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In recent years, development of biopolymeric nanofibers as an active biodegradable packaging system has attracted specific attention. The objective of this research was to develop zein‐based electrospun nanofibers (NFs) incorporated with geraniol‐loaded nanoliposomes (G‐loaded NLPs). Geraniol was encapsulated into NLPs with an efficiency of 79.23%. The particle size and zeta potential of G‐loaded NLPs were 121.50 nm and −38.30 mV, respectively. The successful loading of geraniol in the NLPs was approved by Fourier transform infrared (FT‐IR) spectroscopy. The liposomal vesicles showed spherical shapes. G‐loaded NLPs were added in the zein‐based electrospun NFs at three different concentrations (0.25, 0.5, and 1%w/v). All NFs samples exhibited fibrillar structure. The increase of NLPs concentration enhanced the thermal stability of the NFs. However, the crystalline structure of zein NFs did not change by the addition of G‐loaded NLPs. The highest surface hydrophobicity was related to the NFs containing 1% G‐loaded NLPs. The mechanical parameters of NFs depend on the concentration of NLPs. The NFs incorporated with G‐loaded NLPs showed inhibition activity against four foodborne pathogenic bacteria (Staphylococcus aureus, Listeria monocytogenes, Escherichia coli, and Salmonella typhimurium) with an inhibition zone of 4.5–22 mm. Moreover, the α‐diphenyl‐β‐picrylhydrazyl (DPPH) scavenging activity of NFs samples was located at the range of 20%–48%. These findings represent the Efficiency of the G‐loaded NLPs for use as bioactive compound in the zein‐based NFs as an active packaging material. [ABSTRACT FROM AUTHOR]

Highlights Biodegradable plastics are gaining popularity as environmentally friendly functional materials. This study focuses on the preparation of aluminum hydroxide (Al(OH)3) reinforced cellulose acetate composite films using a cost‐effective approach. The process involves synthesizing bamboo‐derived cellulose acetate (BDCA), dissolving it in tetrahydrofuran with glycerol as a plasticizer, and incorporating Al(OH)3 particles into the casting solution to reinforce the cellulose acetate film. Analyses on microstructure and characteristics of the films were conducted through various techniques, including scanning electron microscopy (SEM), Fourier transform infrared (FT‐IR) spectroscopy, x‐ray diffraction (XRD), water contact angle measurement, and tensile testing. The results indicate that the Al(OH)3 particles were well‐dispersed in the composite films, leading to a strong interaction with the cellulose acetate matrix. As a result, the prepared composite films exhibited significantly higher tensile strength compared to pure bamboo‐derived cellulose film. Additionally, they demonstrated improved anti‐ultraviolet properties and a lower water vapor transmission rate, despite being more hydrophilic. This method holds significant potential for commercial applications in producing high‐performance cellulose acetate‐based composite films. Bamboo‐derived cellulose acetate was synthesized through chemical processes. BDCA based composite film reinforced with Al(OH)3 was prepared by casting method. The Al(OH)3 significantly enhance the functional properties of the composite film. Composite films showed good performances for packaging according to the results. [ABSTRACT FROM AUTHOR]

This study focuses on developing a biodegradable film using a novel hybrid citrus peel pectin. A bilayer approach with PLA was proposed and optimized using Response Surface Methodology (RSM) to complement pectin films' mechanical and barrier property limitations. The optimized film composition (2.90 g PLA and 1.96 g pectin) showed enhanced mechanical strength with a tensile strength (TS) of 7.04 MPa and an elongation at break (EAB) of 462.63%. In addition, it demonstrated lower water vapor (1.45 × 10−10 g/msPa), oxygen (2.79 × 10−7 g/ms) permeability, and solubility (23.53%). Compared to single-layer pectin films, the optimized bilayer film had a 25% increased thickness, significantly improved water barrier (3806 times lower) and oxygen barrier (3.68 times lower) properties, and 22.38 times higher stretchability, attributed to hydrogen bond formation, as confirmed by FTIR analysis. The bilayer film, effectively protected against UV and visible light, could be a barrier against light-induced lipid oxidation. Moreover, it demonstrated superior seal efficiency, ensuring secure sealing in practical applications. The bilayer pouch containing mustard dressing exhibited stable sealing with no leakage after immersion in hot water and ethanol, making it suitable for secure food pouch packaging. [ABSTRACT FROM AUTHOR]

Considering the increasingly notorious environmental implications caused by plastic waste, sustainable alternatives are needed. Thus, biodegradable polymers are presented as a concrete alternative within the food packaging sector, where their storage, transport and marketing involve large volumes of plastic waste. Therefore, in this study, PHBV/PLA thin sheets were developed by extrusion and solvent casting as a first stage in the search for biodegradable plastic sheeting to replace non-biodegradable common materials such as polypropylene (PP) in food packaging. Although PHBV (poly 3-hydroxy butyrate-co-3-hydroxy valerate, the main polymer in the formulation) has excellent crystallinity, barrier properties and biodegradability, unfortunately, its thermal instability and high rigidity create difficulties in its processing. Thus, PLA gives the PHBV/PLA mixture greater plasticity and thermal resistance. Consequently, PHBV/PLA thin sheets were obtained by solvent casting and extrusion at four proportions: 50/50, 60/40, 80/20 and 100/0 (%w/w). Since most research on films is done by the solvent-cast method, considering the ease of this method, it is interesting to study and compare the physicochemical and mechanical properties of this method with another that allows easy scaling, such as extrusion. Therefore, thin sheets obtained by the two methodologies were characterized by transmittance, stress–strain, water absorption, water vapour permeability and hydrophobicity tests. The results show that the extruded thin sheets have better mechanical properties than solvent-casted sheets. On the other hand, of the formulations studied, PHBV/PLA 50/50 presented the physicochemical and mechanical properties closest to PP. [ABSTRACT FROM AUTHOR]

To optimize the functional properties of edible films or coatings, mixtures of several ingredients are used, including food processing by-products. In this way, pectin from fruit pomace, whey proteins from whey as a by-product of rennet cheese production, and gelatin from by-products of the processing of slaughtered animals can be obtained. The aim and scope of the investigation were to verify the hypothesis of the research, which assumes that the addition of beef broth to edible gelatin films will affect the gelation processes of the tested film-forming solutions and will allow for the modification of the edible properties of the films obtained based on these solutions. Measurements were carried out to determine the visual parameters, mechanical strengths, surface and cross-sectional structures, FTIR spectra, thermal degradation rates, and hydrophilicities of the prepared gelatin films. The water content, water vapor permeability, and course of water vapor sorption isotherms of the films were also examined, as well as the course of the gelation process for film-forming solutions. The addition of broth to film-forming solutions was found to increase their opacity and color saturation, especially for the ones that were yellow. The films with the addition of broth were more uneven on the surface and more resistant to stretching, and in the case of the selected types of gelatins, they also formed a more stable gel. The broth increased the hydrophilicity and permeability of the water vapor and reduced the water content of the films. The addition of broth enables the practical use of edible films, but it is necessary to modify some features. [ABSTRACT FROM AUTHOR]

With an increase in environmental pollution and microplastic problems, it is more urgent now to replace non-biodegradable films with biodegradable films that are low-cost and from renewable resources. Cotton gin motes (GM), a type of cellulosic waste that is generated from cotton ginning, is an excellent candidate for fabricating biodegradable films due to its properties and abundance. In this study, GM was first mechanically milled into a fine powder, followed by compounding with polycaprolactone (PCL) and extruded to produce composite pellets which were then compress-moulded into composite films. This environmentally friendly process used physical processing and all the materials were consumed in the process without generating any waste residue. To improve the compatibility and mixing properties between GM and PCL, the use of a plasticiser (polyethylene glycol) was considered. A high content of GM powder (up to 50%) was successfully compounded with the polymer. The SEM images of the composite films showed smooth surface morphology and well-distributed GM powder in the PCL matrix. The added advantage of compounding GM with the polymer matrix was that the composite film developed UV-shielding properties due to the presence of lignin in the GM powder. This property will be critical for films used in UV-resistance applications. Furthermore, the composite even with high GM content (50%), showed good mechanical properties, with 9.5 MPa yield strength and 442% elongation, which was only a 50% decrease in elongation when compared with clear PCL film. The soil biodegradation of GM composite films under controlled temperature (20 °C) and humidity (50%) for 1 month showed around 41% weight loss. Overall, this study demonstrates the potential of GM to be used as a biodegradable and UV-protective composite film for a wide array of applications, such as packaging and UV-protective coverings. [ABSTRACT FROM AUTHOR]

