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Graphene is a very attractive material for nanomechanical devices and membrane applications. Graphene blisters based on silicon oxide micro-cavities are a simple but relevant example of nanoactuators. A drawback of this experimental set up is that gas leakage through the graphene-SiO2 interface contributes significantly to the total leak rate. Here we study the diffusion of air from pressurized graphene drumheads on SiO2 micro-cavities and propose a straightforward method to improve the already strong adhesion between graphene and the underlying SiO2 substrate, resulting in reduced leak rates. This is carried out by applying controlled and localized ultrahigh pressure (> 10 GPa) with an Atomic Force Microscopy diamond tip. With this procedure, we are able to significantly approach the graphene layer to the SiO2 surface around the drumheads, thus enhancing the interaction between them allowing us to better seal the graphene-SiO2 interface, which is reflected in up to ~ 4 times lower leakage rates. Our work opens an easy way to improve the performance of graphene as a gas membrane on a technological relevant substrate such as SiO2., Comment: pages 19, 4 figures + supplementary information

Contrary to most materials, graphene exhibits a negative thermal expansion coefficient (TEC), i.e it contracts when heated. This contraction is due to the thermal excitation of low energy out-of-plane vibration modes. These flexural modes have been reported to govern the electronic transport and the mechanical response of suspended graphene. In this work, we systematically investigate the influence of defects in the TEC of suspended graphene membranes. Controlled introduction of low densities of mono-vacancies reduces the graphene TEC, up to one order of magnitude for a defect density of $5\times10^{12}$~cm$^{-2}$ . Our molecular dynamics simulations reproduce the observed trend and show that TEC reduction is due to the suppression of out-of-plane fluctuations caused by the strain fields created by mono-vacancies in their surrounding areas. These results highlight the key role of defects in the properties of "real-life" graphene, and pave the way for future proposals of electronic and mechanical defect engineering., Comment: 19

We study the properties of graphene wormholes in which a short nanotube acts as a bridge between two graphene sheets, where the honeycomb carbon lattice is curved from the presence of 12 heptagonal defects. By taking the nanotube bridge with very small length compared to the radius, we develop an effective theory of Dirac fermions to account for the low-energy electronic properties of the wormholes in the continuum limit, where the frustration induced by the heptagonal defects is mimicked by a line of fictitious gauge flux attached to each of them. We find in particular that, when the effective gauge flux from the topological defects becomes maximal, the zero-energy modes of the Dirac equation can be arranged into two triplets, that can be thought as the counterpart of the two triplets of zero modes that arise in the dual instance of the continuum limit of large spherical fullerenes. We further investigate the graphene wormhole spectra by performing a numerical diagonalization of tight-binding hamiltonians for very large lattices realizing the wormhole geometry. The correspondence between the number of localized electronic states observed in the numerical approach and the effective gauge flux predicted in the continuum limit shows that graphene wormholes can be consistently described by an effective theory of two Dirac fermion fields in the curved geometry of the wormhole, opening the possibility of using real samples of the carbon material as a playground to experiment with the interaction between the background curvature and the Dirac fields., Comment: 18 pages, 6 figures

We study the electronic structure of the junctions between a single graphene layer and carbon nanotubes, using a tight-binding model and the continuum theory based on Dirac fermion fields. The latter provides a unified description of different lattice structures with curvature, which is always localized at six heptagonal carbon rings around each junction. When these are evenly spaced, we find that it is possible to curve the planar lattice into armchair (6n,6n) as well as zig-zag (6n,0) nanotubes. We show that the junctions fall into two different classes, regarding the low-energy electronic behavior. One of them, constituted by the junctions made of the armchair nanotubes and the zig-zag (6n,0) geometries when n is a multiple of 3, is characterized by the presence of two quasi-bound states at the Fermi level, which are absent for the rest of the zig-zag nanotubes. These states, localized at the junction, are shown to arise from the effective gauge flux induced by the heptagonal carbon rings, which has a direct reflection in the local density of states around the junction. Furthermore, we also analyze the band structure of the arrays of junctions, finding out that they can also be classified into two different groups according to the low-energy behavior. In this regard, the arrays made of armchair and (6n,0) nanotubes with n equal to a multiple of 3 are characterized by the presence of a series of flat bands, whose number grows with the length of the nanotubes. We show that such flat bands have their origin in the formation of states confined to the nanotubes in the array. This is explained in the continuum theory from the possibility of forming standing waves in the mentioned nanotube geometries, as a superposition of modes with opposite momenta and the same quantum numbers under the C_6v symmetry of the junction., Comment: 13 pages, 8 figures

We observe variations on the surface potential of graphite samples that we attribute to the adsorption physisorption of tetracene isomers., Comment: The paper is now submitted to Carbon journal. A fully revised version of the manuscript will replace the previous one

