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Multichannel quantum defect theory is applied in the treatment of the dissociative recombination and vibrational excitation processes for the BeD$^+$ ion in the twenty four vibrational levels of its ground electronic state ($\textrm{X}\,{^{1}\Sigma^{+}},v_{i}^{+}=0\ldots 23$). Three electronic symmetries of BeD$^{**}$ states (\ensuremath{^{2}\Pi}, \ensuremath{^{2}\Sigma^{+}}, and \ensuremath{^{2}\Delta}), are considered in the calculation of cross sections and the corresponding rate coefficients. The incident electron energy range is $10^{-5}$--2.7 eV and the electron temperature range is 100--5000~K. The vibrational dependence of these collisional processes is highlighted. The resulting data are useful in magnetic confinement fusion edge plasma modelling and spectroscopy, in devices with beryllium based main chamber materials, such as ITER and JET, and operating with the deuterium-tritium fuel mix. An extensive rate coefficients database is presented in graphical form and also by analytic fit functions whose parameters are tabulated in the supplementary material., Comment: 7 pages, 5 figures, 3 tables

The latest molecular data - potential energy curves and Rydberg$/$valence interactions - characterizing the super-excited electronic states of CO are reviewed, in order to provide inputs for the study of their fragmentation dynamics. Starting from this input, the main paths and mechanisms for CO$^+$ dissociative recombination are analyzed; its cross sections are computed using a method based on Multichannel Quantum Defect Theory. Convoluted cross sections, giving both isotropic and anisotropic Maxwellian rate-coefficients, are compared with merged-beam and storage-ring experimental results. The calculated cross sections underestimate the measured ones by a factor of $2$, but display a very similar resonant shape. These facts confirm the quality of our approach for the dynamics, and call for more accurate and more extensive molecular structure calculations., Comment: 12 pages, 8 figures 5 tables

The latest molecular data - potential energy curves and Rydberg-valence interactions - characterising the super-excited electronic states of BF are reviewed in order to provide the input for the study of their fragmentation dynamics. Starting from this input, the main paths and mechanisms of BF$^+$ dissociative recombination and vibrational excitation are analysed. Their cross sections are computed for the first time using a method based on the multichannel quantum defect theory (MQDT), and Maxwellian rate-coefficients are calculated and displayed in ready-to-be-used format for low temperature plasma kinetics simulations., Comment: 8 pages, 4 figures, 4 tables

Cross-sections for dissociative recombination and electron-impact vibrational excitation of the BF$^+_2$ molecular ion are computed using a theoretical approach that combines the normal modes approximation for the vibrational states of the target ion and use of the UK R-matrix code to evaluate electron-ion scattering matrices for fixed geometries of the ion. Thermally-averaged rate coefficients are obtained from the cross-sections for temperatures in the 10-3000 K range., Comment: 6 pages, 5 figures, 2 tables

The reactive collisions of the CH$^+$ molecular ion with electrons is studied in the framework of the multichannel quantum defect theory, taking into account the contribution of the core-excited Rydberg states. In addition to the $X^1\Sigma^+$ ground state of the ion, we also consider the contribution to the dynamics of the $a^3\Pi$ and $A^1\Pi$ excited states of CH$^+$. Our results - in the case of the dissociative recombination in good agreement with the storage ring measurements - rely on decisive improvements - complete account of the ionisation channels and accurate evaluation of the reaction matrix - of a previously used model., Comment: 8 pages, 8 figures

The present study focuses on the application of a picosecond (ps) TALIF technique in krypton (Kr) at variable pressure (0.1-10 mbar). The laser intensity (I, units W.cm$^{-2}$) is tuned between 1 and 480 MW.cm$^{-2}$, and the depletion of the density of the Kr 5p'[3/2]$_2$ fluorescing state through photoionization (PIN) and amplified stimulated emission (ASE) is investigated. This is done by combining TALIF experiments with a simple 0D numerical model. We demonstrate that for a gas pressure of 3 mbar and 15 < $\le$ 480 MW.cm$^{-2}$, a saturated fluorescence signal is obtained, which is largely attributed to PIN, ASE being negligible. Also, a broadening of the two-photon absorption line (i.e. 4p$^6$ $^1$S0$\to$5p'[3/2]$_2$) is recorded due to the production of charged species through PIN, inducing a Stark effect. For I$\le$15 MW.cm$^{-2}$, though, PIN is significantly limited, the absorption line is noticeably narrowed, and the quadratic dependence of the TALIF signal intensity versus the laser energy is obtained. Thus, in this case, the investigated Kr TALIF scheme, using the 5p'[3/2]$_2\to$5s[3/2]$_1$ fluorescence channel, can be used for calibration purposes in ps-TALIF experiments. These results are of interest for fundamental research since most ps-TALIF studies performed in Kr do not investigate in detail the role of PIN and ASE on the depletion of the Kr 5p'[3/2]$_2$ state density. Moreover, this work contributes to the development of ps-TALIF for determining absolute densities and quenching coefficients of H and N atoms in plasmas. This is useful in numerous plasma-based applications (e.g. thin film synthesis, biomedical treatments, plasma-assisted combustion, ...), for which the knowledge of the density/kinetics of reactive atoms is essential.

A simplified and straightforward methodology that may be used to measure N(4 S) density by TALIF technique in strongly emissive plasmas is presented. The method makes use of the absorption peak intensities instead of the fully integrated absorption line intensity. The use of this method, along with a physics-based fitting/filtering procedure enables strongly reducing the experimental uncertainty and performing measurement even in strongly emitting discharges. After validation, the method was employed to investigate the transients of a strongly emissive pulsed microwave discharge. We especially showed the existence of unexpected increase of N(4 S) density at the early stage of the transition from high-to lowpower phase. The use of a self-consistent quasi-homogenous plasma model taking into account a detailed state-to-state kinetics, enables to attribute this enhancement to surface deexcitation of N(2 D) and N(2 P).

We provide cross sections and Maxwell rate coefficients for reactive collisions of slow electrons with BeH$^+$ ions on all the eighteen vibrational levels ($X{^{1}\Sigma^{+}},v_{i}^{+}=0,1,2,\dots,17$) using a Multichannel Quantum Defect Theory (MQDT) - type approach. These data on dissociative recombination, vibrational excitation and vibrational de-excitation are relevant for magnetic confinement fusion edge plasma modelling and spectroscopy, in devices with beryllium based main chamber materials, such as the International Thermonuclear Experimental Reactor (ITER) and the Joint European Torus (JET). Our results are presented in graphical form and as fitted analytical functions, the parameters of which are organized in tables., Comment: Atomic Data and Nuclear Data Tables, in press