Search

Beamline I22 at Diamond Light Source is dedicated to the study of soft matter systems from both biological and materials science. The beamline can operate in the range 3.7 keV to 22 keV for transmission SAXS and 14 keV to 20 keV for microfocus SAXS with beamsizes 240 x 60 {\mu}m$^{2}$ spot [Full width half maximum (FWHM) Horizontal (H) x Vertical (V)] at sample for the main beamline, and approximately 10 x 10 {\mu}m$^{2}$ for the dedicated microfocussing platform. There is a versatile sample platform for accommodating a range of facility, and user developed, sample environments. The high brilliance of the insertion device source on I22 allows structural investigation of materials under extreme environments (for example fluid flow at high pressures and temperatures). I22 provides reliable access to millisecond timescales, essential to understanding kinetic processes such as early folding events in proteins or structural evolution in polymers and colloids., Comment: Preprint. 27 pages, 5 figures. Supplementary Info. 8 pages, 7 figures

Echelle spectra of HD 183143 [B7Iae, E(B-V) = 1.27] were obtained on three nights, at a resolving power R = 38,000 and with a signal-to-noise ratio ~1000 at 6400 A in the final, combined spectrum. A catalog is presented of 414 diffuse interstellar bands (DIBs) measured between 3900 and 8100 A in this spectrum. The central wavelengths, the widths (FWHM), and the equivalent widths of nearly all of the bands are tabulated, along with the minimum uncertainties in the latter. Among the 414 bands, 135 (or 33%) were not reported in four previous, modern surveys of the DIBs in the spectra of various stars, including HD 183143. The principal result of this study is that the great majority of the bands in the catalog are very weak and fairly narrow. Typical equivalent widths amount to a few mA, and the bandwidths (FWHM) are most often near 0.7 A. No preferred wavenumber spacings among the 414 bands are identified which could provide clues to the identities of the large molecules thought to cause the DIBs. At generally comparable detection limits in both spectra, the population of DIBs observed toward HD 183143 is systematically redder, broader, and stronger than that seen toward HD 204827 (Paper II). In addition, interstellar lines of C2 molecules have not been detected toward HD 183143, while a very high value of N(C2)/E(B-V) is observed toward HD 204827. Therefore, either the abundances of the large molecules presumed to give rise to the DIBs, or the physical conditions in the absorbing clouds, or both, must differ significantly between the two cases., Comment: Additional data and figures available at http://dibdata.org. To appear as Astrophysical Journal, 705, 32-45 (Nov. 1, 2009)

The abundances of gas and dust (solids and complex molecules) in the interstellar medium (ISM) as well as their composition and structures impact practically all of astrophysics. Fundamental processes from star formation to stellar winds to galaxy formation all scale with the number of metals. However, significant uncertainties remain in both absolute and relative abundances, as well as how these vary with environment, e.g., stellar photospheres versus the interstellar medium (ISM). While UV, optical, IR, and radio studies have considerably advanced our understanding of ISM gas and dust, they cannot provide uniform results over the entire range of column densities needed. In contrast, X-rays will penetrate gas and dust in the cold (3K) to hot (100,000,000K) Universe over a wide range of column densities (log NH=20-24 cm^-2), imprinting spectral signatures that reflect the individual atoms which make up the gas, molecule or solid. *X-rays therefore are a powerful and viable resource for delving into a relatively unexplored regime for determining gas abundances and dust properties such as composition, charge state, structure, and quantity via absorption studies, and distribution via scattering halos.*, Comment: 8 pages, 6 figures. White paper submitted to the Astro2010 Decadal survey for Astronomy and Astrophysics

Echelle spectra of the double-lined spectroscopic binary HD 204827 were obtained on five nights, at a resolving power R = 38,000 and with a S/N ratio = 750 near 6000 A in the final, combined spectrum. The stars show E(B-V) = 1.11 and spectral types near O9.5V and B0.5III. A catalog is presented of 380 diffuse interstellar bands (DIBs) measured between 3900 and 8100 A in the stars' spectrum. The central wavelengths, the widths (FWHM), and the equivalent widths of nearly all of the bands are tabulated, along with the minimum uncertainties in the latter. The reliable removal of very weak stellar lines from the catalog, and of some stellar lines from the less severe blends with DIBs, is made generally easy by the highly variable radial velocities of both stars. The principal result of this investigation is that the great majority of the bands in the catalog are very weak and relatively narrow. Typical equivalent widths amount to a few mA, and the band widths (FWHM) are most often near 0.55 A. Therefore, most of these DIBs can be detected only in spectra obtained at a resolving power and a S/N ratio at least comparable to those used here. In addition, the anomalous interstellar reddening and the very high value of the ratio N(C2)/E(B-V) seen toward HD 204827 indicate that the physical conditions in one or more of the several interstellar clouds seen in this direction differ significantly from those found toward the prototypical DIB target HD 183143, for example. Probably primarily for these reasons, 113 of the 380 bands, or 30%, were not detected in four previous, modern surveys of the DIBs seen in the spectra of stars other than HD 204827. Both the tabulated data for the DIBs and a plot of our spectrum of HD 204827 are available online at http://dibdata.org, Comment: 85 pages (17 of text, 14 of tables, 54 of figures). To appear in the Astrophysical Journal