Consumer demands to utilize environmentally friendly packaging have led researchers to develop packaging materials from naturally derived resources. In recent years, plant protein-based films as a replacement for synthetic plastics have attracted the attention of the global food packaging industry due to their biodegradability and unique properties. Biopolymer-based films need a filler to show improved packaging properties. One of the latest strategies introduced to food packaging technology is the production of nanocomposite films which are multiphase materials containing a filler with at least one dimension less than 100 nm. This review provides the recent findings on plant-based protein films as biodegradable materials that can be combined with nanoparticles that are applicable to food packaging. Moreover, it investigates the characterization of nanocomposite plant-based protein films/edible coatings. It also briefly describes the application of plant-based protein nanocomposite films/coating on fruits/vegetables, meat and seafood products, and some other foods. The results indicate that the functional performance, barrier, mechanical, optical, thermal and antimicrobial properties of plant protein-based materials can be extended by incorporating nanomaterials. Recent reports provide a better understanding of how incorporating nanomaterials into plant protein-based biopolymers leads to an increase in the shelf life of food products during storage time. [ABSTRACT FROM AUTHOR]

The present study refers to the microbiological characterization of some biodegradable packaging made on the basis of polylactic acid and other additives with antimicrobial properties that confer a longer shelf life for fresh food products compared to their traditional packaging, i.e. with different compositions of polyethylene or polyethylene terephthalate. As additives for the final chemical composition of biodegradable packaging, several volatile oils and products resulting from the secondary valorization of agricultural waste from the manufacture of wine, respectively, were tested. The data obtained showed that the hydroalcoholic extract of the grape pomace does not contain compounds with antimicrobial activity and the results of the UV-VIS analyses indicated a significant composition of it in polyphenolic compounds. Also, the investigations demonstrated that a chemical composition of the newly obtained packaging supplemented with thyme essential oil increased the shelf life of freshly packaged food products in the traditional system up to 8 days from packaging. [ABSTRACT FROM AUTHOR]

Starch-based foams can be used in packaging development to replace nonbiodegradable petrochemical plastics. However, starch-based materials possess poor mechanical properties and low water resistance. These properties can be improved by adding plasticizers and fillers to the bulk composition. In the present work, the effect of rice husk ash content on physical, morphological, and mechanical properties of cassava starch-based foams produced by thermal expansion was investigated. The composites were formed by mixing cassava starch, rice husk ash (content varying from 0 to 60%), water, and glycerol. The obtained dough was placed in a metallic mold and then expanded in a thermohydraulic press machine. The addition of 20–50% of ash content improved thermal stability, density, and biodegradation of starch-based foams and decreased water absorption capacity. Filled starch-based foams also exhibited smaller pores in internal structure. Compared to foams without ash filler, the addition of 20–40% ash increased the flexural tensile strength and the addition of more than 50% dropped the mechanical resistance. Hence, based on the results obtained, rice husk ash can be a great filler in biodegradable starch-based foams. [ABSTRACT FROM AUTHOR]

In an era marked by a burgeoning environmental crisis, the pharmaceutical industry's reliance on nonbiodegradable packaging has become a pressing concern. This comprehensive review marks a pioneering effort to examine the entire spectrum of pharmaceutical packaging, from traditional materials to innovative biodegradable alternatives, with an emphasis on the industry's role in sustainability. Beginning with a detailed investigation into the prevalent materials and their environmental impact, the review unveils a landscape riddled with challenges but ripe with opportunities. By delving into biodegradable packaging technologies, including polylactic acid, polyhydroxyalkanoates, and other biopolymers, we present a cogent roadmap toward an eco-friendly future. Our analysis further extends to the intricate web of regulations, market dynamics, consumer behavior, real-world applications, and critical future directions. The study culminates in a robust set of recommendations that amalgamate scientific innovation with practical strategies, thus setting a precedent for collaborative action. This review stands as a seminal contribution to the field, offering a holistic perspective on an issue central to global sustainability and human well-being. Its findings not only underline the feasibility of transitioning to sustainable packaging within the pharmaceutical industry but also underscore the urgency of this shift. The paper concludes with a resonant call to action, inviting all stakeholders to partake in a collective endeavor that transcends conventional boundaries and illuminates a path toward a greener, healthier world. [ABSTRACT FROM AUTHOR]

Active packaging manufactured with biopolymers extracted from agri-food waste is one of the most innovative and eco-sustainable strategies for maintaining food quality. However, biopolymers often present poor performances, which hinders their competitiveness compared with plastics. This work focused on developing and optimizing a natural polymeric blend produced by solvent casting based on zein and chitosan to improve the pure biopolymers' properties. The best results were obtained by blending zein and chitosan in a 1:2 weight ratio. The films were characterized in terms of morphology, mechanical and oxygen barrier properties, thermal stability, transparency and wettability. The blend production allowed us to obtain lower brittleness and lower stiffness materials compared with pure polymer films, with oxygen permeability values two orders of magnitude lower than pure zein, better optical properties with respect to pure chitosan and good thermal stability. The wettability properties of the blend did not result in being altered with respect to the single polymer, which was found to have hydrophilic behavior, highlighting the strong influence of glycerol used as a plasticizer. The results suggested that the polymer blending strategy is a viable and cost-effective method for producing packaging materials as alternatives to plastics. [ABSTRACT FROM AUTHOR]

Given the global environmental issues associated with petroleum‐based packaging materials, developing green packaging films is a promising innovative approach to packaging food products. In this regard, starch films added with plant extracts and essential oils have been explored for different packaging types of food products. The availability of starch in nature makes starch films a cheap substitute for petroleum‐based packaging material, thus reducing the impact on the environment, packaging costs, and complexity. Recent investigations emphasize identifying and isolating natural ingredients from different plants for use in starch‐based green packaging. Plant extracts and essential oils influence the mechanical and barrier properties and impart antioxidant and antimicrobial properties to the developed films. These films show promising applications in the food industry. This review provides recent insights into the effects of plant extracts and essential oils on starch‐based green packaging films' properties. [ABSTRACT FROM AUTHOR]

Abstract The use of packaging in the food industry is essential to protect food and improve its shelf life. However, traditional packaging, based on petroleum derivatives, presents some problems because it is non-biodegradable and is obtained from nonrenewable sources. In contrast, protein-based smart packaging is presented as an environmentally friendly strategy that also permits obtaining packaging with excellent characteristics for the formation of smart films and coatings. This review aims to summarize recent developments in smart packaging, focusing on edible films/coatings materials, originating from animal and plant protein sources. Various characteristics like mechanical, barrier, functional, sensory, and sustainability of packaging systems are discussed, and the processes used for their development are also described. Moreover, relevant examples of the application of these smart packaging technologies in muscle foods and some innovations in this area are presented. Protein-based films and coatings from plant and animal origins have great potential to enhance food safety and quality, and reduce environmental issues (e.g., plastic pollution and food waste). Some characteristics of the packages can be improved by incorporating polysaccharides, lipids, and other components as antioxidants, antimicrobials, and nanoparticles in protein-based composites. Promising results have been shown in many muscle foods, such as meat, fish, and other seafood. These innovative smart packaging systems are characterized by their renewable and biodegradable nature, and sustainability, among other features that go beyond typical protection barriers (namely, active, functional, and intelligent features). Nonetheless, the utilization of protein-based responsive films and coatings at industrial level still need optimization to be technologically and economically valid and viable. [ABSTRACT FROM AUTHOR]

