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We analyze JWST MIRI/MRS observations of the infrared PAH bands in the nuclear and circumnuclear regions of local AGN from the GATOS Survey. In this work, we examine the PAH properties in the circumnuclear regions of AGN and AGN-outflows, and compare them to those in star-forming regions and the innermost regions of AGN. This study employs 4.9-28.1 micron sub-arcsecond angular resolution data to investigate the properties of PAH in three nearby sources (DL~30-40 Mpc). Our findings align with previous JWST studies, showing that the central regions of AGN show a larger fraction of neutral PAH molecules (i.e. elevated 11.3/6.2 and 11.3/7.7 PAH ratios) compared to star-forming galaxies. We find that the AGN might affect not only the PAH population in the innermost region but also in the extended regions up to ~kpc scales. By comparing our observations to PAH diagnostic diagrams, we find that, in general, regions located in the projected direction of the AGN-outflow occupy similar positions on the PAH diagnostic diagrams as those of the innermost regions of AGN. Star-forming regions that are not affected by the AGN in these galaxies share the same part of the diagram as Star-forming galaxies. We examine the potential of the PAH-H2 diagram to disentangle AGN versus star-forming activity. Our results suggest that in Sy-like AGN, illumination and feedback from the AGN might affect the PAH population at nuclear and kpc scales, in particular, the ionization state of the PAH grains. However, PAH sizes are rather similar. The carriers of the ionized PAH bands (6.2 and 7.7 micron) are less resilience than those of neutral PAH bands (11.3 micron), which might be particularly important for strongly AGN-host coupled systems. Therefore, caution must be applied when using PAH bands as star-formation rate indicators in these systems even at kpc scales, with the ionized ones being more affected by the AGN., Comment: Accepted for publication in A&A. 21 pages, 13 Figures

We present an analysis of the combined NIRSpec and MIRI spectra of dusty galaxies between 1.5 - 28 $\mu$m restframe by implementing a differential extinction model, where the strength of extinction varies across the spectrum as different layers of the obscuring dust are probed. Our model is able to recover a 2D distribution of dust temperature and extinction which allows inference of the physical nature of the dust in these environments. We show that differential extinction is necessary to reproduce the spectra of 4 highly obscured Luminous Infrared Galaxies observed with NIRSpec IFU and MIRI MRS, where simple screen or uniformly mixed dust distributions fail to fit the data. We additionally compare the extinction of HII regions in these galaxies via hydrogen recombination lines, the extinction of molecular gas via the H$_2$ lines, Polycyclic Aromatic Hydrocarbons via the 12.7/11.3 PAH ratio and the stellar continuum. We find that the molecular gas is deeply buried with the HII regions in star-forming regions, with a similar extinction to the hottest dust components. However we find the cooler dust to be less obscured, at a similar extinction to the stellar continuum and PAHs. The nuclei show a complex dust distribution with VV114 NE, NGC 3256 S, IIZw96 SW showing a deeply buried continuum source relative to the molecular gas/HII regions. Additionally, NGC 3256 S, NGC 7469 and VV114 SW show an isolated hot dust component, indicative of AGN heating, where NGC 3256 S and NGC 7469 are previously known AGN., Comment: 19 pages, 13 figures. Accepted for publication in MNRAS

