.49 and 0.43, respectively) are poor indicators, whereas HCO−3 and pCO2 saturation indexes (0.83 and 0.78, respectively) are good indicators of sinkhole susceptibility in the study area. The result confirmed application of hydrogeochemical anomaly analyses and the ROC validation method in covered karst can be a useful tool for prediction of sinkhole prone zones forming in region, where sparse data are available. [ABSTRACT FROM AUTHOR]

In this paper, magnesium hydroxide has been obtained from seawater by a well-known industrial process which involves the chemical reaction between magnesium ions of seawater with dolomite lime to produce the magnesium hydroxide precipitate. Furthermore, the precipitate was modified by ultrasound of high intensity. The purpose was to obtain magnesium hydroxide with high purity and reduced particle size without agglomeration. The precipitated magnesium hydroxide is characterized by the particle size distribution determined by the laser scattering method in the range of 20 nm–2 mm, and by the SEM analysis. Likewise, in order to investigate the effect of particle size on the thermal stability, thermokinetic study of magnesium hydroxide samples was performed by non-isothermal thermogravimetry in an inert atmosphere at different heating rates. The gained thermogravimetric data were utilized for the kinetic analysis, which was performed by using the isoconversional Friedman method in combination with the multivariate nonlinear regression method. For each degradation stage of investigated samples, kinetic parameters (activation energy, pre-exponential factor and kinetic model) were calculated and compared. [ABSTRACT FROM AUTHOR]

Acid-fracture conductivity has a major impact on acid-fracturing effects. In this paper, influences of acid concentration, temperature, and closure-stress loading time on conductivity under different acid-fluid systems have been researched based on experimental analysis for deep limy dolomite reservoirs. The measured conductivity showed high correlation and specific changing patterns with the above factors. Quantified relationships and equations between the conductivity and these factors were suggested in this paper. Additionally, a strong acid-etching effect caused by crosslinked acid and diverting acid has been observed during the tests. This could lead to high conductivity as well as broken rocks due to pressing with high-concentration acid. In this study, a 50-hour long-term conductivity test has been designed under the closure stress of 60 MPa which was closest to the actual reservoir conditions. The results showed that conductivity retention rate for each test group is less than 40%. By establishing assessment criteria of long-term and short-term conductivity based on the conductivity retention rate, linear relationships with high correlation and quantified equations of the conductivity retention rate in the same acid-rock reaction system could be obtained. [ABSTRACT FROM AUTHOR]

The genesis of the fine crystalline dolomites that exhibit good to excellent reservoir properties in the upper fourth member of the Eocene Shahejie Formation (Es) around the Sikou Sag, Bohai Bay Basin, is uncertain. This paper investigates the formation mechanisms of this fine crystalline dolomite using XRD, SEM, thin section analysis and geochemical data. The stratigraphy of the Sikou lacustrine carbonate is dominated by the repetition of metre-scale, high-frequency deposition cycles, and the amount of dolomite within a cycle increases upward from the cycle bottom. These dolomite crystals are 2-30 μm in length, subhedral to anhedral in shape and typically replace both grains and matrix. They also occur as rim cement and have thin lamellae within ooid cortices. Textural relations indicate that the dolomite predates equant sparry calcite cement and coarse calcite cement. The Sr concentrations of dolomites range from 900 to 1200 ppm. Dolomite δO values (−11.3 to −8.2 ‰ PDB) are depleted relative to calcite mudstone (−8.3 to −5.4 ‰ PDB) that precipitated from lake water, while δC values (0.06-1.74 ‰ PDB) are within the normal range of calcite mudstone values (−2.13 to 1.99 ‰ PDB). High Sr/Sr values (0.710210-0.710844) indicate that amounts of Ca and Mg have been derived from the chemical weathering of Palaeozoic carbonate bedrocks. The high strontium concentration indicates that hypersaline conditions were maintained during the formation of the dolomites and that the dolomites were formed by the replacement of precursor calcite or by direct precipitation. [ABSTRACT FROM AUTHOR]

