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The simultaneous addition of various Carbon based additives (in the present case B4C + SiC) to Mg and B powders has been introduced as a new concept in view of enhancing the superconducting parameters Bc2, Birr and Jc values of in situ Fe/MgB2 wires. A series of Fe sheathed monofilamentary wires of 1.1 mm diameter with a MgB2 core of 600 microm diameter was prepared with various B4C:SiC ratios, the relation being 2.5:7.5, 5:5, 7.5:2.5 and 7.5:7.5 (values in wt. %). After reaction of 1 hour at 760 C, the wire containing 7.5 wt.% B4C and 2.5 wt.% SiC powders exhibited a Jc value of 1x104 A/cm2 at 11.3 T and 4.2 K. Although only 2.5 wt.% SiC were added, these values are considerably above those of ternary wires with B4C additions, where the same Jc value is obtained at 10T. The slope Jc vs. B for the B4C + SiC wires is steeper than for SiC additives, the Jc values at 4.2 K being superior at fields below 9 T. The lattice parameters a of the B4C + SiC added wires exhibit lower values than ternary wires with the same nominal C content, suggesting a higher C content in the MgB2 phase. The disorder in the MgB2 structure has been characterized as a partial substitution of B by Carbon. A reduction of the domain sizes in the c direction as well as in-plane to 250 Angstrom and 124 Angstrom has been determined from the FWHM and the breath values of the (110) and (002) peaks. With the simultaneous introduction of B4C + SiC, a strong improvement of Jc and Birr has been obtained with respect to B4C additions. A further enhancement of Jc is expected when using different combinations of additives with and without Carbon, aiming for a further raise of Jc in wires with multiple additives, as a result of the combination of different mechanisms., Comment: 21 pages, 6 figures

An improvement of the transport critical current density, Jc, of MgB2 wires was obtained after addition of 10 wt.% B4C powders, after reaction at 800 C: Jc values of 1.10^4 A/cm2 at 4.2 K and 9T were obtained for wires of 1.11 mm diameter in a Fe matrix. The starting mixture of Mg and B was doped with sub-micrometric B4C, the ratio being Mg : B : B4C = 1: 2 : 0.08, corresponding to 10 wt.% B4C. For T > 800 C, a decrease of Jc was found, due to the reaction with the Fe sheath. In order to investigate the origin of the improvement of the transport properties for heat treatments up to 800 C, X-ray diffraction measurements were performed. A decrease of the lattice constant a from 0.30854 nm to 0.30797 nm was found, thus suggesting an effect of the substitution of Carbon on the properties of the wires. A comparison with the literature data shows that the addition of B4C powders leads to the second highest improvement of Jc reported so far after SiC, thus constituting an alternative for future applications., Comment: 18 pages, 8 figures, 1 table

We report a study of the pinning properties of Fe/MgB2 tapes performed by means of ac magnetic susceptibility measurements. In particular, the third harmonic response has been measured as a function of the dc magnetic field up to 9 T, at different temperatures, for various frequencies and amplitudes of the ac field. The irreversibility line has been determined using the third harmonic onset criterion for samples made with different ball-milled MgB2 powders. The study of the harmonic response allows us to probe the nature of the vortex pinning and to analyse its influence on the enhancement of the irreversibility field in strongly ball-milled samples. We have also investigated the dynamical regimes governing the vortex motion in the tapes by comparing the experimental curves with numerical simulations of the non-linear diffusion equation for the magnetic field., Comment: 12 pages, 9 figures

Fe/MgB2 tapes have been prepared starting with pre-reacted binary MgB2 powders. As shown by resistive and inductive measurements, the reduction of particle size to a few microns by ball milling has little influence on Bc2, while the superconducting properties of the individual MgB2 grains are essentially unchanged. Reducing the particle size causes an enhancement of Birr from 14 to 16 T, while Jc has considerably increased at high fields, its slope Jc(B) being reduced. At 4.2K, values of 5.3*10^4 and 1.2*10^3 A/cm^2 were measured at 3.5 and 10 T, respectively, suggesting a dominant role of the conditions at the grain interfaces. A systematic variation of these conditions at the interfaces is undertaken in order to determine the limit of transport properties for Fe/MgB2 tapes. The addition of 5% Mg to MgB2 powder was found to affect neither Jc nor Bc2. For the tapes with the highest Jc values, very high exponential n factors were measured: n = 148, 89 and 17 at 3.5, 5 and 10T, respectively and measurements of critical current versus applied strain have been performed. The mechanism leading to high transport critical current densities of filamentary Fe/MgB2 tapes based on MgB2 particles is discussed., Comment: Presented at ICMC 2003, 25-28 May 2003

Mono- and multifilamentary MgB2/Fe tapes and wires with high transport critical current densities have been prepared using the powder-in-tube (PIT) process. The fabrication details are described. The effect of powder grain sizes and recrystallization temperature on jc has been investigated. At 25K and 1 T, jc values close to 105 A/cm2 were measured, while jc of 106 A/cm2 were extrapolated for 4.2K/0T in our monofilamentary tape. MgB2/Fe tapes exhibit high exponential n factors for the resistive transition: n ~ 80 and 40 were found at 5 T and 7 T, respectively. The highest transport jc values obtained so far in MgB2/Fe wires with 7 filaments were 1.1 * 105 A/cm2 at 4.2 K and in a field of 2 T, which is still lower than for monofilamentary tapes. Improved deformation and recovering processing is expected to lead to higher jc values., Comment: 4 pages, 8 figures; Submitted to ASC 2002