We analyze JWST NIRSpec$+$MIRI/MRS observations of the infrared (IR) gas-phase molecular bands of the most enshrouded source (D1) within the interacting system and luminous IR galaxy II Zw 096. We report the detection of rovibrational lines of H$_2$O $\nu_2$=1-0 ($\sim$5.3-7.2 $\mu$m) and $^{12}$CO $\nu$=1-0 ($\sim$4.45-4.95 $\mu$m) in D1. The CO band shows the R- and P-branches in emission and the spectrum of the H$_2$O band shows the P-branch in emission and the R-branch in absorption. The H$_2$O R-branch in absorption unveils an IR-bright embedded compact source in D1 and the CO broad component features a highly turbulent environment. From both bands, we also identified extended intense star-forming (SF) activity associated with circumnuclear photodissociation regions (PDRs), consistent with the strong emission of the ionised 7.7 $\mu$m polycyclic aromatic hydrocarbon band in this source. By including the 4.5-7.0 $\mu$m continuum information derived from the H$_2$O and CO analysis, we modelled the IR emission of D1 with a dusty torus and SF component. The torus is very compact (diameter of $\sim$3 pc at 5 $\mu$m) and characterised by warm dust ($\sim$ 370 K), giving an IR surface brightness of $\sim$3.6$\times$10$^{8}$ L$_{\rm sun}$/pc$^2$. This result suggests the presence of a dust-obscured active galactic nucleus (AGN) in D1, which has an exceptionally high covering factor that prevents the direct detection of AGN emission. Our results open a new way to investigate the physical conditions of inner dusty tori via modelling the observed IR molecular bands., Comment: Accepted for publication in A&A (official date of acceptance: 27/12/2023; submitted 27/11/2023). 11 pages, 10 figures

We use JWST/MIRI MRS spectroscopy of a sample of six local obscured type 1.9/2 active galactic nuclei (AGN) to compare their nuclear mid-IR absorption bands with the level of nuclear obscuration traced by X-rays. This study is the first to use sub-arcsecond angular resolution data of local obscured AGN to investigate the nuclear mid-IR absorption bands with a wide wavelength coverage (4.9-28.1 $\mu$m). All the nuclei show the 9.7 $\mu$m silicate band in absorption. We compare the strength of the 9.7 and 18 $\mu$m silicate features with torus model predictions. The observed silicate features are generally well explained by clumpy and smooth torus models. We report the detection of the 6 $\mu$m dirty water ice band (i.e., a mix of water and other molecules such as CO and CO$_2$) at sub-arcsecond scales ($\sim$0.26 arcsec at 6 $\mu$m; inner $\sim$50 pc) in a sample of local AGN with different levels of nuclear obscuration in the range log N$_{\rm H}^{\rm X-Ray}$(cm$^{-2}$)$\sim22-25$. We find a good correlation between the 6 $\mu$m water ice optical depths and N$_{\rm H}^{\rm X-Ray}$. This result indicates that the water ice absorption might be a reliable tracer of the nuclear intrinsic obscuration in AGN. The weak water ice absorption in less obscured AGN (log N$_H^{X-ray}$ (cm$^{-2}$)$\lesssim$23.0 cm$^{-2}$) might be related to the hotter dust temperature ($>$T$_{sub}^{H_2O}\sim$110 K) expected to be reached in the outer layers of the torus due to their more inhomogeneous medium. Our results suggest it might be necessary to include the molecular content, such as, H$_2$O, aliphatic hydrocarbons (CH-) and more complex PAH molecules in torus models to better constrain key parameters such as the torus covering factor (i.e. nuclear obscuration)., Comment: Accepted for publication in A&A. 13 pages, 12 Figures

Context. Compact Obscured Nuclei (CONs) are an extreme phase of galaxy evolution where rapid supermassive black hole growth and$/$or compact star-forming activity is completely obscured by gas and dust. Aims. We investigate the properties of CONs in the mid-infrared and explore techniques aimed at identifying these objects such as through the equivalent width (EW) ratios of their Polycyclic Aromatic Hydrocarbon (PAH) features. Methods. We model Spitzer spectra by decomposing the continua into nuclear and star-forming components from which we then measure the nuclear optical depth, $\tau_N$, of the $9.8 \mu$m silicate absorption feature. We also use Spitzer spectral maps to investigate how PAH EW ratios vary with aperture size for objects hosting CONs. Results. We find that the nuclear optical depth, $\tau_N$, strongly correlates with the HCN-vib emission line in the millimetre for CONs with a Pearson correlation coefficient of 0.91. We find the PAH EW ratios technique to be effective at selecting CONs and robust against highly inclined galaxies where strong dust lanes may mimic a CON like spectrum by producing a high $\tau_N$. Our analysis of the Spitzer spectral maps showed that the efficacy of the PAH EW ratios to isolate CONs is reduced when there is a strong star-forming component from the host galaxy. In addition, we find that the use of the inferred nuclear optical depth is a reliable method to identify CONs in $36^{+8}_{-7}\%$ of ULIRGs and $17^{+3}_{-3}\%$ of LIRGs, consistent with previous work. Conclusions. We confirm mid-IR spectra to be a powerful diagnostic of CONs where the increased sensitivity of JWST will allow identification of CONs at cosmic noon revealing this extreme but hidden phase of galaxy evolution., Comment: Accepted for publication in A&A. 23 pages, 15 figures, 3 tables