Extensive use of petrochemical plastic packaging leads to the greenhouse gas emission and contamination to soil and oceans, posing major threats to the ecosystem. The packaging needs, hence, are shifting to bioplastics with natural degradability. Lignocellulose, the biomass from forest and agriculture, can produce cellulose nanofibrils (CNF), a biodegradable material with acceptable functional properties, that can make packaging among other products. Compared to primary sources, CNF extracted from lignocellulosic wastes reduces the feedstock cost without causing an extension to agriculture and associated emissions. Most of these low value feedstocks go to alternative applications, making their use in CNF packaging competitive. To transfer the waste materials from current practices to the packaging production, it is imperative to assess their sustainability, encompassing environmental and economic impacts along with the feedstock physical and chemical properties. A combined overview of these criteria is absent in the literature. This study consolidates thirteen attributes, delineating sustainability of lignocellulosic wastes for commercial CNF packaging production. These criteria data are gathered for the UK waste streams, and transformed into a quantitative matrix, evaluating the waste feedstock sustainability for CNF packaging production. The presented approach can be adopted to decision scenarios in bioplastics packaging conversion and waste management. [ABSTRACT FROM AUTHOR]

This research carried out a bibliometric analysis and literature review on the production of gelatin-based films for application as food packaging, addressing the main advances and limitations. The search for articles was performed in the Scopus database, and bibliometric data were obtained using the Bibliometrix tool (RStudio software). It was observed that a wide variety of compounds can be incorporated into gelatin films to overcome the limitations related to their high solubility and low mechanical properties, as well as to obtain active or smart functions. Among the most reported compounds were essential oils, pigments extracted from vegetables, and other antimicrobial agents. The most reported foods as an application matrix were meat (fish, chicken, and shrimp), milk, cheese, and minimally processed fruits. Even with promising trends, the biggest challenge for large-scale applications is to obtain easily degradable biopolymers with structural and functional stability similar to synthetic polymers. Thus, a greater focus on this theme in research may favor significant advances in the use of these packages and positively impact several of the Sustainable Development Goals, as recommended by the United Nations. [ABSTRACT FROM AUTHOR]

Composite films were prepared by combining different concentrations of curcumin with chitin and glucan complexes (CGCs) extracted from Agaricus bisporus via a solution casting method. The developed curcumin doped CGC (CGC/Cu) films were characterized in terms of surface, optical, structural, barrier, mechanical, antioxidant, and antimicrobial properties. The biodegradability of CGC/Cu films was determined in soil for 14 days. The incorporation of curcumin significantly affected the surface morphology and improved light barrier properties, radical scavenging activity, and total phenolic content of the films. The CGC/Cu films containing different concentrations of curcumin showed antibacterial activity against Escherichia coli , while antibacterial activity against Staphylococcus aureus was not observed with the developed films. Afterward, the microbial properties of the fresh chicken breast were examined during refrigerated storage for 10 days. The shelf-life of chicken samples wrapped in the developed film was extended at least 40 % compared to the control sample. In conclusion, curcumin incorporated CGC based films can serve as a promising biodegradable active packaging material to improve the shelf-life of meat products. [Display omitted] • Chitin and glucan complexes (CGCs) were extracted from Agaricus bisporus. • Curcumin at different concentrations was added to CGCs with glycerol to fabricate the CGC/Cu films. • Curcumin addition improved biodegradability, light barrier properties, antioxidant activity, and the total phenolic content. • The developed films had an inhibitory effect against Escherichia coli. • CGC/Cu10 films extended the shelf-life of skinless chicken breast meat by at least 40 %. [ABSTRACT FROM AUTHOR]

This research evaluated the possibility of alkaline treatment to solve the problem of molding due to moisture during storage of areca leaf sheaths (ALSs) to be used for biodegradable ALS plate production. The effect of alkaline treatment on the properties of ALSs was studied. Sodium hydroxide (NaOH) and sodium bicarbonate (NaHCO3) were used as chemicals for surface treatment. The solution of NaOH and NaHCO3 was varied at 1%, 3%, and 5% w/v. Surface treatment with NaOH and NaHCO3 partially removed hemicellulose, cellulose, lignin, and impurities from the surface of the ALSs and increased the moisture resistance property of the ALSs. Treatment with NaOH made the ALSs' surface rougher, whereas treatment with NaHCO3 had no effect on the surface of the ALSs. The decomposition temperature (Td2) of the NaOH-treated ALSs decreased by approximately 7.0 to 10.5%, while for the NaHCO3-treated ALSs it changed only slightly. The overall tensile properties of the NaOH-treated ALSs were better than those of the NaHCO3-treated ALSs. The surface treatment with 1% NaOH and 1% NaHCO3 increased the tensile modulus by 20.5% and 6.2%, respectively, as compared with the nontreated ALS. It was found that surface treatment with 1% NaOH and 1% NaHCO3 could create suitable conditions for ALS plate production. This work is a preliminary study; more research still needs to be done. [ABSTRACT FROM AUTHOR]

The aim of this study was to develop and characterize sodium alginate films loaded with 10–40 % Clitoria ternatea extract (CTE) and apply to monitoring the quality of milk, pork and shrimp. Films loaded with CTE showed high light barrier capacity and improved tensile strength by 3.8 times over control films. The incorporation of CTE in alginate films improved the thermal stability of the materials due to intermolecular interactions and crosslinking of polymeric networks. The addition of 40 % of CTE generated films with antibacterial action against E. coli. The alginate films showed biodegradable characteristics in soil and beach sand in 15 days. The food simulant test revealed that the loaded films show good compatibility with aqueous and acidic foods due to the release of higher levels of polyphenols and anthocyanins. The films showed great colorimetric potential due to their ability to change color at different pH (pink-green), ammonia gas (blue-green) and sterilization process (blue-yellow). When the film loaded with 40 % CTE (F40) was applied to monitor the freshness of milk and meat products (shrimp and pork), its blue color changed to purple and green, respectively. Therefore, the F40 has great potential to be used as a biodegradable indicator of freshness. [Display omitted] • Clitoria ternatea extract (CTE) changes color with pH variation. • Packaging properties improved with the incorporation of CTE. • The loaded films showed antimicrobial and antioxidant activity. • Films sensitive to pH, ammonia and sterilization were developed. • Alginate film loaded with CTE monitored the freshness of milk and meat products. [ABSTRACT FROM AUTHOR]

Food packaging was not as important in the past as it is now, because the world has more people but fewer food resources. Food packaging will become more prevalent and go from being a nice-to-have to an essential feature of modern life. Food packaging has grown to be an important industry sector in today's world of more people and more food. Food packaging innovation faces significant challenges in extending perishable food products' shelf life and contributing to meeting daily nutrient requirements as people nowadays are searching for foods that offer additional health advantages. Modern food preservation techniques have two objectives: process viability and safe, environmentally friendly end products. Long-term storage techniques can include the use of edible coatings and films. This article gives a succinct overview of the supplies and procedures used to coat food products with conventional packaging films and coatings. The key findings summarizing the biodegradable packaging materials are emphasized for their ability to prolong the freshness and flavor of a wide range of food items; films and edible coatings are highlighted as viable alternatives to traditional packaging methods. We discuss the safety concerns and opportunities presented by applying edible films and coatings, allowing it to be used as quality indicators for time-sensitive foods. [ABSTRACT FROM AUTHOR]