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Dolomite is the most important component of the prolific reservoirs in the Ma55 to Ma51 submembers of the Ordovician Majiagou Formation in the central Yishan Slope, Ordos Basin. However, the origins of the different types of dolomite are unclear because of the different diagenetic environments and complex diagenetic fluids. This paper mainly focuses on the diagenetic environment and diagenetic fluid associated with the dolomite. The petrographic features of the dolomite were studied on the basis of core observation and thin section identification. Geochemical characteristics were analyzed according to the O, C and Sr stable isotopes and major and trace elements. The results demonstrate that, petrographically, the dolomite can be divided into four types, namely, type 1, type 2, type 3 and type 4. Type 1 is mainly characterized by dolomite with gypsum and salt dissolution as well as breccia structures with no clay minerals filling between breccia clasts. Type 2 is characterized by powder-fine crystalline dolomite with apparent residual textures and residual intergranular and intercrystal pores. Type 3 is characterized by leopard limestone or dolomite with leopard textures and massive bioborings. Finally, type 4 is characterized by karst breccia dolomite with many fractures and caves filled by abundant terrigenous clay minerals. In combination with the petrographic data, analysis of the geochemical data reveals that the type 1 dolomite formed in an early near-surface diagenetic environment and the diagenetic fluid might have been early freshwater. Type 2 and type 3 dolomite formed in a shallow-burial diagenetic environment. The diagenetic fluid of type 2 dolomite might have been hypersaline brine that was influenced by freshwater, but that of type 3 dolomite might have been a mixed fluid consisting of seawater and freshwater, which was less saline than the type 2 dolomite fluid. Type 4 dolomite formed in an epidiagenetic near-surface environment and the diagenetic fluid might have been superficial freshwater carrying abundant terrigenous clay minerals. The study shows that the analysis of the diagenetic environment and fluid of dolomite has great significance for research on dolomite origins. The porosity and permeability values of the four types of dolostone reservoirs indicate that type 1 dolomite reservoirs are the best reservoir, type 2 dolomite reservoirs have good physical properties, type 4 dolomite reservoirs are relatively good reservoirs, and the worst reservoir is the type 3 dolomite reservoirs. [ABSTRACT FROM AUTHOR]

Design block size is of vital importance for rockfall countermeasure design. According to the Austrian normative document ONR 24810, the design block is specified as fractile (V95-V98) of the block size distribution depending on rockfall frequency. For rock formations, which form very large rockfall blocks (> 10 m3), the use of fractiles V95–V98 appears too high with regard to economically justifiable protective measures. The paper deals with the determination of design blocks for the Dachstein Formation on the basis of data from three Austrian test regions. The formation's bedded limestone represents a key rock of the eastern part of the Northern Calcareous Alps and is very common along some major transport routes. A range of design blocks is derived from a synopsis of block size distributions, magnitude-frequency relations, and considerations about the rockfall barriers' service life. In the process, the knowledge of the return period of the determinated design block is considered more important than the overall rockfall frequency. Analyzing available rockfall event data and block size distributions, it is possible to identify a return period of 21–26 years for a rockfall event ≥ 1 m3/1000 m route section. Thus, such events are rare. Events that affect the V97–V100 fractiles of the block size distribution are even rarer; they yield very large design block volumes, which show return periods > 100 years. For the bedded Dachstein limestone of the test areas, the application of the fractiles V95–V96 (0.15–2.25 m3) is useful for adapting the return period of the design block to the working life of the rock fall barrier (25–50 years). [ABSTRACT FROM AUTHOR]

Water in Central Asia is a precious resource in the semiarid and arid environments in which people live in the region. Understanding the groundwater quality is important as it is the main factor determining its suitability for drinking and agricultural purposes. This paper presents results of a groundwater hydrochemical assessment in the Herat City by measuring its physicochemical parameters: major cations and anions, pH, total dissolved solids and electrical conductivity. In the light of progressive depletion of groundwater reservoirs and water quality deterioration, an investigation of dissolved major constituents in 27 groundwater samples was performed. The objective was detection of processes for geochemical assessment throughout the area. Herat City has been intensively inhabited during the last decenniums, leading to expansion of the residential and agricultural areas. Besides semi-aridity, rapid social and economic development stimulates greater demand for water, which is gradually fulfilled by groundwater extraction. Groundwater of the study area are characterized by the dominance of Ca + Mg over Na + K. , which was found to be the dominant anion, followed by Cl– and . The hydrochemical types in the area can be divided into two major groups: the first group includes mixed Ca–Mg–Cl and Ca–Cl types. The second group comprises mixed Ca–Na–HCO3 and Ca–HCO3 types. Calcite and aragonite have high SI values, which indicates precipitation as the result of evaporation, whereas dolomite shows an undersaturation state. Most of the samples are within the permissible limit of WHO standards. Interpretation of data suggests that weathering, ion exchange reactions, and evaporation to some extent are the dominant factors that determine the groundwater chemistry in the study area. [ABSTRACT FROM AUTHOR]

