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We briefly discuss the history of pumping schemes for the common 22-GHz maser transition in o-H2O, and note that radiative mechanisms have been considered in the past, as well as the better known collisional pumping mechanisms associated with shock waves. Substantial IR irradiation is indeed destructive to inversion at 22-GHz under a wide range of physical conditions. We identify a small number of transitions, including 22 GHz, that can be pumped by both collisional and radiative schemes, and, through radiative transfer modelling over a grid of values in kinetic temperature, number density, and dust temperature, identify loci in density-kinetic temperature space where these schemes lead to strong inversions. The radiative pumping scheme generally operates at higher dust temperature, and lower kinetic temperature, than the collisional scheme. We identify a small network of transitions that form a radiative pumping scheme for the 22-GHz maser, involving radiative transitions of wavelength approximately 6  |$\mu$| m. This network is capable of supplying more than 50 per cent of the 22-GHz inversion under typical radiative pumping conditions, and it is consistent with the need for high dust and low kinetic temperatures determined from the modelling. We identify a probable case of radiative pumping in a massive star-forming region from the observation of a positive correlation between the flux densities of 22-GHz H2O masers and 6.7-GHz methanol masers. We discuss possibilities for finding radiatively pumped H2O maser lines in other source types. [ABSTRACT FROM AUTHOR]

We consider the structure of mildly relativistic shocks in dense media, taking into account the radiation and pair loading, and diffusive radiation energy transfer within the flow. For increasing shock velocity (increasing post-shock temperature), the first important effect is the efficient energy redistribution by radiation within the shock that leads to the appearance of an isothermal jump, whereby the flow reaches the final state through a discontinuous isothermal transition. The isothermal jump, on scales much smaller than the photon diffusion length, consists of a weak shock and a quick relaxation to the isothermal conditions. Highly radiation-dominated shocks do not form isothermal jump. Pair production can mildly increase the overall shock compression ratio to ≈10 (4 for matter-dominated shocks and 7 of the radiation-dominated shocks). [ABSTRACT FROM AUTHOR]