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Fe 2 O 3 wrapped by few layered graphene nanosheets composites (Fe 2 O 3 -FLG) have been synthesized via a facile and massive one-step P-milling method, which is effective in reducing the particle size of Fe 2 O 3 and exfoliating the graphite into FLG. The composite shows good electrochemical performance due to the tight wrapping of FLG nanosheets, which is beneficial to electric conductivity and integrity of the electrode. The sample treated under 20 h retains a reversible capacity of 758 mAh g −1 at 200 mA g −1 after 300 cycles, which equals to 88% of its theoretic capacity. With the superior electrochemical performance, Fe 2 O 3 -FLG composites prepared via the P-milling method could be promising as anode materials for high performance lithium-ion batteries. [ABSTRACT FROM AUTHOR]

In order to enhance the cycleability and electronic conductivity of Si-based anodes, we fabricated a hierarchical micro-nano structured silicon/graphene nanosheets (Si/GNs) hybrid by discharge plasma-assisted milling (P-milling) using Si nanoparticles and expanded graphite (EG) as starting materials. Owing to the synergistic effect of rapid plasma heating and ball mill grinding with Si nanoparticles as nanomiller, the graphene nanosheets was exfoliated efficiently from the loose structured EG, which tightly wrapped and connected the Si nanoparticles to form microsized composite agglomerates. This high powder tap density Si/GNs hybrid exhibited a high reversible capacity of 942 mAh g −1 (857 mAh cm −3 ) at the current density of 0.2 Ag −1 , with 88% capacity retention after 100 cycles. The charge capacity remained super stable more than 350 times when the electrode was cycled with a fixed lithiation capacity of 1000 mAh g −1 at a current density of 0.2 Ag −1 between 0.01 and 1.5 V (vs. Li/Li + ). This superior cycle performance was attributed to the microsized GNs matrix which facilitated the electronic conductivity and the Li + diffusion in the hybrid, and effectively accommodated the volume change of Si nanoparticles during Li + alloying and dealloying processes. [ABSTRACT FROM AUTHOR]