Are the organic molecules crucial for life on Earth abundant in early-epoch galaxies? To address this, we searched for organic molecules in extragalactic sources via their absorption features, known as diffuse interstellar bands (DIBs). There is strong evidence that DIBs are associated with polycyclic aromatic hydrocarbons (PAHs) and carbon chains. Galaxies with a preponderance of DIBs may be the most likely places in which to expect life. We use the method of quasar absorption lines to probe intervening early-epoch galaxies for the DIBs. We present the equivalent width measurements of DIBs in one neutral hydrogen (HI) abundant galaxy and limits for five DIB bands in six other HI-rich galaxies (damped Lyman-alpha systems--DLAs). Our results reveal that HI-rich galaxies are dust poor and have significantly lower reddening than known DIB-rich Milky Way environments. We find that DIBs in HI-rich galaxies do not show the same correlation with hydrogen abundance as observed in the Milky Way; the extragalactic DIBs are underabundant by as much as 10 times. The lower limit gas-to-dust ratios of four of the HI-rich early epoch galaxies are much higher than the gas-to-dust ratios found in the Milky Way. Our results suggest that the organic molecules responsible for the DIBs are underabundant in HI-rich early epoch galaxies relative to the Milky Way., Comment: 6 pages, 2 figures

The composite grain is made up of a host silicate spheroid and graphite inclusions. The extinction efficiencies of the composite spheroidal grains for three axial ratios are computed using the discrete dipole approximation (DDA). The interstellar extinction curve is evaluated in the spectral region 3.40--0.10$\mu m$ using the extinction efficiencies of the composite spheroidal grains. The model extinction curves are then compared with the average observed interstellar extinction curve. We also calculate the linear polarization for the spheroidal composite grains at three orientation angles and find the wavelength of maximum polarization. Further, we estimate the volume extinction factor, an important parameter from the point of view of cosmic abundance, for the composite grain models that reproduce the average observed interstellar extinction. The estimated abundances derived from the composite grain models for both carbon and silicon are found to be lower than that are predicted by the bare silicate/graphite grain models but these values are still higher than that are implied from the recent ISM values., Comment: 11 pages, 12 figures, 5 tables To appear in 2007 MNRAS

We present extinction curves that include data down to far ultraviolet wavelengths (FUV; 1050 - 1200 A) for nine Galactic sight lines. The FUV extinction was measured using data from the Far Ultraviolet Spectroscopic Explorer. The sight lines were chosen for their unusual extinction properties in the infrared through the ultraviolet; that they probe a wide range of dust environments is evidenced by the large spread in their measured ratios of total-to-selective extinction, R_V = 2.43 - 3.81. We find that extrapolation of the Fitzpatrick & Massa relationship from the ultraviolet appears to be a good predictor of the FUV extinction behavior. We find that predictions of the FUV extinction based upon the Cardelli, Clayton & Mathis (CCM) dependence on R_V give mixed results. For the seven extinction curves well represented by CCM in the infrared through ultraviolet, the FUV extinction is well predicted in three sight lines, over-predicted in two sight lines, and under-predicted in 2 sight lines. A Maximum Entropy Method analysis using a simple three component grain model shows that seven of the nine sight lines in the study require a larger fraction of grain materials to be in dust when FUV extinction is included in the models. Most of the added grain material is in the form of small (radii < 200 A) grains., Comment: Accepted for publication in the Astrophysical Journal. 31 pages with 7 figures

We have obtained new STIS/HST spectra to search for structure in the ultraviolet interstellar extinction curve, with particular emphasis on a search for absorption features produced by polycyclic aromatic hydrocarbons (PAHs). The presence of these molecules in the interstellar medium has been postulated to explain the infrared emission features seen in the 3-13 $\mu$m spectra of numerous sources. UV spectra are uniquely capable of identifying specific PAH molecules. We obtained high S/N UV spectra of stars which are significantly more reddened than those observed in previous studies. These data put limits on the role of small (30-50 carbon atoms) PAHs in UV extinction and call for further observations to probe the role of larger PAHs. PAHs are of importance because of their ubiquity and high abundance inferred from the infrared data and also because they may link the molecular and dust phases of the interstellar medium. A presence or absence of ultraviolet absorption bands due to PAHs could be a definitive test of this hypothesis. We should be able to detect a 20 \AA wide feature down to a 3$\sigma$ limit of $\sim$0.02 A$_V$. No such absorption features are seen other than the well-known 2175 \AA bump., Comment: 16 pages, 3 figure, ApJ in press