Methods of composite mechanics were used to evaluate the effective elastic moduli and Biot's parameter of porous media. Natural composites — dolomites and hyaloclastites — were considered as examples, which were also examined experimentally. The microscopic structure of the rocks was studied under a microscope, and their mineral composition was determined by the X-ray diffractometry. A comparison of experimental and calculated elastic moduli of dolomites showed their good agreement, which proved that the averaging method can be used to rapidly evaluate their effective elastic properties. For dolomites, Young's modulus and Biot's parameter were determined as functions of porosity using the calculation results and experimental data. The computation method described in this paper allows one to calculate Biot's tensor in the general case of an anisotropic and inhomogeneous matrix and to evaluate the influence of pore shape on stresses and strains at the microlevel, which is not possible by experimental methods. Using samples of hyaloclastites with round and angular pores, the effect of pore shape on the elastic moduli and the effective stress coefficient was investigated. The effect of pore orientation was also studied using anisotropic dolomite samples with elongated pores. [ABSTRACT FROM AUTHOR]

In this paper, two types of reinforcement agents of fibrous palygorskite (PAL) and rhombohedral dolomite (DOL) have been used together by simply mixing in order to improve the mechanical and thermal properties of waterborne polyurethane (WPU). A great synergistic effect between 1D PAL and 3D DOL on reinforcing WPU matrix has been observed. In comparison to neat WPU, the tensile strength of such three components WPU-based composite has been significantly improved by 178% with an addition of 4 wt% PAL and 6 wt% DOL. Furthermore, its initial decomposition temperature also has been increased 55 °C. The formation of 3D conjugated filler network with 1D PAL inserted into the 3D DOL network could be attributed to such synergistic reinforcement of WPU. This work provides a good example and eco-friendly pathway for the preparation of high performance polymer composites by simply using micro/nano-fillers with different dimension together. [ABSTRACT FROM AUTHOR]

This paper takes the thick and widely distributed crystal dolomite of Xixiangchi Formation, Upper Cambrian in Southeastern Sichuan basin as an example, the reservoir characteristics and main controlling factors of crystal dolomite have been analyzed systematically, and the genesis and reservoir formation mechanism of crystal dolomite have been discussed. It shows that the main reservoir rocks of crystal dolomite include powder crystalline dolomite and finely crystalline dolomites, and the intercrystal pores and dissolved intercrystal pores are the main reservoir spaces, with few dissolved vugs and fractures developed in the reservoir. The pore structure analysis shows that the throats of crystal dolomite reservoir are mainly lamellar, reflecting a good configuration between pores and throats, medium- low porosity and low permeability, representing typical porous-type reservoir. Dolomitization analysis indicates that the dolomitization occurred in the penecontemporaneous or early diagenetic stage. The degree of dolomitization decreased gradually from the top to the bottom in each sedimentary cycle, and distribution of dolomite in the study area shows that the content of dolomites decreases from the west to the east, which reflects the degree of dolomitization weakening eastward. Combined with the geochemical research of crystal dolomite, the C and O isotope data reflect the same characteristics of seawater during the late Cambrian. It indicates that the dolomitization might be related to the seepage-reflux of seawater in the early time. Recrystallization played an important role in the genesis of the crystal dolomite, because most of crystal dolomites remain residual granular texture. The intercrystal pores formed by seepage–reflux dolomitization acted as superior seepage channels for the reservoir transformation, and the recrystallization adjusted the previous pores and made them better, while the karstification was the key to the dissolved pore formation. [ABSTRACT FROM AUTHOR]