Carbon nanotubes are a good realization of one-dimensional crystals where basic science and potential nanodevice applications merge. Defects are known to modify the electrical resistance of carbon nanotubes. They can be present in as-grown carbon nanotubes, but controlling externally their density opens a path towards the tuning of the nanotube electronic characteristics. In this work consecutive Ar+ irradiation doses are applied to single-walled nanotubes (SWNTs) producing a uniform density of defects. After each dose, the room temperature resistance versus SWNT-length [R(L)] along the nanotube is measured. Our data show an exponential dependence of R(L) indicating that the system is within the strong Anderson localization regime. Theoretical simulations demonstrate that mainly di-vacancies contribute to the resistance increase induced by irradiation and that just a 0.03% of di-vacancies produces an increase of three orders of magnitude in the resistance of a 400 nm SWNT length., Comment: 16 pages, 4 figures

The adsorption of C60 on Si(111) has been studied by means of first-principles density functional calculations. A 2x2 adatom surface reconstruction was used to simulate the terraces of the 7x7 reconstruction. The structure of several possible adsorption configurations was optimized using the ab initio atomic forces, finding good candidates for two different adsorption states observed experimentally. While the C60 molecule remains closely spherical, the silicon substrate appears quite soft, especially the adatoms, which move substantially to form extra C-Si bonds, at the expense of breaking Si-Si bonds. The structural relaxation has a much larger effect on the adsorption energies, which strongly depend on the adsorption configuration, than on the charge transfer., Comment: 4 pages with 3 postscript figures, to appear in Surf. Science. (proceedings of the European Conference on Surface Science ECOSS-19, Sept 2000)

The KPNO International Spectroscopic Survey (KISS) is a new objective-prism survey for extragalactic emission-line objects. It combines many of the features of previous slitless spectroscopic surveys with the advantages of modern CCD detectors, and is the first purely digital objective-prism survey for emission-line galaxies. Here we present the first list of emission-line galaxy candidates selected from our red spectral data, which cover the spectral range 6400 to 7200 Angstroms. In most cases, the detected emission line is H-alpha. The current survey list covers a one-degree-wide strip located at Dec (1950) = 29.5 degrees and spanning the RA range 12h 15m to 17h 0m. An area of 62.2 sq. degrees is covered. A total of 1128 candidate emission-line objects have been selected for inclusion in the survey list (18.1 per sq. degree). We tabulate accurate coordinates and photometry for each source, as well as estimates of the redshift and emission-line flux and equivalent width based on measurements of the digital objective-prism spectra. The properties of the KISS emission-line galaxies are examined using the available observational data., Comment: 18 pages, 9 figures, A.J. in press. Full resolution versions of Figures 1 & 2 are available at http://www.astro.wesleyan.edu/~slaz/research/kiss/kisspubs.html

The KPNO International Spectroscopic Survey (KISS) is a new objective-prism survey for extragalactic emission-line objects. It combines many of the features of previous slitless spectroscopic surveys that were carried out with Schmidt telescopes using photographic plates with the advantages of modern CCD detectors. It is the first purely digital objective-prism survey, and extends previous photographic surveys to substantially fainter flux limits. In this, the first paper in the series, we give an overview of the survey technique, describe our data processing procedures, and present examples of the types of objects found by KISS. Our first H-alpha-selected survey list detects objects at the rate of 18.1 per square degree, which is 181 times higher than the surface density of the Markarian survey.Since the sample is line-selected, there is an imposed redshift limit of z ~ 0.095 due to the filter employed for the objective-prism observations. We evaluate the quality of the observed parameters derived from the survey data, which include accurate astrometry, photometry, redshifts, and line fluxes. Finally, we describe some of the many applications the KISS database will have for addressing specific questions in extragalactic astronomy. Subsequent papers in this series will present our survey lists of emission-line galaxy candidates., Comment: 19 pages, 8 figures, A.J. in press

We comment on relations between the linear W_{2,4}^{linear} algebra and non-linear W(2,4)$ algebra appearing in a Sp(4) particle mechanics model by using Lax equations. The appearance of the non-local V_{2,2} algebra is also studied., Comment: 10 pages, latex

Classical {\W}$_3$ transformations are discussed as restricted diffeomorphism transformations (\W-Diff) in two-dimensional space. We formulate them by using Riemannian geometry as a basic ingredient. The extended {\W}$_3$ generators are given as particular combinations of Christoffel symbols. The defining equations of \W-Diff are shown to depend on these generators explicitly. We also consider the issues of finite transformations, global $SL(3)$ transformations and \W-Schwarzians., Comment: 10 pages, UB-ECM-PF 94/20, TOHO-FP-9448, QMW-PH-94-25

We introduce a particle mechanics model with Sp($2M$) gauge invariance. Different partial gauge-fixings by means of sl(2) embeddings on the gauge algebra lead to reduced models which are invariant under diffeomorphisms and classical non-linear \W-transformations as the residual gauge symmetries thus providing a set of models of gauge and matter fields coupled in a \W-invariant way. The equations of motion for the matter variables give Lax operators in a matrix form. We examine several examples in detail and discuss the issue of integration of infinitesimal \W-transformations., Comment: 34 pages, LaTeX, no figures. Several changes (including Title) and new material added. Version to appear in Ann. Phys

A relation between an $Sp(2M)$ gauge particle model and the zero-curvature condition in a two-dimensional gauge theory is presented. For the $Sp(4)$ case we construct finite \W-transformations., Comment: 14 pages, UTTG-04-93