We present a study of the abundances and physical conditions in the interstellar gas toward the heavily reddened star HD 192639 [E_(B-V) = 0.64], based on analysis of FUSE and HST/STIS spectra covering the range from 912 to 1361 A. This work constitutes a survey of the analyses that can be performed to study the interstellar gas when combining data from different instruments. Low-velocity (-18 to -8 km/s) components are seen primarily for various neutral and singly ionized species such as C I, O I, S I, Mg II, Cl I, Cl II, Mn II, Fe II and Cu II. Numerous lines of H2 are present in the FUSE spectra, with a kinetic temperature for the lowest rotational levels T_(01) = (90 +/- 10) K. Analysis of the C I fine-structure excitation implies an average local density of hydrogen n_H = (16 +/- 3) cm^-3. The average electron density, derived from five neutral/first ion pairs under the assumption of photoionization equilibrium, is n_e = (0.11 +/- 0.02) cm^-3. The relatively complex component structure seen in high-resolution spectra of K I and Na I, the relatively low average density, and the measured depletions all suggest that the line of sight contains a number of diffuse clouds, rather than a single dense, translucent cloud. Comparisons of the fractions of Cl in Cl I and of hydrogen in molecular form suggest a higher molecular fraction, in the region(s) where H2 is present, than that derived considering the average line of sight. In general, such comparisons may allow the identification and characterization of translucent portions of such complex lines of sight. The combined data also show high-velocity components near -80 km/s for various species which appear to be predominantly ionized, and may be due to a radiative shock. A brief overview of the conditions in this gas will be given., Comment: 37 pages, accepted for publication in ApJ

Space Telescope Imaging Spectrograph (STIS) and archival International Ultraviolet Explorer (IUE) data were used to search for structure in the ultraviolet interstellar extinction curve. Between 1250 and 3200 A, in addition to the well-known 2175 A bump, there is only one fairly small (10%) absorption feature at 2700 A. The feature is very broad (>400 A). It coincides extremely well in position and shape with laboratory measurements of presolar diamond grains found in meteorites. As this feature appears in both the new STIS and archival IUE data, it is unlikely to be an instrumental effect. This feature appears to be ubiquitous in the ISM as it is seen along sightlines toward various clouds with reddenings in the range of E(B-V) = 0.35 to 1.73 mag. The identification with diamonds remains tentative since it is based on a single, weak feature. If the feature is due to interstellar diamonds then they require an order of magnitude more absorption strength per gram/cm^2 than the presolar meteoritic diamonds measured in the lab., Comment: Paper withdrawn after reanalysis of data. Paper no longer available for download

As part of an extensive survey of diffuse interstellar bands (DIBs), we have obtained optical spectra of the moderately reddened B5V star HD 62542, which is known to have an unusual UV extinction curve of the type usually identified with dark clouds. The typically strongest of the commonly catalogued DIBs covered by the spectra -- those at 5780, 5797, 6270, 6284, and 6614 A -- are essentially absent in this line of sight, in marked contrast with other lines of sight of similar reddening. We compare the HD 62542 line of sight with others exhibiting a range of extinction properties and molecular abundances and interpret the weakness of the DIBs as an extreme case of deficient DIB formation in a dense cloud whose more diffuse outer layers have been stripped away. We comment on the challenges these observations pose for identifying the carriers of the diffuse bands., Comment: 20 pages, 4 figures; aastex; accepted by ApJ

The Lyman and Werner band systems of deuterated molecular hydrogen (HD) occur in the far UV range below 1200 A. The high sensitivity of the FUSE mission can give access, at moderate resolution, to hot stars shining through translucent clouds, in the hope of observing molecular cores in which deuterium is essentially in the form of HD. Thus, the measurement of the HD/H2 ratio may become a new powerful tool to evaluate the deuterium abundance, D/H, in the interstellar medium. We report here on the detection of HD toward the high extinction star HD 73882 [E(B-V)=0.72]. A preliminary analysis is presented., Comment: 4 pages + 4 .ps figures. This paper will appear in a special issue of Astrophysical Journal Letters devoted to the first scientific results from the FUSE mission

We present Far Ultraviolet Explorer (FUSE) spectra for three Magellanic Cloud O stars (Sk 80, Sk -67 05 and Sk -67 111) with repeated observations. The data demonstrate the capabilities of FUSE to perform time-resolved spectroscopy on extragalactic stars. The wavelength coverage of FUSE provides access to resonance lines due to less abundant species, such as sulfur, which are unsaturated in O supergiants. This allows us to examine wind variability at all velocities in resonance lines for stars with higher mass loss rates than can be studied at longer (lambda > 1150 A) wavelengths. The FUSE wavelength range also includes resonance lines from ions which bracket the expected dominant ionization stage of the wind. Our observations span 1-4 months with several densely sampled intervals of 10 hours or more. These observations reveal wind variability in all of the program stars and distinctive differences in the ionization structure and time scales of the variability. Sk -67 111 demonstrates significant wind variability on a time scale less than 10 hours and the coolest O star (Sk -67 05) exhibits the largest variations in O VI., Comment: 3 pages of text and 3 JPG figures. To be included in the FUSE ApJ Letters special issue