The study of the critical zones (CZs) of the Earth link the composition and function of aboveground vegetation with the characteristics of the rock layers, providing a new way to study how the unique rock and soil conditions in karst regions affect the aboveground vegetation. Based on survey results of the rocks, soils and vegetation in the dolomite and limestone distribution areas in the karst area of central Guizhou, it was found that woody plant cover increases linearly with the number of cracks with a width of more than 1 mm, while the cover of herbaceous plants shows the opposite trend (p<0.01). The dolomite distribution area is characterized by undeveloped crevices, and the thickness of the soil layer is generally less than 20 cm, which is suitable for the distribution of herbaceous plants with shallow roots. Due to the development of crevices in the limestone distribution area, the soil is deeply distributed through the crevices for the deep roots of trees, which leads to a diversified species composition and a complicated structure in the aboveground vegetation. Based on moderate resolution imaging spectroradiometer (MODIS) remote sensing data from 2001 to 2010, the normalized differentiated vegetation index (NDVI) and annual net primary productivity (NPP) results for each phase of a 16-day interval further indicate that the NDVI of the limestone distribution area is significantly higher than that in the dolomite distribution area, but the average annual NPP is the opposite. The results of this paper indicate that in karst CZs, the lithology determines the structure and distribution of the soil, which further determines the cover of woody and herbaceous plants in the aboveground vegetation. Although the amount of soil in the limestone area may be less than that in the dolomite area, the developed crevice structure is more suitable for the growth of trees with deep roots, and the vegetation activity is strong. At present, the treatment of rocky desertification in karst regions needs to fully consider the rock-soilvegetation- air interactions in karst CZs and propose vegetation restoration measures suitable for different lithologies. [ABSTRACT FROM AUTHOR]

This paper presents the preliminary results of investigations of carbonate nodules from red paleosols of the reference sections of the Middle and Upper Permian of the Kazan Volga region. The main genetic types of paleosols are calcic gleysols and gleyed vertisols, the pedogenic nodules are composed of dolomite and calcite. Scanning electron microscopy and spectroscopic and isotopic methods of analysis show that the nodules retained their original mineral composition and were formed with the participation of soil microorganisms under conditions of contrasting seasonality in an arid climate. In the vicinity of the Kiama-Illawarra paleomagnetic boundary, the Urzhumian paleosols show a transition in the composition of pedogenic nodules from dolomite to calcite. It is suggested that this transition was caused by the humidization of climate, which is supported by lithological and isotopic data. [ABSTRACT FROM AUTHOR]

Exploration practice has proved that deep and ultra-deep reservoirs consist of mainly matrix-porous dolomite reservoirs and fractured-vuggy karst reservoirs and still will be very important targets for future exploration, in which large oil and gas fields such as Anyue, Yuanba, Halahatang, Fuman and Shunbei have been discovered. This paper systematically summarizes three theoretical and technical achievements in studying deep and ultra-deep carbonate reservoirs in the past decade. (1) The micro-zone and multi-parameter experiment analysis technology featured by determining the “age, temperature, pressure and fluid properties” of carbonate reservoirs, together with experimental simulation of cross-tectonic-period pore formation and preservation featured by the “multi-stage, continuous, visualized and online detection technology”, providing useful tools for studying the pore formation and preservation mechanism of deep and ultra-deep carbonate rocks from the perspective of “forward” and “inversion”. (2) Deep and ultra-deep matrix-porous dolostone reservoirs are still controlled by sedimentary facies, among which reef (mound) and/or beach contribute most. The reservoir space is mainly composed of sedimentary primary pores and supergene dissolution pores and fractures, though some of reservoir spaces are formed by burial dissolution and they tend to develop and may locally concentrate following the pre-existing porous zone. In other words, burial dissolution vugs are inherited rather than newly formed. Early dolomite precipitation (or dolomitization) has a high potential to preserve early pores. (3) The development and preservation mechanism of fractured-vuggy karst limestone reservoirs in deep and ultra-deep realm was analyzed. Pene-contemporaneous dissolution and interlayer and buried-hill karstification control the development of early and late supergene fractured-vuggy reservoirs. Strike-slip faults superimposed with supergene karstification lead to the development of “fence-style” faulted karst reservoirs. Dissolution simulation experiments reveal that the development of karst fracturedvuggy reservoirs is facies-controlled in certain degree, mainly developed in packstone. Rock mechanics analysis reveals that the preservation of caves is under the control of lithology, cave size, and the distance to the unconformity, and caves can be well preserved at 10,000 m. The theoretical and technical achievements provide supports for carbonate oil and gas exploration into ten thousand meters deep. [ABSTRACT FROM AUTHOR]