Compact Obscured Nuclei (CONs) potentially hide extreme supermassive black hole (SMBH) growth behind large column densities of gas/dust. We present a spectroscopic analysis of the heavily obscured nucleus and the surrounding environment of the eastern region of the nearby ($z = 0.02007$) interacting galaxy VV 114 with the JWST Mid-InfraRed Instrument (MIRI). We model the spectrum from 4.9 - 28 $\mu$m to extract Polycyclic Aromatic Hydrocarbon (PAH) emission and the underlying obscured continuum. We find that the NE nucleus (A) is highly obscured where the low PAH equivalent width (EW) ratio, EW(12.7)/EW(11.3), reveals a dust enshrouded continuum source. This is confirmed by decomposing the continuum into nuclear and star-forming where the nuclear component is found to be typical of CONs. The 11.3/6.2 PAH flux ratio is consistent with originating in star-forming regions rather than typical AGN. The second nucleus (B) is much less obscured, with PAH flux ratios also typical of star-forming regions. We do not detect any high ionisation lines such as [Ne V] or [Ne VI] which suggests that if an AGN is present it must be highly obscured. Additionally, we detect a shock front south of the secondary nucleus (B) in the [Fe II] (5.34 $\mu$m) line and in warm molecular hydrogen. The 6.2 PAH emission does not spatially coincide with the low-J transitions of H$_2$ but rather appears strong at the shock front which may suggest destruction of the ionised PAHs in the post-shock gas behind the shock front., Comment: 15 pages, 15 figures. Accepted for publication in MNRAS

Polycyclic Aromatic Hydrocarbons (PAHs) are carbon-based molecules that are ubiquitous in a variety of astrophysical objects and environments. In this work, we use JWST/MIRI MRS spectroscopy of three Seyferts to compare their nuclear PAH emission with that of star-forming regions. This study represents the first of its kind using sub-arcsecond angular resolution data of local luminous Seyferts (Lbol>10^44.46 erg/s) on a wide wavelength coverage (4.9-28.1 micron). We present an analysis of their nuclear PAH properties by comparing the observed ratios with PAH diagnostic model grids, derived from theoretical spectra. Our results show that a suite of PAH features is present in the innermost parts (~0.45 arcsec at 12 micron; in the inner ~142-245 pc) of luminous Seyfert galaxies. We find that the nuclear regions of AGN lie at different positions of the PAH diagnostic diagrams, whereas the SF regions are concentrated around the average values of SF galaxies. In particular, we find that the nuclear PAH emission mainly originates in neutral PAHs. In contrast, PAH emission originating in the SF regions favours ionised PAH grains. The observed PAH ratios in the nuclear region of AGN-dominated galaxy NGC 6552 indicate the presence of larger-sized PAH molecules compared with those of the SF regions. Therefore, our results provide evidence that the AGN have a significant impact on the ionization state (and probably the size) of the PAH grains on scales of ~142-245 pc., Comment: 12 pages, 10 figures. Small changes to match the accepted for publication version in A&A (official date of acceptance: 20/09/2022)