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Hypothesis: Generating multi-layer cargo using conventional methods is challenging. We hypothesize that incorporating a Y-junction compound droplet generator to encase a target core inside a second liquid can circumvent the kinetic energy dependence of the impact-driven liquid-liquid encapsulation technique, enabling minimally restrictive multi-layer encapsulation. Experiments: Stable wrapping is obtained by impinging a compound droplet (generated using Y-junction) on an interfacial layer of another shell-forming liquid floating on a host liquid bath, leading to double-layered encapsulation. The underlying dynamics of the liquid-liquid interfaces are captured using high-speed imaging. To demonstrate the versatility of the technique, we used various liquids as interfacial layers, including magnetoresponsive oil-based ferrofluids. Moreover, we extended the technique to triple-layered encapsulation by overlaying a second interfacial layer atop the first floating interfacial layer. Findings: The encapsulating layer(s) effectively protects the water-soluble inner core (ethylene glycol) inside the water bath. A non-dimensional experimental regime is established for successful encapsulation in terms of the impact kinetic energy, interfacial layer thickness, and the viscosity ratio of the interfacial layer and the outer core liquid. Using selective fluorescent tagging, we confirm the presence of individual shell layers wrapped around the core, which presents a promising pathway to visualize the internal morphology of final encapsulated droplets., Comment: Utsab Banerjee and Sirshendu Misra contributed equally to this work

We investigate the interfacial dynamics involved in the impact of a droplet on a liquid-liquid system, which involves the impingement of an immiscible core liquid drop from a vertical separation onto an interfacial shell liquid layer floating on a host liquid bath. The dynamics have been studied for a wide range of impact Weber numbers and two different interfacial shell liquids of varying volumes. The core drop, upon impact, dragged the interfacial liquid into the host liquid, forming an interfacial liquid column with an air cavity inside the host liquid bath. The dynamics is resolved into cavity expansion and rapid contraction, followed by thinning of the interfacial liquid. The interplay of viscous dissipation, interfacial pull, and core drop inertia influenced the necking dynamics. The viscous dissipation increases with the thickness of the interfacial layer, which depends on its volume and lateral spread over the water. The necking dynamics transitioned from inertia-dominated deep seal closure at higher spread, lower interfacial film volumes, and higher Weber numbers, into inertia-capillary dominated deep seal closure with an increase in film volumes, decrease in the spread of the interfacial fluid or decrease in Weber number, and finally transitioned into a no seal closure at high volumes, low spread, and low Weber numbers.

Sessile hydrogel drops on rigid surfaces exhibit wetting/contact morphology intermediate between liquid drops and glass spheres. Using density functional theory, we reveal the contact forces acting between a hydrogel and a rigid glass surface. We show that while transitioning from liquid-like to solid-like hydrogels, there exists a critical hydrogel elasticity which enables a switch from attractive to repulsive interaction with the underlying rigid glass surface. Our theoretical model is validated by experimental observations of sessile Polyacrylamide (PAAm) hydrogels of varying elasticity on glass surfaces. Further, the proposed model successfully approaches Young's law in the pure liquid limit and work of adhesion in the glassy limit. Lastly, we show a modified contact angle relation taking into account the hydrogel elasticity to explain the features of a distinct hydrogel foot.

Raindrops falling on window panes spread upon contact, whereas hail can cause dents or scratches on the same glass window upon contact. While the former phenomenon resembles classical wetting, the latter is dictated by contact and adhesion theories. The classical Young-Dupre law applies to the wetting of pure liquids on rigid solids, whereas conventional contact mechanics theories account for rigid-on-soft or soft-on-rigid contacts with small deformations in the elastic limit. However, the crossover between adhesion and wetting is yet to be fully resolved. The key lies in the study of soft-on-soft interactions with material properties intermediate between liquids and solids. In this work, we translate from adhesion to wetting by experimentally probing the static signature of hydrogels in contact with soft PDMS of varying elasticity of both the components. Consequently, we probe this transition across six orders of magnitude in terms of the characteristic elasto-adhesive parameter of the system. In doing so, we reveal previously unknown phenomenology and a theoretical model which smoothly bridges adhesion of glass spheres with total wetting of pure liquids on any given substrate. Lastly, we highlight how solid like hydrogels can be treated as potential candidates for cleaning impurities from conventionally sticky PDMS substrates.

In this paper, we obtain analytical results for shear stress distributions inside an elastic body placed in a low Reynolds number transport. The problem definition is inspired by a recent experimental study (Valiei et al., Lab Chip, 2012, 12, 5133-5137) that reports the flow-triggered deformation of bacterial biofilms, formed on cylindrical rigid microposts, into long filamentous structures known as streamers. In our analysis, we consider an elastic body of finite thickness (forming a rim) placed over a rigid cylinder, i.e., we mimic the biofilm structure in the experiment. We consider Oseen flow solution to describe the low Reynolds transport past this cylindrical elastic structure. The stress and strain distributions inside the elastic structure are found to be functions of position, Poisson ratio, initial thickness of the elastic rim and the ratio of the flow-driven shear stress to the shear modulus of the elastic body. More importantly, these analyses, which can be deemed as one of the first formal analyses to understand the fluid-structure-interaction issues associated with the biofilm streamer formation, help us interpret several qualitative aspects associated with the streamer formation reported in different experiments., Comment: 20 pages, 3 figures

In this fluid dynamics video we show capillary rise experiments with diethyl ether in short tubes. The height of each short tube is less than the maximum height the liquid can achieve, and therefore the liquid reaches the top of the tube while still rising. Over a narrow range of heights, the ether bulges out from the top of the tube and spreads onto the external wall., Comment: Includes 2 videos for the Gallery of Fluid Motion in the 2013 American Physical Society Division of Fluid Dynamics Annual Meeting

In this fluid dynamics video we show simulations of droplet breakup and collisions in simple shear flow. Due to the high resolution of the GPU-based simulations, we capture the transition from coalescence at low capillary numbers to sliding at higher values., Comment: Contains high and low resolution videos for the Gallery of Fluid Motion at the 2012 APS DFD Annual Meeting