This study deeply explores the characteristics of the dolomite reservoir and its controlling factors in the Ordovician Majiagou Formation in the southern Gaoqiao area of the Jingbian gas field in the Ordos Basin, aiming to provide a more accurate scientific basis for oil and gas exploration. The study reveals the petrological characteristics and reservoir properties of the reservoir through core analysis, thin- section observation and porosity and permeability testing. The results show that the reservoir in this area is dominated by mud-crystalline dolomite and crystalline dolomite, especially mud-crystalline dolomite shows excellent storage and permeability performance due to the development of pore-soluble pores. The porosity mainly ranges from 2% to 6%, with an average porosity of 3.03%, and the permeability mainly ranges from 0.01 to 5 mD, with an average of 2.14 mD. The analysis of the main controlling factors of the reservoir shows that karst plays a decisive role in the development of dolomite reservoirs, and especially the formation and distribution of the paste-solution pores have a significant influence on the storage and seepage performance. The depositional characteristics of gypsum nodules and their distribution pattern during the rock-forming process have an important influence on the porosity and permeability of the reservoir. Differences in the physical properties of the reservoir in the sedimentary microphase environment have a significant impact on the reservoir performance, in which the microphase reservoir containing gypsum cloud ping exhibits higher porosity and permeability. In addition, reservoir destructive primary control factors, such as compaction and pressure-solubilization effects and cementation and filling effects, negatively affected reservoir properties. Taken together, this study provides important scientific support for understanding the formation mechanism of dolomite reservoirs in the region, assessing the hydrocarbon resource potential, and guiding future exploration activities. [ABSTRACT FROM AUTHOR]

Sandification can degrade the strength and quality of dolomite, and to a certain extent, compromise the stability of a tunnel's surrounding rock as an unfavorable geological boundary. Sandification degree classification of sandy dolomite is one of the non-trivial challenges faced by geotechnical engineering projects such as tunneling in complex geographical environments. The traditional methods quantitatively measuring the physical parameters or analyzing some visual features are either time-consuming or inaccurate in practical use. To address these issues, we, for the first time, introduce the convolutional neural network (CNN)-based image classification methods into dolomite sandification degree classification task. In this study, we have made a significant contribution by establishing a large-scale dataset comprising 5729 images, classified into four distinct sandification degrees of sandy dolomite. These images were collected from the vicinity of a tunnel located in the Yuxi section of the CYWD Project in China. We conducted comprehensive classification experiments using this dataset. The results of these experiments demonstrate the groundbreaking achievement of CNN-based models, which achieved an impressive accuracy rate of up to 91.4%. This accomplishment underscores the pioneering role of our work in creating this dataset and its potential for applications in complex geographical analyses. [ABSTRACT FROM AUTHOR]

We critically discuss both advantages and limitations of helicopter-borne GPR surveys in rugged mountainous areas by analyzing a pseudo 3D data set acquired over the Marmolada Glacier, which constitutes the largest ice body in the Dolomites (Eastern Alps) and contains several peculiar features both in terms of the internal structures and the surrounding topography. In this paper we analyze several possible issues that can be encountered when performing airborne surveys in mountain regions, related to both the local conditions in the particular survey areas, and the general performance of the data acquisition equipment, which includes the GPR device, the GPS system, and the helicopter itself. Based on our analyses and observations, we propose a few guidelines and optimization strategies in order to address several issues, including the choice of various data acquisition parameters, interpretation problems related to curvilinear or irregular flight paths, and trace positioning errors caused by GPS malfunctioning or oscillating antennas. Such results have general validity and can be used for helicopter-borne survey planning, as well as for data analysis and interpretation. [ABSTRACT FROM AUTHOR]

