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We present an experimental study on the etching of detonation nanodiamond (DND) seeds during typical microwave chemical vapor deposition (MWCVD) conditions leading to ultra-thin diamond film formation, which is fundamental for many technological applications. The temporal evolution of the surface density of seeds on Si(100) substrate has been assessed by scanning electron microscopy (SEM). The resulting kinetics have been explained in the framework of a model based on the effect of particle size, according to the Young-Laplace equation, on both chemical potential of carbon atoms in DND and activation energy of reaction. We found that seeds with size smaller than a critical radius, r*, are etched away while those greater than r* can grow. Finally, the model allows to estimate the rate coefficients for growth and etching from the experimental kinetics., Comment: 28 pages; 15 Figures, 3 Tables

In the present article we describe the calibration measurements of the compact neutron spectrometer at certified PTB neutron source. The spectrometer is based on two diamond detectors enclosing the Li-6 neutron converter. The incident neutron energy is measured through the sum of energies of the two conversion reaction products: t and alpha. The prototype used in this work was based on two 4x4 mm2, 100 um thick single crystal CVD commercial diamond plates. The measurements were performed in the fission spectrum domain at five different neutron energies varying from 0.3 up to 2 MeV. The obtained data showed a very good neutron energy reconstruction, i.e. in agreement with its reference values within statistical uncertainties or with deviation below 11 keV in absolute scale. The energy resolution of the spectrometer was found to be about 100 keV (RMS) with a small (about 9 keV/MeV) rising trend towards higher energies. The measured detection efficiency was found to be compatible with expectations based on analytical calculations and on Geant4 simulations within 3% statistical and 4% systematic precision., Comment: 20 pages, 14 figures

In this paper a new version of Li6-based neutron spectrometer for high flux environments is described. The new spectrometer was built with commercial single crystal Chemical Vapour Deposition diamonds of electronic grade. These crystals feature better charge collection as well as higher radiation hardness. Ohmic metal contacts were deposited on the diamonds suppressing build-up of space charge observed in the previous prototypes. New passive preamplification of signal at detector side was implemented to improve the resolution. This preamplification is based on RF transformer not sensitive to high neutron flux. Compact mechanical design allowed to reduce detector size to a tube of 1 cm diameter and 13 cm long. The spectrometer was tested in thermal column of TRIGA reactor and at DD neutron generator. The test results indicate an energy resolution of 72 keV (RMS) and coincidence timing resolution of 68 ps (RMS). The measured data are in agreement with Geant4 simulations except for larger energy loss tail presumably related to imperfections of metal contacts and glue expansion., Comment: 18 pages, 10 figures