1. Ultralight and rigid PBO nanofiber aerogel with superior electromagnetic wave absorption properties.
- Author
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Peng, Yanmeng, Gong, Kaijie, Liu, An, Yan, Han, Guo, Hua, Wang, Jin, Guo, Xiaoli, Yang, Xiaonan, Qi, Shuhua, and Qiu, Hua
- Subjects
FIREPROOFING ,MAGNETIC flux leakage ,AEROSPACE materials ,ELECTROMAGNETIC wave absorption ,ELECTROMAGNETIC waves ,MAGNETIC structure ,THERMAL insulation - Abstract
• The CNT/PNF electromagnetic wave absorption aerogel was prepared through sol-gel method and freeze-drying method. The RL min of CNT/PNF aerogel was −34.4 dB at 11.76 GHz, and the EAB was 3.44 GHz (8.88 GHz to 12.32 GHz). • The CoNi/CNT/PNF composite aerogel was obtained with the introduction of CoNi particles into CNT/PNF aerogel by in-situ growth and thermal annealing. Its RL min reached −44.7 dB at 6.88 GHz at the thickness of 4.0 mm, meanwhile, the EAB was 12.32 GHz (5.68 GHz to 18 GHz), covering the entire X-band, Ku-band and most of the C-band. • The 3D conductive/magnetic cage-like skeleton was constructed by PNFs and CNTs intertwining with each other and decorating with CoNi particles. The electromagnetic waves were dissipated in the cage-like skeleton through conduction loss and magnetic loss, in conjunction with multiple reflection, scattering, and absorption, favoring for the enhancement of wave absorption property. Polymer-based aerogels are emerging as promising candidates for lightweight and high performance electromagnetic (EM) wave absorption materials. In this study, an ultralight and rigid poly(p -phenylene benzobisoxazole) nanofiber (PNF) based composite aerogel with excellent EM wave absorption performance was fabricated with cobalt-nickel alloy (CoNi) nanoparticles and carbon nanotubes (CNTs) as magnetic and conductive fillers, respectively. A CNT/PNF composite aerogel was first prepared through a sol-gel and freeze-drying method, and then CoNi nanoparticles were introduced therein through hydrothermal reaction and thermal annealing to obtain the CoNi/CNT/PNF aerogel. CNTs and PNFs were interwoven and constructed a three-dimensional conductive/magnetic cage-like skeleton structure decorating with magnetic CoNi nanoparticles. The cage-like skeleton structure allowed the dissipation of EM waves through multiple mechanisms encompassing conduction loss, magnetic loss, multiple reflection, scattering, and absorption. When its thickness was 4 mm, the CoNi/CNT/PNF aerogel showed a minimal reflection loss of −44.7 dB (at 6.88 GHz), and its broad effective absorption bandwidth covered the entire X-band and Ku-band and most of the C-band (12.32 GHz, from 5.68 GHz to 18 GHz). In addition, the rigid aerogel exhibited an ultralow density (0.107 g/cm
3 ), excellent thermal insulation, and flame retardancy, demonstrating its potential application as a high-performance EM wave absorption material in the fields of aerospace and national defense. [Display omitted] [ABSTRACT FROM AUTHOR]- Published
- 2025
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