We report the results of initial FUSE observations of molecular hydrogen (H2) in translucent clouds. These clouds have greater optical depth than any of the diffuse clouds previously observed for far-UV H2 absorption, and provide new insights into the physics and chemistry of such regions. Our initial results involve observations of HD 73882, a well-studied southern hemisphere star lying behind substantial interstellar material (E(B-V) = 0.72; A_V = 2.44). We find a total H2 column density, N(H2) = 1.2 x 10^{21} cm^{-2}, about three times larger than the values for diffuse clouds previously measured in the far-UV. The gas kinetic temperature indicated by the ratio N(J=1)/N(J=0) is 58 +/- 10 K. With the aid of ground-based data to calculate an appropriate multi-component curve of growth, we have determined column densities for all rotational levels up to J = 7. The J >= 2 states can be reasonably fitted with a rotational excitation temperature of 307 +/- 23 K. Both the kinetic and rotational temperatures are similar to those found in previous investigations of diffuse clouds. The ratios of carbonaceous molecules to hydrogen molecules are also similar to ratios in diffuse clouds, suggesting a similar chemistry for this line of sight., Comment: 7 pages, 3 figures, to appear in ApJ Letters (FUSE first-results issue)

We compare the stellar wind features in far-UV spectra of Sk -67 111, an O7 Ib(f) star in the LMC, with Sk 80, an O7 Iaf+ star in the SMC. The most striking differences are that Sk 80 has a substantially lower terminal velocity, much weaker O VI absorption, and stronger S IV emission. We have used line-blanketed, hydrodynamic, non-LTE atmospheric models to explore the origin of these differences. The far-UV spectra require systematically lower stellar temperatures than previous determinations for O7 supergiants derived from plane-parallel, hydrostatic models of photospheric line profiles. At these temperatures, the O VI in Sk -67 111 must be due primarily to shocks in the wind., Comment: 10 pages, 2 figures. AASTeX preprint format. This paper will appear in a special issue of Astrophysical Journal Letters devoted to the first scientific results from the FUSE mission

We describe a moderate-resolution FUSE mini-survey of H2 in the Milky Way and Magellanic Clouds, using four hot stars and four AGN as background sources. FUSE spectra of nearly every stellar and extragalactic source exhibit numerous absorption lines from the H2 Lyman and Werner bands between 912 and 1120 A. One extragalactic sightline, PKS 2155-304, with low N(HI) shows no detectable H2 and could be the "Lockman Hole" of molecular gas, of importance for QSO absorption-line studies. We measure H2 column densities in low rotational states (J = 0 and 1) to derive rotational and/or kinetic temperatures of diffuse interstellar gas. The higher-J abundances can constrain models of the UV radiation fields and gas densities. In three optically thick clouds toward extragalactic sources, we find n(H) ~ 30-50 cm(-3) and cloud thicknesses of 2-3 pc. The rotational temperatures for H2 at high Galactic latitude, = 107 +/- 17 K (seven sightlines) and 120 +/- 13 K (three optically thick clouds), are higher than those in the Copernicus sample composed primarily of targets in the disk. We find no evidence for great differences in the abundance or state of excitation of H2 between sight lines in the Galaxy and those in the SMC and LMC. In the future, we will probe the distribution and physical parameters of diffuse molecular gas in the disk and halo and in the lower-metallicity environs of the LMC and SMC., Comment: To appear in ApJL (FUSE first-results issue), 4 pages + 2 figures (.ps)

The H II region W40 harbors a small group of young, hot stars behind roughly 9 magnitudes of visual extinction. We have detected gaseous carbon monoxide (CO) and diatomic carbon (C_2) in absorption toward the star W40 IRS 1a. The 2-0 R0, R1, and R2 lines of 12CO at 2.3 micron were measured using the CSHELL on the NASA IR Telescope Facility (with upper limits placed on R3, R4, and R5) yielding an N_CO of (1.1 +/- 0.2) x 10^18 cm^-2. Excitation analysis indicates T_kin > 7 K. The Phillips system of C_2 transitions near 8775 Ang. was measured using the Kitt Peak 4-m telescope and echelle spectrometer. Radiative pumping models indicate a total C_2 column density of (7.0 +/- 0.4) x 10^14 cm^-2, two excitation temperatures (39 and 126 K), and a total gas density of n ~ 250 cm^-3. The CO ice band at 4.7 micron was not detected, placing an upper limit on the CO depletion of delta < 1 %. We postulate that the sightline has multiple translucent components and is associated with the W40 molecular cloud. Our data for W40 IRS 1a, coupled with other sightlines, shows that the ratio of CO/C_2 increases from diffuse through translucent environs. Finally, we show that the hydrogen to dust ratio seems to remain constant from diffuse to dense environments, while the CO to dust ratio apparently does not., Comment: To appear in The Astrophysical Journal 17 pages total, 5 figures Also available at http://casa.colorado.edu/~shuping/research/w40/w40.html

