1. Low-density functionalized amorphous carbon nanofoam as binder-free Supercapacitor electrode
- Author
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Ghosh, Subrata, Righi, Massimiliano, Macrelli, Andrea, Goto, Francesco, Bussetti, Gianlorenzo, Russo, Valeria, Bassi, Andrea Li, and Casari, Carlo S.
- Subjects
Physics - Applied Physics ,Condensed Matter - Materials Science - Abstract
Nanoporous carbon materials containing small domains of sp2-carbon with highly disordered structures are promising for supercapacitor applications. Herein, we synthesize amorphous carbon nanofoam with 98% volumetric void fraction and low mass density of around 30 mg/cm3 by pulsed laser deposition at room temperature. With the unavoidable oxygen functional groups on the nanoporous surface, pristine and nitrogen-functionalized carbon nanofoams are directly grown on the desired substrate under background gas of Ar, N2 and N2-H2employed as supercapacitor electrodes. Among the background gases used in synthesis, the use of nitrogen yields nanofoam with higher thickness and more N-content with higher graphitic-N, which is correlated with plasma plume behaviour. From the test of amorphous carbon nanofoam supercapacitor device, nitrogenated amorphous carbon show a higher areal capacitance of 4.1 mF/cm2 at 20 mV/s in aqueous electrolyte, a better capacitance retention at higher current, and excellent cycle stability (98%) over prolonged 10000 charge-discharge cycles are achieved for compared to pristine counterpart prepared under Ar background gas (2.7 mF/cm2 and cycle stability of 88%)., Comment: 14 pages main article, 2 pages supporting material, 5 figures, 3 supporting figures, 1 table
- Published
- 2024