Plastics around the globe have been a matter of grave concern due to the unavoidable habits of human mankind. Taking waste statistics in India for the year 2019–20 into account, the data of 60 major cities show that the generation of plastic waste stands tall at around 26,000 tonnes/day, of which only about 60 % is recycled. A majority of the non‐recycled plastic waste is petrochemical‐based packaging materials that are non‐biodegradable in nature. Vegetative/food waste is another global issue, evidenced by vastly populated countries such as China and India accounting for 91 and 69 tonnes of food wastage, respectively in 2019. The mitigation of plastic packaging issues has led to key scientific developments, one of which is biodegradable materials. However, there is a way that these two waste‐related issues can be fronted as the analogy of "taking two shots with the same arrow". The presence of various bio‐compounds such as proteins, cellulose, starch, lipids, and waxes, etc., in food and vegetative waste, creates an opportunity for the development of biodegradable packaging films. Although these flexible packaging films have limitations in terms of mechanical, permeation, and moisture absorption characteristics, they can be fine‐tuned in order to convert the biobased raw material into a realizable packaging product. These strategies could work in replacing petrochemical‐based non‐biodegradable packaging plastics which are used in enormous quantities for various household and commercial packaging applications to combat the ever‐increasing pollution in highly populated countries. This paper presents a systematic review based on modern scientific tools of the literature available with a major emphasis on the past decade and aims to serve as a standard resource for the development of biodegradable packaging films from food/vegetative waste. [ABSTRACT FROM AUTHOR]

The effect of different amounts of pickering emulsion on the physical, thermal, and structural properties of gelatin nanocomposite film containing chitin nanocrystals (NCs) was examined in the present study. Pickering emulsions were produced using chitin NCs with 0.7, 1, and 1.3% concentrations, and their characteristics were investigated. The physical and thermal stability and zeta potential of the emulsion containing 1.3% nanocrystals were higher than those of the other emulsions; therefore, it was chosen to prepare the films. Nanocomposite films were produced with 10, 20, and 30% of pickering emulsion, and their physical, thermal, and structural characteristics were studied. The differential scanning calorimetry (DSC) thermograph showed good thermal stability of emulsion films compared to pure gelatin film. Fourier transform infrared spectroscopy (FT-IR) results confirmed the excellent compatibility of nanoparticles with gelatin film. The barrier property of emulsion films was better than that of pure gelatin film. Therefore, about 10% emulsion containing 1.3% nanoparticles in nanocomposite films can create biodegradable biopolymers for food packaging. • The amounts of 0.7, 1 and 1.3% chitin nanocrystals can make the emulsion stable for about one month. • Pickering emulsion containing the highest amount of nanoparticles leads to the highest stability and zeta potential, making it more suitable for preparing nanocomposite film. • Emulsion films containing the lowest emulsion concentration have the best mechanical and barrier (against water vapor and oxygen) properties. • FT-IR results confirm the excellent compatibility of nanoparticles with gelatin film. [ABSTRACT FROM AUTHOR]

This article focuses on agar biopolymer films that offer promise for developing biodegradable packaging, an important solution for reducing plastics pollution. At present there is a lack of data on the mechanical performance of agar biopolymer films using a simple plasticizer. This study takes a Design of Experiments approach to analyze how agar-glycerin biopolymer films perform across a range of ingredients concentrations in terms of their strength, elasticity, and ductility. Our results demonstrate that by systematically varying the quantity of agar and glycerin, tensile properties can be achieved that are comparable to agar-based materials with more complex formulations. Not only does our study significantly broaden the amount of data available on the range of mechanical performance that can be achieved with simple agar biopolymer films, but the data can also be used to guide further optimization efforts that start with a basic formulation that performs well on certain property dimensions. We also find that select formulations have similar tensile properties to thermoplastic starch (TPS), acrylonitrile butadiene styrene (ABS), and polypropylene (PP), indicating potential suitability for select packaging applications. We use our experimental dataset to train a neural network regression model that predicts the Young's modulus, ultimate tensile strength, and elongation at break of agar biopolymer films given their composition. Our findings support the development of further data-driven design and fabrication workflows. [ABSTRACT FROM AUTHOR]

The development of bio-based food packaging with antioxidant properties is an important research topic and has gained prominence these days. In this study, bioactive films were developed based gelatin-corn starch (GCS) incorporated with corn stigma extract (CSE) at different concentrations (15% and 25%; w / v). In preliminary tests, the extract maintained cell viability above 90% indicating that it is safe for application as an active ingredient. Insertion of the extract did not influence the thickness of the films but caused a slight change in optical properties. Scanning electron microscopy (SEM) analysis revealed interactions between the extract's bioactive compounds with gelatin and corn starch compounds, which may have improved the mechanical properties (elongation at break, Young's modulus). The addition of 25% corn stigma extract increased the contact angle, giving the film a hydrophobic character. Furthermore, at this concentration, a 15% reduction in water vapor permeability was observed. The elaborated films showed complete biodegradability before the tenth day of the study. It can be inferred that the films with corn stigma extract have good antioxidant properties, indicating that they can be used as an ingredient for food packaging. • Gelatin/cornstarch films were prepared with the addition of corn stigma extract. • 25% extract improved mechanical property, contact angle and water vapor barrier. • SEM analysis revealed a homogeneous structure of the prepared films. • The complete biodegradability of the films occurred before the tenth day of the study. • Films with bioactive extract exhibited remarkable antioxidant activity. [ABSTRACT FROM AUTHOR]

Cassava inner bark (CIB) and grape stalks (GS), residues from agro-industrial activities, were applied in the development of biodegradable foams by thermocompression. The samples produced with untreated stalks (sample GSWT) and with stalks only physically treated (sample GSP) presented good mechanical strength (2.1 MPa and 2.5 MPa, respectively) and low water absorption capacity (58% and 56% at 90 min, respectively). Therefore, these samples were selected for the storage of carrot cake and cherry tomatoes. Compared with the cakes stored in the supermarket packaging, there were no significant moisture content differences of the cakes stored in the biodegradable packaging developed by the formulation with the GSP sample (25% and 23%, respectively). The cakes' hardness increased up to 88% when stored in S + CIB + GSWT foam. More interesting, it was observed that the biodegradable packaging is more suitable for the storage of cherry tomatoes than the supermarket ones once the firmness of this product was maintained during storage (initial firmness of 5.4 N and final firmness of 5.3 N after 15 days in S + CIB packaging). Thus, biodegradable packaging developed from agro-industrial residues (CIB and GS) can be considered environmentally-friendly and promising materials to preserve the quality and freshness of carrot cake and cherry tomatoes. • Residues from cassava and grape processing were applied in foams development. • Foams' performance was evaluated in the storage of cake and tomatoes. • Most of the cakes' quality properties did not significantly change over time. • The freshness of cherry tomatoes was preserved longer in the biodegradable foams. • Biodegradable packaging is a good alternative for storage of cake and tomatoes. [ABSTRACT FROM AUTHOR]

In this study, starch/PBAT antimicrobial film, based on the synergistic effects of two commercial antimicrobial peptides, was fabricated by blown extrusion. The blends with nisin exhibited higher storage modulus and complex viscosity than those with ε-polylysine hydrochloride (ε-PL) alone. ATR-FTIR spectra revealed that new intermolecular hydrogen bonds were formed among starch, nisin, and ε-PL. XRD results indicated that antimicrobial peptides facilitated the destruction of the original crystalline structure of starch. Combination of ε-PL and nisin enhanced tensile strength, flexibility, moisture permeability, and oxygen barrier property of the films with more homogeneous morphology. SP-PN1/2 film (1% ε-PL + 2% nisin) exhibited over 90% inhibition rates against Staphylococcus aureus and Escherichia coli , and prolonged the shelf life of fresh peaches. The antimicrobial film with nisin and ε-PL showed high safety, cost-effectiveness, consumer acceptability, and thus it had a good application prospect in the food packaging field. [Display omitted] • Starch/PBAT films with antimicrobial peptides were fabricated by blown extrusion. • Combination of ε-PL and nisin led to more homogeneous morphology. • High proportion of ε-PL in ε-PL-nisin mixtures improved film performance. • ε-PL and nisin effectively inhibited the growth of S. aureus and E. coli. • The films with antimicrobial peptides extended the shelf life of fresh peaches. [ABSTRACT FROM AUTHOR]

