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In Einstein's gravitational theory, the spacetime is Riemannian, that is, it has vanishing torsion and vanishing nonmetricity (covariant derivative of the metric). In the gauging of the general affine group ${A}(4,R)$ and of its subgroup ${GL}(4,R)$ in four dimensions, energy--momentum and hypermomentum currents of matter are canonically coupled to the one--form basis and to the connection of a metric--affine spacetime with nonvanishing torsion and nonmetricity, respectively. Fermionic matter can be described in this framework by half--integer representations of the $\overline{SL}(4,R)$ covering subgroup. --- We set up a (first--order) Lagrangian formalism and build up the corresponding Noether machinery. For an arbitrary gauge Lagrangian, the three gauge field equations come out in a suggestive Yang-Mills like form. The conservation--type differential identities for energy--momentum and hypermomentum and the corresponding complexes and superpotentials are derived. Limiting cases such as the Einstein--Cartan theory are discussed. In particular we show, how the ${A}(4,R)$ may ``break down'' to the Poincar\'e (inhomogeneous Lorentz) group. In this context, we present explicit models for a symmetry breakdown in the cases of the Weyl (or homothetic) group, the ${SL}(4,R)$, or the ${GL}(4,R)$., Comment: 197 pages

In quantum models of gravity, it is surmized that configurations with degenerate coframes could occur during topology change of the underlying spacetime structure. However, the coframe is not the true Yang--Mills type gauge field of the translations, since it lacks the inhomogeneous gradient term in the gauge transformations. By explicitly restoring this ``hidden" piece within the framework of the affine gauge approach to gravity, one can avoid the metric or coframe degeneracy which would otherwise interfere with the integrations within the path integral. This is an important advantage for quantization., Comment: 14 pages, Preprint Cologne-thp-1993-H2

In Minkowski spacetime it is well-known that the canonical energy-momentum current is involved in the construction of the globally conserved currents of energy-momentum and total angular momentum. For the construction of conserved currents corresponding to (approximate) scale and proper conformal symmetries, however, an improved energy-momentum current is needed. By extending the Minkowskian framework to a genuine metric-affine spacetime, we find that the affine Noether identities and the conformal Killing equations enforce this improvement in a rather natural way. So far, no gravitational dynamics is involved in our construction. The resulting dilation and proper conformal currents are conserved provided the trace of the energy-momentum current satisfies a (mild) scaling relation or even vanishes., Comment: 14pp

The inhibition of the oligomerization of HCN by montmorillonite clays is shown to be caused by oxidation of diaminomaleonitrile (DAMN) by ferric ion in the clay lattice, with ferrous ion and oxalic acid the reaction products. It is demonstrated that diiminosuccinonitrile is the initial reaction product and is rapidly hydrolized to oxalic acid and HCN. The same oxidative transformations are effected by ferric ion bound to Dowex 50, ferric ion in solution, and Ni(NH3)6(2+). The rate of reaction of DAMN indicates no catalytic role for the clay in the oxidation of DAMN, and little reaction of the latter was observed with montmorillonite in which the bulk of the iron was in the divalent state. The possible significance of these redox reactions to chemical evolution is discussed.