Aims: The objective of this paper was to develop a method based on infrared spectroscopy to compare mineral content in soils and apply it to evaluate soil mineralogical variations in pairs of inter-patch and patch soils in a semi-arid area. Methods: Mixtures of several minerals were analyzed by infrared spectroscopy, the second derivative of the spectra was calculated and the spectra normalized respect to calcite or quartz signals (711 cm−1 or 800 cm−1 respectively). The intensities of representative signals of each mineral were related to their concentration in the mixtures. Pairs of patch and inter-patch soils from five different sites were analyzed by this method. Elemental analysis and total lime analysis were performed in some soil pairs. Results: Soils were dominated by calcite and quartz, or by montmorillonite and kaolinite. Inter-patch soils were richer in calcite and poorer in quartz or clays than patch soils. Calcite losses in patch soils might be related to soil acidification by CO2 from respiration and/or organic matter. Elemental analysis showed high values of S, Cl, and K in patch soils with respect to inter-patch soils. Conclusions: The proposed FTIR method was useful to compare soil mineralogy in specific areas. Fertile spots by accumulation of water, soluble salts and sediments may favor plant growth in semi-arid regions and these plants may increase the fertility of the spot. Changes in soil mineral composition could be used to monitor the biological activity of soil in arid and semi-arid zones. [ABSTRACT FROM AUTHOR]

This paper deals with thermal analyses, burning trials and reactivity tests on 15 carbonate rocks, i.e., pure and impure carbonates, mud-supported and grain-supported limestones, crystalline marbles, and dolomites, used for the production of different lime products in industrial vertical shaft kilns worldwide. In particular, thermogravimetric and differential thermogravimetric analysis (TG–DTG) on massive (80–120 g) fine-grained (< 3.35 mm) samples allowed the extrapolation of the Arrhenius kinetic parameters, i.e., the (apparent) activation energy (Ea) and the pre-exponential or frequency factor (A). Other calcination parameters, i.e., the duration time, starting and ending calcination times and temperatures, and peaks of maximum calcination rate were also extrapolated in order to enhance their relationships with quicklime reactivity. Moreover, thermal analyses (TG–DTG–DTA) were repeated on powders (90 mg) using a more accurate analyzer to compare results. The study is completed by a thorough chemical–physical and mineralogical–petrographic characterization of carbonate rocks and derived burnt products. Results pointed out that medium-to-coarse crystalline materials, i.e., grain-supported limestones, diagenetic dolomites, and granoblastic marbles presented the highest activation energy, burnability and slaking reactivity. Conversely, microcrystalline carbonates with the highest micrite-to-sparite ratio, i.e., mud-supported limestones, and impure carbonates, enriched in quartz, clay minerals, and other subordinated non-carbonate impurities, presented the lowest activation energy, burnability, and slaking reactivity. This study also investigated the effect of BET-specific surface area and real density, depending on specific sintering tendency, on quicklime reactivity. Results from this multidisciplinary research activity put further constraints on carbonate rocks calcination kinetics and their suitability in the lime industry. [ABSTRACT FROM AUTHOR]

Evaluation of paleo-seawater pH is an important aspect to study the paleo-ocean environment. The Paleozoic strata lack foraminiferal shells; therefore, reconstruction of paleo-seawater pH is difficult. In this paper, the Cambrian-Lower Ordovician evaporate sequence present in the Tarim Basin is used as an example to work out methods for reconstruction of paleo-seawater pH for evaporate sequences through study of boron isotopes. Analysis of diagenetically unaltered samples yields δ11B values for normal seawater in an open environment ranging from 7.5 to 12.6‰ (average = 9.4‰) and those of evaporative salt-lake facies ranging from − 4.7 to − 1.8‰ (average = − 3.3‰). With increase in the rate of evaporation of seawater, its pH decreases gradually and the δ11B values of tricoordinated and tetracoordinated compounds decrease synchronously. Using a salt-lake brine with pH 7, δ11B value in sedimentary rock of − 3.3‰ and unfractionated δ11B in tetracoordinated B(OH)4− in solution, the average δ11B of the Middle Cambrian-Early Ordovician paleo-seawater came to be 16.2‰. It establishes a workable relationship between δ11B in sedimentary rock and seawater pH. The Middle Cambrian-Early Ordovician normal paleo-seawater pH estimated using the δ11B value of sedimentary rock representing the weakest evaporation intensity is ~ 9.1 that is 0.9 higher than pH of modern seawater. In these calculations, it is assumed that the total dissolved inorganic carbon is unchanged between the Cambrian-Early Ordovician paleo-seawater and modern seawater and the [CO32−] content in the paleo-seawater is greater by a factor of 2-3 than that in modern seawater. This increase in [CO32−] content is inferred to be one of the main factors for the widespread development of dolomite. [ABSTRACT FROM AUTHOR]

