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We re-examine the likelihood for alien civilizations to develop communication technology on the basis of the general assumption that life elsewhere could have a non-carbon chemical foundation. We particularized the discussion to a complex silicon-based biochemistry in a nitrogen solvent, and elaborate on the environment in which such a chemistry is feasible, and if so, on what scales. More concretely, we determine the region outside the habitable zone where such organisms can grow and flourish and after that we study how our findings impact the recently derived upper limit on the fraction of living intelligent species that develop communication technology $\langle \xi_{\rm biotec} \rangle$. We also compare this new restriction on $\langle \xi_{\rm biotec} \rangle$ with that resulting from the extension of the habitable zone to accommodate subsurface exolife, originating in planets with subsurface (water) oceans., Comment: To be published in the International Journal of High School Research (IJHSR)

The Fermi paradox is the discrepancy between the strong likelihood of alien intelligent life emerging (under a wide variety of assumptions) and the absence of any visible evidence for such emergence. We use this intriguing unlikeness to derive an upper limit on the fraction of living intelligent species that develop communication technology <\xi_{biotec}>. <...> indicates average over all the multiple manners civilizations can arise, grow, and develop such technology, starting at any time since the formation of our Galaxy in any location inside it. Following Drake, we factorize <\xi_{biotec}> as the product of the fractions in which: (i) life arises, (ii) intelligence develops, and (iii) communication technology is developed. In this approximation, the number of communicating intelligent civilizations that exist in the Galaxy at any given time is found to be N = <\zeta_{astro}> <\xi_{biotec}> L_\tau, where <\zeta_{astro}> is the average production rate of potentially habitable rocky planets with a long-lasting (~ 4 Gyr) ecoshell and L_{\tau} is the length of time that a typical civilization communicates. We estimate the production rate of exoplanets in the habitable zone and using recent determinations of the rate of gamma-ray bursts (GRBs) and their luminosity function, we calculate the probability that a life-threatening (lethal) GRB could make a planet inhospitable to life, yielding <\zeta_{astro}> ~ 2 \times 10^{-3} yr^-1. Our current measurement of N =0 then implies <\zeta_{biotec}> < 5 \times 10^{-3} at the 95\% C.L., where we have taken L_\tau > 0.3 Myr such that c L_\tau >> propagation distances of Galactic scales (~ 10 kpc), ensuring that any advanced civilization living in the Milky Way would be able to communicate with us., Comment: To be published in Proceedings of the 35th International Cosmic Ray Conference (ICRC 2017), Bexco, Busan, Korea; v2 references added

The excitonic finestructure of colloidal quantum dots (CQDs) is comprised of a manifold of transitions, of which only the lowest are populated and contribute to photoluminescence. This leads to a Stokes shift in emission relative to absorption. Here we show experimentally that the Stokes shift in Pb and Cd-based chalcogenide CQDs is correlated with the degree of surface passivation, and develop a model that explains how coupling to the surface affects the core electronic states. Dark and bright transitions can reorder and split, increasing the Stokes shift even without the formation of deep traps. Our findings resolve the highly-debated topic of excess Stokes shifts in PbS nanocrystals as due to parity-forbidden transitions instead of traps. We predict that the Stokes shift in PbS can be eliminated via core stoichiometry control, a critical step towards enhancing the open circuit voltage in quantum dot solar cells.

We present a detailed experimental characterization of the spectral and spatial structure of the confined optical modes for oxide-apertured micropillar cavities, showing good-quality Hermite-Gaussian profiles, easily mode-matched to external fields. We further derive a relation between the frequency splitting of the transverse modes and the expected Purcell factor. Finally, we describe a technique to retrieve the profile of the confining refractive index distribution from the spatial profiles of the modes., Comment: 4 pages, 3 figures

We experimentally characterize the spatial far-field emission profiles for the two lowest confined modes of a photonic crystal cavity of the L3 type, finding a good agreement with FDTD simulations. We then link the far-field profiles to relevant features of the cavity mode near-fields, using a simple Fabry-Perot resonator model. The effect of disorder on far-field cavity profiles is clarified through comparison between experiments and simulations. These results can be useful for emission engineering from active centers embedded in the cavity., Comment: 9 pages, 7 figures

Photonic crystal membranes (PCM) provide a versatile planar platform for on-chip implementations of photonic quantum circuits. One prominent quantum element is a coupled system consisting of a nanocavity and a single quantum dot (QD) which forms a fundamental building block for elaborate quantum information networks and a cavity quantum electrodynamic (cQED) system controlled by single photons. So far no fast tuning mechanism is available to achieve control within the system coherence time. Here we demonstrate dynamic tuning by monochromatic coherent acoustic phonons formed by a surface acoustic wave (SAW) with frequencies exceeding 1.7 gigahertz, one order of magnitude faster than alternative approaches. We resolve a periodic modulation of the optical mode exceeding eight times its linewidth, preserving both the spatial mode profile and a high quality factor. Since PCMs confine photonic and phononic excitations, coupling optical to acoustic frequencies, our technique opens ways towards coherent acoustic control of optomechanical crystals., Comment: 11 pages 4 figures

Systems of photonic crystal cavities coupled to quantum dots are a promising architecture for quantum networking and quantum simulators. The ability to independently tune the frequencies of laterally separated quantum dots is a crucial component of such a scheme. Here, we demonstrate independent tuning of laterally separated quantum dots in photonic crystal cavities coupled by in-plane waveguides by implanting lines of protons which serve to electrically isolate different sections of a diode structure., Comment: 3 pages, 3 figures