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We studied the relationship between the lattice constant and magnetism of L10-ordered FePt under high pressure by means of first-principles calculations and synchrotron x-ray measurements. Based on our calculations, we found that the c/a ratio shows an anomaly at ~ 20 GPa and that the Pt magnetic moment is sharply suppressed at ~ 60 GPa. As for the c/a, we experimentally verified the anomaly at ~ 20 GPa by powder x-ray diffraction. We also measured the x-ray magnetic circular dichroism at the Pt L edge up to ~ 20 GPa. Any significant change of the Pt magnetic moment was not observed, in agreement with the calculations. These results thus indicate the possibility that novel magnetic states can be created in L10-ordered FePt by lattice deformation under high pressure., Comment: 6 pages, 6 figures

Magnetic circular dichroism (MCD) in the x-ray absorption spectroscopy (XAS) at the L2,3 edges for almost entire series of rare-earth (RE) elements in RE2Fe14B, is studied experimentally and theoretically. By a quantitative comparison of the complicated MCD spectral shapes, we find that (i) the 4f-5d intra-atomic exchange interaction not only induces the spin and orbital polarization of the 5d states, which is vital for the MCD spectra of the electric dipole transition from the 2p core states to the empty 5d conduction band, but also it accompanies a contraction of the radial part of the 5d wave function depending on its spin and orbital state, which results in the enhancement of the 2p-5d dipole matrix element, (ii) there are cases where the spin polarization of the 5d states due to the hybridization with the spin polarized 3d states of surrounding irons plays important roles, and (iii) the electric quadrupole transition from the 2p core states to the magnetic vale! nce 4f states is appreciable at the pre-edge region of the dipole spectrum. Especially, our results evidence that it is important to include the enhancement effect of the dipole matrix element in the correct interpretation of the MCD spectra at the RE L2,3 edges., Comment: 9 pages, 5 figures, 1 table, REVTeX