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Metallic lead nanowires were deposited within pores of commercial anodic alumina membranes having an average pore diameter of 210 nm. “Direct” electrodeposition was attempted from 0.1 M Pb(NO3)2aqueous solution with a variable concentration of H3BO3as a chelating agent, but it gave unsatisfactory results. An “indirect” two-step deposition procedure was then adopted, consisting of the anodic electrodeposition of α-PbO2nanowires, followed by their in situ reduction to metallic lead. Both these processes occurred at a high rate so that the indirect method led to a complete template pore filling with pure polycrystalline Pb in short times and with a high current efficiency.