Due to recent interest in molecular anions as possible interstellar species, we have carried out several laboratory studies of anion chemistry. The reactions of the series C(sub n)(sup -); and C(sub n)H(sup -) with H and H2 were studied to address the viability of such species in the diffuse interstellar medium and to address their ability to be carriers of the diffuse interstellar bands (DIBs). These same molecules were also reacted with N and O to show possible heteroatomic products. C(sub m)N(sup - was a particularly stable product from the reaction of C(sub n)(sup -) + N. C3N(sup -) was further reacted with H to study chemistry that could produce HC3N, a known interstellar species. The reactions were done in a flowing afterglow selected ion flow tube apparatus (FA-SIFT). The anions were generated in an electron impact or cold cathode discharge source and the anion of interest was then selected by a quadrupole mass filter. The selected ion was then reacted with the atomic or molecular species in the flow tube and products were detected by another quadrupole. While the C(sub n)(sup -) species do not appear to be viable DIB carriers, their possible presence could provide a mechanism for the formation of known heteroatomic neutral molecules detected in the interstellar medium (ISM).

Infrared spectral properties of silicate grains in interplanetary dust particles (IDPs) were compared with those of astronomical silicates. The approximately 10-micrometer silicon-oxygen stretch bands of IDPs containing enstatite (MgSiO3), forsterite (Mg2SiO4), and glass with embedded metal and sulfides (GEMS) exhibit fine structure and bandwidths similar to those of solar system comets and some pre-main sequence Herbig Ae/Be stars. Some GEMS exhibit a broad, featureless silicon-oxygen stretch band similar to those observed in interstellar molecular clouds and young stellar objects. These GEMS provide a spectral match to astronomical "amorphous" silicates, one of the fundamental building blocks from which the solar system is presumed to have formed.

The C10H8(+) cation and its dehydrogenated derivatives, C10H7(+) and C10H6(+), have been studied using a selected ion flow tube (SIFT). Reactions with molecules and atoms of interstellar interest show that C10H8(+) reacts with N md O to give neutral products HCN and CO, respectively. C10H6(+) and C10H6(+) are moderately reactive and reactions proceed through association with molecules. The implications of these results for the depletion of C10H(n)(+) in the interstellar medium are briefly discussed.

A profile fitting technique is employed to identify the velocities and Doppler b values for H I and H II clouds along the line of sight to Theta Car. Total abundances and depletions for 12 elements, plus column densities for the J = 0 to J = 5 rotational levels of H2 are obtained. Electron densities for both clouds are calculated from the ratios of the fine-structure levels of C II and N II, obtaining 0.08/cu cm and 1.2/cu cm. The fine-structure levels of C I, which led to 120/cu cm, are used to calculate the neutral hydrogen density for the H I region. D I is also present in the data from the Theta Car line of sight, yielding a D/H ratio of 5 x 10 exp -6. Elemental depletions are calculated for the H I region as well. Comparison of the results for Theta Car and those for Zeta Oph and Alpha Vir shows that the absolute depletions are different; however, the relative depletions are remarkably stable for different physical conditions.

From Copernicus observations of Sigma Sco, 57 individual lines of 11 elements plus the molecular species H2 and CO were identified. By using a profile-fitting technique, rather than curves of growth, it was possible to obtain column densities and Doppler b values for up to four separate components along this line of sight. Electron density in the major H I component was derived from the photoionization equilibrium of sulfur, obtaining, n(e) of about 0.3/cu cm. The neutral hydrogen density in the same component was also derived using fine-structure excitation of O I. An H II component is also present in which the electron density was n(e) about 20/cu cm. As a by-product of this analysis, previously undetermined oscillator strengths for two Mn II lines were obtained: for 1162.-017 A, f about 0.023 and for 1164.211 A, f about 0.0086.

The results of a UV survey of stellar winds and circumstellar shells in 40 B6-B9.5e stars covering luminosity classes V-III are presented. A graph is presented of the region from 1520-1560 A, which includes both the Si II UV multiplet 2 transitions and the C IV resonance transition for selected Be stars in the sample. The detection of shortward-shifted discrete component absorption features in nine of the program stars suggests that the material is produced in a stellar wind, which attains velocities of at least a few hundred km/s.

The paper presents the results of an ultraviolet survey of stellar winds in 62 Be and 43 normal B stars covering spectral types B0.5-B5 and luminosity classes V-III. Excess wind absorption in Be stars over that detected in normal B stars is found in C IV and Si IV, confirming results of previous surveys. The stars showing excess wind absorption also show one or more shortward-shifted discrete absorption components, suggesting that much of the excess wind absorption is in the form of discrete absorption components. Evidence is presented that the high-velocity and highly ionized stellar wind observed in some Be stars is a function of latitude.

Since the launch of Copernicus in 1972, studies have been made of the depletion of gas-phase elements onto dust grains. A few stars have been studied in detail, resulting in a standard depletion pattern which has since been used for comparison. Recent developments, however, have suggested that this standard pattern may need to be re-examined. Some weak, semi-forbidden lines were detected recently which may be able to resolve some of the ambiguities. Studies of single elements have shown that depletion of carbon and oxgyen are much smaller than previously determined. The high resolution ultraviolet spectral scans of sigma Sco were originally made in 1973, but have only recently been analyzed. All these stars are bright and moderately reddened. All four stars will be analyzed in detail, but sigma Sco is the first one completed. The data has broad coverage of ions, making these stars excellent candidates for determination of accurate depletions. A profile-fitting analysis was used rather than curves-of-growth in order to determine separate abundances and depletions in components separated by several km/sec.