Diagenetic boundaries are paleo-reaction fronts, which have the potential to archive the termination of metasomatic processes in sedimentary rocks. They have not been extensively studied, perhaps because they appear simple in outcrop. Recent work has demonstrated the significance of paleo-reaction fronts to decipher multiphase recrystallization processes and provide high porosity zones. This paper provides a detailed documentation of reaction front evolution in a tectonically active salt basin and reveals a high level of complexity, associated with multiple fluid flow and tectonic events. Here, consistent patterns of increasing dolomite stoichiometry and ordering, along with a change from seawater-derived, fabric-retentive dolomite to fracture-controlled, fabric-destructive hydrothermal dolomite are observed vertically across the stratabound dolomite bodies. These patterns, coupled with a decrease in porosity, increase in ∆47 temperature and δ18Owater values indicate multiphase recrystallization and stabilization by warm, Mg-rich fluids. The stratabound dolomite bodies apparently terminated at a fracture-bound contact, but the presence of dolomite fragments within the fracture corridor suggests that fracturing post-dated the first dolomitization event. The termination of dolomite formation is therefore interpreted to be associated with a decrease in the capacity of the magnesium-rich fluids to dolomitize the rock, as indicated by the presence of non-stoichiometric and poorly ordered dolomite at the reaction fronts. The fracture corridors are interpreted to exploit dolostone-limestone boundaries, forming prior to a later, higher temperature, hydrothermal dolomitization event, which coincided with the formation and growth of the anticline. Karstification subsequently exploited these fracture corridors, widening fractures and leading to localized collapse and brecciation. The results demonstrate that an apparently simple reaction front can have a complex history, governed by the inheritance of prior diagenetic events. These events modified rock properties in such a way that fluid flow was repeatedly focused along the original dolomite-limestone boundary, overprinting much of its original signature. These findings have implications to the prediction of structurally controlled diagenetic processes and the exploration of naturally fractured carbonate reservoirs for energy exploration globally. [ABSTRACT FROM AUTHOR]

The paper presents systematized and synthesized data on the parameters and evolutionary sequence of metasomatic processes that accompanied interaction between Permian-Triassic trap complex and rocks of the sedimentary cover of the Siberian Platform at the large skarn iron deposits. Relations of the textural-compositional, morphological, and genetic diversity of the skarns and ores with the phases and stages of the origin of ore-bearing volcano-tectonic edifices are demonstrated with reference to the Korshunovskoe and Rudnogorskoe deposits. The genetic reconstructions are based on survey materials and data on the mineralogy of the rocks and ores (obtained by optical and scanning electron microscopy, microprobe analysis, EPR, Raman and IR spectroscopy, and by studying inclusions in minerals). A principally important feature of the volcano-tectonic edifices of the large mineral deposits is their multistage evolution and combinations of fluid-conducting zones, which are related to (1) volcanic apparatuses, (2) shallow-depth magmatic chambers (laccoliths) hosted in carbonate-salt rocks, and (3) multistage fracture structures produced by the collapse of the leached space. The major ore-bearing structures were formed simultaneously with the development of an intermediate magmatic chamber hosted in Cambrian carbonate-salt rocks beneath a seal of terrigenous sedimentary rocks. Magmatic-stage magnesian skarns with disseminated ores in them and in the calciphyres were produced during the prograde stage in the apical parts of the laccoliths, at contacts between the dolerites and dolomites. During the early prograde stage, skarn-ore bodies developed around injection bodies of globulated dolerites, laccoliths, and sills; stockworks and steep bodies of fragmentary magnesian and calcic skarns and ores were formed within the diatremes; and conformable bodies and veins were produced in the splay fracture zones. The later reactivation of faults and fractures and the involvement of connate brines and solutions from the evaporite complex triggered the redeposition of the ore masses, crystallization of the mineral assemblages of hydrated skarns, development of large domains of serpentine-chlorite-epidote-amphibole rocks, calcic skarns, and ores. Data on multiphase fluid inclusions in the forsterite, apatite, and halite indicate that the mineral-forming fluid initially was a highly concentrated solution-melt (total salinity of 60%) with high-density reduced gases. The magnesian skarns were formed during the following stages: (1) forsterite + fassaite + spinel + first-population magnetite (820-740°C); (2) phlogopite + titanite + pargasite + second-population magnetite (600-500°C), and (3) clinochlore + serpentine + tremolite + pyrrhotite + chalcopyrite (≥450°C). [ABSTRACT FROM AUTHOR]

