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Context. Barium (Ba) stars are dwarf and giant stars enriched in elements heavier than iron produced by the slow neutron-capture process (s process). They belong to binary systems where the primary star evolved through the asymptotic giant branch (AGB) phase,during which it produced the s-process elements and transferred them onto the secondary, now observed as a Ba star. Aims. We compare the largest homogeneous set of Ba giant star observations of the s-process elements Y, Zr, La, Ce, and Nd with AGB nucleosynthesis models to reach a better understanding of the s process in AGB stars. Methods. By considering the light-s (ls: Y and Zr) heavy-s (hs: La, Ce, and Nd) and elements individually, we computed for the first time quantitative error bars for the different hs-element/ls-element abundance ratios, and for each of the sample stars. We compared these ratios to low-mass AGB nucleosynthesis models. We excluded La from our analysis because the strong La lines in some of the sample stars cause an overestimation and unreliable abundance determination, as compared to the other observed hs-type elements. Results. All the computed hs-type to ls-type element ratios show a clear trend of increasing with decreasing metallicity with a small spread (less than a factor of 3). This trend is predicted by low-mass AGB models where 13C is the main neutron source. The comparison with rotating AGB models indicates the need for the presence of an angular momentum transport mechanism that should not transport chemical species, but significantly reduce the rotational speed of the core in the advanced stellar evolutionary stages. This is an independent confirmation of asteroseismology observations of the slow down of core rotation in giant stars, and of rotational velocities of white dwarfs lower than predicted by models without an extra angular momentum transport mechanism., Comment: 15 pages, 7 figures, accepted for publication in Astronomy and Astrophysics

In this paper we present an homogeneous analysis of photospheric abundances based on high-resolution spectroscopy of a sample of 182 barium stars and candidates. We determined atmospheric parameters, spectroscopic distances, stellar masses, ages, luminosities and scale height, radial velocities, abundances of the Na, Al, $alpha$-elements, iron-peak elements, and s-process elements Y, Zr, La, Ce, and Nd. We employed the local-thermodynamic-equilibrium model atmospheres of Kurucz and the spectral analysis code {\sc moog}. We found that the metallicities, the temperatures and the surface gravities for barium stars can not be represented by a single gaussian distribution. The abundances of $alpha$-elements and iron peak elements are similar to those of field giants with the same metallicity. Sodium presents some degree of enrichment in more evolved stars that could be attributed to the NeNa cycle. As expected, the barium stars show overabundance of the elements created by the s-process. By measuring the mean heavy-element abundance pattern as given by the ratio [s/Fe], we found that the barium stars present several degrees of enrichment. We also obtained the [hs/ls] ratio by measuring the photospheric abundances of the Ba-peak and the Zr-peak elements. Our results indicated that the [s/Fe] and the [hs/ls] ratios are strongly anti-correlated with the metallicity. Our kinematical analysis showed that 90% of the barium stars belong to the thin disk population. Based on their luminosities, none of the barium stars are luminous enough to be an AGB star, nor to become self-enriched in the s-process elements. Finally, we determined that the barium stars also follow an age-metallicity relation., Comment: 30 pages, 26 figures, 18 tables, accepted for publication in MNRAS

High-velocity halo stars provide important information about the properties of the extreme Galactic halo. The study of unbound and bound Population II stars permits us to better estimate the mass of the halo.} {We carried out a detailed spectroscopic and kinematic study and have significantly refined the distance and the evolutionary state of the star. Its atmospheric parameters, chemical abundances and kinematical properties were determined using high-resolution optical spectroscopy and employing the local-thermodynamic-equilibrium model atmospheres of Kurucz and the spectral analysis code {\sc moog}. We found that CD-62$\degr$1346 is a metal-poor ([Fe/H]=$-$1.7) evolved giant star with $T_{\rm eff}=5300$ K and $\log g=1.7$. The star exhibits high carbon and s-element abundances typical of CH stars. It is also a lead star. Our kinematic analysis of its 3D space motions shows that this star has a highly eccentric ($e=0.91$) retrograde orbit with an apogalactic distance of $\sim 100$ kpc, exceeding by a factor of three the distance to the Magellanic Clouds. The star travels with very high velocity relative to the Galactocentric reference frame ($V_{\rm GRF}=570$ km\,s$^{-1}$). CD-62$\degr$1346 is an evolved giant star and not a subgiant star, as was considered earlier. Whether it is bound or unbound to the Galaxy depends on the assumed mass and on the adopted Galactic potential. We also show that the star HD 5223 is another example of a high-velocity CH star that exceeds the Galactic escape velocity. Possible origins of these two high-velocity stars are briefly discussed. CD-62$\degr$1346 and HD 5223 are the first red giant stars to join the restricted group of hypervelocity stars., Comment: Accepted for publication in Astronomy and Astrophysics