Using International Ultraviolet (IUS) archival low-dispersion spectra, ultraviolet spectral extinctions were derived for the circumstellar envelopes of two M supergiants: HD 60414 and HD 213310. The observed stellar systems belong to a class of widely-separated spectroscopic binaries that are called VV Cephei stars. The total extinction was calculated by dividing the reddened fluxes with unreddened comparison fluxes of similar stars (g B2.5 for HD 213310 and a normalized s+B3 for HD 60414) from the reference atlas. After substracting the interstellar extinctions, which were estimated from the E(B-V) reddening of nearby stars, the resultant circumstellar extinctions were normalized at about 3.5 inverse microns. Not only is the 2175 A extinction bump absent in the circumstellar extinctions, but the far-ultraviolet extinction rise is also absent. The rather flat, ultraviolet extinction curves were interpreted as signatures of a population of noncarbonaceous, oxygen-rich grains with diameters larger than the longest observed wavelength.

New observations of lines from neutral atoms in the lines of sight to three stars in the Rho Oph cloud are combined with literature data to look for evidence of density-enhanced regions with higher elemental depletions than those characterizing the cloud as a whole. The depletions inferred from neutral species, however, are comparable to those measured directly from observations of ions, suggesting that no strong density enhancements exist in the observed lines of sight. This conclusion is supported by electron densities derived from the observed ionization fractions, which also show no evidence for a strong variation of density with depth in the cloud. It appears that the overall density (and overall level of depletion) in the cloud is higher than in typical diffuse clouds, despite the apparent lack of strong condensations with enhanced relative depletions.

There are few aspects of interstellar grains that can be unambiguously defined. Very little can be said that is independent of models or presuppositions; hence issues are raised and questions categorized, rather than providing definitive answers. The questions are issues fall into three general areas; the general physical and chemical nature of the grains; the processes by which they are formed and destroyed; and future observational approaches.

A tentative synthesis of visual and IUE observations of 59 Cyg during 1978-1983 when the new Be phase began to develop is presented. The study reveals correlation between those spectral features originating in the cool H-alpha-emitting envelope and features originating in superionized regions exhibiting C IV and N V lines. The long-term variability patterns of the V/R ratio, the H-alpha emission, and the C IV absorption reveal striking similarities and a close correlation. The early development of the new Be phase is accompanied by remarkably large and striking C IV line-profile changes. It is also suggested that short-term V/R variations at H-alpha may be associated with short-term C IV changes.

Calcium depletions toward five moderately reddened (E/B - V/ greater than 0.35 and less than 0.45) stars and toward HD 147889, a heavily reddened (E/B - V/ = 1.08) member of the Rho Ophiuchi cloud complex is reported. A developmental Multi-Anode Microchannel Array Detector was used to collect the data; its performance is characterized. Comparing the results for calcium from one line of sight to another and to those for other species, it is found that calcium exhibits a depletion pattern remarkably similar to that of silicon. The depletion of iron, on the other hand, has smaller variations and therefore does not correlate as well. Also, the depletion results for manganese and sulfur, both normally undepleted in diffuse clouds, have been included for comparison.

The International Ultraviolet Explorer (IUE) Satellite was used to collect interstellar extinction curves for 58 moderately reddened lines of sight. Spectral types of the background stars ranged from O7 to A0. All luminosity classes are represented, but early B main-sequence stars predominate. E(B-V) reddening values ranged from 0.14 to 1.13 mag, with an average of 0.63 mag. These extinction curves, less some 10 curves judged of lower quality, were co-added in order to reduce the random and fixed-pattern noise of the instrument. The resulting averaged curve was examined for evidence of small-scale structure, with negative results. The 2-sigma limits were found to be 0.09 mag for wavelengths between 1150 A and 2000 A, and 0.16 mag for wavelengths between 2000 A and 2300 A. Because of mismatch errors in weak stellar lines, it is unlikely that much improvement in these results is possible. The implications of these negative results are discussed with particular reference to the MgO theory of interstellar grains and diffuse bands.

An IUE satellite search is reported for chromospheric emission in the UV spectra of the brightest pre-main sequence stars the open cluster NGC 2264. Einstein X-ray observations to search for variability of the bright O7 V ((f)) star S Mon = W131, which may be the most massive member of the cluster, are also reported. Fifteen cluster members of spectral type B-K, ranging in age from a million to ten million yr, were observed in the ultraviolet. The only star exhibiting chromospheric emission is W79, a faint, heavily veiled T Tauri star that lies below the main sequence of NGC 2264. The observations are consistent with the generally accepted idea that chromospheric activity of late-type stars subsides with age.

