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Based on our first detailed $^{181}$Ta nuclear quadrupole resonance (NQR) studies from 2017 on the Weyl semimetal TaP, we now extended our NQR studies to another Ta-based monopnictide TaAs. In the present work, we have determined the temperature-dependent $^{181}$Ta-NQR spectra, the spin-lattice relaxation time $T_{1}$, and the spin-spin relaxation time $T_{2}$. We found the following characteristic features that showed great contrast to what was found in TaP: (1) The quadrupole coupling constant and asymmetry parameter of EFG, extracted from three NQR frequencies, have a strong temperature dependence above $\sim$80 K that cannot be explained by the density functional theory calculation incorporating the thermal expansion of the lattice. (2) The temperature dependence of the spin-lattice relaxation rate, $1/T_{1} T$, shows a $T^{4}$ power law behavior above $\sim$30 K. This is a great contrast with the $1/T_{1} T \propto T^{2}$ behavior found in TaP, which was ascribed to the magnetic excitations at the Weyl nodes with a temperature-dependent orbital hyperfine coupling. (3) Regarding the nuclear spin-spin interaction, we found the spin-echo signal decays with the pulse separation simply by a Lorentzian function in TaAs, but we have observed spin-echo modulations in TaP that is most likely due to the indirect nuclear spin-spin coupling via virtually excited Weyl fermions. From our experimental findings, we conclude that the present NQR results do not show dominant contributions from Weyl fermion excitations in TaAs., Comment: 8 pages, 10 figures

When the particle size of a metal is reduced, it is expected that an energy gap will open due to the quantum size effect. However, the energy gap in platinum (Pt) metal nanoparticles has not been observed directly by nuclear magnetic resonance (NMR). To investigate the particle size dependence of the electronic state of Pt nanoparticles, we performed 195Pt NMR experiments on thiol-capped Pt nanoparticles with three different average diameters of less than 3 nm. For the nanoparticles with a diameter of 2.8 nm, we observed usual metallic behavior with a smaller density of states than that of the bulk Pt. In contrast, the temperature dependence of 1/T1T in nanoparticles less than 2.5 nm in diameter is an activation-energy form above 150 K, which is semiconducting behavior with an energy gap of the order of 2000 K. The significant decrease in 1/T1T by more than two orders of magnitude in the smaller Pt nanoparticles compared to the bulk Pt is attributable to the disappearance of the density of states at the Fermi energy, which is consistent with the opening of an energy gap. These results indicate a metal-insulator transition below 2.5 nm in diameter is present in our thiol-capped Pt nanoparticle samples. The effect of the thiol capping on the electronic structure suggested by the experimental results is also discussed.