In this review, a historical perspective, functional and application trends of natural polymers used to the development of edible food packaging were presented and discussed. Polysaccharides and proteins, i.e., alginate; carrageenan; chitosan; starch; pea protein, were considered. These natural polymers are important materials obtained from renewable plant, algae and animal sources, as well as from agroindustrial residues. Historically, some of them have been widely used by ancient populations for food packaging until these were replaced by petroleum-based plastic materials after World War II. Nowadays, biobased materials for food packaging have attracted attention. Their use was boosted especially because of the environmental pollution caused by inappropriate disposal of plastic packaging. Biobased materials are welcome to the design of food packaging because they possess many advantages, such as biodegradability, biocompatibility and low toxicity. Depending on the formulation, certain biopolymer-based packaging may present good barrier properties, antimicrobial and antioxidant activities Thus, polysaccharides and proteins can be combined to form diverse composite films with improved mechanical and biological behaviors, making them suitable for packaging of different food products. [ABSTRACT FROM AUTHOR]

Plant-based proteins as an alternative to synthetic polymers have attracted the interest of the global packaging industry in the last decade due to their biodegradability, sustainability, environmental, and beneficial health claims. This review covers the recent developments in biodegradable packaging such as edible films/coatings and innovative packaging materials based on plant protein sources. The importance, sources, and techno-functional properties of plant-derived proteins for food packaging are discussed. The impact of different additives on the functionality of plant protein-based biodegradable materials is also investigated. In addition, plant protein-based packaging characteristics and their application in food are also introduced. The sustainability, biodegradability, renewability, and appropriate mechanical and techno-functional properties of proteins from plant origin make them an emerging substitute to the conventional synthetic polymers currently used as food packaging. The functional performance of plant protein-based biodegradable materials can be extended or enhanced by incorporating other additives or biopolymers. Bio-packaging materials made from plant-based proteins provide great potential for enhancing food quality and safety, reducing the environmental pollution. Schematic representation of major plant sources with protein components as the origin of biopolymeric packaging materials for applications in food packaging. [Display omitted] • Plant-based protein films/coatings provide great potential for enhancing food quality. • Plant-based protein films/coatings are delivery systems for various bioactives. • Blending plant-based protein with nanoparticles improves functionality of coatings/films. • Plant-based protein packaging characteristics and their application in foods are summarized. [ABSTRACT FROM AUTHOR]

This study aimed to investigate the effects of polydimethylsiloxane (PDMS) with a low surface energy on the structure and physicochemical properties of starch/poly (butylene adipate- co -terephthalate) (PBAT) blown films. The film's appearance was not significantly changed after the addition of PDMS. Compared with the films without PDMS, the films with PDMS displayed a smoother surface. A 2% w/w PDMS addition resulted in the maximum mechanical properties (8.10 MPa of strength, 211.00% of modulus) and surface hydrophobicity (87°) of the films. By contrast, the film with 3% w/w PDMS showed the lowest light transmittance, water vapor (2.73 × 10−11 g·cm·cm2·s−1·Pa−1) and oxygen permeability (9.73 × 10−13·cm3·cm·cm−2·s−1·Pa−1), owing to the improved tightness of the matrix, which increased the zigzag path for molecules to pass through. Films with higher PDMS contents effectively extended the shelf life of packaged bananas and shiitake mushrooms, benefiting from the outstanding and appropriate barrier properties, according to principal component analysis results. Findings supported that high-content starch/PBAT films containing PDMS had potential in the preservation of fresh agricultural products. [Display omitted] [ABSTRACT FROM AUTHOR]

Two biobased composite films have been prepared with poly (lactic acid-trimethylene carbonate), polylactic acid and Laponite by solvent evaporation method. The 1H NMR and FTIR spectrums illustrate that P (LA-TMC) polymer is successfully synthesized and designed composite films are produced. Morphometric analyses demonstrate that the roughnesses of the film's surface and cross-section are on the increase with higher PLA and Laponite content. Mechanical performances reveal that the rise in tensile strength and modulus while maintaining excellent elongation at break is mainly due to the increase in the content of polylactic acid and Laponite. By utilizing the nano effect of Laponite, the maximum tensile strength of the composite film reaches 34.59 MPa. Thermal property results illustrate that the Tg and initial decomposition temperature are on the growth with the increase of PLA content. However, it is not significant on the effect of Laponite on the initial decomposition temperature. The water vapor permeability measurements prove that the barrier property of P(LA-TMC)/PLA/Laponite composite film is on the ascent with the Laponite addition. Hydrolytic degradation tests indicate that PLA and Laponite play avital part in accelerating the degradation rate of composite films and alkaline media is superior acidic and neutral conditions. [ABSTRACT FROM AUTHOR]

The development of active and smart packaging from non-conventional food sources is an ecological trend to ensure safe food supply in the food chain. The study aimed to develop multifunctional films based on alginate blended with different concentrations of purple onion peel (POPE) and butterfly-pea flower extract (BFE). The addition of the extracts increased the opacity of the films by 80 %, indicating greater UV-light barrier ability. The tensile strength and elongation at break of the films increased by 70 % and 30 %, while water vapor permeability decreased by 15 %. The interaction between the extract and the alginate positively modified the structure of the films, increasing the melting temperature of the films (112–131 °C). Mixing both extracts in the matrix generated materials with antioxidant activity, antimicrobial capabilities, and sensitivity to freshness factors (gases, pH, and temperature) superior to films added with a single extract, suggesting better active and intelligent performances. The films protected the color of food products against the effects of UV-light, being strongly capable of colorimetrically checking the deterioration of protein-rich products. Therefore, alginate films blended with POPE and BFE have a promising potential for developing smart materials, preserving, and monitoring the food quality. [Display omitted] • Alginate films were functionalized with extracts from two non-conventional sources. • The addition of two sources of bioactive compounds promoted better packaging performances. • Films with high bioactivity and freshness sensing potential were manufactured. • The color of banana and beef was preserved by the UV-light blocking films developed. • The freshness of shrimp and beef was duly monitored by the films developed. [ABSTRACT FROM AUTHOR]

Gelatin-sodium alginate-based active packaging films were formulated by including date pits extracts (DPE), as bioactive compound, in raw minced beef meat packaging. The DPE effects at 0.37, 0.75 and 1.5% (w/w, DPE/ gelatin-sodium alginate) on physical, optical, antioxidant and antibacterial properties of established films were assessed. Findings showed that film lightness decreased with the incorporation of DPE. Physical, antioxidant and anti-food-borne pathogens capacities were enhanced by increasing DPE concentration in the films. For 2,2-Diphenyl-1-picrylhydrazyl (DPPH) and 2,2'-azino-bis(3-ethylbenzothiazoline-6-sulfonic acid) (ABTS), the films with 1.5% DPE had the greatest levels (94 and 88%, respectively). DPE films (1.5%) also exhibited the highest anti- Listeria moncytogenes activity, with an inhibition zone of 25 mm. Moreover, during 14 days at 4 °C, the bio-preservative impact of gelatin-sodium alginate film impregnated with DPE at three levels on microbial, chemical, and sensory characteristics of meat beef samples was evaluated. By the end of the storage, DPE at 1.5% enhanced the instrumental color, delayed chemical oxidation and improved sensory traits. By chemometric techniques (principal component analysis (PCA) and heat maps), all data allowed to obtain helpful information by segregating all the samples at each storage time. PCA and heat maps could connect oxidative chemical changes, instrumental color parameters, and microbiological properties to sensory attributes. These data offer an approach to well interpreting the sensory quality and how they are affected by chemical and microbiological changes in the studied meat samples. Our findings indicated the potential of the gelatin-sodium alginate film incorporated with DPE for enhancing meat safety and quality. • Gelatin-sodium alginate based active packaging films including DPE were developed. • The DPE improved the optical, physical and biological properties of DPEs films. • The shelf-life of beef samples packed with DPE films was extended to 14 days. • Chemometric analysis showed significant correlation between the studied parameters. • The new prepared DPE films could be potentially used in food packaging. [ABSTRACT FROM AUTHOR]