Bone adhesives are known as a promising fracture treatment material because they can quickly heal broken bones. However, the existing bone adhesives have the disadvantages of weak binding ability to bone tissue, non-absorption, or difficulty in curing under wet conditions, which limits their wide application in the field of bone tissue engineering. In this study, the raw material of magnesium phosphate bone adhesive was modified, and the composite material of magnesium phosphate bone repair was prepared by the method of solid–liquid blending crosslinking. Mineral-organic composite, a new type of bone adhesive was prepared using calcined dolomite and montmorillonite as mineral components, phytic acid and gelatin as organic components. The compressive strength, porosity and bonding strength of the magnesium phosphate-based bone adhesive were analyzed by Fourier transform infrared spectroscopy, X-ray diffraction and scanning electron microscopy. When the dosage of dolomite is 8 wt% and the concentration of gelatin is 9 wt%, the adhesion strength of the bone adhesive is 2.04 MPa after 168 h placement. And the compressive strength of the bone adhesive was 6.66 MPa after 168 h placement. After the prepared bone adhesives were immersed in SBF solution for 14 and 21 days, EDS analysis showed that the accumulated material was bone-like hydroxyapatite, indicating that the prepared bone adhesives had good osteogenic activity. In addition, it was also found that the bone adhesive had fluid absorption ability and no cytotoxicity. So, conclusively it can be stated that such newly synthesized bone adhesive has significant medical potential. [ABSTRACT FROM AUTHOR]

Spontaneous water imbibition into matrix blocks can be a significant oil recovery mechanism in fractured reservoirs. Many enhanced oil recovery methods, such as injection of modified salinity brine, are proposed for improving spontaneous imbibition efficacy. Many scaling equations are developed in the literature to predict spontaneous imbibition oil recovery. However, almost none of them included the impact of the diversity in ionic composition of injected and connate brines and the blending/interaction of a low salinity imbibing brine with a higher salinity connate brine. In this research, these two issues are included to propose new scaling equations for the scaling of spontaneous imbibition oil recovery by modified salinity imbibing brines. This study uses experimental data of the spontaneous imbibition of modified salinity brines into oil-saturated rock samples with different lithologies containing an irreducible high salinity connate brine. The collected tests from the literature were performed at high temperatures and on aged altered wettability cores. The results of 110 available spontaneous imbibition laboratory experiments (85, 12 and 13 tests on chalks, dolomites and sandstones, respectively) are gathered. This research initially shows the poor ability of three selected convenient scaling equations from the literature to scale imbibition recovery by modified salinity brine. Then, our newly proposed technique to find the scaling equation for spontaneous imbibition recovery by modified salinity brine, during the abovementioned conditions in limestones (Bassir et al. in J Pet Explor Prod Technol 13(1): 79–99, 2023. https://doi.org/10.1007/s13202-022-01537-7) is used in chalks, dolomites and sandstones to develop the three new scaling equations. Finally, a new general equation to scale imbibition recovery by modified salinity brine for all four lithologies is presented. Moreover, for each of the four datasets (chalk, dolomite, sandstone and all the four lithologies), the scaled data by the new equations is matched by two mathematical expressions based on the Aronofsky et al. model and the Fries and Dreyer model. These mathematical expressions can be used to develop transfer functions in reservoir simulators for a more accurate prediction of oil recovery by spontaneous imbibition of modified salinity brine in fractured reservoirs. [ABSTRACT FROM AUTHOR]