The effect of a low-velocity shock on depletion in interstellar clouds is studied. High-resolution Copernicus observations of interstellar absorption lines toward four stars in the Rho Ophiuchi cloud complex were used to measure differential depletion in interstellar clouds separated by velocities of 10-15 km/s. Optical observations of CH and CH(+) were used as indicators of shock strength and direction of propagation. Observations indicate the presence of a shock with velocity about 10 km/s expanding away from the sun into the Rho Oph cloud. The existence of this shock is supported by the other observations quoted in the literature. Two distinct regions in the lines of sight have been found. A low-density, less depleted, predominantly atomic region is associated with preshock gas, while postshock gas accounts for a predominantly molecular, more highly depleted region. Apparently a weak shock, has the effect of enhancing grain formation or grain growth as a result of increased density in the postshock gas. It is possible for grain growth by accretion to occur in the shocked gas on time scales short compared with the cloud-crossing time of the shock.

Archival IUE data on the deeply embedded Rho Oph cloud star HD 147889 have been used to derive column densities for several species. The poor data quality and limited useful spectral coverage made unambiguous abundances very difficult to deduce, but firm limits could be set. Absolute depletions have been estimated, based on an assumed value of the total hydrogen column density, but they are uncertain due to uncertainty in N(H). The data appear to indicate that depletions are generally very large in this line of sight. There is also some indication that the relative depletions are enhanced in the densest portions of the cloud.

Data on neutral atomic species are analyzed for the purpose of inferring relative elemental abundances and depletions in diffuse cloud cores, where it is assumed that densities are enhanced in comparison with mean densities over integrated lines of sight. Column densities of neutral atoms are compared to yield relative column densities of singly ionized species, which are assumed dominant in cloud cores. This paper incorporates a survey of literature data on neutral atomic abundances with the result that no systematic enhancement in the depletions of calcium or iron in cloud cores is found, except for zeta Ophiuchi. This may imply that depletions are not influenced by density, but other data argue against this interpretation. It is concluded either that in general all elements are depleted together in dense regions so that their relative abundances remain constant, or that typical diffuse clouds do not have significant cores, but instead are reasonably homogeneous. The data show a probable correlation between cloud-core depletion and hydrogen-molecular fraction, supporting the assumption that overall depletions are a function of density.

The results of a monitoring program with IUE and Einstein are presented for three stars, delta-Ori A, l-Ori A, and 15 Mon. Line profile variability is observed in the UV profiles accessible to IUE and the relation between the variation in the different ions suggests that the ionization level is varying in the winds of these stars. This is consistent with Einstein observations of soft X-ray variability for two of the stars.

Correlations between UV extinction parameters and diffuse band strengths are south, using a data base of 50 stars with recently measured extinction curves. A novel aspect of this study is that the basic dependence of most interstellar parameters on E(B-V) (or, nearly equivalently, on the total hydrogen column density) has been largely canceled out. After this cancellation, a weak correlation is found between the 4430 A diffuse band and the 2175 A extinction feature. No other correlations are found. These results support a molecular origin for the 5780 A and 6284 A bands. It is speculated that the correlation pattern found for the 4430 A band can be explained if this band originates in reactions on disordered grain surfaces.

Results are reported from the combined CfA Stellar Survey of selected bright A stars and an Einstein Guest Observer program for Ap and Am stars. In an initial report of results from the CfA Stellar Surveys by Vaiana et al. (1981) it was noted that the spread in observed X-ray luminosities among the few A stars observed was quite large. The reasons for this large spread was studied by Pallavicini et al. (1981). It was found that the X-ray emission from normal stars is related very strongly to bolometric luminosity for early-type stars and to rotation rate for late-type stars. However, an exception to this rule has been the apparently anomalous behavior of A star X-ray emission, for which the large spread in luminosity showed no apparent correlation with either bolometric luminosity or stellar rotation rate. In the present study, it is shown that the level of emission from normal A stars agrees with the correlation observed for O and B stars.

Nightly variations in He II 4686 A have been observed in four Of stars, HD 152408, HD 151804, 9 Sge, and Lambda Cep. Three of the stars were not previously known to show such variations. In one case, Lambda Cep, simultaneous observations with IUE showed variations in ultraviolet (UV) resonance-line profiles during the same time period as those in He II 4686 A. This implies that the perturbations causing the He II 4686 A variability affect the entire wind acceleration zone.

It has been found for the Rho Ophiuchi cloud, and suggested for diffuse cloud cores in general, that H2 has a lower formation rate than normally expected in diffuse clouds. It is proposed that this may be due to a reduction in grain surface area per unit volume, if the grains in these regions are enlarged due to coagulation. For the Rho Oph cloud, there is independent evidence that grain coagulation has occurred, so this hypothesis regarding H2 formation has a more substantial basis than for other clouds, where the evidence for suppressed H2 formation is less certain, and for which there is little information on grain sizes.