Plastic pollution has posed a serious threat to the environment in the world. Biodegradable plastics can be widely expected to effectively mitigate plastic pollution. The subsequent industrial composting can also be treated to reduce the growing demand for landfills. In this research, the microorganisms responded to the biodegradation mechanism was proposed for the PBAT-PLA biodegradable packaging under the controlled industrial aerobic composting, according to the national standard (GB/T 19277.1-2011). Microcrystalline cellulose was used as reference material. The compost samples were taken on day 140 when the degradation was in the active period. The initial compost (before degradation), compost without any biodegradable material, compost with microcrystalline cellulose, and compost with PBAT-PLA packaging materials were then labeled as compost A, B, C, and D, respectively. The bacterial/fungal community was analyzed during degradation, including the species diversity, speciation, and species difference. A sample comparison was made through 16S/18S high-throughput sequencing of microorganisms in compost. The microscopic morphologies of PBAT-PLA packaging materials and microcrystalline cellulose were characterized by a Scanning Electron Microscope (SEM), in order to explore the intrinsic microbial response to the degradation mechanism. The results showed that the bacterial diversity of compost B under the industrial composting at 58 ± 2 ℃ was significantly lower than that of initial compost A since only some thermophilic bacteria survived. The bacterial diversities in compost C and D were significantly higher than that of compost B, due to the addition of cellulose or biodegradable packaging materials which provided carbon sources. There was no significant change in the fungal diversity, due to unsuitable for most fungi to survive at high temperatures. The fungal abundance changed, due to the temperature and carbon source in the compost, where the compost B (blank sample) showed the lowest fungal abundance. The dominant bacteria in the compost C and D were Sphaerobacter, Longispora, norank_f_norank_o_Actinomarinales, and Rubrobacter, which belonged to Actinomycete. The student’s T-test was used to compare the composition of bacteria and fungi in the compost C and D with those in the compost B. The significant growing bacteria in the compost C and D, including norank_f_Euzebyaceae, unclassified_c_Actinobacteria, and Actinobacteria, belonged to Actinomycetes. Therefore, there were similar degrading microorganisms of PBAT-PLA membrane bag and microcrystalline cellulose at (58±2) ℃. The SEM images showed that the surface of PBAT-PLA packaging after degradation was covered with a layer of biofilm. The biofilm was mainly composed of the clusters of ellipsoid bacteria, which were inferred to be Sphaerobacter. Actinomycetes presented a positive effect on the depolymerization of polyester and the degradation of cellulose under industrial composting conditions. The complete biodegradation of polyester and cellulose depended on the microbial synergy, rather than a single strain. Therefore, the dominant bacteria and significant growth bacteria of biodegradable materials under industrial composting conditions can be expected to serve as a theoretical basis for screening key biodegradation bacteria in the future. It can also greatly contribute to breaking through the technical barriers of the long detection cycle with the current biodegradation for higher efficiency and speed. The identification of microbial communities can be an important indicator to evaluate the impact of the compost produced by biodegradable plastics on crops growth, and agricultural ecological environment. Consequently, a theoretical foundation can be made to optimize the industrial composting and biodegradable plastic testing standards. The finding can also provide a scientific basis for the large-scale promotion of biodegradable plastic films and the application of the compost produced from biodegradable plastics in advanced (or modern) agriculture. [ABSTRACT FROM AUTHOR]

Summary: Starch‐based films incorporated with cellulose nanofibres (CNFs) were tested as packaging to improve the stability of cashew nut kernels (CNKs). CNKs were conditioned in four packings: commercial polyethylene film (PEF), starch film (CF), nanocomposite CHF (starch + CNFs from chemical hydrolysis) and nanocomposite EHF (starch + CNFs from enzymatic hydrolysis). Effect of the packaging methods on peroxides value (POV), acidity value (AV), weight gain (WG), water activity (Aw), hardness and colour properties of the CNKs was investigated. CNKs packed with CHF and EHF showed lower POV (0.91 and 0.92 meqperoxide/kgsample, respectively) after 21 days of storage than other packed (1.07–1.13 meqperoxide/kgsample) and unpacked samples (1.32 meqperoxide/kgsample). CNKs packaged with nanocomposites presented similar WG to samples packaged with PEF and lower values than unpackaged CNKs. Biodegradable nanocomposites films showed potential to be used as packaging for food product, being an effective material for extending oilseeds shelf life. [ABSTRACT FROM AUTHOR]

This study reviews the importance of gelatin, nanoparticles and their interactions in the formulation of biodegradable composite films. Gelatin is widely used in packaging because of its unique characteristics, i.e., film-forming ability and barrier properties. However, high moisture sensitivity and hydrophilic nature of gelatin restrict its application in food packaging. Therefore, gelatin is used in the formulation of composite films with better functional and barrier properties for food packing. The incorporation of nanoparticles (NPs) in gelatin film-forming solution improves the mechanical, thermal, barrier and optical characteristics of gelatin composite films. Furthermore, this review compiles the functional properties of gelatin extracted from different sources and functional characteristics of gelatin composite films incorporated with different NPs. [ABSTRACT FROM AUTHOR]

In the modern minds of the advanced ecology and safety of food products control, it is relevant the development of antimicrobial biodegradable packaging. The article presents the results of the antagonistic action of nanodispersed titanium dioxide powder (TiO2) at the warehouse of biodegradable packaging for bakery products on the living of microorganisms (Escherichia сoli, Bacillus subtilis, Candida albicans, Aspergillus niger). It is known there are developments on the use of antimicrobial substances of both organic and inorganic origin, the microbiological action of the substances used have an effect on pathogenic, opportunistic, fungi, gram-negative and gram-positive bacteria. We found that the introduction of 1% TiO2 r into the molding solution allows to give the package antibacterial properties, as it inhibits the development of Escherichia coli and Bacillus subtilis, as there is a delay in the growth of their colonies compared to the sample without packaging with TiO2. According to the results of provocative testing, biodegradable packaging with a content of 1% TiO2 has an inhibitory effect on Bacillus subtilis. In addition to antimicrobial properties, the package under study must also have barrier properties, so the vapor permeability of the presented package was determined. The study results show that the addition of 1% TiO2 slightly reduces the vapor permeability, but the increase in the concentration 2–5 % of TiO2 causes an increase in vapor permeability from 4.7 to 5.2 mg / (m∙h∙kPa). The vapor permeability of the presented biodegradable antimicrobial packaging is due to the presence of pores, the number and size of which were determined experimentally. Thus, nanodispersed TiO2 in the amount of 1% in the molding solution of the biodegradable coating is an effective antimicrobial component for antimicrobial coatings, which does not impair their barrier properties. [ABSTRACT FROM AUTHOR]

Summary: The effects of ultraviolet (UV)‐C irradiation on the physicochemical properties of oyster mushroom polysaccharide (OMP) films were investigated. The prepared OMP films were subjected to UV‐C treatment (5.4 kJ m−2). UV‐C irradiation increased the tensile strength and decreased the water vapour permeability of the OMP films. In addition, the incorporation of 1.0% Cudrania tricuspidata leaf extract (CTLE) enhanced the antioxidant activity as well as antimicrobial activity of OMP films; however, UV‐C treatment did not affect the activities of films containing CTLE. Furthermore, UV‐C‐irradiated films had higher contact angles than non‐irradiated films, indicating increased surface hydrophobicity. Microstructural imaging revealed that UV‐C treatment caused the surface of treated films to be smoother than that of untreated films owing to surface degradation. These results indicated that UV‐C irradiation can be used for OMP films to improve film properties that are associated with application of films as food packaging material. [ABSTRACT FROM AUTHOR]

