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Biochar produced from pellet obtained from grapevine (GV) and sunflower husk (SFH) at different temperature (400 and 500°C) were studied by pyrolysis batch reactor. Chemical and physical evolution of biomass under pyrolysis conditions was determined and products characterization was evaluated, including main organic components in gaseous stream. The Biochar is a “porous carbonaceous solid” produced by thermochemical conversion of organic materials in an oxygen depleted atmosphere, which has physiochemical properties suitable for the safe and long-term storage of carbon in the environment and, potentially, soil improvement. Results have shown a decrease in yield as an increase in temperature. The objective of this work is to improve the acknowledgment for the alternative use of the biochar gained from agro-forestry biomass residuals grapevine and sunflower husks by means of modern chemical and physical characterization tools.

Conjugation of proteins to copolymers from poly(acrylic acid) grafted onto PEO−PPO−PEO backbone (Pluronic-PAA) following adsorption of the conjugates onto hydrophobic surfaces is reported. Insulin-Pluronic-PAA conjugates show negligible internalization of insulin into human uterine smooth muscle cells as well as enhancement of mitogenic activity. Glucose-induced release of glycated albumin complexed with a Pluronic-PAA-concanavalin conjugate and adsorbed onto polystyrene nanospheres may provide a model for a glucose-responsive protein delivery system or a heterogeneous diagnostic device.