Observational technology is now reaching the point where optical absorption-line studies of dark interstellar clouds are becoming feasible. Such studies are of great interest. In particular, it will be important to discover the degree of depletion which has occurred in dark clouds. In order to assess depletions on the basis of observations of a limited range of ionization stages, it is necessary to analyze the ionization balance. The present investigation is concerned with such an analysis. The two key parameters necessary for deducing the ionization balance are the electron density and the radiation field intensity. A summary is provided regarding the existing data on the cloud density using data from the literature, and the radiation field intensity is derived from the observed H2 rotational excitation. The implications of both the density and radiation field data for the ionization balance of several species are discussed. It is found that for all species treated the first ion is dominant in the line of sight toward HD 147889.

A telescope-spectrometer on the Copernicus spacecraft made possible the measurement of many ultraviolet absorption lines produced by the interstellar gas. The present survey provides data on ultraviolet absorption lines in the spectra of 88 early-type stars. The stars observed are divided into four classes, including reddened stars, unreddened bright stars, moderately reddened bright stars, and unreddened and moderately reddened faint stars. Data are presented for equivalent width, W, radial velocity V, and rms line width, D, taking into account some 10 to 20 lines of N I, O I, Si II, P II, S II, Cl I, Cl II, Mn II, Fe II, Ni II, Cu II, and H2. The data are based on multiple scans for each line. Attention is given to details of observations, the data reduction procedure, and the computation of equivalent width, mean velocity, and velocity dispersion.

Neutral nitrogen and oxygen column densities or limits are derived for 53 path lengths through the diffuse interstellar medium and compared with column densities of neutral hydrogen. For neither N nor O is a systematic increase of depletion found as reddening increases. The value found for forbidden O/N is 8, and the abundances of N and O are both between 40% and 70% of the solar values. Implications of these results for models of interstellar grains are briefly discussed.

Data on the interstellar Ca II H and K lines toward HD 147889, a star deeply embedded in the rho Ophiuchi dark cloud, were obtained at the Mauna Kea Observatory of the University of Hawaii, using a multi-anode microchannel array (MAMA) detector. An upper limit on the Ca II column density of 1.7 x 10 to the 11th/sq cm was derived, which, together with ionization considerations and an estimated lower limit on the total hydrogen column density, implies that the calcium-to-hydrogen ratio in this line of sight is 0.00000795 or less, relative to the solar value. The logarithmic depletion is up to -5.10, the largest yet measured, and implies that gas-grain interaction in this region has proceeded to a much greater degree than is typical of diffuse clouds.

An intensive search for OH and H2O in the directions of sigma Sco, alpha Cam, and micron Per was undertaken with the Copernicus satellite. Multiple scans were carried out over the wavelength region for the expected absorption features due to the OH D-X and H2O C-X transitions. The feature due to OH was detected marginally towards sigma Sco, and only an upper limit can be given towards alpha Cam. H2O was not detected in any of the stars at the signal level accumulated. The OH abundance towards sigma Sco and the respective lower limits for the OH/H2O ratios are discussed with regard to the extant models for the steady state abundances of OH and H2O, and shown not to be inconsistent with ion-molecule schemes.

Twenty stars classified as either Ap or Am have been imaged by the Imaging Proportional Counter on the Einstein Observatory in a search for evidence of coronal emission. It is found that an Am star will not be a source (at the 10 to the 28th ergs/sec level) unless it is in a spectroscopic binary with a period below about 10 days. The X-rays in the close binaries can be explained by the RS CVn effect in the late-type secondary, and the evidence is against strong emission from Am stars. Among the nine Ap stars observed, four were detected. While it is possible that the X-rays are being generated by undetected late-type dwarf companions, the large fraction of detections makes the Ap stars themselves the likely source of emission.

(Previously announced in STAR as N82-30203)

The presence of narrow, shifted absorption features superposed on the wide P Cygni profiles of the UV resonance lines in the spectra of O and B stars is studied and possible explanations of the narrow components are discussed. Spectra from 26 stars of spectral types O4f to B1 Ib were examined for the presence of narrow components in the absorption part of the profiles, and positive evidence was detected in 17. The central velocities of the features are found to be similar for different ions of the same star, and typically equal to 0.75 times the terminal velocity of the stellar wind. The width of the narrow absorptions is about 18% of the terminal stellar wind velocity, with a column density generally not correlated with the effective temperature or mass loss rate. Possible explanations for the narrow components include peaks in the degree of ionization, a stationary stellar shell, a plateau in the stellar wind velocity law, a decelerating stellar wind, a variable mass loss rate or a two component stellar wind with low-velocity, low-density material found at a distance greater than 2 stellar radii, which explanation appears most likely.

Mass loss rates for a number of early-to-mid-B main-sequence stars are compared with extrapolations of recently derived empirical correlations between M and stellar parameters for luminous OB stars. The order of magnitude of the rates for the B stars is consistent with a simple dependence on luminosity over the range from Of to mid-B, and is not consistent with previously derived correlations involving a dependence on mass or radius, which implies that luminosity is the dominant factor in driving the mass loss throughout the range of spectral types from mid-B main-sequence to Of. The winds in Be stars may represent a straightforward extension of the OB wind phenomenon to lower luminosities, and there appears to be no significant difference between B and Be stars in terms of their wind characteristics.