Polysaccharide-based packaging has been directed toward the development of technologies for the generation of packaging with biodegradable materials that can serve as substitutes for conventional packaging. Polysaccharides are reliable sources of edible packaging materials with excellent renewability, biodegradability, and bio-compatibility as well as antioxidant and antimicrobial activities. Apart from these properties, packaging film developed from a single polysaccharide has various disadvantages due to undesirable properties. Thus, to overcome these problems, researchers focused on ternary blend-based bio-packaging instead of the primary and binary complex to improve their characteristics and properties. The review emphasizes the extraction of polysaccharides and their combination with other polymers to provide desirable characteristics and physico-mechanical properties of the biodegradable film which will upgrade the green packaging technology in the future generation This review also explores the advancement of ternary blend-based biodegradable film and their application in foods with different requirements and the future aspects for developing advanced biodegradable film. Moreover, the review concludes that cellulose, modified starch, and another plant-based polysaccharide film mostly provides good gas barrier property and better tensile strength, which can be used as a safeguard of perishable and semi-perishable foods which brings them closer to replacing commercial synthetic packaging. [Display omitted] • Conventional plastic causes environmental pollution and adverse effect on human health. • Plant-based polysaccharides are used as an alternative packaging to enhance characteristics. • Ternary complex packaging can enhance the physio-mechanical and barrier properties. • Film application shows a new direction in the intelligent packaging industry. [ABSTRACT FROM AUTHOR]

Polysaccharide-based packaging has been directed toward the development of technologies for the generation of packaging with biodegradable materials that can serve as substitutes for conventional packaging. Polysaccharides are reliable sources of edible packaging materials with excellent renewability, biodegradability, and bio-compatibility as well as antioxidant and antimicrobial activities. Apart from these properties, packaging film developed from a single polysaccharide has various disadvantages due to undesirable properties. Thus, to overcome these problems, researchers focused on ternary blend-based bio-packaging instead of the primary and binary complex to improve their characteristics and properties. The review emphasizes the extraction of polysaccharides and their combination with other polymers to provide desirable characteristics and physico-mechanical properties of the biodegradable film which will upgrade the green packaging technology in the future generation This review also explores the advancement of ternary blend-based biodegradable film and their application in foods with different requirements and the future aspects for developing advanced biodegradable film. Moreover, the review concludes that cellulose, modified starch, and another plant-based polysaccharide film mostly provides good gas barrier property and better tensile strength, which can be used as a safeguard of perishable and semi-perishable foods which brings them closer to replacing commercial synthetic packaging. [Display omitted] • Conventional plastic causes environmental pollution and adverse effect on human health. • Plant-based polysaccharides are used as an alternative packaging to enhance characteristics. • Ternary complex packaging can enhance the physio-mechanical and barrier properties. • Film application shows a new direction in the intelligent packaging industry. [ABSTRACT FROM AUTHOR]

Summary: Biopolymer films were prepared using pectin extracted from mandarin peel, a by‐product of fruit processing. Varying amounts (0.6%, 1.0% and 1.4%) of sage leaf extract (SLE) were also added to mandarin peel pectin (MPP) films to enhance its antioxidant abilities. Compared with the MPP film alone, the total phenolic contents of the MPP films containing SLE were higher. The MPP film with 0.6% SLE possessed the most desirable physical properties with tensile strength of 23.31 MPa and an elongation at break of 18.82%. We used four different methods to identify the antioxidant property of the MPP films with SLE, and the results showed that the antioxidant activity increased with increase in the amount of SLE added. In contrast, the addition of SLE lowered the thermal stability and water resistance of the MPP film. These results indicate that the developed MPP films containing SLE can be potentially used for food‐based applications. [ABSTRACT FROM AUTHOR]

Summary: The results of infestation by maize weevil, Sitophilus zeamais (Coleoptera, Curculionidae), in different packaging filled with pasta are presented in this research. Three different types of packaging were used, that is, two paper tubes (one novel, laminated with bio‐based polyethylene and one without lamination) and commercial polypropylene, pillow pouch packaging. Material properties such as grammage, thickness, surface analysis, moisture and water resistance, tensile and compressive strength were analysed. Improved compressive strength, moisture and water resistance were detected at the bio‐polyethylene laminated tube packaging (approx. 30%), compared to the non‐laminated sample. The obtained results demonstrated that adult maize weevils revealed significant preferences to enter the pasta packages through the already existing holes which were in the polypropylene packaging, while no infestation was observed inside the packages at the paper tube packaging. The study revealed that the shape and construction, for example, tube packaging with an innovative bio‐polyethylene film, are very effective regarding insect infestation and mechanical overloads. [ABSTRACT FROM AUTHOR]

Biodegradable packaging from natural biopolymers can be further enhanced with antimicrobial and antioxidant agents to form active packaging. Plant extracts are attractive components for biodegradable food packaging owing to their natural origin and functionality (antimicrobial/antioxidant activity). Here we demonstrate the effect of bioactive contents of tropical plants and their by-products as promising natural ingredients in the fabrication of biopolymer food packaging. Different parts of tropical plants, such as leaves, flowers, seeds, and roots, can potentially be utilized for new and green packaging systems due to their biological nature. In the food industry, lipid oxidation and microbial spoilage are two problems which reduce the shelf life of food products. It seems that the use of potential bioactive agents in biodegradable packaging is a promising strategy to solve this problem, offering a green alternative to traditional packaging and enhancing the shelf-life of food. Image 1 • Antimicrobial tropical plants mostly disseminate efficiently in bio-active packaging. • Byproducts of tropical plants can impart antimicrobial and antioxidant properties. • Active packaging with natural antimicrobial/antioxidant agents enhances food shelf life. [ABSTRACT FROM AUTHOR]

This study was aimed to develop and investigate the characteristics of the intelligent films made from gelatin with oleic acid (OA) and anthocyanin extract incorporation. Anthocyanin was extracted from red cabbage (RC), sweet potato (SP), black bean coat seed (BB), and purple rice (CR), and then tested for pH sensitivity. Anthocyanin from SP was selected as it showed the highest pH sensitivity. Gelatin film was incorporated with 20% of anthocyanin extract and 50% OA. The films with OA and anthocyanin extracts incorporation was selected for application as the color changes can be observed clearly at pH 2 -11. Red color was present on the film added with anthocyanin extract from SP. OA incorporation significantly decreased the elongation of the film, while it was on the contrary for anthocyanin extract incorporation. Both OA and anthocyanin extracts incorporation decreased thickness, moisture content, and tensile strength of the film significantly (P<0.05). Additionally, there was a reduction trend of water vapor permeability for gelatin film incorporated with OA and anthocyanin. However, this reduction was insignificantly different with the control (P>0.05). The incorporation of OA provided wavier surfaces while anthocyanin extract incorporation enhanced the compactness and smoothness of the films, and provided smoother surfaces of the film. A higher enthalpy was needed for melting the film with anthocyanin extract. [ABSTRACT FROM AUTHOR]

In this study, bio-based emitting sachets containing eugenol (EUG), carvacrol (CAR) and trans -anethole (ANT) were inserted into cellulose (CE) and polypropylene (PP) pillow packages of organic ready-to-eat (RTE) iceberg lettuce to investigate their functional features. EUG, CAR and ANT sachets in CE; and CAR in PP packages showed antimicrobial activities against coliforms (Δlog CFU g –1 of −1.38, −0.91, −0.93 and −0.93, respectively). EUG and ANT sachets in both packages reduced discoloration (ΔE of 9.5, 1.8, 9.4 and 5.6, respectively). ANT in both, and EUG only in PP packages induced biosynthesis of caffeoyl derivatives (C a T A , D i C a T A , D i C a Q A ), total phenolics and antioxidant activity (FRAP). Also, ANT and EUG in both packages improved overall freshness and odor. Principal component analysis separated ANT and EUG from CAR in both packages. The Pearson correlation confirmed that overall quality improvements were more pronounced by ANT inside the packages in comparison to EUG and CAR. [ABSTRACT FROM AUTHOR]

In the present work, the composite films were obtained by the solution casting method from chitosan and rice protein hydrolysates, reinforced with cellulose nanocrystals (CNC) of different contents (0 %, 3 %, 6 % and 9 %). The influence of different CNC loadings on the mechanical, barrier and thermal properties was discussed. SEM showed the formation of intramolecular interactions between the CNC and film matrices, leading to more compact and homogeneous films. These interactions had a positive influence on the mechanical strength properties, which was reflected in higher breaking force of 4.27 MPa. The elongation dwindled from 132.42 % to 79.37 % with increasing CNC levels. The linkages formed between the CNC and film matrices reduced the water affinity, leading to a reduction in their moisture content, water solubility and water vapor transmission. Thermal stability of the composite films was also improved in the presence of CNC, by increasing maximum degradation temperature from 311.21 to 325.67 °C with increasing CNC contents. The strongest DPPH inhibition of the film was 45.42 %. The composite films exhibited the highest inhibition zone diameter against E. coli (12.05 mm) and S. aureus (12.48 mm), and the hybrid of CNC and ZnO nanoparticles exhibited stronger antibacterial activity than their single existent forms. The present work shows the possibility of obtaining CNC-reinforced films with improved mechanical, thermal and barrier properties. • The tensile strength increased from 2.12 to 4.27 MPa with the presence of CNC. • Solubility and water vapor transmission fell by 13.63 % and 20.96 %, respectively. • The inhibition zone of S. aureus was increasing from 7.95 mm to 12.48 mm. • The film with 3 % CNC had the highest inhibition zone against E. coli of 12.05 mm. [ABSTRACT FROM AUTHOR]

Interest increased recently in manufacturing food packaging, such as films and coatings, from protein-based biopolymers. Among various protein sources, canola protein is a novel source for manufacturing polymer films. It can be concentrated or isolated by aqueous extraction technology followed by protein precipitation. Using this procedure, it was claimed that more than 99% of protein was extracted from the defatted canola meal, and protein recovery was 87.5%. Canola protein exhibits thermoplastic properties when plasticizers are present, including water, glycerol, polyethylene glycol, and sorbitol. Addition of these plasticizers allows the canola protein to undergo glass transition and facilitates deformation and processability. Normally, canola protein-based bioplastics showed low mechanical properties, which had tensile strength (TS) of 1.19 to 4.31 MPa. So, various factors were explored to improve it, including blending with synthetic polymers, modifying protein functionality through controlled denaturation, and adding cross-linking agents. Canola protein-based bioplastics were reported to have glass transition temperature,Tg, below −50°C but it highly depends on the plasticizer content. Canola protein-based bioplastics have demonstrated comparable mechanical and moisture barrier properties compared with other plant protein-based bioplastics. They have great potential in food packaging applications, including their use as wraps, sacks, sachets, or pouches. [ABSTRACT FROM PUBLISHER]

Cassava starch was grafted with three different esters by the etherification reaction and its modification was characterized by 1 H NMR, FTIR, DSC, SEM, XDR, contact angle and SLS. The samples grafted with diethyl maleate, dipropyl maleate, and dibutyl maleate showed DS values of 2.3, 1.0 and 2.0, respectively, determined from 1 H NMR analysis and confirmed by FTIR analysis, with the appearance of bands at 1721, 1550 and 1126 cm −1 . The FTIR, XRD, SEM and DSC results indicated a change in the intra and intermolecular hydrogen interactions in the grafted starch when compared to native starch. Based on the contact angles, it was observed that the macromolecular starch chain acquired hydrophobic characteristics through the substitution of the hydrogens with di maleate esters. The characteristics acquired by grafted starch allow it to be used for the encapsulation of bioactive molecules for the production of bioactive packages and the production of biodegradable packages. [ABSTRACT FROM AUTHOR]

This study aimed to improve the properties of whey protein isolate (WPI) films by incorporating palm oil (6, 7, and 8% w/w) and glycerol (40, 50 and 60% w/w). The lightness of the films increased as glycerol levels increased, but the redness increased with the increased amount of oil content. Increasing the amounts of palm oil and glycerol improved flexibility (P<0.05), but reduced the strength of the film (P<0.05). Films with higher levels of palm oil and lower amounts of glycerol were less permeable to water vapor and oxygen, but more thermally stable. The size of particles and air bubbles in the films reduced with increased palm oil content, regardless of glycerol level. Among all formulae, the film prepared with 8% palm oil and 40% glycerol showed the best overall results. Modifying WPI films with palm oil and glycerol offers a simple technique for producing packaging with better environmental barrier properties. [ABSTRACT FROM AUTHOR]

The aim of this study was to verify the effectiveness of an active biodegradable film on the maintenance of extra-virgin olive oil (EVOO) quality attributes. Level of peroxides, acidity, K232, color, chlorophylls, and carotenoids were determined as parameters to verify the oil quality over storage period. Maltodextrin was used to encapsulate anthocyanins and was the major component in the films, which were used as pouches to pack the oil. The samples were stored at 40°C, exposed to fluorescent light, and monitored during 12 days. The film successfully maintained the quality of EVOO under the limits established by Codex Alimentarius for over 8 days (13.6 meq O2/kg of peroxides at the 8th day), while the oil packed in polypropylene pouches was degraded before the 4th day of storage (326.5 meq O2/kg). Therefore, the results demonstrated the effectiveness of the film on maintaining the quality of EVOO and its promising application as active packaging. Practical application Extra-virgin olive oil (EVOO) is an oxidation-sensitive product and has been shown to quickly deteriorate when stored under less than ideal conditions. The study brings a new packaging possibility to the commercialization of EVOO with longer shelf-life. The storage of extra-virgin olive oil in biodegradable pouches produced with anthocyanins could preserve EVOO from oxidation and consequently extent its shelf-life. The study proves the efficacy of an active biodegradable packaging on maintaining quality attributes of EVOO. The commercialization of EVOO in active biodegradable pouches could be an eco-friendly and sustainable way to bring health and practicality to consumers. [ABSTRACT FROM AUTHOR]

Purpose The purpose of this paper is to acquaint the readers with recent developments in biopolymer-based food packaging materials like natural biopolymers (such as starches and proteins), synthetic biopolymers (such as poly lactic acid), biopolymer blending and nanocomposites grounded on natural and synthetic biopolymers. This paper is an attempt to draw the readers towards the advantages and attributes of new era polymers to diminish the usage of traditional non-biodegradable polymers.Design/methodology/approach Plastic packaging for food and associated applications is non-biodegradable and uses up valuable and treasured non-renewable petroleum products. With the current focus on researching alternatives to petroleum, research is progressively being channelized towards the development of biodegradable food packaging, thereby reducing adverse impact on the environment.Findings Natural biopolymer-based nanocomposite packaging materials seem to have a scintillating future for a broad range of applications in the food industry, including advanced active food packaging with biofunctional attributes. The present review summarizes the scientific information of various packaging materials along with their attributes, applications and the methods for production.Originality/value This is an apropos review as there has been a recent renewed concern in research studies, both in the industry and academe, for development of new generation biopolymer-based food packaging materials, with possible applications in many areas. [ABSTRACT FROM AUTHOR]